1.

Explain smelting process .

Answer»

Solution :Smelting ( in a Blast Furnance ) :
(i) The charge consisting of roasted ore, cok and limestone in the ratio 8:1 .
(ii) Smelted in a blast furnanceby introducingit through the CUP and cone arrangement at the top.
Thereare three important regions in the furnance.

(a) The Lower Region (Combustion Zone ) :
(i) The temperatureis at `1500^(@)C`.
Coke burnswith oxygento form `CO_2` whenthe chargecomesin contact with a hot blastof air .
`C+O_2 underset(Delta)overset(1500^(@)C) to CO_2 +"Heat"`
It is an exothermic reaction since heat is liberated .
(b) The MiddleRegion ( Fusion Zone ) :
(iii) The temperatureprevailsat ` 1000^(@)C`.
(iv) `CO_2` is reduced to ` CO`
`CO_2+C underset(Delta)overset(1000^(@)C)to2CO+"Heat"`
Limestone decomposes to calcium oxide and `CO_2`.
`CaCO_3underset(Delta)toCO_2+"Heat"`
(V) These TWO reactions are endothermicdue to absorption of heat .
(vi) Calcium oxide combineswith silicato form calciumsilicate slag.
`CaO+SiO_2 to CaSiO_2`
(c) The Upper Region ( Reduction Zone ) :
(i) The temperatureprevailsat ` 400^(@)` C .
(ii) Carbonmonoxide reduces ferric oxide to form a fairly PURE spongy IRON.
`Fe_2O_3+3CO overset(400^(@)C) to 2Fe+3CO_2`
The molten iron is collectedat the bottom of the furnanceafter removingthe slag .
(iii) The iron thus formed is called pig iron.
(iv) It'sremelted and cast into different moulds. This iron is called cast iron.


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