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Some groups of three elements are given below: Which of these groups is not an example of Dobereiner's triad ? Explain it.

Answer»

SOLUTION :For group .A. : <BR> Average of ATOMIC masses of N and As
`=(14+74.9)/(2)=44.45u`
This average VALUE is not equal to the actual atomic mass of the middle ELEMENT phosphorus (P).
Therefore, these three elements do not form a Dobereiner.s triad.
For group .B. :
Average of atomic masses of Ca and Ba
`=(40.1+137.3)/(2)`
=88.7u
This average value is approximately equal to the atomic mass of the middle element strontium (Sr).
Therefore, these three elements form a Dobereiner.s triad.
For group .C. :
Average of atomic masses of Cl and I
`=(35.5+126.9)/(2)`
=81.2u
This average value is approximately equal to the mass of the middle element bromatomic ine (Br).
Therefore, these three elements form a Dobereiner.s triad.


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