1.

The freezing point (in `.^(@)C)` of a solution containing `0.1g` of `K_(3)[Fe(CN)_(6)]` (Mol. wt. `329`) in `100 g` of water `(K_(f) = 1.86 K kg mol^(-1))` is :A. `-2.3 xx 10^(-2)`B. `-5.7 xx 10^(-2)`C. `-5.7 xx 10^(-3)`D. `-1.2 xx 10^(-2)`

Answer» Correct Answer - A
`K_(3)[Fe(CN)_(6)]rarr3K^(+)+[Fe(CN)_(6)]^(3-)`
`i=4`
`DeltaT=ixxK_(f)xx(w_(B)xx1000)/(m_(B)xxw_(A))=4xx1.86xx(0.1xx1000)/(329xx100)`
`=2.3xx10^(-2)`
`:.` Freezing point of solution will be `-2.3 xx 10^(-2) .^(@)C`]


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