

InterviewSolution
Saved Bookmarks
1. |
The freezing point of solution containing `0.2 g` of acetic acid in `20.0 g` of benzene is lowered by `0.45^(@)C`. Calculate the degree of association of acetic acid in benzene. `(K_(f)=5.12 K^(@) mol^(-1) kg^(-1))` |
Answer» Correct Answer - 0.945 Acetic acid -B, Benzene-A For acetic acid,` "n=2"` `Delta"T"_("f")="i"xx("K"_("f")xx"W"_("B")xx1000)/("m"_("B")xx"W"_("A")("g"))" "0.45xx"i"xx(5.12xx0.2xx1000)/(60xx20)` `"i=0.527"` `1-(alpha)/(2)=1` `1-(alpha)/(2)=0.527` `alpha=0.945` `alpha=94.5%` |
|