1.

The normal boiling point of toluene is `110.7^(@)C` and its boiling point elevation constant `3.32 " K kg mol"^(-1)`. The enthalpy of vaporization of toluene is nearly :A. `"17 kJ mol"^(-1)`B. `"21 kJ mol"^(-1)`C. `"51 kJ mol"^(-1)`D. `"68 kJ mol"^(-1)`

Answer» Correct Answer - B
`K_(b)=(RT_(0)^(2))/(1000L),3.32=((8.314xx10^(-3))xx(383.7)^(2))/(1000xxL)`
`L=0.368kJ//g`
Latent heat per mol `= 0.368 xx` molar mass of acetone
`= 0.368xx58=21.344" kJ mol"^(-1)`].


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