1.

The temperature at which molarity of pure water is equal to its molality is `:`A. 273 KB. 298 KC. 277 KD. None of these

Answer» Correct Answer - C
Molality and mole fraction are related as follows:
`m = (x_(B) xx 1000)/((1 - x_(B)) m_(A))`
`1 = (x_(B) xx 1000)/((1 - x_(B)) xx 18)`
[ `m = 1 x_(B) =` mole fraction of solute `m_(A)=` molar mass of solvent]
`x_(B) = 0.0176, " " x_(A) = 0.9824`
`p = p_(0) x_(A)`
`p = 760 xx 0.9824`
`= 746.624`
`Delta p = P_(0) - p = 760 - 746.624`
`~~ 13.4` mm Hg


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