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The vapour pressure of pure benzene and pure toluene at a particular temperature are 100 mm and 50 mm repectively. The mole fration of benzene in the vapour phase in contact with equimolar solution os benzene and toluene is:A. 0.67B. 0.75C. 0.33D. 0.5 |
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Answer» Correct Answer - a For equimole solutions, `X_(B)=X_(f)=0.5` `P_(B)=X_(B)xxP_(B)^(@)=0.5xx100=500mm` `P_(T)=X_(T)xxP_(T)=0.5xx50-25 mm` `"Total vapour pressure "(P_("Total")=75mm` Mole fraction of benzene in the vapour phase= `P_(B)/_("Total")=50/75=2/3=0.67.` |
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