1.

Themolecular mass of a salt of oxyacid of chlorine of a divalent metal, which contains more number of oxygen atoms than its corresponding -ic' acid is 239. What will be themolecular masses of its (a) phosphate(b) iodide (c ) bisulphate be?

Answer»

Solution :The formula of perchlorate of a divalent METAL M is `M(ClO_(4))_(2)`.
Molecular mass of `M(ClO_(4))_(2) ` is 239.
Let X be the ATOMIC mass ofbivalent metal.
`:. X + 2[35.5 + 64] = 239 rArrx = 40`
`:.` The element is calcium.
(a) The formula of its phosphate is `Ca_(3)(PO_(4))_(2)`.
`:.` Its molecular mass is `(3 xx 40)+2[31+64] = 310`
(b) The formula of its iodide is `CaI_(2)`.
`:.` Its molecular mass is `40+(2 xx 127) = 294`
(c ) The formulaof bisulphate is `Ca(HSO_(4))_(2)`
`:.` Its molecular mass is ` 40 +2[1+32+64] = 234`


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