1.

Which postulate was disproved by Wohler ? Explain with example.

Answer»

Solution :Carbon atom possesses characteristic features of tetravalency and catenation, and due to this it FORMS a large number of compounds.
Among these, many compounds have the same non-carbon atom or group of atoms attached to DIFFERENT carbon chains.
These compounds were initially extracted from natural substances.
It was believed that organic compounds could only be formed within a living system, that is, it was POSTULATED that .vital force. was necessary for their synthesis.
German scientist, Friedrich Wohler disproved this in 1826.
EXAMPLE : He prepared organic compound urea by heating inorganic compound ammonium cyanate.
`underset("cyanate")underset("Ammonium")(overset(+)(N)H_(4)bar(O)NC)overset(Delta)toNH_(2)-underset("Urea")underset(O)underset(||)(C)-NH_(2)`


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