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`x g` of non-electrolytic compound (molar mass =200) is dissolved in `1.0 L` of `0.05 M NaCl` solution. The osmotic pressure of this solution is found to be `4.92 atm` at `27^(@)C`. Calculate the value of `x`. Assume complete dissociation of `NaCl` and ideal behaviour of this solution. |
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Answer» a. For `NaCl : pi =iCRT = 2xx0.05xx0.0821xx30` `= 2.463` , b.For unknown compound: `pi=CRT=pi/200xx0.0821xx300=0.1231x atm` Total osmotic pressure `pi=pi_(1)+pi_(2)` `4.92=2.463+0.1231x` `x = 19.959 g` |
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