This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Predict giving reason the outcome of the reaction LiI + KF to |
| Answer» Solution :`LiI + KF to LIF + KI` , larger CATION `(K^(+))` stabilizes larger anion `(I^(-))`. | |
| 2. |
Predict all the alkenes that would be formed by the dehydrohalogenation of the following halides with sodium ethoxide and identify the major alkene : (i) 2-Chloro-2-methylbutane (ii) 2, 2, 3-trimethyl-3-bromopentane (iii) Cyclohexylmethyl bromide (iv) 1-Bromo-1-methylcyclohexane |
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Answer» Solution :(i) 2-Methylbut-2-ene (MAJOR) + 2-methylbut-1-ene (II) 3,4,4-Trimethylpent-2-ene (major) + 2,3,3-trimethylpent-1-ene (III) 1-Methylcyclohexene (major) + methylene cyclohexane (IV) same as (iii) |
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| 3. |
Predict all the alkenes that would be formed by dehydrohalogenation of the following alkyl halides with sodium ethoxide in ethanol and identify the major alkene : (i)1-Bromo-1-methylcyclohexane,(ii)2-Chloro-2-methylbutane (iii)2,2,3-Trimethyl-3-bromopentane , (iv) |
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Answer» |
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| 4. |
Predict theposition of theelement in theperiodic tablesatisfyingthe electronic configuration(n-1) d^(1) ns^(2) " for " n=4 |
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Answer» Solution :Forn=4the ELECTRONIC CONFIGURATION = (4-1) `d^(1) 4s^(2) =3d^(1) 4s^(2)`. Theelementcorrespondingto this configurations is SCANDIUM whichis a d- blockelement. Group number = NOOF electrons in (n-1) d subshell + No. of electrons in thenthshell = 1+2=3 |
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| 5. |
Power alcohol is a mixture of petrol and alcohol in the ratio od |
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Answer» `4:1` |
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| 6. |
ppi-ppioverlapping of C-atom with other elements is not effective when ........... |
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Answer» the SIZE of ATOMIC ORBITAL is small. |
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| 7. |
Potassium superoxide (KO_(2)) is used as a source of oxygen in submarines , space shuttles and in oxygen musks . How does it work ? |
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Answer» SOLUTION :The moisture of the breath reacts with potassium superoxide `(KO_(2))` to LIBERATE `O_(2)` , and at the same time the KOH FORMED removes `CO_(2)` as it is EXHALED thereby allowing the atmosphere in the submarines , space shuttles and oxygen masks to be continuously REGENERATED . `4 KO_(2) (s) + 2 H_(2)O (s) to4KOH (aq) + 3 O_(2)(g)` `KOH (aq) + CO_(2) (g) to KHCO_(3)(s)` |
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| 8. |
Potassium superoxide finds use in breathing equipment and safeguards the use to breathe in oxygen generated internally in the apparatus without being exposed to toxic fumes outside. The supply of oxygen is due to(i) show decomposition of KO_(2)(ii) reaction of superoxide with moisture in the exhaled air (iii) reaction of KO_(2) with CO_(2) in the exhaled air. |
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Answer» (i), (ii) and (iii) are correct `4KO_(2)(s) + 2H_(2)O(g) rarr4KOH(aq) + 3O_(2)(g)` `2KO_(2)+2H_(2)Orarr2KOH+H_(2)O_(2)+O_(2)``KO_(2)` also continuously combines DIRECTLY with `CO_(2)` forming `K_(2)CO_(3)` and with `CO_(2)` and moisture together forming `KHCO_(3)` `4KO_(2)+2CO_(2)rarr2K_(2)CO_(3)+3O_(2)` `4KO_(2)+4CO_(2)+2H_(2)Orarr4KHCO_(3)+3O_(2)` |
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| 9. |
Potassium super oxide is preferred to sodium peroxide to purify air. Why? |
| Answer» Solution :Air usually CONTAINS CARBON monoxide and carbondioxide pollutants. Sodium peroxide converts carbondioxide to oxygen, but it has no reaction with carbonmonoxide. POTASSIUM superoxide REACTS with both carbonmonoxide and carbondioxide GIVING oxygen. Hence `KO_(2)` is preferred over `Na_(2)O_(2)`. | |
| 10. |
Potassium permanganate is titrated against ferrous ammonium sulphate in acidic medium, the equivalent mass of potassium permanganate is : |
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Answer» `("molecular mass")/(3)` `MnO_(4)^(-)+5Fe^(2+)+8H^(+) to MN^(2+)+4H_(2)O+5Fe^(3+)` Since, a molecular of `KMnO_(4)` accepts 5 electrons in ACID medium, its EQUIVALENT mass will be `(("molecular mass")/(5))`. |
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| 11. |
Potassium permanganate acts as an oxidising agent in acidic, alkaline as well as neutral media. Which among the following statements is incorrect ? |
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Answer» `N=M//5` (in ACID MEDIUM ) |
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| 12. |
Potassium permanganate oxidises oxalic acid in suphuric acid medium to give potassium sulphate, manganous sulphate, carbondioxide and water. |
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Answer» Solution :(a) The SKELETON equation is written as `KMnO_(4) +H_(2)C_(2)O_(4)+H_(2)SO_(4) to K_(2)SO_(4)+MnSO_(4)+CO_(2)+H_(2)O` (b) Focusing on the oxidation numbers `overset(+1)(K) overset(+7)(Mn) overset(-2)(O_(4))+overset(+1)(H_(2)) overset(+3)(C_(2)) overset(-2)(O_(4))+overset(+1)(H_(2)) overset(+6)(S) overset(-2)O_(4) to overset(+1)(K_(2)) overset(+6)(S) overset(-2)(O_(4)) + overset(+2)(Mn) overset(+6)(S) overset(-2)(O_(4))+overset(+4) (C) overset(-2)(O_(2)) +overset(+1)(H_(2)) overset(-2)(O)` (c) Location atoms undergoing change in oxidation numbers. `KM overset(+7)(n)O_(4)+H_(2) overset(+3)(C_(2))O_(4) to Mn overset(+2)(SO_(4))+C overset(+4)(CO_(2))` (d) DETERMINE the change in oxidation numbers (e) Cris- crossing these changes in oxidation numbers `2KMnO_(4)+5H_(2)C_(2)O_(4) to MnSO_(4)+CO_(2)` (f) Balancing the atoms other than hydrogen and oxygen `2KMnO_(4)+5H_(2)C_(2)O_(4)+3H_(2)SO_(4) to K_(2)SO_(4)+2MnSO_(4)+10CO_(2)+H_(2)O` (g) Balancing the atoms hydrogen and oxygen `2KMnO_(4)+5H_(2)C_(2)O_(4)+3H_(2)SO_(4) to K_(2)SO_(4)+2MnSO_(4)+10CO_(2)+8H_(2)O` This is the balanced EQUATIONS. |
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| 13. |
Potassium metal is heated strongly in O_(2). It produces |
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Answer» `K_(2)O` |
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| 14. |
Potassium metal is a better reducing agent that sodium but still potassium metal can be obtained by reduction of potassium chloride with sodium . How does it happen ? |
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Answer» Solution :Potassium can be OBTAINED by reduction of KCl and Na vapours at 1125 K in a large fractionating column . `KCl +Na overset(1125K)(to) NaCl + K` This reduction occurs because the lattice energy of NaCl is higher `(-770 kJ mol^(-1))`than that of KCl `(-703 kJ mol^(-1)`) . |
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| 15. |
Potassium metal is - and then sodium? |
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Answer» LIGHTER, SOFTER, more reactive |
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| 16. |
Potassium is used in photogalvanic cells. Why? |
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Answer» Solution :Potassium is highly electropositive. Ionisation potential and work FUNCTION of potassium are LESS. `KtoK^(+)+e^(-)` . The ionisation or separation of VALENCE electron of potassium is EASY. |
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| 17. |
Potassium gives a _________colour to the Bunsen flame |
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Answer» VIOLET |
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| 18. |
Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound, very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromit (FeCr_(2)O_(4))ore according to the following reactions: (a) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4)+Na_(2)CO_(3)+O_(2) to Na_(2)CrO_(4)+Fe_(2)O_(3)+CO_(2) (b) Acidifying filetered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4)+H_(2)SO_(4) to Na_(2)Cr_(2)O_(7)+Na_(2)SO_(4)+H_(2)O (c) Treating sodium dichromate with potassium chloride. Na_(2)Cr_(2)O_(7)+KCl to K_(2)Cr_(2)O_(7)+NaCl Answer the following questions using above information. If whole of the chromite ore given in the previous question gets consumed and sufficient amount of rest of the reactants are given, then the mass of K_(2)Cr_(2)O_(7) obtained is : |
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Answer» 14.7gm |
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| 19. |
Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound, very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromit (FeCr_(2)O_(4))ore according to the following reactions: (a) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4)+Na_(2)CO_(3)+O_(2) to Na_(2)CrO_(4)+Fe_(2)O_(3)+CO_(2) (b) Acidifying filetered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4)+H_(2)SO_(4) to Na_(2)Cr_(2)O_(7)+Na_(2)SO_(4)+H_(2)O (c) Treating sodium dichromate with potassium chloride. Na_(2)Cr_(2)O_(7)+KCl to K_(2)Cr_(2)O_(7)+NaCl Answer the following questions using above information. If you are intially provided with 224 gm of pure chromite ore and 169.6gm of sodium carbonate, the minimum volume of air required at 1 atm and 273 K to consume at least one of the reactant completely, if aire contains 20% by volume of oxygen gas is : |
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Answer» 156.8L |
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| 20. |
Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound, very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromit (FeCr_(2)O_(4))ore according to the following reactions: (a) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4)+Na_(2)CO_(3)+O_(2) to Na_(2)CrO_(4)+Fe_(2)O_(3)+CO_(2) (b) Acidifying filetered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4)+H_(2)SO_(4) to Na_(2)Cr_(2)O_(7)+Na_(2)SO_(4)+H_(2)O (c) Treating sodium dichromate with potassium chloride. Na_(2)Cr_(2)O_(7)+KCl to K_(2)Cr_(2)O_(7)+NaCl Answer the following questions using above information. If the number of moles of reactants available for reactions are: {FeCr_(2)O_(4)=0.25 moles, O_(2)=0.35 moles, Na_(2)CO_(3)=0.60 moles, H_(2)SO_(4)=0.2 mol,es, KCl=0.1 moles}, then the maximum number of moles of K_(2)Cr_(2)O_(7), that can be produced is : |
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Answer» 0.05 moles |
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| 21. |
Potassium crystallizes with a |
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Answer» face CENTRED CUBIC lattice |
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| 22. |
Potassium carbonate cannot be produced by Solvay process. Why? |
| Answer» Solution :SOLVAY process cannot be EXTENDED to MANUFACTURE of POTASSIUM carbonate because potassium hydrogen carbonate is too soluble to be PRECIPITATED by the addition of ammonium hydrogen carbonate to a saturated solution of potassium chloride. | |
| 23. |
Potassium carbonate cannot be prepared by Solvay process. Why ? |
| Answer» Solution :Potassium HYDROGEN carbonate (`KHCO_3`) is fairly soluble in water EVEN in the presence of EXCESS of carbon DIOXIDE and does not get PRECIPITATED. Hence, `K_2CO_3` cannot be prepared by Solvay process. | |
| 24. |
Potassium carbonate cannot be prepared by Solvay process. Why? |
| Answer» SOLUTION :In Solvay.s PROCESS,initally `KHCO_3`will be FORMED which is more SOLUBLE and cannot be PRECIPITATED. | |
| 25. |
Potassium carbonate cannot be prepared by Solvay process . Why ? |
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Answer» Solution :POTASSIUM carbonate cannot be prepared by Solvay PROCESS because potassium bicarbonate being more soluble than sodium bicarbonate does not get precipitated when `CO_(2)` is passed through a concentrated solution of KCl saturated with AMMONIA . `KCl + CO_(2) + NH_(3) + H_(2)O to KHCO_(3) + NH_(4)CL` |
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| 26. |
Potash alum is used as a |
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Answer» Disinfectant |
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| 27. |
Possible structures of A is/are |
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Answer»
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| 28. |
Possible oxidation states of boron family elements are |
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Answer» `+1` |
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| 29. |
Possible number of cyclic isomers for the compound having molecular formula C_(6)H_(4)Cl_(2) is ….. . |
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Answer» 6
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| 30. |
possible geometrical isomer are : |
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Answer» |
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| 31. |
Possible enols in the reaction are ? |
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Answer»
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| 32. |
Positronium consists of an electron and a positron (a particle which has the same mass as an electron , but opposite charge ) orbiting round their common centre of mass. Calculate the value of the Rydberg constant for this system |
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Answer» `R_oo //4` |
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| 33. |
Positive Tollens test Compound (A) is: |
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Answer» `CH_(3)-overset(O)overset(||)C-underset(OCH_(3))underset(|)(CH-)underset(OCH_(3))underset(|)(CH_(2)`
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| 34. |
Positive soil pollution is |
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Answer» Reduction is soil productivity due to addition of PESTICIDES fertllizers and inductrial wastes |
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| 35. |
Positive catalyst for the decomposition of H_2O_2 among the following |
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Answer» Alcohol |
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| 36. |
Positive and Negative electromeric effect |
| Answer» SOLUTION :(a) NEGATIVE (-E) ELECTROMERIC effect (B) Positive (+E) electromeric effect | |
| 37. |
Portland cement is manufactured by using |
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Answer» lime stone, CLAY and SAND |
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| 38. |
Portland cement does not contain: |
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Answer» `CaSiO_(4)` |
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| 39. |
Portland cement clinker has highest weight percentage of |
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Answer» DICALCIUM silicate |
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| 40. |
Polythene is |
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Answer» `(-H_(2)C=CH_(2)-)_(N)` |
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| 41. |
Polytetrafluoroethylene is commercially known as |
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Answer» Teflon |
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| 42. |
Polyphosphates llike sodium hexametaphosphate (calgon) are used as water softening agents because they |
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Answer» form soluble complexes with ANIONIC species `Na_(6)P_(6)O_(18)to 2NA^(+)+Na_(4)P_(6)O_(18)^(2-)` `M^(2+)+Na_(4)P_(6)O_(18)^(2-)to [Na_(2)MP_(6)O_(18)]^(2-)+2Na^(+)` |
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| 43. |
Polyphosphates are used as water softening agents because they..... |
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Answer» form soluble complex with ANIONIC species |
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| 44. |
Polynuclear aromatic compound of the following is |
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Answer» BENZENE |
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| 45. |
Polymers 'X' and 'Y' respectively are: |
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Answer» nylon-6, nylon-6,6 |
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| 46. |
Polymers are made up of small molecules called monomers. Polymer which are formed by one type of monomer is called homopolymer and which are formed by more than one type of monomers are called co-polymers. Natural polymers are biodegradable whereas synthetic polymers may or may not be. Addition or chain growth polymerization involves the repeated addition of monomers to the polymer chain. The monomers are unsaturated compounds and this type of polymerization takes place by ionic (cationic or anionic) as well as free radical mechanism. Condensation or step growth polymerization involves a series of condensation reactions between twomonomers. Each monomer normally contains two functional groups. Branch chain polymers may be condensation or addition but cross linked polymers are always condensation polymers. Which one of the following polymers is prepared by condensation polymerization? |
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Answer» DACRON |
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| 47. |
Polymers are made up of small molecules called monomers. Polymer which are formed by one type of monomer is called homopolymer and which are formed by more than one type of monomers are called co-polymers. Natural polymers are biodegradable whereas synthetic polymers may or may not be. Addition or chain growth polymerization involves the repeated addition of monomers to the polymer chain. The monomers are unsaturated compounds and this type of polymerization takes place by ionic (cationic or anionic) as well as free radical mechanism. Condensation or step growth polymerization involves a series of condensation reactions between twomonomers. Each monomer normally contains two functional groups. Branch chain polymers may be condensation or addition but cross linked polymers are always condensation polymers. Which one of the following monomer is most reactive for anionic polymerization? |
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Answer» `C_(6)H_(5)-CH=CH_(2)` |
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| 48. |
Polymers are made up of small molecules called monomers. Polymer which are formed by one type of monomer is called homopolymer and which are formed by more than one type of monomers are called co-polymers. Natural polymers are biodegradable whereas synthetic polymers may or may not be. Addition or chain growth polymerization involves the repeated addition of monomers to the polymer chain. The monomers are unsaturated compounds and this type of polymerization takes place by ionic (cationic or anionic) as well as free radical mechanism. Condensation or step growth polymerization involves a series of condensation reactions between twomonomers. Each monomer normally contains two functional groups. Branch chain polymers may be condensation or addition but cross linked polymers are always condensation polymers. Which one of the following is biodegradable polymer? |
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Answer» Nuylon6,6 |
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| 49. |
Polymers are made up of small molecules called monomers. Polymer which are formed by one type of monomer is called homopolymer and which are formed by more than one type of monomers are called co-polymers. Natural polymers are biodegradable whereas synthetic polymers may or may not be. Addition or chain growth polymerization involves the repeated addition of monomers to the polymer chain. The monomers are unsaturated compounds and this type of polymerization takes place by ionic (cationic or anionic) as well as free radical mechanism. Condensation or step growth polymerization involves a series of condensation reactions between twomonomers. Each monomer normally contains two functional groups. Branch chain polymers may be condensation or addition but cross linked polymers are always condensation polymers. Which of the following is a chain growth polymer? |
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Answer» Polystryrene |
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| 50. |
Polyethylene is a/an : |
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Answer» RANDOM co-polymer |
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