This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 3. |
What is the wavelength of the light emitted when the electron in a hydrogen atom undergoes transition from an energy level with n=4 to an energy level with n=2 ? What is the colour corresponding to this wavelength ? (Rydberg constant =109, 677 cm^(-1)) |
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Answer» Solution :`bar(v)=R(1/n_(1)^(2)-1/n_(2)^(2))=109677 (1/2^(2)-1/4^(2)) CM^(-1) =20564.4 cm^(-1)` `lambda =1/v=1/(20564.4 cm^(-1))=486xx10^(-7) cm=486xx10^(-9) m=486 nm` The colour CORRESPONDING to this wavelength is blue. |
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| 4. |
What will be the effect on concentration by decrease the volume of vessel containing CO_((g)) + 3H_(2(g)) hArr CH_(4(g)) + H_2O_((g)) ? |
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Answer» Solution :The concentration of reactants and pressure increases. As the VOLUME of vessel decrease TOTAL pressure increases. Now pressure is proportional to the concentration. So as the volume decrease concentration increases. Concentration`PROP` pressure `prop`MOLE so as the volume decrease concentration of REACTANT increases as reactants have 4 mole and product is has 2 mole. |
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| 5. |
Which elements of group-1 have highest hydration enthalpy? Why? |
| Answer» Solution :The hydration ENTHALPIES of alkali metal ions decrease with increase in ionic SIZES. `Li^(+)` has maximum degree of hydration and for this REASON lithium salts are mostly HYDRATED. | |
| 6. |
Write short notes on Metallic Hydrides. |
| Answer» Solution :Metallic (Interstitial) Hydride: Metalic hydrides usually obtained by hydrogenation of METALS and alloys inwhich hydrogen occupies the interstitial ites (voids). Hence, they are called interstitial hydrides. These hydrides SHOW properties similar to parent metals and hence they are also know as metallic hydries. Most of the hydries are non-stoichiometric with variable compositon `(TiH_(1.5-1.8)" and "PdH_(0.6-0.8)`, some are relatively LIGHT, inexpensive and THERMALLY unstable which MAKES them useful for hydrogen storage applications. | |
| 7. |
Which is not a property of water ? |
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Answer» It is a COLOURLESS and TASTELESS liquid. |
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| 8. |
Three moles of B_(2)H_(6) are completely reactedwith methanol. The numberof moles of boron containingproduct formed is |
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Answer» `3B_(2)H_(6) + 8 MEOH RARR UNDERSET("Trimethylborate")(6B(Ome)_(3))+ 18H_(2)` |
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| 9. |
Use molecular orbital theory to explain why Be, molecule does not exist. |
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Answer» Solution :The atomic no. (z) of Be is 4. This means that S ELECTRONS are to be FILLED in the M.O. of `Be_(2)` The configuration is : `sigma1s^(2)sigma**1s^(2)sigma2s^(2)sigma**2s^(2)`: `B.O.=1/2[N_(b)-N_(a)]=1/2[4-4]=0` As bond order of `Be_(2)` is zero the MOLECULE of `Be_(2)` does not exit. |
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| 10. |
When one mole of the given compound reats with sodium metal then how many moles of H_(2) gas will release |
| Answer» Answer :D | |
| 11. |
Write the reaction involved in formation of LiBH_4 |
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Answer» |
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| 12. |
What changes are observed in atoms undergoing ionic bonding? |
| Answer» Solution :The atom ATTAINS STABLE octet CONFIGURATION and FORMS electrostatic forces of attraction. | |
| 13. |
Which of the following is not a method of preparation of colloidal solution |
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Answer» Electrical dispersion |
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| 14. |
Which of the following is correct option for free expansion of an ideal gas under adiabatic condition ? |
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Answer» `q=0, Delta T NE 0, W=0` |
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| 15. |
Which is the decreasing order of strength of bases : OH^- , NH_2^(-), HC -=C^(-) and CH_3 CH_2^(-) ? |
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Answer» `CH_3CH_2^(-) GT NH_2^(-) gt HC-=C^(-) gt OH^(-)` |
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| 16. |
What is the maximum probability for an electron to be present within the atomic orbital ? |
| Answer» SOLUTION :`90 - 95%` | |
| 17. |
Which of the following will be the most hydrated salt ? (1) NaCl (2) MgCl_2 (3) AlCl_3 (4) SiCl_4 |
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Answer» |
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| 18. |
Which of the following carbides on treatment with water give methane? |
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Answer» `CaC_(2)` `Al_(4)C_(3)+12H_(2)Oto4Al(OH)_(3)+underset("Methane")(CH_(4))` `CaC_(2)+2H_(2)OtoCa(OH)_(2)+underset("Acetylene")(C_(2)H_(2))` `MgC_(3)+4H_(2)Oto2Mg(OH)_(2)+underset("PROPYNE")(HC-=C-CH_(3))` |
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| 19. |
What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down the group? |
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Answer» Solution :ATOMIC size: With the increase in atomic size, the NUMBER of electron SHELLS increase. Therefore, the force that binds the electrons with the nucleus decreases. The ionization enthalpy thus decreases with the increase in atomic size. Screening or shielding effect of inner shell electron: With the addition of new shells, the number of inner electron shells which SHIELD the VALENCE electrons increases. As a result, the force of attraction of the nucleus for the valence electrons further decreases and hence the ionization enthalpy decreases. |
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| 20. |
Which of the following hydrides conduct clectricity? |
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Answer» `SiH_4 ` |
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| 21. |
When 10 ml of hydrogen and 12.5 ml of chlorine are allowed to react the final mixture contains under the same conditions |
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Answer» 22.5 ML of HCl |
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| 22. |
Which of the following is not used for the purification of solid impurities? |
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Answer» DISTILLATION |
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| 23. |
Which of the following transistions in hydrogen atom will require the highest amount of energy |
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Answer» n=1 to n=2 |
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| 24. |
Write short notes on the following (i) Raschig process. (ii) Dows process. (iii) Darzens process. |
Answer» Solution :(i) Raschig process: Chloro benzene is commerically prepared by passing a MIXTURE of benzene vapour, air and HCL over heated cupric chloride is reaction is called Raschig process. (ii) Dows Process: `underset("Chlorobenzene")(C_(6)H_(5)Cl+NaOH) underset(300atm)overset(350^(@)C) to underset("Phenol")(C_(6)H_(5)OH)+NACL` This reaction is known as Dow's process. (iii) Darzens process: This reaction is known as Darzen's HALOGENATION. |
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| 25. |
Which is the unit of Dipole moment ? |
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Answer» SOLUTION :D bye in SHORT D. It is a 1 D = `3.33564 XX 10^(-30)` cm |
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| 26. |
What is the molecular formula of Borazole ? |
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Answer» `B_(2)H_(6)` |
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| 27. |
What is Kernel ? |
| Answer» SOLUTION :According to Lewis Kernel is positively charged part with the NUCLEUS PLUS the INNER ELECTRONS | |
| 28. |
What do you mean by syngas ? |
| Answer» | |
| 29. |
What is the molecular formula of aluminium chloride ? |
| Answer» SOLUTION :`Al_2 Cl_6` | |
| 30. |
Which of the following quantum numbers for orbitals in hydrogen atom has a greater energy for electrons ? (i) n=3, l=2 and m=+1(ii) n=3, l=2 and m=-1 |
| Answer» SOLUTION :Same ENERGY but DIFFERENT ORIENTATIONS | |
| 31. |
Which element accept one electron and get noble gas like configuration ? |
| Answer» Solution :HYDROGEN ELEMENT accept one ELECTRON and get NOBLE gas like CONFIGURATION. | |
| 32. |
Which of the following species have five unpaired electrons ? |
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Answer» `Cr^(3+)` |
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| 33. |
Which of the following is not the characteristics of an arene? |
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Answer» A. Resonance |
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| 34. |
Which elements of group-I and group-ll are differ from the other elements of same group? |
| Answer» SOLUTION : Lithium and beryllium, the first elements of Group-1 and Group-2 RESPECTIVELY exhibit some properties which are different from those of the other members of the RESPECTIVE group. Lithium shows similarities to MAGNESIUM and beryllium to ALUMINIUM in many of their properties. | |
| 35. |
Why alkali metals are soft and have low melting points? |
| Answer» Solution :ALKALI METALS have only one VALENCE electron per metal atom. As a result, the binding energy of alkali metal ions in the close-packed metal lattices are WEAK. Therefore, these are soft and have low melting point | |
| 36. |
Which among the following statement is false |
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Answer» The ADSORPTION may be monolayered or multilayered |
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| 37. |
What is the pH of normal rain water? What happens to the pH of rain water if it is accompanied by a thunderstorm and why? |
| Answer» Solution :pH of normal rain WATER is about 5.6 When rain is accompanied by a thunderstorm `N_2` and `O_2` of the air COMBINE to FORM NO which is further oxidized to `NO_2` and DISSOLVES in rain water to form `HNO_3`. Hence rain water becomes more acidic and hence pH falls below 5.6. | |
| 38. |
Which d-orbitals has its four lobes along the axes |
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Answer» `d_(XY)` |
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| 39. |
X and Y are respectively : |
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Answer»
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| 40. |
Which of the following statements is/are correct with respect to behaviour of real gas. |
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Answer» For every vander Waal gas at CRITICAL condition, attractive force will be dominant. |
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| 41. |
Write suitable chemical equations to show their nature. |
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Answer» SOLUTION :(i)`B_2O_3, SiO_2, CO_2` it reacts with bases to form salts . It reacts with NaOH. `B_2O_3+2NAOH to underset"SODIUM metaborate"(2NaBO_2)+H_2O` `SiO_2+2NaOH oversetDeltato underset"Sodium silicate"(Na_2SiO_3) + H_2O` `CO_2 + 2NaOH to underset"Sodium carbonate"(Na_2CO_3) + H_2O` (ii) Due to amphoteric nature of both `Al_2O_3` and `PbO_2` they can react with both acid and base. `Al_2O_3 + 2NaOH to underset"Sodium meta aluminate"(NaAlO_2+ H_2O)` `Al_2O_3 + 3H_2SO_4 to Al_2(SO_4)_3 + 3H_2O` `PbO_2 + 2NaOH to underset"Sodium plumbet"(Na_2PbO_3) + H_2O` `2PbO_2 + 2H_2SO_4 to 2PbSO_4 + 2H_2O + O_2` (III) `Tl_2O_3` it reacts with acids to form salts . It reacts with HCl to form thallium chloride. `Tl_2O_3 + 6HCl to 2TlCl_3 + 3H_2O` |
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| 42. |
Why alkane is used as fuel ? |
| Answer» Solution :High ENERGY is PRODUCED during combustion reaction of alkane compound and hence, alkane is used as FUEL. | |
| 43. |
What do you understand by rest mass of the electron ? What is its value on the unified scale ? How is the mass of the electron related to its velocity ? What will be the mass of the electron if it travels with velocity equal to the velocity of light ? |
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Answer» Solution :Rest mass of the electron is the mass of the electron when it is moving with a velocity much less than the velocity of light. Its value `= 9.1095 xx 10^(-31)kg or 0.0005486u`. When the electron is moving with velocity v, its mass is given by : `m = (m_("rest"))/(SQRT(1 - ((v)/(c))^(2)))` where c is the velocity of light. Thus, when electron is moving with the velocity of light so that v = c, its mass is infinite. |
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| 44. |
Which of the following contains both covalent and ionic bond? |
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Answer» `CCl_(4)` |
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| 45. |
What happens if ferric salt is added to the equilibrium of thr reaction between Fe^(3+) and SCN^(-) ions ? |
| Answer» SOLUTION :RED COLOUR DEEPENS. | |
| 46. |
Which of the following is (are) correct order(s) for basic strength ? |
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Answer» `NaOHgtNH_(4)OHgtH_(2)O` |
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| 47. |
The value of equilibrium constant of reaction HI_((g))hArr1/2H_(2(g))+1/2I_(2(g)) is 8.0. The equilibrium constant of the reaction , H_(2(g))+I_(2(g))hArr2HI_((g)) will be |
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Answer» `1/8` Then when the reactants & products CONCENTRATION are doubled, hence equilibrium constant is also doubled. |
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| 48. |
What is the molecular mass or molar volume at STP or NTP and SATP ? |
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Answer» Solution :At STP Molar VOLUME or ideal GAS = 24.413996 L But in calculation we can take 22.71098 L, 22.71 L Molar volume of ideal gas at SATP `= 24.787 L mol^(-1)`. |
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| 49. |
What is the volume strenth of H_(2)O_(2)? |
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Answer» SOLUTION :Volum strenth `=5.6xx"normality and"` VOLUME STRENGTH `=11.2xx"MOLARITY."` |
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| 50. |
What is the molecular formula of plaster of paris? |
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Answer» `2CaSO_(4).H_(2)O` |
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