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This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Give ozonized structure for following : (i) Propene (ii) Ethene (iii) 1-butene (iv) 2-butene (v) Benzene (vi) Buta-1,3-diene |
Answer» Solution :(i) Ozonized structure of propene `(CH_(3)CHC=CH_(2))` (ii) Ozonized structure of ethene `CH_(2) = CH_(2)` (iii) Ozonized structure of 1-butene `(CH_(2)=CHCH_(2)CH_(3))` (iv) Ozonized structure of 2-butene `(CH_(3)CH=CHCH_(3))` (v) Ozonized structure of BENZENE. It has THREE C=C and so its ozonized sructure is `C_(6)H_(6)(O_(3))_(2)` (vi) Ozonized structure of Buta-1,3-diene `(CH_(2)=CH-CH=CH_(2))` is dioznonized `C_(4)H_(6)(O_(3))_(2)`
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| 3. |
Give origin of group 13 elements |
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Answer» Solution :Boron is a typical non-metal Aluminium is a metal but shows MANY chemical similarities to boron.While gallium , indium ,thallium and nihonium are almost exclusivelymetallic in character. Boron is a fairly rare element , it mainly occurs as orthoboric acid `(H_3BO_3)`, borax `(Na_2B_4O_7. 10H_2O)` and kernite `(Na_2B_4O_7 . 4H_2O)`. In India borax occurs in Puga valley (Ladakh) andSambhar Lake (Rajasthan) .The abundance of boron in earth crust is less than0.0001% by mass. There are two ISOTOPIC forms of boron `.^10B` (19%) and `.^11B` (81%) Aluminium is the most abundant metal and the THIRD most abundant element in the earth.s crust (8.3% by mass) after oxygen (45,5%) and Si (27.7%) Bauxite `(Al_2O_3 . 2H_2O)` and cryolite `(Na_3AlF_6)` are the important minerals of aluminium.In India it is found as MICA in Madhya Pradesh, Karnataka , Orissa and Jammu. Gallium , indium and thallium are less abundant elements in nature . |
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| 4. |
Give order of repulsion of electron with central atom in covalent molecule. |
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Answer» Solution :`({:("REPULSION of "),("NON boding "),("electronpair"),("and non bonding"),(e^(-)"pair"):}) gt ({:("Repulsion of "),("non boding "),("pair"),("bonding "e^(-)),("pair"):}) lt ({:("Repulsion of "),("non bonding "),(e^(-) "pair" ),("bonding " e^(-) ),("pair "):})` i.e., `({:(LP - lp),("repulsion"):}) gt ({:(lp - bp),("repulsion"):}) gt ({:(bp - bp),("repulsion"):})` Here, lp = nonbonding `e^(-)` pair bp = bonding `e^(-)` pair |
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| 5. |
Give order of stability for different alkenes. |
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Answer» Solution :`R_(2)C=CR gt R_(2)C = CHR gt RCH = CHR ("trans") gt` `R_(2)C = CH_(2) gt RCH = CHR ("cis") gt RCH = CH_(2) gt CH_(2)=CH_(2)`. |
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| 6. |
Give order of energy of solid, liquid and gas. |
| Answer» Solution :ENERGY ORDER : Solid `LT` Liquid `lt` GAS | |
| 7. |
Give order of kinetic energy of solid, liquid, gas. |
| Answer» Solution :ORDER of kinetic ENERGY : SOLID `lt` LIQUID `lt` Gas | |
| 8. |
Giveorbitalpictureof followingelementsNa MgAl ,SiP , S , CI , Ar , K , Ca |
Answer» Solution : NOTE: where`NE^(10)`MEANS`1s^(2)2s^(2) 2p^(6) ` and`(Ar)^(18)` means`1s^(2)2s^(2) 2p^(6) 3S^(2) 3p^(6) ` |
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| 9. |
Give only reaction for detection of nitrogen in organic compound |
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Answer» SOLUTION :In fusion with Na: `N + Na + C rarr NaCN` `6CN^(-) Fe^(2+) rarr [Fe(CN)_(6)]^(4-)` `Fe^(2+) rarr Fe^(3+)` and then `4Fe^(3+) + 3[Fe(CN)_(6)]^(4-) overset(xH_(2)O)rarr Fe_(4) [Fe(CN)_(6)]_(3). x H_(2)O` |
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| 11. |
Give one method for industrial preparation and one forlaboratory preparationof CO and CO_(2) endcarbonmonoxide. |
| Answer» Solution :`{:("CARBON monoxide",, "Carbon dioxide"),("Industrial" : 2C(s) + O_(2)(g) overset("Limited")underset("air")rarr2CO(g),,,C(s)+O_(2)(g)overset("Excess")underset("air")rarrCO_(2)(g)),("Laboratory": underset("Formic acid")(HCOOH)overset(H_(2)SO_(4))rarrCO+H_(2)O,,,CaCO_(3)(s)+HCL(AQ) rarr CaCl_(2)(aq) + CO_(2)(g) + H_(2)O(L)) :}` | |
| 12. |
Give one method for industrial preparation and one for laboratory preparation of CO and CO_2 each. |
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Answer» Solution :Carbon monoxide (CO): CO is commercially prepared by passing steam over hot coke. The reaction involved is as follows: `2C_((s)) + O_2 underset"COMBUSTION"overset"Incomplete"to 2CO_((g))` In the laboratory, CO is prepared by the dehydration of formic ACID with conc. `H_2 SO_4` at 373 K. The reaction involved is as follows: `underset"Formic acid"(HCOOH) overset(H_2SO_4) toCO+ H_2O` Carbon dioxide `(CO_2)`: In the laboratory, `CO_2` can be prepared by the action of dilute hydrochloric acid on calcium carbonate. The reaction involved is as follows: `CaCO_3 + 2HCl to CaCl_2 + CO_2 + H_2O` `CO_2` is commercially prepared by heating limestone. The reaction involved is as follows : `C_((s)) + O_(2(g)) underset"combustion"overset"COMPLETE"to CO_(2(g))` |
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| 13. |
Give one important uses of following compounds. (i) NaHCO_(3) (ii) Slaked lime (iii) NaOH |
| Answer» Solution :(i) Sodium bicarbonate is USED as ANTACID. (ii) slaked lime is used for WHITE washing (iii) NAOH is used in manufacture of soap. | |
| 14. |
Give one Important pratical application of photoelectric effect |
| Answer» Solution :In automatic 'electric EYE' door openers, when a person come near to the door, the interuption LIGHT BEAM is CAUSED by the person. As a result, the door automatically OPENS | |
| 15. |
Give one important ore of each of sodium and potassium . |
| Answer» SOLUTION :NA : NACL and K : KCL . | |
| 16. |
Give one example with structure and name for each of the following compounds. (a) Primary haloalkane (b) Secondary haloalkane (c) Tertiary haloalkane |
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Answer» SOLUTION :(a) Primary HALOALKANE`UNDERSET("CHLOROETHANE")(CH_3-underset(H)underset(|)overset(H)overset(|)C- Cl)"("1^@" Haloalkane)"` (b) Secondary haloalkane`underset("2-chloropropane")(CH_3-underset(H)underset(|)overset(H)overset(|)C -CH_3)(2^@"Haloalkane")` (c ) Tertiary haloalkane `underset("2-Iodo-2-methylpropane")(CH_3-underset(I)underset(|)overset(CH_3)overset(|)C -CH_3)(3^@"Haloalkane")` |
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| 17. |
Give one example of everyday life in which there is gas solution equilibrium . |
| Answer» SOLUTION :SODA- WATER BOTTLE. | |
| 18. |
Give one example of each of the following reactions : (i) Wurtz Reaction(ii) Wurtz - Fitting reaction |
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Answer» Solution :(i) Wurtz Reaction : It involves conversion of alkyl halides into ALKANE . Example `CH_(3) Cl + 2 NA + CH_(3) Cl overset("DRY ETHER ") (to) 2 NaCl + C_(2) H_(6)` (ii) Wurtz - FITTING reaction : It involves the reaction of an aryl halide and alkyl halide to form the corresponding hydrocarbon.
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| 19. |
Give one example of each of the following: (i) Isotope of ._(17)^(35)Cl (ii) Isobar of ._(18)^(40)Ar (iii) Isotone of ._(6)^(14)C |
| Answer» SOLUTION :(i) `._(17)^(37)Cl` (ii) `._(19)^(40)K`(iii) `._(8)^(16)O` | |
| 20. |
Give one example of a reversible reaction taking place in aqueous solution. |
| Answer» Solution :`CH_(3)COOH (l) + C_(2) H_(5) OH (l) HARR CH_(3) COOC_(2)H_(5) (l) + H_(2)O (l)` | |
| 21. |
Give one example of a compound containing ionic, covalent and coordinate bond. |
| Answer» SOLUTION :`[H_(3)NtoH^(*)]+CL^(-)=NH_(4)Cl` AMMONIUM chloride. | |
| 22. |
Give one example for the relation between K_(p)andK_(c) for a reaction, if Deltan= 0. |
| Answer» SOLUTION :`N_(2(G))+O_(2(g))hArr2NO_((g))` | |
| 23. |
Give two examples for each of the following type of organic compounds. (i) non-benzonoid aromatic, (ii) aromatic heterocyclic, (iii) alicyclic and (iv) aliphatic open chain. |
Answer» SOLUTION :(i)
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| 25. |
Give one example each for homogeneous and heterogeneous equilibrium. |
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Answer» SOLUTION :HOMOGENOUS equilibrium: `N_(2(g))+O_(2(g))hArr2NO_((g))` HETEROGENOUS equilibrium: `CaCO_(3(S))hArrCaD_((s))+CO_(2(g))` |
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| 26. |
Give one chemical reaction to show that : (i) Tin (II) is a reeducing agent whereas Pb(II) is not. (ii) Tin (II) chloride is a reducing agent. |
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Answer» Solution :(i) Both tin and lead show two oxidation state of `+2` and `+4` due to inrt pair effect . But the inert pair effect. But the inert pair effectis more prominaent in case of Pb than in Sn. In other words +2, oxidation state of Sn is less stablethan its +4oxidation state. Therefore, `Sn(II)`acts asa reducing agent and GETS cor. erted into more stable `Sn (IV)` by losing two electrons. For example it reduces `Fe^(3+)` to `Fe^(2+)` ions. `2Fe^(+) + Sn^(2+) RARR 2Fe^(2+) + Sn^(4+)` In contrast`+2` oxidation state of Pb is more stable than its +4 oxidation state. In other words, `Pb(II)` does not lose electrons easily and HENCE does not acts as a redusingagent. (ii) Being areducingagent,tin (II) CHLORIDE reeducesmercuric chloride `(HgCl_(2))` to mercurous chloride `(Hg_(2)Cl_(2))` and ferric salt to ferrous salts. `SnCl_(2) + 2HgCl_(2) rarr SnCl_(4) + Hg_(2)Cl_(2)` `SnCl_(2) + 2FeCl_(3) rarr SnCl_(4) + 2 FeCl_(2)` |
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| 27. |
Givenumberofunpairedelectronin Ni^(2+) |
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Answer» 0 |
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| 28. |
Give number of sigma and pi bonds in above compounds of questions (i). |
| Answer» Solution :8 C-H `SIGMA` bond + 5 C-C `sigma` bond = TOTAL 13 `sigma` bond and `3pi` BONDS are present. | |
| 29. |
Give number of pi bond and sigma hond of the following. (i) Methane (ii) Ethane (iii) Ethene (iv) Ethyne (v) dioxygen (vi) dinitrogen (vii) Benzene (viii) Ozone |
Answer» SOLUTION :
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| 30. |
Give number of H atoms in 0.046 g ethanol. |
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Answer» `6xx10^(20)` |
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| 31. |
Give number of H atom attach with terminate carbon in |
Answer» Solution :At the end of the C-H is PRESENT MEANS, at LEFT handside, carbon has triple BOND. So, it has one hydrogen other right end indicates the `CH_(3)`
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| 32. |
Give number of carbon and its name in alkane |
Answer» Solution :(A) Number of carbon - Prefixies: The name of such compounds are based on their carbon carbon chai and this carbon chain is decided by number of carbon (B) 1 to 10 carbon containing alkane and its name and formula: The name of such compounds are based on their chain structure adn with suffix .-ane. and CARRY a prefix indicating the number of carbon atoms present in teh chain. e.g. If 4 carbon present then .But. + suffix .ane. i.e., the name is Butane. Some formula and names of alkane series are as under. The alkanes are differ from each other by merely the number of `-CH_(2)` group in the chain. The general formula of alkane: `C_(n) H_(2N + 2)` Prefix: Alk: Alk.Suffix: ane Name : Alkane
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| 33. |
Give num ber of protons, electrons and neutrons respectively in ._(16)^(32)S^(2-) |
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Answer» 16,16,16 |
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| 34. |
Give nitration products of toluene and benzoic acid ? |
Answer» SOLUTION :
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| 35. |
Giveno. of energystate,orbitalandelectronsin N orbital . |
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Answer» 4,12,32 |
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| 37. |
Give name of group-2 elements. |
| Answer» Solution :The group-2 ELEMENTS comprise BERYLLIUM, MAGNESIUM, calcium, STRONTIUM, barium and radium. | |
| 38. |
Give name of group 13 elements. |
| Answer» SOLUTION :Boron (B), Aluminum (Al), GALLIUM (Ga), INDIUM (In) and Thallium (Th) are group 13 ELEMENTS. They have `ns^2 np^1` general electronic configuration. | |
| 40. |
Give name of following |
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Answer» Solution :(a) (i) Methyl CYCLOPENTANE (ii) 1-cyclopentyl HEXANE (B) (i) Methyl cyclopropane (ii) 1-cyclopropyl butane (c ) 2-(Butyl) CYCLOHEXANE (d) 3, 5-cyclohex -1-ene |
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| 41. |
Give name of element, symbol & electronic configuration of 1^(st)group. |
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Answer» Solution :Elements in the same VERTICAL column or group have similar valence shell electronic configurations, the same number of electrons in the outer orbitals and similar properties. e.g. The group 1 elements (alkali METALS `ns^(1)` have his valence shell electronic CONFIGURATION as shown below : THSU it can be see that the properties of an element have PERIODIC dependence upon its atomic number and not on relative atomic mass . |
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| 42. |
Give name of 4 compounds of polymerized substance. And give their polymer name. |
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Answer» Solution :(i) `UNDERSET("BENZENE")underset(darr)("Acetelene")` (ii) `underset("polyethelene")underset(darr)("Ethelene")` (III) `underset(PVC)underset(darr)("Vinyl chloride")` (iv) `underset("Polypropene")underset(darr)("PROPENE")` (v) `underset("POLYBUTADIENE")underset(darr)("Butadiene")` |
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| 43. |
Give name and structure of cancer causing hydrocarbon. |
Answer» SOLUTION :
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| 44. |
Give name and structure of aromatic hydrocarbon with molecular formula C_(12)H_(10) which contain two benzene ring. |
Answer» Solution :`C_(12)H_(10)` POSSESS two benzene RING. So two `C_(6)H_(5)` structure is possible, such two `C_(6)H_(5)` compound on FUSION will gives biphenyl.
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| 45. |
Give name and structure of aromatic compound with C_(10)H_(8) molecular formula. And give the number of sigma and pi bonds present in the structure. |
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Answer» Solution :`C_(10)H_(8)` is aromatic compound. So it has 14 LESS Hydrogen that `C_(10)H_(22)`, it possess two RINGS and 5 DOUBLE BOND, the compound is nepthelene. There are 11 C-C sigma bond and 8 C-H sigma bonds so total 19 sigma bonds are present in it. It has 5 double bond. So it possess five C=C `pi` bond.
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| 46. |
Give moles of 50 gAl_(2) (SO_(4))_(3) ......... |
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Answer» 0.083 |
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| 47. |
Give molecular formula for washing soda. |
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Answer» `Na_(2)CO_(3)*10H_(2)O` |
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| 48. |
Give molecular structure of SO_(2) and calculate formal charge. |
Answer» SOLUTION : BONDING electron : 6 Nonbonding electron : 12 Total electron : 18 `N_(A)` = Non.bonding electron `N_(B)` = Bonding electron Total valence electron : 6 + 12 = 18 Formal charge of O (1) = `({:("velence"),("electron"):}) - (N_(A) + (1)/(2) N_(b))` = 6 - `[ 4 + (1)/(2) (4)] = 6 -6 = 0 ` Formal charge of O (2) = `6 - [ 6 + (1)/(2) (2) ] , ` Formal charge of S = ` 6 - [ 2 + (1)/(2) (6) ] = 6 - 5 = +1 ` |
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| 49. |
Give molarity and strength % w/v accordingly in 30 volume of H_2O_2 solution. |
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Answer» 2.678 M, 18.22% |
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| 50. |
Give MO diagram and explain Ne_(2) molecule is not possible. |
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Answer» Solution :`Ne_(2) (z = 10) 1S^(2) 2s^(2) 2p^(6)`. In `Ne_(2)` valence orbital 8 electrons and affected in bond structure are 16 electrons. ELECTRON configuration in MO for `Ne_(2) ` : KK `(sigma 2s)^(2) (sigma^(**) 2s) (pi 2p_(z))^(2)(pi 2p_(x))^(2) = (pi 2p_(y))^(2) (pi^(**)2p_(x))^(2)= (pi^(**) 2p_(y))^(2) (sigma^(**) 2p_(z))^(2) ` Bond order `= (1)/(2) (N_(b) - N_(a)) = (1)/(2) (10 - 10)` = 0 BO is zero, So it is unstable means does not exist. energy DIAGRAM for `Ne_(2)` .
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