This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Ionic radil is // are : |
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Answer» directly PROPORTIONAL to effective nuclear charge |
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| 2. |
lonic radii (in oversetoA) of As^(3+), Sb^(3+) and Bi^(3+) follow the order |
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Answer» `As^(+3) GT SB^(+3) gt BI^(+3) ` |
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| 3. |
Ionic radii vary in.... |
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Answer» inverse proportion to the EFFECTIVE nuclear CHARGE. Ionic radius `prop (1)/("effective nuclear charge")` Further, ionic radius increases as the screening effect increases. Ionic radius a screening effect. Ionic radius`prop` screening effect |
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| 4. |
Ionic radii of (1) Ti^(4+) lt Mn^(7+) (2) ""^(35)Cl^(-) lt ""^(37)Cl^(-) K^(+) gt Cl^(-) Pt^(3+) gt P^(3+) |
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Answer» (2) `""^(35)CL^(-) and ""^(37)Cl^(-)` are isotopes, hence,`""^(35)Cl cong ""^(37)Cl^(-)` (3) Again, `K^+ and Cl^(-)` are isoelectronic, hence, `K^+ lt Cl^(-)` (4) `P^(3+)` has 12 electrons and 15 protons, while `P^(5+)` has 10 electrons and 15 protons, hence `P^(5+) lt P^(3+)` |
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| 5. |
Ionic radii of zirconium and hafnium become almost identical because |
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Answer» They are 'd' block ELEMENTS |
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| 6. |
Ionicradii vary in |
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Answer» inverseproportion to theeffectivenuclear charge furtherionicradiusincreases as the screeningeffectincreases. In otherwordsoption (d)is correctwhileoption(d) isincorrect. |
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| 7. |
Ionic radii are |
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Answer» Inversly PROPORTIONAL to EFFECTIVE NUCLEAR charge. |
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| 9. |
Ionic product of water at 310 K is 2.7xx10^(-14) .What is the pH of neutral water at this temperature ? |
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Answer» Solution :Calculation `[H^+]` : There is FOLLOWING EQUILIBRIUM in water. `H_2O_((l))+ H_2O_((l)) =H_3O_((aq))^(+) + OH_((aq))^(-)` `K_W=[H_3O^+][OH^-]= 2.7xx10^(-14)` but `[H_3O^+]=[OH^-]` `THEREFORE [H_3O^+]^2=2.7xx10^(-14)` `therefore [H_3O^+]= sqrt(2.7xx10^(-14)) =1.6432xx10^(-7)` Calculation of pH : pH=-log `[H^+]` =-log `(1.6432xx10^(-7))` =-(0.2157-7.0)=6.7843 |
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| 10. |
Ionic mobility of which of the following alkali metal ions is lowest when aqueous solution of their salts are put under an electric field ? |
| Answer» Solution :`Li^(+)` being the smallest alkali metal cation is most HIGHLY hydrated . As a result , the mass of the hydrated species is the highest and its mobility in the electric field is the lowest . | |
| 11. |
Ionic hydrides react with water to give |
| Answer» Answer :A | |
| 12. |
Ionic hydrides are usually |
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Answer» GOOD electrically conductors when SOLID |
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| 13. |
Ionic hydrides are usallly |
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Answer» GOOD CONDUCTORS of ELECTICITY in SOLID state |
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| 14. |
Ionic hydrides are frequently used to remove last traces of water from organic compounds. How does it happen ? Explain. |
| Answer» SOLUTION :`H^(-)` being is STRONG Bronsted base REACTS with `H_(2)O` READILY liberating `H_(2)` gas. | |
| 15. |
Ionic hydride contains ......... property. |
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Answer» Crystal |
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| 16. |
Ionic hydrides are formed by |
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Answer» halogens |
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| 17. |
Ionic, covalent, dative and hydrogen bonds are present in |
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Answer» ICE |
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| 18. |
Ionic compounds are insoluble in ether. |
| Answer» Solution :Ionic compound does not ionize in ether i.e. ether cannot SEPARATE the CATIONS and ANIONS of ionic SOLIDS. | |
| 19. |
Ionic bond is defined as the electrostatic force of attraction holding the oppositely charged ions. Ionic compounds are mostly crystalline solids having high melting and boiling points, electrical conductivity in molten state, solubility in water etc., Covalent bond is defined as the force which binds atoms of same or different elements by mutual sharing of electrons in a covalent bond. Covalent compounds are solids, liquids or gases. They are low melting and boiling point compounds. They are more soluble in non polar solvents. Examples of covalent compounds are |
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Answer» UREA |
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| 20. |
Ionic bond is defined as the electrostatic force of attraction holding the oppositely charged ions. Ionic compounds are mostly crystalline solids having high melting and boiling points, electrical conductivity in molten state, solubility in water etc., Covalent bond is defined as the force which binds atoms of same or different elements by mutual sharing of electrons in a covalent bond. Covalent compounds are solids, liquids or gases. They are low melting and boiling point compounds. They are more soluble in non polar solvents. The valence electrons not involved in fonnation of covalent bonds are called |
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Answer» Bond pairs |
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| 21. |
Ionic bond is defined as the electrostatic force of attraction holding the oppositely charged ions. Ionic compounds are mostly crystalline solids having high melting and boiling points, electrical conductivity in molten state, solubility in water etc., Covalent bond is defined as the force which binds atoms of same or different elements by mutual sharing of electrons in a covalent bond. Covalent compounds are solids, liquids or gases. They are low melting and boiling point compounds. They are more soluble in non polar solvents. The amount of energy released when one mole of ionic solid fonned by close packing of gaseous ions is called |
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Answer» Ionization ENERGY |
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| 22. |
Iopic & covalent compounds are soluble in water due to |
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Answer» formation of H - bonds c) Ion - dipole INTERACTINS between ionic of water MOLECULES |
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| 23. |
Ion with maximum number of unpaired electrons |
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Answer» `LU^(3+)` |
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| 24. |
One mole ion which has two moles of charge |
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Answer» sulphate |
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| 25. |
............ion plays an important role as neuronal messenger. |
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Answer» `NA^(+)` |
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| 26. |
Ion having -2 chargeposseselectronconfiguration1s^(2)2s^(2) 2p^(6) statethe ion ? |
| Answer» Solution :`O^(2)`ion .As the chargeis -2so if twoelectrondeletedfromelectronconfigurationthan it willbe `1s^(2) 2S^(2) 2P^(4)` | |
| 27. |
Ion-dipole attractions are present in |
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Answer» Water |
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| 28. |
Iodoform has antiseptic properties. Give one reason to support this. |
| Answer» SOLUTION :IODOFORM has antiseptic properties due to free LIBERATED IODINE. | |
| 29. |
Iodobenzene can be obtained by- |
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Answer» `C_(6)H_(6)+I_(2)to` |
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| 30. |
Iodine titrations: Compounds containing iodine are widely used in titrations, commonly known as iodine titration. It is of two kinds: (i) lodometric titrations (ii) lodimetric titrations. (i) lodometric titrations : It is nothing but an indirect method of estimating the iodine. In this type of titration, an oxidising agent is made to react with excess of KI, in acidic medium or, basic medium in which I_2oxidises into L. Now the liberated I_2can be titrated with Na_(2)S_(2)O_3 .solution. KI overset("Oxidising Agent")rarrI_(2)overset(Na_(2).S_(2)O_(3)//H^(+))rarrI^(-)+Na_(2)S_(4)O_6Although solid I_2is black and insoluble in water, but it converts into soluble I_3ions underset("Black")(I_2(s))+IhArrunderset("Dark brown")(I_3^(-))Starch is used as indicator near the end point or equivalence point. Even small amount of I_2molecules, gives blue colour with starch. The completion of the reaction can be detected when blue colour disappears at the and point. In iodimetric titration, the strength of reducing agent is determined by reacting it with I_2A solution containing Cu^(+2) and C_(2)O_(4)^(-2) ions M which on titration with M/10 KMnO_4requires 50 mL. The resulting solution is neutralized with K_(2)CO_(3)then treated with excess of KI. M The liberated I_2required 25 mL M/10 Na_(2)S_(2)O_3in acidic solution, then what is the difference of the number of m mole of Cu^(+2) and C_(2)O_(4)^(-2)ions in the solution ? |
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Answer» 40 |
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| 31. |
Iodine titrations: Compounds containing iodine are widely used in titrations, commonly known as iodine titration. It is of two kinds: (i) lodometric titrations (ii) lodimetric titrations. (i) lodometric titrations : It is nothing but an indirect method of estimating the iodine. In this type of titration, an oxidising agent is made to react with excess of KI, in acidic medium or, basic medium in which I_2oxidises into L. Now the liberated I_2can be titrated with Na_(2)S_(2)O_3 .solution. KI overset("Oxidising Agent")rarrI_(2)overset(Na_(2).S_(2)O_(3)//H^(+))rarrI^(-)+Na_(2)S_(4)O_6Although solid I_2is black and insoluble in water, but it converts into soluble I_3ions underset("Black")(I_2(s))+IhArrunderset("Dark brown")(I_3^(-))Starch is used as indicator near the end point or equivalence point. Even small amount of I_2molecules, gives blue colour with starch. The completion of the reaction can be detected when blue colour disappears at the and point. In iodimetric titration, the strength of reducing agent is determined by reacting it with I_2When 214 g of KIO_3reacts with excess of KI in presence of H^(+)then it produces I_2Now I_2is completely reacted with 1 MNa_(2)S_(2)O_3solution in basic medium, where it converts into SO_4^(-2)ions. Then what volume of Na_(2)S_(2)O_3is needed to react the end point of the reaction? |
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Answer» 500 ml 214 g `KIO_3=1` mol of `KIO_3` mole of `I_2` (in the balanced chemical reaction ) = 6 EQ. of Let the vol.of `I_2` (n f = 2) = 6000 m eq. of `I_2` Let the vol of `Na_(2)S_(2)O_(3)=vmL`. then `(v xx 1 xx 8) = 6000 , v = 750 mL` |
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| 32. |
Iodine titrations: Compounds containing iodine are widely used in titrations, commonly known as iodine titration. It is of two kinds: (i) lodometric titrations (ii) lodimetric titrations. (i) lodometric titrations : It is nothing but an indirect method of estimating the iodine. In this type of titration, an oxidising agent is made to react with excess of KI, in acidic medium or, basic medium in which I_2oxidises into L. Now the liberated I_2can be titrated with Na_(2)S_(2)O_3 .solution. KI overset("Oxidising Agent")rarrI_(2)overset(Na_(2).S_(2)O_(3)//H^(+))rarrI^(-)+Na_(2)S_(4)O_6Although solid I_2is black and insoluble in water, but it converts into soluble I_3ions underset("Black")(I_2(s))+IhArrunderset("Dark brown")(I_3^(-))Starch is used as indicator near the end point or equivalence point. Even small amount of I_2molecules, gives blue colour with starch. The completion of the reaction can be detected when blue colour disappears at the and point. In iodimetric titration, the strength of reducing agent is determined by reacting it with I_2When 79.75 g of CuSO_4sample containing inert impurity is reacted with KI, the liberated I, is reacted with 50 mL (1M) Na_(2)S_(2)O_3in basic medium, where it oxidises into SO_(4)^(2-) ions, and I_2reduces into I^(-)then what will be the % purity of CuSO_4in sample ? |
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Answer» `60%` wt. of `CuSO_(4) = (7.975 xx 8) `g % purity of `CuSO_(4)=( 7.975 xx 8 xx100)/(79.75)=80%` |
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| 33. |
Iodine titrations: Compounds containing iodine are widely used in titrations, commonly known as iodine titration. It is of two kinds: (i) Iodometric titrations (ii) Iodimetric titrations. (i) Iodometric titrations: It is nothing but an indirect method of estimating the iodine. In this type of titration, an oxidising agent is made to react with excess of KI, in acidix medium or , basic medium in which I^(-) oxidises into I_(2). Now the liberated I_(2) can be titrated with Na_(2)S_(2)O_(3) solution. KI overset("Oxidising Agent")rarr I_(2) overset("Na_(2)S_(2)O_(3)//H^(+))rarr I^(-)+Na_(2)S_(4)O_(6) Although solid I_(2) is black and insoluble in water, but it converts into soluble I_(3) ions {:(I_(2)(s)+I^(-) hArr, I_(3)^(-)),("Black","dark brown"):} Strach is used as indicator near the end point or equivalence point. Even small amount of I_(2) molecules, gives blue colour with strach. The completion of the reaction can be detected when blue colour disappears at the and point. In iodimetric titration, the strength of reducing agent is determined by reacting it with I_(2). A solution containing Cu^(+2) and C_(2)O_(4)^(-2)ions M which on titration with M//10 KMnO_(4) requires 50mL. The resulting solution is neutralized with K_(2)CO_(3), then treated with excess of KI. M The liberated I_(2) required 25mL M//10 Na_(2)S_(2)O_(3) in acidic solution, then what is the difference of the number of m mole of Cu^(+2) and C_(2)O_(4)^(-2) ions in the solution? |
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Answer» 40 m eq. of `KMnO_(4)` used (n F = 5) = 25 m eq. of `C_(2)O_(4)^(-2)` m moles of `C_(2)O_(4)^(-2) (n = 2) = (24)/(2) = 12.5` m eq of `Na_(2)S_(2)O_(3) = 2.5 =m` eq. of `CU^(+2) (n = 1)` m eq. of `Cu^(+2) (n = 1) = 2.5` DIFFERENCEIN number of m moles of `Cu^(+2)` and `C_(2)O_(4)^(-2) = 12.5 - 2.5 = 10` |
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| 34. |
Iodine titrations: Compounds containing iodine are widely used in titrations, commonly known as iodine titration. It is of two kinds: (i) Iodometric titrations (ii) Iodimetric titrations. (i) Iodometric titrations: It is nothing but an indirect method of estimating the iodine. In this type of titration, an oxidising agent is made to react with excess of KI, in acidix medium or , basic medium in which I^(-) oxidises into I_(2). Now the liberated I_(2) can be titrated with Na_(2)S_(2)O_(3) solution. KI overset("Oxidising Agent")rarr I_(2) overset("Na_(2)S_(2)O_(3)//H^(+))rarr I^(-)+Na_(2)S_(4)O_(6) Although solid I_(2) is black and insoluble in water, but it converts into soluble I_(3) ions {:(I_(2)(s)+I^(-) hArr, I_(3)^(-)),("Black","dark brown"):} Strach is used as indicator near the end point or equivalence point. Even small amount of I_(2) molecules, gives blue colour with strach. The completion of the reaction can be detected when blue colour disappears at the and point. In iodimetric titration, the strength of reducing agent is determined by reacting it with I_(2). When 79.75g of CuSO_(4) sample containing inert impurity is reacted with KI, the liberated I_(2) is reacted with 50mL (1M) Na_(2)S_(2)O_(3) in basic medium, where it oxidises into SO_(4) ions, and I_(2) reduces into I^(-), then what will be the % purity of CuSO_(4) in sample? |
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Answer» `60%` `(w)/(159.5) = (50 xx 1 xx 8)/(1000)` wt of `CuSO_(4) = (7.975 xx 8)g` `%` purity of `CuSO_(4) = (7.975 xx 8 xx 100)/(79.75) = 80%` |
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| 35. |
Iodine titrations: Compounds containing iodine are widely used in titrations, commonly known as iodine titration. It is of two kinds: (i) Iodometric titrations (ii) Iodimetric titrations. (i) Iodometric titrations: It is nothing but an indirect method of estimating the iodine. In this type of titration, an oxidising agent is made to react with excess of KI, in acidix medium or , basic medium in which I^(-) oxidises into I_(2). Now the liberated I_(2) can be titrated with Na_(2)S_(2)O_(3) solution. KI overset("Oxidising Agent")rarr I_(2) overset("Na_(2)S_(2)O_(3)//H^(+))rarr I^(-)+Na_(2)S_(4)O_(6) Although solid I_(2) is black and insoluble in water, but it converts into soluble I_(3) ions {:(I_(2)(s)+I^(-) hArr, I_(3)^(-)),("Black","dark brown"):} Strach is used as indicator near the end point or equivalence point. Even small amount of I_(2) molecules, gives blue colour with strach. The completion of the reaction can be detected when blue colour disappears at the and point. In iodimetric titration, the strength of reducing agent is determined by reacting it with I_(2). When 214g of KIO_(3) reacts with excess of KI in presence of H^(+), then it produces I_(2). Now I_(2) is completely reacted with 1M Na_(2)S_(2)O_(3) solution in basic medium, where it converts into SO_(4)^(-2) ions. then what volume of Na_(2)S_(2)O_(3) is needed to react the end point of the reaction? |
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Answer» 500ml 214 g `KIO_(3) = 1` mole of `KIO_(3)` = 3 mole of `I_(2)` (in the balanced chemical reaction) = 6 eq. of `I_(2) (n f=2) = 6000` m eq. of `I_(2)` LET the vol of `Na_(2)S_(2)O_(3) =V mL`, then `(V xx 1 xx 8) = 6000, v = 750 mL` |
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| 36. |
Iodine titration can be iodemotric or iodimetric depending on using iodine directly or indirectly is an oxidising agent in the redox titration. a. Iodimetric titration in which a standard iodine solution is used as an oxidant and iodine is directly or indirectly titrated against a reducing agent. For example. 2CuSO_(4)+4KJtoCu_(2)I_(2)+2K_(2)SO_(4)+I_(2) b. Iodimetric procedures are used for the datermination of strength of reducing agent such as thiosulphates, sulphites, arsenties adn stanous chloride etc. by titrating them against standard solution of iodine in a burette. 2Na_(2)SO_(3)to2 NaI +Na_(2)S_(4)O_(6) Starch is used as indicator near the end point whilch form blue colour complex with I_(3)^(-). The blue colour disappeams whenthere is not more of free I_(2) . The volume of KI solutioin used for CuSO_(4) will be |
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Answer» 100 ml `1XX(100)/(1000)xx1=0.5xx1xxV` `V=0.2` lit implies `V=200ml` |
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| 37. |
Iodine solution is prepared by dissolving iodine in : |
| Answer» Solution :N//A | |
| 38. |
Iodine oxidises sodium borohydride to give |
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Answer» `B_2H_6` `2NaBH_4 + I_2 overset"DIGLYME"to B_2H_6+2NaI + H_2` |
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| 39. |
Iodine monochloride molecule is formed by the overlap of |
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Answer» s-s ORBITALS |
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| 40. |
Iodine monochloride molecle is formed by the overlap of |
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Answer» s-s ORBITALS |
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| 41. |
Iodine molecules are held in the crystals lattice by ______ |
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Answer» LONDON FORCES |
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| 42. |
Iodine molecules are held in the crystals lattice by …….. |
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Answer» London forces |
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| 43. |
Iodine is moresoluble in water in the presence of potassium iodide. Why ? |
| Answer» Solution :In the PRESENCE of iodide, dipole is induced in IODINE. Due to the ION-induced dipole ATTRACTION, a complex ion, `I_(3)^(-)` is formed which INCREASES solubility. | |
| 44. |
Iodination of alkane is best carried out in the presence of |
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Answer» `H_2O` |
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| 45. |
Iodination of alkane is carried out in the presence of |
| Answer» Answer :B | |
| 46. |
Iodate oxidises chromic hydroxide and gives iodide and chromate in basic medium. |
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Answer» Solution :(a) The ionic SKELETON equation is written as `IO_(3)^(-) +Cr(OH)_(3) OVERSET(OH^(-))to I^(-)+CrO_(4)^(2-)` (b) Writing oxidation numbers `overset(+5)(I) overset(-2)(O_(3)^(-)) +overset(+3)(Cr) overset(-2 +1)(OH_(3)) to overset(-1)(I^(-))+overset(+6)(Cr) overset(-2) (O_(4)^(-2))` (c) Locating atoms undergoing change in oxidation numbers. `overset(+5)(IO_(3)^(-)) +overset(+3)(Cr(OH)_(3)) to overset(-1) (I^(-)) +overset(+6)(Cr) O_(4)^(-2)` (d) Dividing the reaction into two halves and balancing in ACIDIC medium, separately. (e) Equalising the ELEMENTS and adding the two halves `eq (a) xx 2+eq (b) xx 1," we get"` `2Cr(OH)_(3)+10OH^(-) to 6e^(-)+2CrO_(4)^(2-)+8H_(2)O` `IO_(3)^(-)+6H_(2)O+6e^(-) to I^(-)+6OH^(-)` `IO_(3)^(-)+2Cr(OH)_(3)+4OH^(-) to I^(-)+2CrO_(4)^(2-)+5H_(2)O` This is the balanced equation. |
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| 47. |
Inversion temperature of a gas is how many times the Boyle's temperature? |
| Answer» SOLUTION :`T_i = (2A)/(RB) T_b = a/(Rb)`. | |
| 48. |
Inversion temperature (Ti=2aRb) is defined as the temperature above which if gas is expandedadiabatically it gets warm up but if temperature of gas is lower than Ti then it will cool down. What willhappen to gas if it is adiabatically expanded at 50∘C if its Boyle's temperature is 20∘C |
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Answer» Solution :`T_b = 290 K IMPLIES T_1 = 2 T_b = 580 K, 600 > Ti ` `:.` Heating. |
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| 49. |
Intramolecular hydrogen bondingis presentin |
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Answer» WATER |
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| 50. |
Intramolecular hydrogen bond is present in |
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Answer» orthohydroxy benzaldehyde |
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