InterviewSolution
This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 89501. |
A gaseous mixture contains 56 g of N_2 ,44 g CO_2and 16 g of CH_4The total pressure of the mixture is 720 mm Hg. The partial pressure of CH_4 is |
| Answer» ANSWER :A | |
| 89502. |
A gaseous mixture contains 50% helium and 50% methane by volume. What is the percent by weight of methane in the mixture? |
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Answer» `19.97%` `("No. of molecules of He")/("No. of molecules of" CH_(4))=(1)/(1)` `("MASS of He")/("Mass of" CH_(4))=(4)/(16)=(1)/(4)` `:.` Percentage of `CH_(4)` in mixture `(4)/(5)xx100=80%` |
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| 89503. |
A gaseous mixture contains 40% H_(2) and 60% He, by volume. What is the average molecular mass of mixture ? |
| Answer» Solution :`M_("av")=(SUM(%"by VOL."XX"MOLECULES"))/(100)=(40xx2+60xx4)/(100)=3.20` | |
| 89504. |
A gaseous mixture contains 220 g of carbon dioxide and 280 g of nitrogen gas. If the partial pressure of nitrogen gas in the mixture is 1.5 atm then the partial pressure of carbon dioxide gas in the mixture will be |
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Answer» 1.25 atm |
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| 89505. |
A gaseous mixture contain four gases A, B, C and D. The mole fraction of "B" is 0.5. The mole fraction of "A" is |
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Answer» `0.525` |
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| 89506. |
A gaseous mixture contain 50% He and 50% CH_4by volume. What is the percent by weight of CH_4in the mixture ? |
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Answer» 0.1997 ` ("no. of MOLECULES of He")/("no. of molecules of " CH_4) = 1/1` `(" mass of He")/("mass of " CH_4) = 4/16 = 1/4` % of `CH_4` in mixture `= (4 xx 100)/(5) = 80.03%` |
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| 89507. |
A gaseous hypothetical chemical equations ,is carried out in a closed vessel . The concentration of B is found to increase by 5 xx 10^(-3) mol l^(-1) in 10 second . The rate of appearance of B is |
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Answer» `5 xx 10^(-4) mol L^(-1) sec^(-1)` Rate of apperance ofB = `("Increase of conc. B")/("Time TAKEN")` `= (5xx 10^(-3) mol l^(-1))/(10"sec") = 5 xx 10^(-4) mol l^(-1) sec^(-1)`. |
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| 89508. |
A gaseoushydrocarbon'X'on reactionwithbromineinlight formsa mixtureof twomonobromo alkanesand HBr.The hydrocarbon'X'is : |
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Answer» `C_(2) H_(6) ` |
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| 89509. |
A gaseous hydrocarbon was exploded with excess of oxygen. On cooling a contraction of 1.5 times the volume of the hydrocarbon was observed. When treated with NaOH a further contraction of double the volume of the hydrocarbon was noted. The molecular formula of the hydrocarbon is: |
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Answer» `C_2 H_4` |
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| 89510. |
A gaseous hydrocarbon requires 6 times its own volume of O_(2) for complete oxidation and produces 4 times its volume of CO_(2). What is its formula ? |
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Answer» Solution :The balanced EQUATION for combustion `C_(x) H_(y)+(x+(y)/(4))O_(2) rarr xCO_(2) +(y)/(2) H_(2)O` 1 VOLUME `(x+(y)/(4))` volume `therefore x+(y)/(4)=6` (by equation) or 4x+y=24 Again x=4 since evolved `CO_(2)` is 4 times that of hydrocarbon `therefore 16 +y=24" or "y=8 therefore` formula of hydrocarbon `C_(4)H_(8)` |
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| 89511. |
A gaseous hydrocarbon has 85%C and its vapour density is 28. The possible formula of the compound is |
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Answer» `C_(3)H_(6)` `{:("Element","Percentage","Mole","Mole ratio"),(C,85,85//12=7.08,1),(H,15,15//1=15,2):}` Empirical formula `=CH_(2)` Empirical formula mass `=12+2=14` Molecular mass `=28xx2=56` `n=(56)/(14)=4` Molecular formula `=(CH_(2))_(4)=C_(4)H_(8)` |
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| 89512. |
A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO_(2). The empirical formula of the hydrocarbon is : |
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Answer» `C_(2)H_(4)` Moles of `H_(2)O = (0.72)/(18) = 0.04` Moles of `CO_(2)= (3.08)/(44) = 0.07` `-""x : (y)/(2) = 0.07 : 0.04` or `x : y = 0.07 : 0.08 or 7 : 8` `therefore""C : H = 7 : 8` Therefore, the empirical formula is `C_(7)H_(8)`. |
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| 89513. |
A gaseous hydrocarbon given upon combustion, 0.72g water and 3.08g of CO_(2). The empirical formula of the hydrocarbon is: |
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Answer» `C_(6)H_(5)` Number of moles of `CO_(2)=(3.08)/(44)=0.07` `n_(H)=2n_(H_(2))=2xx0.04=0.08` `n_(C)=n_(CO_(2))=0.07` `C:H=0.07:0.08=7:8` `THEREFORE` Empirical =`C_(7)H_(8)`. |
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| 89514. |
A gaseous hydrocarbon gives upon combustion, 0.72 g of water and 3.08 g of CO_(2). The empirical formula of the hydrocarbon is |
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Answer» `C_(2)H_(4)` `:. 0.72 g H_(2)O` contains `0.08 g H` `44 g CO_(2)` contains `12 g C` `:. 3.08 g CO_(2)` contains `0.84 g C` `:. C : H = (0.84)/(12): (0.08)/(1) = 0.07:00.08 = 7 : 8` `:. ` Empirical formula `= C_(7)H_(8)`. |
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| 89515. |
A gaseous hydrocarbon contaisn 85.7% carbon and 14.3% hydrogen 1 litre of the hydrocarbon weights 1.26g at NTP. Determine the molecular formula of the hydrocarbon. |
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Answer» |
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| 89516. |
A gaseous compound which contains only C, H and S is burnt with oxygen under such conditions that individual volumes of the reactant and product can be measured at the same temperature and pressure. It is found that 3 volumes of the compound react with oxygen to yield 3 volumes of CO_(2), 3 volumes of SO_(2) and 6 volumes of water vapour. What volume of oxygen is required for teh combustion? What is the formula of the compound ? Is this an empirical formula or molecular formula ? |
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Answer» Solution :`{:("COMPOUND",+,O_(2),rarr,CO_(2),+,SO_(2),+,H_(2)O),(3 "vol",,v"vol(say)",,3 "vol",,3"vol",,6"vol"),(or " 3 moles",,v"moles",,3"moles",,3"moles",,6"moles"):}` Applying POAC for O atoms, moles of O in `O_(2)` =moles of O in `CO_(2) +` moles of O in `SO_(2)`+ moles of O in `H_(2)O 2xx` moles of `O_(2)` `=2 xx` moles of `CO_(2)+2 xx` moles of `SO_(2) +1 xx` moles of `H_(2)O` `2v=2 xx 3+2 xx3 +1 xx 6= 18, v= 9` `therefore` volume of `O_(2)` required for combustion is 9. Again, moles of C in `CO_(2)=1 xx` moles of `CO_(2)=3` moles of S in `SO_(2)=1XX` moles of `SO_(2)=3` moles of H in `H_(2)O=2 xx` moles of `H_(2)O=12` `therefore` formula is `C_(3)S_(3)H_(12) or CSH_(4)` Now we see 3 moles of the compound contain 3 moles of C atoms in `C_(3)S_(3)H_(12)`. Hence i mole of the compound should contain 1 mole of C atoms and therefore, the molecular formula is `CSH_(4)`. |
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| 89517. |
A gaseous compound of carbon and nitrogen containing 53.8% by weight of nitrogen was found to have a vapour density of 25.8. What is the molecular formula of the compound. |
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Answer» |
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| 89518. |
A gaseous compound A reacts by three independent first order process (as shown in figure) with rate constant 2xx10^(-3),3xx10^(-3) and 1.93xx10^(-3) sec^(-1) for products B, C and D respectively, If initially pure A was taken in a closed container with p=8 atm then the partial pressure of B (in atm) after 100 sec from starting the experiment. |
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Answer» `0.288` |
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| 89519. |
A gaseous compound is composed of 85.7% by weight of C and 14.3% by weight of H. Its density is 2.28 g/L at 300 K and 1 atm pressure. Calculate the molecular formula of the compound. |
| Answer» SOLUTION :`C_(4)H_(8)` | |
| 89520. |
A gaseous carbon compound is soluble in dilute HCl. The solution on treating with NaNO_(2) gives off nitrogen leaving behind a solution which smells of wood spirit. The carbon compound is |
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Answer» A)`HCHO` `CH_(3)NH_(2) underset(NaNO_(2))overset(HCL)to CH_(3)OH+N_(2)+H_(2)O`. |
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| 89521. |
A gaseous alkane (C_(n)H_(2n+2)) is exploded with oxygen. The volume of O_(2) and CO_(2) formed are in the ratio of 7:4, Deduce the value of n. |
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Answer» `(n+((n+1))/(2))/(n)=(7)/(4)` or n=2 |
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| 89522. |
A gaseous A_(2)(g) rarr B(g) +(1)/(2) C(g), shows increase in pressure from 100 mm to 120 mm in 5 min. The rate of disappearance of A_(2) is |
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Answer» 4 mm `"MIN"^(-1)` Total pressure = `100 - p + p +(1)/(2) p = 100 +(1)/(2) p` `therefore` Increase in pressure =` (1)/(2) p = 120 - 100 = 20 mm` `therefore` Decrease in pressure of `A_(2) = 2 xx 20 = 40 mm` `therefore` Rate of disappearance of `A_(2)=(DX)/(dt)=(40)/(5)=8 mm " min"^(-1)` |
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| 89523. |
A gas X turns line water milky. The milkiness disappears if excess of 'X' is passed. Milkiness reappears on heating the colourless solution. The gas is |
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Answer» `CO_(2)` `Ca(OH)_(2)+SO_(2) tounderset("Milky white")(CaSO_(3)) underset("Excess "H_(2)O) overset(SO_(2))to Ca(HSO_(3))_(2)` |
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| 89524. |
A gas X is passedthroughwater to forms a saturated solution .The aqaeoussolutionon tretment aqeoussolutionalsodissolve magnassium ribbon with the evolation of a colourless gas Y identify X and Y |
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Answer» `X = CO_(2),Y = Cl_(2)` `CI_(2) + H_(2)O rarr HCI +HOCI` `HCI + AgNO_(3) rarr underset(WHITE)(AgCI darr ) + HNO_(3)` `Mg + 2HCI rarr MgCI_(2) + H_(2) uarr ` |
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| 89525. |
A gas 'X' is passed through water to form a saturated solution. The aqueous solution on treatment with silver nitrate gives a white precipitate. The saturated aqueous solution also dissolves magnesium ribbon with evolution of a colourless gas 'Y'. Identify 'X' and 'Y': |
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Answer» `X = CO_(2), Y = CI_(2)` |
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| 89526. |
A gas 'X' is passed through water to form a saturated solution. The aqueous solution on treatment with silver nitrate gives a white ppt. The saturated aqueous solution also dissolve magnesium ribbon with evolution of a colourless gas 'Y'. Identify 'X' and 'Y'. |
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Answer» `X=CO_(2), Y=Cl_(2)` |
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| 89527. |
A gas 'X' is passed through water to form a saturated solution. The aqueous solution on treatement with silver nitrate gives a white precipitate. The saturated aqueous solution also dissolves magnesium ribbon with evolution of a colourless gas 'Y' Identify 'X' and 'Y' |
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Answer» `X=CO_(2),Y=Cl_(2)` `underset((X))(Cl_(2))+H_(2)OtoHOCl+HCl,` `HCl+AgNO_(3) to underset(White)(AgCl)darr+HNO_(3)` `2HCl+Mgto MgCl_(2)+underset((Y))(H_(2))UARR` |
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| 89528. |
A gas 'X' diffuses five times as rapidly as another gas 'Y'. Calculate the ratio of molecular weights of 'X' and 'Y'. |
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Answer» |
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| 89529. |
A gas 'X' is passed through water to form a saturated solution. The aqueous solution on treatment with silver nitrate gives a white precipitate. The saturated aqueous solution also dissolves magnesium ribbon with evolution of colourless gas Y , X and Y are : |
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Answer» `X=CO_2 , Y=Cl_2` `AgNO_3 + HCl tounderset ("WHITE ppt")(AGCL) + HNO_3 ` `Mg+2HCl to Mg Cl_2 + underset((Y))(H_2)uarr` |
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| 89530. |
A gas X at 1 atm is bubbled through a solution containing a mixture of 1 M Y^(-) and 1 M Z^(-) at 25^(@)C. If the order of reduction potentials is Z gt Y gt X, then |
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Answer» Y will OXIDISE X and not Z |
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| 89531. |
A gas X at 1 atm is bubbles through a solution containing a mixture of 1M Y^(-) and MZ^(-) at 25^(@)C If the reduction potential of ZgtYgtX, then, |
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Answer» Y will oxidize X and not Z Z REDUCED and Y oxidized, Z reduced and X oxidised, Y reduced and X oxidized. Hence, Y will oxidize X and not Z. |
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| 89532. |
A gas X at 1 atm is bubbled through a solution containing a mixture of 1M Y^(-) and 1MZ^(-) ions at 25^(@)C. If the reduction potential of ZgtYgtX, then, |
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Answer» Y will OXIDIZE but not Z. Thus, Y will oxidize X but not Z. lt |
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| 89533. |
A gas X at 1 atm is bubbled through a solution containing a mixture of 1M Y and 1MZ ions at 25^(@)C if the reduction potential of ZgtYgtX, then |
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Answer» Y will oxidise X but not Z `ZgtYgtX ` Hence Y will oxidise X but not Z. |
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| 89534. |
A gas X at 1 atm is bubbled through a solution containing a mixture of 1 M Y^(-) and 1 M Z^(-) at 25^(@)C. If the reduction potential of ZgtYgtX, then |
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Answer» Y will OXIDISE X and not Z |
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| 89535. |
A gas X at 1 atm is bubbled through a solution containg a mixture of 1 M Y^- and 1M Z^- at 25^@C. If the reduction potential of Z gt Y gt X, then : |
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Answer» Y will oxidise X and not Z |
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| 89536. |
A gas X at 1 atm is bubble through a solution containing a mixture of 1MY^(-) and 1MZ^(-) at 25^@C . If the reduction potential of Z > Y > X, then |
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Answer» Y will oxidized X and not Z |
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| 89537. |
A gas X at 1 atm is bubble through a solution containing a mixture of 1MY^(-)"and " 1MZ^(-) at 25^(@)C. If the reduction potential of Z gt Y gt X, then |
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Answer» Y will OXIDIZE X and not Z |
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| 89538. |
A gas X at 1 atm is bubblcd through a soluution containing a mixture of 1 M Y ^(-) and 1 M Z ^(-) at 25^(@)C. If the rcduction potential tial of Z gt Y gt X, then, |
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Answer» Y will oxidize X and not Z Z reduced andY oxidised Z reduced and X oxidised Y reduced and X oxidised Hence, Y will oxidise X and not Z. |
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| 89539. |
A gas will approach ideal behaviour at : |
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Answer» LOW T and HIGH P |
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| 89540. |
A gas will approach ideal behaviour at |
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Answer» LOW TEMPERATURE and low pressure |
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| 89541. |
A gas which is used as anaesthetic in dental surgery is |
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Answer» `N_(2)` |
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| 89543. |
A gas when passed through the K_(2)Cr_(2)O_(7) and dil. H_(2)SO_(4) solution, turns it green, the gas is |
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Answer» `H_(2)S` |
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| 89545. |
A gas when passed through K_(2)Cr_(2)O_(7) and dil. H_(2)SO_(4) solution turns it green, the gas is |
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Answer» `CO_(2)` |
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| 89546. |
A gas turns lime water milky and acidified K_(2)Cr_(2)O_(7) solution green then gas is : |
| Answer» ANSWER :C | |
| 89547. |
A gas that cannot be collected over water is : |
| Answer» Answer :B | |
| 89548. |
A gas reacts with CaO but not with NaHCO_3. The gas is |
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Answer» `CO_2` |
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| 89549. |
A gas reacts with CaOand not with NaHCO_3 is: |
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Answer» `CO_2` |
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| 89550. |
A gas phase reaction has energy of activation 200 "kJ mol"^(-1).If the frequency factor of the reaction is 1.6xx10^(13) s^(-1). Calculate the rate constant at 600 K . (e^(-40.09)=3.8xx10^(-18)) . |
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Answer» SOLUTION :`k=Ae^((-(E_a)/(RT)))` `k=1.6xx10^(13)s^(-1)_e^(-((200xx103"J mol"^(-1))/(8.314"JK "^(-1)mol^(-1)xx600K)))` `k = 1.6xx10^(13)s^(-1)e^(-(40.1))` `k=1.6xx10^(13)s^(-1)xx3.8xx10^(-18)` `k=6.21xx10^(-5)s^(-1)` |
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