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10851.

Valence bond theory does not give quantitative interpretation of magnetic data.

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ANSWER :1
10852.

Which of the following contains nitrogen?

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PROTEINS
Fats
OILS
Carbohydrates

Solution :Proteins contain nitrogen. Nitrogen is present.in amino ACID which is a major CONSTITUENT of protein.
10853.

Whatdoyou meanbybenefactionprocess ?

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SOLUTION :The process used toconcentratean ore iscalledthebenefactionprocess. FOREXAMPLE, FROTHFLOATATION,electromagneticseparation, leaching, ETC.
10854.

Which statement is NOT correct?

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Potassium PERMANGANATE is a powerful oxidising SUBSTANCE.
Potassium permanganate is a weaker oxidising substance than potassium dichromate.
Potassium permanganate is a STRONGER oxidising substance than potassium dichromate.
Potassium dichromate OXIDISES a secondary ALCOHOL into a ketone.

Answer :B
10855.

What is the characteristic valence shell configuration of coinage metals ?

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`ns^2np^6`
`(n-1)d^2np^6`
`nd^9ns^1`
`(n-1)d^10ns^1`

ANSWER :D
10856.

Which of the following reagents can convert

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`RMgX//H_(2)O`
`(CH_(2)OH)_(2)`
ROR'
`RH//H_(2)O`.

Solution :This is a cyclic ketal RESULTING from the reaction of ethylene glycol on DIETHYL ketone.
10857.

Write the IUPAC names of the following (i)[Co(NH_(3))_(6)Cl_(3) (ii)[Co(NH_(3))_(5)Cl]Cl_(2) (iii) K_(3)[Fe(CN)_(6)] (iv)K_(3)[Fe(C_(2)O_(4))_(3)] (v) K_(2)[PdCl_(4)] (vi) [Pt(NH_(3))_(2)Cl(NH_(2)CH_(3))]Cl

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SOLUTION :`(i)` Hexaamine cobalt (III) chloride
`(ii)` Pentaamine chloridocobalt (III) chloride
`(iii)` Potassium HEXACYANOFERRATE (III)
`(iv)` Potassium trioxalatoferrate (III)
`(v)` Potassium tetrachlorido palladate (II)
`(vi)` Diamminechlorido (METHYLAMINE) PLATINUM (II) chloride
10858.

What type of defect can arise when a solid is heated? Which physical property is affected by it and in what way?

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SOLUTION :On heating, some atoms or ions leave the lattice sites and vacance DEFECT is produced. It RESULTS in DECREASE in the density of the substance.
10859.

Which shows weak ionisation in water

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`H_(2)SO_(4)`
NACL
`HNO_(3)`
`NH_(3)`

SOLUTION :Because it is a weak electrolyte.
10860.

Which one is most reactive towards electrophilic reagent ?

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SOLUTION :is most reactive DUE to the presence of electron RELEASING GROUP.
10861.

Which of the following curve will represent the variation of conductance C during titration of CH_(3)COOH by gradual addition of NaOH solution (V)

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ANSWER :D
10862.

Which one of the following esters cannot undergo Claisen self-condensation ?

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`CH_3 CH_2CH_2 CH_2 COOC_2H_5`
`C_6H_5COOC_2H_5`
`C_6H_5CH_2 COOC_2H_5`
`C_6H_11CH_2 COOC_2H_5`

ANSWER :B
10863.

Vapour pressure of pure A = 100 torr, moles = 2. Vapour pressure of pure B = 80 torr, moles = 3. Total vapour pressure of mixture is

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440 torr
460 torr
180 torr
88 torr

Solution :`P_("total")=p_(A)^(@)x_(A)+p_(B)^(@)x_(B)`
`P_("total")=P_(A)+P_(B)=100xx(2)/(5)+80xx(3)/(5)=88` torr.
10864.

Which of the following compounds is formed when acetophenone is treated with bromine in acidic medium ?

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`##CHY_CHE_ORG_XII_P2_PYQ_17_E01_061_O04.png" width="30%">

ANSWER :C
10865.

Total number of Bravais lattices is

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3
7
10
14

Answer :D
10866.

When ethanol on dehydration with conc. H_(2)SO_(4) at 443 K gives ethane. What will be obtained if the temperature is raised to 413 K ?

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SOLUTION :ETHOXYETHANE
10867.

What is lucas reagent? How does it help in distinguishing primary, secondary and tertiary alcohols?

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Solution :Lucas reagent is a mixture of conc. HCl and ANHYDROUS `ZnCl_(2)`. The product is alkyl chloride ACCOMPANIED by white turbidity and cloudiness.
`-underset(1^(@), 2^(@)"or"3^(@))underset(("Alcohol")) underset(|)overset(|)(C)-OH+H-Cloverset(ZnCl_(2))(to)-underset(("Alkyhchloride"))underset(|)overset(|)(C)-Cl+H_(2)O`
(i) It turbidiy appears immediately, alcohol is tertiary `(3^(@))`
(ii) It turbidity appears after sometime, alcohol is secondary `(2^(@))`
(iii) In case turbidity appears on heating, alcohol is primary `(1^(@))`
10868.

What is battery?

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SOLUTION :BATTERY is a COMBINATION of GALVANIC cells in series where the chemical energy of redox reaction is converted to ELECTRICAL energy. Batteries are used as a source of electrical energy.
10869.

Water gas is

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`CO+CO_2`
`CO+N_2`
`CO+H_2`
`CO+N_2+H_2`

ANSWER :D
10870.

Which one of the following species is diamagnetic in nature ?

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`He_(2)^(+)`
`H_(2)`
`H_(2)^(+)`
`H_(2)^(-)`

SOLUTION :`H_(2):(sigma_(1S))^(2)` is DIAMAGNETIC.
10871.

What are biodegradable and non-biodegradable detergents? Give one example of each.

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SOLUTION :Biodegradable detergents are DECOMPOSED by micro-organisms present in sowage.
Non-biodegradable detergents which have branches CHAIN alkyl groups are not decomposed by micro-organisms and create WATER POLLUTION.
10872.

Vapour pressure of solution decreases with ____ in temperature.

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SOLUTION :INCREASES
10873.

Which of the following compounds cannot be used as solvent in Friedel-Crafts reaction ?

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Nitrobenzene
o - dinitrobenzene
Cyanobenzene
Toluene

Solution :`-NO_(2)` GROUP RING de-activating
10874.

Which of the following compounds is colourless?

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`Fe^(3+)`
`TI^(4+)`
`CO^(2+)`
`Ni^(2+)`

Solution :`Ti^(4+)` contains no UNPAIRED electrons in d orbital, hence no d-d TRANSITION.
10875.

Which acid of each pair shown here would you expect to be stronger ? .

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SOLUTION :.
10876.

Which of the following statement (s) is (are) correct

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The pH of `1.0 xx 10^(-8) M` solution of HCl is 8
The conjugate base of `H_(2)PO_(4)^(-)` is `HPO_(4)^(2-)`
Autoprotolysisconstant of WATER increases with temperature
When a solution of a weak monoprotic ACID is titrated against a strong base, at half-neutralisation POINT `pH = (1//2) pK_(a)`

Solution :pH of `1 xx 10^(-8) M` is below to 7
`H_(2)PO_(4)^(-) + H_(2)O hArr HPO_(4)^(2-) + H_(3)O^(+)`
`H_(2)O + H_(2)O hArr OH^(-) + H_(3)O^(+)`
K (Auto protolysis constant of water i.e., ionic product of water) increases with temperature.
For half neutralisation of a weak acid by a weak base,
`pH = pK_(a) + log.(["Salt"])/(["Acid"])`
[Salt] = [Acid], `:. pH = pK_(a)`.
10877.

Two gaseous equlibriua SO_(2(g))+1/2O_(2(g))hArrSO_(3(g))and 2SO_(3(g))hArr2SO_(2(g))+O_(2(g)) have equlibrium constants K_(1) and K_(2) respectively at 298K. Which of the following relationship between K_(1)and K_(2) is correct

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`K_(1)=K_(2)`
`K_(2)=K_(1)^(2)`
`K_(2)=(1)/(K_(1)^(2))`
`K_(2)=(1)/(K_(1))`

SOLUTION :`K_(1)=([SO_(3)])/([SO_(2)][O_(2)]^(1//2))and K_(2)=([SO_(2)]^(2)[O_(2)])/([SO_(3)]^(2)),K_(2)=(1)/(K_(1)^(2)).`
10878.

Which of the following are addition polymers ?

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Nylon
Melamine FORMALDEHYDE resin
Orlon
Polystyrene

Answer :A::C::D
10879.

Which one is the complementary base in RNA strand to the adenine base in DNA during protein synthesis:

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Adenine
Guanine
Uracil
Cytosine

Answer :D
10880.

Which of the following countries had an issue related to the migration of Rohingyas?

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NEPAL
BHUTAN
Myanmar
China

Answer :C
10881.

What is complex salt ?

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Solution :These SALTS RETAIN their IDENTITY in solution in water or in any other solvents. It EXISTS in SOLID as well as in solution form.
10882.

What is the action of concentrated sulphuric acid on aniline?

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Solution :ANILINE on treatment with cold sulphuric ACID FORMS anilinium hydrogen sulphate which on HEATING with sulphuric acid at 453-473 k GIVES p-aminobenzene sulphonic acid (sulphanilic acid) as major product.
10883.

Which of the following haloalkanes reacts with aqueous KOH most easily ? Explain giving reason. (i) 1-Bromobutane (ii) 2-Bromobutane (iii) 2-Bromo-2-methylpropane (iv) 2-Chlorobutane.

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SOLUTION :2-Bromo-2-methylpropane (iii) is a `3^(@)` alkyl BROMIDE. It readily undergoes IONIZATION to form a STABLE `3^(@)` carbocation. Therefore, it reacts with aq. KOH most readily.
10884.

There is sudden change is the slopes for some metal oxides like MgO, ZnO , HgO in Ellingham diagram . It is the indication of

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INSUFFICIENT supply of oygen
excess of oxygen
phase change
completion of reaction

Solution :That is the MP or BP of METAL
10885.

Which of the followingis not correct

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A SIGMA BOND is weaker than `pi` bond
A sigma bond is stronger than `pi` bond
A DOUBLE bond is stronger than a SINGLE bond
A double bond is shorter than a single bond

ANSWER :A
10886.

What are reducing and non-reducing sugars ?

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SOLUTION :
10887.

Which of the following chlorofuorocarbon is hyghly toxic ?

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`C ClF_(2)`
`CHClF_(3)`
`CHCl_(2)F_(2)`
`C_(3)H_(2)Cl_(3)F_(3)`

ANSWER :D
10888.

Which of the following is the formula of argol?

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`{:(,,CH(OH)COOH),(,,"|"),(,,CH(OH)COOK):}`
`{:(,CH(OH)COOK),(,"|"),(,CH(OH)COO(SbO)):}`
`{:(,CH(OH)COOK),(,"|"),(,CH(OH)COOK):}`
`{:(,CH(OH)COOK),(," |"),(,CH(OH)COONA):}`

Solution :TARTAREMETIC (i.e., potassium antiomony (+) TARTRATE) i.e., `{:(,CH(OH)COOK),(,"|"),(,CH(OH)COO(SbO)):}` is used as an emetic, i.e., to cause housed and VOMITING during treatment of poisoning.
10889.

Which colour well be observed when Manganese dioxide is fused with KOH in presence of O_(2)?

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Purple
Green
Orange
Red

Solution :`K_(2)MnO_(4)` is FORMED
10890.

Which of the followingppt , is soluble dil , HNO_(3)and NH_(3) solution ?

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`Ag_(2)S_(2)O_(3)`
`Ag_(2)CO_(3)`
`Ag_(2)SO_(3)`
`AGI`

ANSWER :a,b,C
10891.

The units of Normality are

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MOLE. `LIT^(-1)`
mole. `Kg^(-1)`
equivalent. `"lit"^(-1)`
equivalent. `Kg^(-1)`

Answer :C
10892.

What happens when methyl magnesium bromide reacts with ethyl methanoate followed by acid hydrolysis?

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SOLUTION :
10893.

Which one of the following methods is neither meant for the synthesis nor for separation of amines?

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Hinsberg reagent
Hofmann's method
Wurtz reaction
Curtius reaction

Answer :C
10894.

Which of the following has higher IP ?

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OXYGEN
SULPHUR
SELENIUM
TELLURIUM

ANSWER :A
10895.

The standard Gibbs energy change at 300K for the reaction 2A⇋B+C is 2494.2 J. At a given time, the composition of the reaction mixture is [A] =21​ , [B] = 2 and [C] =21​ . The reaction proceeds in the : [R=8.314J/K/mol,e=2.718]

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FORWARD direction because Q>K_c`
reverse direction because Q>`K_c`
forward direction because Qreverse direction because Q

Solution :`2A0=294.2J`
R`=8.314.K^(-1).mol^(-1)" "/_\G^(0)=2.303RTlogK_c`
or `294.2=-2.303xx8.314xx300xxlogK_c`
or `K_c`=ANTILOG`(-04342)" or "K_c=0.3679`
`Q=([B][C])/([A]^2)=(2xx1/2)/((1/2)^2)=4`
Here, `Q>K_c`. Thus, the reaction will PROCEED in the backward direction.
10896.

Which one of the following pairs will gives effervescence with aq. NaHCO_(3)? underset((I))(CH_(3)COCl)""underset((II))(CH_(3)COCH_(3)) underset((III))(CH_(3)COOCH_(3))""underset((IV))(CH_(3)COOCOCH_(3))

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I & II
I & IV
II & III
I & III

Solution :Acid chloride and acid anhydride are extremely REACTIVE out of acid derivatives. They react independently with water even in the absence of CATALYST to give carboxylic acid, which will ultimately reacts with `NaHCO_(3)` to give sodium salt of acid and `CO_(2)`. Ester reacts with water in presence of acid catalyst to produce acid. Acetone is inert toward `NaHCO_(3)` solution.
10897.

Which of the following is liberated when cold HCl is treated with KMNO_4?

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`H_(2)`
`Cl_(2)`
`H_(2)O`
`O_(2)`

ANSWER :B
10898.

The various of equivalent conductance of strong electrolyte with sqrt("concentration") is shown in figures below. Which one is correct?

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ANSWER :B
10899.

Which of the following chemical is responsible to produce more foam in shaving soap ?

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SODIUM tartarate
Sodium acetate
Sodium benzoate
Sodium rosinate 

ANSWER :D
10900.

Which of the following lanthanoid ions is diamagnetic ? (At nos Ce = 58, Sm, =62, Eu =63, Yb = 70)

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`Sm^(2+)`
`Eu^(2+)`
`YB^(+)`
`Ce^(2+)`

Solution :`Sm^(2+)(Z=62)`
`[XE]4f^6 - 6 " unpaired " e^- "" Eu^(2+)(Z=63)`
`[Xe]4f^(7)6S^2 -7 " unpaired "e^- ""Yb^(2+)(Z=70)`
`[Xe]4f^(14)6s^(2)-0 " unpaired " e^- "" Ce^(2+)(Z=58)`
`[Xe]4f^1 5d^1 6s^2 -2` unpaired `e^-`only `Yb^(2+)` is diamagnetic .