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18051.

Which one of the following isomeric structures has the lowest energy ?

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SOLUTION :
18052.

When two compounds Acl_(3) and DCl_(3) of two elements A and D are mixed together a compound ADCl_(6) is formed. Structural analysis showed that AdCl_(6) is an ionic compound. Given that DCl_(3) is trigonal planar and Acl_(3) is trigonal pyramidal, predict the shape of the anion DCl_(4)^(-).

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SEE - saw
Perfect TETRAHEDRAL
SQUARE planar
None of these

Answer :B
18053.

Which type of bond is formed by transition metal with a metal ligand, at the time of hybrid ion formation

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lonic
Hydrogen
Co-ordinate
Covalent

ANSWER :C
18054.

Which of the following is similar to graphite ?

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BN
B
`B_4C`
`B_2H_6`

ANSWER :A
18055.

What are the number of atoms per unit cell and the number of nearest neighbours in a bcc structure ?

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`2 , 12`
`4 , 12`
`2 , 8`
`2, 6`

Answer :C
18056.

What is the ratio by weight of NaF and NaI which when dissolved in water produces the same obtained on evaporation of the salt solution is 0.48 g per 100 mL of solution evaporataed. Assume complete dissociation of the salts.

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Solution :Suppose in 100 mL of the solution, NaF = a G and NaI = b a . Then
`a+b=0.48"…(i)"`
`piV=i n R`
For `NaF+NaI` solution in WATER, `"V = 100 mL = 0.1 L, n"=(a)/(42)+(b)/(150)`
`""`(MOL. mass of NaF = `23+19=42,"Mol. mass of NaI"=23+127=150)`
i = 2 (as NaF or NaI on dissociation produce 2 ions)
`therefore""pixx0.1=2xx((a)/(42)+(b)/(150))xx0.0821xxT"...(II)"`
For ureain water, `pi=CRT"(urea is non - electrolyte)"`
`pi=0.1xx0.0821xxT"..(III)"`
Dividing eqn. (ii) by eqn. (iii)
`0.1=(2xx((a)/(42)+(b)/(150)))/(0.1)"or"(a)/(42)+(b)/(150)=(0.01)/(2)=0.005"or"150a+42b=31.5"...(iv)"`
From eqns. (i) and (iv), on solving `a=0.105, b=0.375`
`therefore"Ratio "=(a)/(b)=(0.105)/(0.375)=0.28`
18057.

Which one of the following will from a hydrophobic sol ?

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GUM
Starch
Egg ALBUMIN
FERRIC HYDROXIDE

ANSWER :D
18058.

Which of the following metal is used as a thin foil in cigarate packet?

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AI 
MG 
ZN 
CU 

ANSWER :A
18059.

Which of the following is a direct dye

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Phenolphthalein
Congo red
Alizarin
Indigo

Solution :DIRECT dyes stick to the fibre through hydrogen bonding. They belong to the class of azo dyes. They are USED to dye the fabric DIRECTLY by placing it in aqueous solution of dye e.g. martius yellow, Congored ETC.
18060.

Which of the following is the fastest reaction ?

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`overset(..)uoverset(..)U1/(2)2overset(250^@C)RARR`
`overset(..)uoverset(..)u1/(2)2overset(500^@C)rarr`
`overset(..)uoverset(..)u1/(2)2overset(750^@C)rarr`
`overset(..)uoverset(..)u1/(2)2overset(1000^@C)rarr`

Answer :D
18061.

When phenol is treated with D_(2)SO_(4)//D_(2)O, some of the hydrogens get exchanged. The final product in this exchange reaction is

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SOLUTION :
18062.

Write short notes on the following : (i) Carbylamine reactions . (ii) Gabriel-Phthalimide synthesis

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SOLUTION :(ii) This is USED to prepare `1^@` amine as EXPLAINED below
18063.

When KMnO_4 reacts with l^- in a slightly alkaline and acidic medium, the respective products obtained are

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`MN^(2+) + lO_3^(-) MnO_2^(+) l_2`
`MnO_2 + l_2Mn^(2+) + lO_3^(-)`
`MnO_2 + lO_3^(-) Mn^(2+) + l_2`
`Mn^(2+) + l_2MnO_2 + lO_3^(-)`

ANSWER :C
18064.

The structure of glucose in Haworth projection formula is

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ANSWER :D
18065.

Which of the following polymers can have strong intermolecular forces?

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NYLON
Polystyrene
Rubber
Polyesters

Answer :A::D
18066.

What is a fuel cell ? Give advantages of a fuel cell.

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Solution :Fuel cell. It is a device which DIRECTLY converts SOLAR energy into electrical energy e.g. `H_(2)-O_(2)` fuel cell.
Advantages of fuel cell :
(i) It does not cause pollution
(ii) It has INFINITE life time.
(III) It has an EFFICIENCY of 60-70%.
18067.

What is caused due to deficiency of vitamin H ?

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BONE DEFORMATION
SCURVY
SKIN DISEASE
Anemia

Solution :Skin disease
18068.

Which enzymeis usedin the conversionof sucroseinto glucoseand fructose ?

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ZYMASE
INVERTASE
DIASTASE
Maltase

Answer :B
18069.

Which is least acidic ? SbH_(3), PH_(3), NH_(3), AsH_(3)

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SOLUTION :A compound which is most BASIC is OBVIOUSLY least ACIDIC. Since `NH_(3)` is the most basic compound, therefore, it is least acidic.
18070.

What is the order of reaction whose rate constant has the same units as rate of reaction ?

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SOLUTION :ZERO ORDER
18071.

When neo pentyl bromide is subjected to Wurtz reaction, the product formed is :

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2, 2, 4, 4-tetramethylhexane
2, 2, 4, 4-tetramethylpentane
2, 2, 5, 5-tetramethylhexane
2, 2, 3, 3-tetramethylhexane

SOLUTION :`H_(3)C-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)Br+2Na+Br-CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(3)rarrCH_(3)-underset("2,2,5,5-tetramethylhexane")underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)-CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(3)`
18072.

When a catalyst is added to a system the:

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Equilibrium CONCENTRATION are increased
Equilibrium concentration are unchanged
Rate of FORWARD reaction is increased and that of BACKWARD reaction is decreased
Value of equilibrium constant is decreased

Answer :B
18073.

which of the following act as catalyst?

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<P> `(PH_(3)P)_(3),RECI
 `TiCl_(4) + (C_(2)H_(5))_(3)AI`
`(C_(2)H_(5))_(4)Pb`
`(CH_(3))_(2) ZN`

Answer :A::B
18074.

Which of the following substance can be used directly as feriliaer?

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`(NH_(4))_(2)SO_(4)`
`Ca_(3)(PO_(4))_(2)`
`Ca(H_(2)PO_(4))_(2)`
`CaCN_(2)+C`

SOLUTION :`Ca_(3)(PO_(4))_(2)` : It is a TERTIARY phophate and not soluble in water hence it is of no USE for plants.
18075.

Which substances chars when warmed with conc H_2SO_4 ?

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Protein
Fat
Hydocarbon
Carbohydrate

Answer :D
18076.

Which complex has square planar structure?

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`NI(CO)_4`
`[NiCl_4]^(2-)`
`[Ni(H_2O)_6]^(2+)`
`[Cu(NH_3)_4]^(2+)`

ANSWER :D
18077.

What organic compound is obtained when ethyl bromide reacts with aq. NaOH solution?

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SOLUTION :When ethyl bromide REACTS with AQ. NAOH ethyl alcohol is obtained.
`CH_3CH_2Br OVERSET(aq. NaOH)rarr CH_3CH_2OH+NaBr`
18078.

Write the Nernst equation and Cell reaction of the following cell Zn|Zn^(2+)(0.01)M)||Cu^(2+)(0.01)M)|Cu

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Solution :`ZntoZn^(2+)+2E`
`Cu^(2+)+2etoCu`
`Zn+Cu^(2+)TOZN^(2+)+Cu` ( CELL reaction )
NERNST equation for the above cell reaction is
`E_("cell")=E_("cell")^(@)+(0.0591)/(2)LOG""([Cu^(2+)])/([Zn^(2+)])`
`E_("cell")=E_("cell")^(@)+(0.591)/(2)log""(0.01)/(0.01)`
`E_("cell")=E_("cell")^(@)+zero`
`E_("cell")=E_("cell")^(@)`
18079.

What is a simple salt?

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SOLUTION :A SIMPLE salt is ONE that contains one BASIC radical and one acid radical.
18080.

What are glycosidic linkages? In which type of biomolecules are they present ?

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Solution :The oxide linkage formed between two or more units of MONOSACCHARIDES by the loss of water MOLECULE is CALLED GLYCOSIDIC linkage. The glycosidic linkages are PRESENT in carbohydrates.
18081.

Which of the following reaction is/ are correct?

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`PhNO_(2)overset(LAH)rarr PhNH_(2)`
`PhNO_(2)overset(NaSnO_(2))underset(+NaOH)(rarr)Ph-N=N-Ph`
`PhNO_(2)overset(Na_(3)AsO_(3)+NaOH)(rarr)Ph-overset(o+)underset(O^(ɵ))underset(.|)(N)=N-Ph`
`PhNO_(2)overset(Al-Hg//H_(2)O)(rarr)Ph-NH-NH-Ph`

Solution : B. ` Ph-N = N - Ph ` (Azohenzene)
d. ` PhNHOH` (Phenyl hydroxyl) amine )
18082.

Which of the following structure is enantiomeric with the molecule (A) given below :

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`(a), (b), (C),(d)`
`(a), (b), (c)`
`(b), (c), (d)`
`(a), (c), (d)`

Solution :CARBON with four DIFFERENT GROUP attached to it is ASYMMETRIC
18083.

Which of these species has a standard enthalpy of formation equal to zero

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`F_(2)(G)`
F(g)
HF(aq)
`F^(-)`(aq)

ANSWER :A
18084.

The reducing power of divalent species decrease in the order

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`GegtSngtPb`
`SngtGegtPb`
`PbgtSngtGe`
NONE of these

Solution :The STABILITY of +2 O.S follows the ORDER`PB^(2+)gtSn^(2+)gtGe^(2+)`
HENCE reducing power,`GegtSngtPb`
18085.

Which product is obtained when chlorobenzene react with NaCN in presence of Cu_(2)(CN)_(2) at 473 K temp and high pressure ?

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PHENYL cynide
PHENOL
Both (A) and (B)
2,4 dinitro phenol

ANSWER :A
18086.

Which of the following acids is a vitamin?

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ASPARTIC ACID
Ascorbic acid
ADIPIC acid
Saccharic acid

Solution :Ascorbic acid is vitamin C. Its structure is
18087.

What are anti fertility drugs? Give examples.

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SOLUTION :ARTIFICIALLY drugs are chemical substances which suppress the action of hormones that promote pregnancy. These drugs actually reduce the chances of pregnancy and ACT as a protection. Antifertility drugs are MADE up of derivatives of synthetic progesterone or a combination of derivatives of oestrogen and progesterone.
Example : Ethynylestradiol, menstranol and norethynodrel etc.
18088.

Which of the following methods yield saturated hydrocarbons

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`RCH=CH_2underset((ii)CH_3COOH)OVERSET((i)BH_3) to `
`CH_2=CH-Roverset(CH_2N_2)to `
`Br-CH_2-CH_2-CH_2-CH_2-CH_2-Br underset(Delta)overset"Na/Ether"to `

SOLUTION :
HENCE, in all these reactions, saturated HYDROCARBONS are PRODUCED .
Hence, choices (a),(b), ( c ) and (d) are correct.
18089.

Which of the following statement is /are correct regarding nucleus of an atom ?

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As number of protons increases in the nucleus, the number of neutrons REQUIRED for overcoming proton-proton repulsions also increase.
Projectile capture reactions involving proton as projectile can occur with slow moving proton also.
When `._(92)^(235) U ` undergoes FISSION reaction to from `._(36)Kr^(90) & ._(56)Ba^(142)` four neutrons are produced per Uraninum atom.
Gamma radiations can be emitted only along with `alpha ` or `beta` - decay and not alone.

Solution :(A) THEORY base
(B) slow moving proton will not capture by the nucleus becose it will be repal be the nucleus
(C) `._(92)^(235)U+._(0)n^(1) rarr .-(36)Kr^(90) +._(56)Ba^(142)+4_(0)n^(1)`
(D) nucleus always release `gamma` ray during `alpha` , `beta` decay.
18090.

Which is the correct representation for Nernst equation :

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`E_(RP) =E_(RP)^@ +_n^(0.059) LOG [OXIDANT]/[reductant]`
`E_(OP)=E_(OP)^@+_n^(0.059)log[oxidant]/[reductant]`
`E_(OP)=E_(OP)^@+_n^(0.59)log[Reductant]/[oxidant]`
All of these

Answer :D
18091.

The term fools gold is used for a mineral which shines likes gold . It is :

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IRON PYRITE
COPPER glance
Cinnabar
CADMIUM sulphide

Answer :A
18092.

Which of the following sequences helps to establish the structure and configuration of maltose?

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oxidation, methylation and hydrolysis
methylation, hydrolysis and oxidation
hydrolysis, oxidation and methylation
oxidation, hydrolysis and methylation

Solution :`(+) -` MALTOSE contain two `D - (+) -` glucose units, joined by an alpha - glucoside linkage between the carbonyl group of one `D - (+) -` glucose and an `-OH` group of the other.
Now two questions remain UNANSWERED: Which`-OH` group is involved, and what are the sizes of the RINGS in the two `D- (+)-` glucose units? ANSWERS to both these questions are given by the sequence of oxidation, methylation, and hydrolysis.
18093.

Which out of the following does not dissolve in dilute HCl ?

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ZnS
MnS
`BaCO_3`
`BaSO_4`

ANSWER :D
18094.

Which among the following order of given properties is correct

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`HOClgtHClO_(2)gtHClO_(3)gtHClO_(4)` - oxidising NATURE
`ClgtFgtBrgtI` - electron affinity
`Cl_(2)gtBr_(2)gtI_(2)gtF_(2)` - bond dissociation energy
`HFltHClltHBrltHI` - ACIDIC nature

Answer :C
18095.

What reagent is used in Hinsberg test of amines?

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`(CH_(3)CO)_(2)O` and PYRIDINE
`C_(6)H_(5)SO_(2)CL` in aq. NaOH
`NaNO_(2)` in aq. `H_(2)SO_(4)`
`CH_(3)I` (excess) FOLLOWED by AgOH

Answer :B
18096.

Which of the following is an example of Emulsion?

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MAYONNAISE
shaving cream
fumes
paint

SOLUTION :mayonnaise
18097.

What conclusion may be drawn from the following results of (a) and (b) ? (a) If a 1 xx 10^(-3) kg body is travelling along the x-axis at 1 m/s within 0.01m/s. Calculate the theoretical uncertainty in its position. (b) If an electron is travelling at 100 m/s within 1m/s, calculate the theoretical uncertainty in its position. [h= 6.63 xx 10^(-34)J.s, mass of electron =9.109 xx 10^(-31)kg]

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Solution :(a) The velocity has an uncertainty of 0.02m/s. (from 0.99 to 1.01 m/s)
`therefore Delta x= (h)/(4pi m Delta v)= (6.63 xx 10^(-34) (J.s))/((4 xx 3.14) (1 xx 10^(-3) kg) (0.02m//s))`
`=3 xx 10^(-30)` metre
(B) `Delta x= (6.63 xx 10^(-34) (J.s))/((4 xx 3.14) (9.109 xx 10^(-31)kg) (2m//s))`
`~~3 xx 10^(-5)` metres
18098.

Which of the following combination of aldehydes gives cross Cannizzaro reaction?

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`CH_(3)CHO,HCHO`
`C_(6)H_(5)CHO,CH_(3)CHO`
`C_(6)H_(5)CHO,HCHO`
all of these

Solution :Both the aldehydes should not have `ALPHA`-HYDROGENS, i.e., `C_(6)H_(5)CHO and HCHO`.
18099.

What is obtained by the oxidation I^(-) with MnO_(4)^(-) in alkaline solution?

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`IO_(4)^(-)`
`IO_(3)^(-)`
`I_(2)`
`IO_(2)^(-)`

ANSWER :B
18100.

What is meant by Faraday ? How is it calculated ?

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Solution :One Faraday is defined as the charge of one mole of electron.
Charge of one electron = `1.6 xx 10^(-19)` C
Charge of 1 mole of electrons = `6.023 xx 10^(23) xx 1.602 xx 10^(-19)` C
`= 6.023 xx 10^(21) xx 1.602 xx 10^(-19) C`
`= 96488 C`
i.e., ` 1 F = 96500 C`