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21751.

Which of the following is very strongly acidic oxide?

Answer»

<P>`P_(2)O_(5)`
`Al_(2)O_(3)`
`Cl_(2)O_(7)`
`B_(2)O_(3)`.

Answer :C
21752.

When isobutyl bromide in dry ether is treated with absolute ethyl alcohol, the products formed are

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`CH_3-UNDERSET(CH_3)underset|CH-CH_2OH` and `CH_3CH_2MgBr`
`CH_3-undersetunderset(CH_3)|CH-CH_2-CH_2-CH_3` and Mg(OH)Br
`CH_3-underset(CH_3)underset(|)CH-CH_3` and `CH_3-CH_2OMgBr`
`CH_3-undersetunderset(CH_3)|CH-CH_3, CH_2=CH_2` and Mg(OH)Br

Solution :`CH_3-undersetunderset(CH_3)(|)CH-CH_2-Mg-Br+C_2H_5OH to underset"ISOBUTANE"(CH_3-undersetunderset(CH_3)(|)CH-CH_3)+underset"ETHOXY magnesium bromide"(C_2H_5OMgBr)`
21753.

Zeolites :

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Are microporous aluminosilicates
Have general formula `M_(x//n) [(A//O_2)_x(SiO_2)_4] mH_2O`
Have PORE size between 260 PM to 740 pm
All

Answer :D
21754.

Which forms interstitial compounds ?

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Fe
Co
Ni
All

Answer :D
21755.

Which of the following is allylic halide ?

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Benzyl CHLORIDE
(1-bromo ethyl) BENZENE
1-bromo benzene
3-chloro CYCLO hex-1-ene

ANSWER :D
21756.

When bromination of anilineis carried out byprotecting -NH_(2). The product is

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o-bromonailine
2,4,6- TRIBROMOANILINE
m-bromoaniline
p-bromoanilie

ANSWER :D
21757.

Which is the most basic of the following oxides:

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`Na_2O`
BAO
`Al_2O_3`
`As_2O_3`

ANSWER :A
21758.

Which loses weight on exposure to the atmosphere ?

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CONC. `H_2SO_4`
NaOH
Anhyd.`AlCl_3`
SATURATED AQUEOUS SOLUTION of `CO_2`

ANSWER :D
21759.

Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. {:("(i) "(CH_(3))_(2)CHNH_(2), " (ii) "CH_(3)(CH_(2))_(2)NH_(2)), ("(iii) "CH_(3)NHCH(CH_(3))_(2)," (iv) "(CH_(3))_(3)CNH_(2)), ("(v) "C_(6)H_(5)NHCH_(3)," (vi) "(CH_(3)CH_(2))_(2)NCH_(3)), ("(vii) "m-BrC_(6)H_(4)NH_(2).," "):}

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Solution :IUPAC names ALONGWITH the classification (primary, secondary and tertiary) of the compounds are given below :
(i) Propan-2-amine `(1^(@))`, (II) Propanamine `(1^(@))`, (III) N-Methylpropan-2-amine `(2^(@))`, (iv) 2 Methylpropan-2-amine `(3^(@))`, (V) N-Methylbenzenamine or N-Methyllaniline `(2^(@))`, (vi) N-Ethyl-N-methylethanamine `(3^(@))`, (vii) 3-Bromobenzenamine or 3-Bromoaniline `(1^(@))`.
21760.

Which one of the following pairs gives effervescence with aq. NaHCO_(3)?

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I and IV
I and III
I and II
II and III

Answer :A
21761.

Which shows inert pair effect ?

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B
Al
Tl
Sc

Answer :C
21762.

Write the principle of method used for the refining of germanium.

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Solution :Refining of germanium is DONE by zone refining. The principle of the METHOD is the impurities are more soluble in the melt than in the solid state of the method. A circular mobile heater is moved along the impure metal rod. As the heater MOVES forward, the pure metal CRYSTALLISES out of the melt.
21763.

tripositive actinides ions are

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with three PROTONS
with three NEUTRONS
with three electrons
with three electrons less than its atomic NUMBER

Answer :D
21764.

What is the function of anhydrous ZnCl2 in Lucas test for distinction between 1^(@) , 2^(@) and 3^(@) alcohols?

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Solution :The REACTION of alcohol with HCl UNDERGOES `SN_2` path way to form chloroalkane. `Cl^(o-)` is not a GOOD nucleophile and in alcohol, -OH is a bad leaving group. Thus, the reaction is carried out in presence of `ZnCl_2` . Since, `ZnCl_2` is a LEWIS acid, it forms a complex with oxygen of alcohol and converts the -OH to a better leaving group, THEREBY leading to the formation of chloroalkane.
21765.

Ultraviolet light of 6.2 eV falls on aluminium surface (work function = 4.2 eV). The kinetic energy (in joule) of the fastest electron emitted is approximately:

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`3xx10^(-21)`
`3xx10^(-19)`
`3xx10^(-17)`
`3xx10^(-15)`

ANSWER :B
21766.

Which one of the following types of drugs reduces fever ?

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Analgesic
Antipyretic
Antibiotic
Tranquilizer

Answer :B
21767.

Which of the following do not have tendency to act as ligands during complex formation?

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`BiH_(3)`
`PH_(3)`
`AsH_(3)`
`SbH_(3)`

Answer :A::C::D
21768.

Vapour density of a gas is 22. its molecular weight will be :

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33
22
44
11

Answer :C
21769.

The viscosity of molten sodium is 4.5 xx 10^(-4) Nm^(-2)sat 473 K and 2.12 xx 10^(-4) Nm^(-2) s at 873 K. Calculate the activation energy for the viscous flow. Also, calculate the viscosity at 673 K.

Answer»

Solution :We have,
`log eta_(1)/eta_(2) = E/(2.303 R) ((T_(2)-T_(1))/(T_(1)T_(2)))`
`log(4.5 xx 10^(-4))/(2.12 xx 10^(-4)) = E/(2.303 xx 8.314) ((873-473)/(473 xx 873))`
E=6461 J/mole
=6.461 kJ/mole
Further, let the viscosity at 673 K be `eta_(2)`
Again, we have, `T_(1) = 473 K, eta_(1) = 4.5 xx 10^(-4)`
`T_(2) = 673 K, eta_(2)`= ?
`log (4.5 xx 10^(-4))/eta_(2) = 6461/(2.303 xx 8.314) ((673-473)/(473 xx 673))`
`eta_(2) = (2.76 xx 10^(-4) Nm^(-2)s)`
21770.

What is the maximum mass of H_(2)O (in gm) which can be obtained if total 42 gm of propyne & oxygen are subjected to combusion ?

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Solution :`{:(C_(3)H_(4(G)),+,4O_(2(g)),to,3CO_(2(g))+2H_(2)O_((l))),((40 GM)/(1/4"mole"),,128 gm,,1/2 "mole" =9 gm):}`
168 gm mixture should have 40 gm psopyne
42 gm mixture should have `40/168 xx42=10 gm`
21771.

The term (-dC/dt) in rate equation refers to:

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The CONCENTRATION of a reactant
The DECREASE in concentration of the reactant with time
The VELOCITY CONSTANT of reaction
None

Answer :B
21772.

Which of the following reagents could be used to distinguish aniline from methanamine ? Bromine water CHCl_(3) and aqueous KOH Dilute HCl Nitration mixture under heated condition

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(i) only
(i) and (II)
(i) and (III)
(i) and (IV)

Solution :When bromine water is added to aniline at room temperature decolourisation of the bromine water OCCURS and a white ppt. of 2,4,6-trinbromoaniline is obtained.

White ppt.
Methanamine do not react with bromin water.
21773.

Which of the following is an example of nucleophilic addition reaction

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`CH-=CH+H_(2) OVERSET(Pd//BaSO_(4).S)to CH_(2)=CH_(2)`
`CH-=CH+H_(2)O overset(HG^(2+)//H_(+))to CH_(3)CHO`
`CH-=CH+H_(2)O to CH_(2)-CHBr_(2)`
`CH-=CH+CH_(3)COOH overset((CH_(3)COO)_(2)Mg)to CH_(3)-CH(OOC CH_(3))_(2)`

Solution :Addition of water and acetic acid to acetylene are examples of nucleophilic addition reactions. Addition of `H_(2)(Pd//BaSO_(2)-S)` and HBr to acetylene are EXAMPLE of electolphilic addition reactions.
21774.

Which one of the following is the hybridised state of C atoms in carbonyl carbon?

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SP
`sp^3 d`
`sp^3`
`sp^2`

SOLUTION :`sp^2`
21775.

The transition metals have a less tendency to form ions due to

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HIGH IONISATION energy
Low HEAT of HYDRATION of ion
High heat of sublimation
All of these

Answer :D
21776.

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH_(3) dissolves O and gives an intense blue solution. The final solution contains

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`[Pb(NH_(3))_(4)]^(2+)` and `[CoCl_(4)]^(2-)`
`[Al(NH_(3))_(4)]^(3+)]` and `[Cu(NH_(3))_(4)]^(2+)`
`[Ag(NH_(3))_(2)]^(+)` and `[Cu(NH_(3))_(4)]^(2+)`
`[Ag(NH_(3))_(2)]^(+)` and `[Ni(NH_(3))_(6)]^(2+)`

Answer :C
21777.

Urea is

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Monoacidic base
Diacidic base
Neutral
Anmphoteric

Solution :UREA BEHAVES as a monoacidic base and react with NITRIC acid and FORM sparingly coluble NITRATE.
21778.

Vapour density of a gas having formula[CO]_x is 70. Find out X

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3.5
4.5
5
6

Answer :C
21779.

Write the IUPAC name of the compound : CH_(3)-underset(OH)underset("|")"CH"-CH_(2)-COOH

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SOLUTION :IUPAC name of the COMPOUND is
`underset("3 - Hydroxybutanoic acid")(overset(4)(CH_(2))-underset(OH)underset("|")overset(3)("CH")-overset(3)(CH_(2))-overset(1)(COOH))`
21780.

The stabilisation of coordination compounds due to chelation is called the chelate effect. Which of the following is the most stable complex species ?

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`[CoCl_(6)]^(4-)`
`[Fe(SCN)_(6)]^(3-)`
`[Fe(C_(2)O_(4))_(3)]^(3-)`
`[Fe(H_(2)O)_(6)]^(3+)`

Answer :C
21781.

Whatare differenttypesof RNAwhichor foundin cell ?

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SOLUTION :RNA molecules areclassifiedaccordingto theirstructureand functioninto three majortypes.
(i) RibosomalRNA(r- RNA)
(ii ) MessengerRNA ( m - RNA)
(III) TransferRNA (t- RNA) .
r- RNA : rRNAis mainlyfoundin cytoplasmand in ribosomes,whichcontain 60 %RNAand 40%PROTEIN. Ribosomesare the sitesat whichproteinsynthesistakes place.
t- RNA : tRNAmolecules havelowestmolecularweightof all nucliecacids . Theyconsist of 73-94 nucleotides in a SINGLECHAIN . The functionof tRNA is to carryanimoacidsot the sitesof proteinsynthesis onribosomes .
m - RNA: mRNAis presentin smallquantityand very short lived. Theyare singlestranded,and theirsynthesistakesplace onDNA . Thesynthesis of mRNA form DNA strandiscalledtransciption . mRNAcarriesgenticinformationform DNAto theribosomes forprotein synthesis.
21782.

What are essential and non-essential amino acids ? Give two examples of each.

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Solution :ESSENTIAL amino acids are those which are not produced in our BODY and required to be supplied from OUTSIDE, e.g., VALINE , leucine.
Non-essential amino acids are those which are produced by our body, e.g., glucine , ALANINE.
21783.

When the pressure and absolute temperature of 5L nitrogen are doubled, the gas would have a volume of :

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10L
5L
15L
20L

Solution :`p_(1) =p`, `p_(2) = 2p`,
`T_(1) = T, T_(2) = 2T`,
`V_(1) = 5L, V_(2) = ?`
`( \p_(1) V_(1))/( T_(1))= ( p _(2) V_(2))/( T_(2))`
or `V_(2) = ( p_(1) V_(1) T_(2))/( T_(1) p _(2))`
`= ( p XX 5 xx 2T )/( T xx 2p ) = 5L`
21784.

What happens when KCIO_3 reacts with cone. H_2SO_4?

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SOLUTION :`ClO_2` GAS is EVOLVED.
`3KClO_3 + 3H_2SO_4 RARR 3KHSO_4+ 2ClO_2 + HClO_4 +H_2O`
21785.

which among the following minerals does not contain aluminium?

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Cryolite
SIDERITE
China clay
Corundum

Solution :Siderite
21786.

Which one is oleum?

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`H_(2)S_(2)O_(7)`
`H_(2)S_(2)O_(5)`
`H_(2)SO_(3)`
`H_(2)S_(2)O_(6)`

ANSWER :A
21787.

Write IUPAC name of the following compound: m-NC-C_6 H_4 -NH_2.

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SOLUTION :3-Cyanobenzenamine or 3-Aminobenzenenitrile.
21788.

What will be the octane no. of best fuel

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80
81
74
65

Solution :The BEST fuel is that which has GREATEST OCTANE number and thus (B) OPTION is correct
21789.

The surface tension of toluene at 298 K is 0.0284 Nm^(-1)and its density is 0.866 g/cc. What is the largest radius of the capillary that will permit the liquid to rise 2 xx 10^(-4) m? Assume theta =0 .

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ANSWER :`3.34 XX 10^(-4) m`
21790.

The VA group elements are present in the Earth's crust as

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Nitrates
Phophates
CARBONATES
Sulphates

Solution : Sources of VA group elements in earth.s crust are nitrates and Phophates like `Mg_(3)N_(2), Ca_(3)(PO_4)_2`PHOSPHATE rock.
21791.

Which of the following aqueous solutions containing 10g of solute in each case, has highest melting point?

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NACL solution
KCl solution
SUGAR solution
GLUCOSE solution

Answer :C
21792.

The strongest bronsted base is:

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`CIO^-`
`CIO_3^-`
`CIO_2`
`CIO_4^-`

ANSWER :A
21793.

Unit of electrochemical equivalent is kg/Faraday. Is it true or false?

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SOLUTION :gram/coulomb
21794.

To determine the elevation of boiling point more accurately. The solvent area should take

Answer»

higher value of `K_(B)`
LOWER value of `K_(b)`
HIGH molar mass
low molar mass

Solution :The solvent with higher value `K_(b)` will give larger value of `Delta T` for the solution of GIVEN MOLALITY, hence comparatively more accuracy.
21795.

Which is not true about the voids formed in three dimensional hexagonal close-packed structure-

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a tetrahedral void is formed when a sphere of the second layer is PRESENT above TRIANGULAR void in the first layer
all the triangular voids are not covered by the spheres of the second layer
tetrahedral voids are formed when the triangular voids in the second layer LIE above the triangular voids in the first layer and the triangular shapes of these voids do not overlap
octahedral voids are formed when the triangular voids in the second layer EXACTLY overlap with SIMILAR voids in the first layer

Answer :C::D
21796.

The reagents A, B and C respectively are

Answer»

`H_(2)//Pd`, PCC, `NaBH_(4)`
`NaBH_(4)`, alk. `KMnO_(4)`, `H_(2)//Pd`
`NaBH_(4)`, PCC, `H_(2)//Pd`
`H_(2)//Pd`, alk. `KMnO_(4)`, `NaBH_(4)`

Solution :(b):
`:.` A = `NaBH_(4)`, B = alk. `KMnO_(4)` and C = `H_(2)//Pd`. `NaBH_(4)` does not REDUCE double bond. However, CATALYTIC hydrogenolysis `(H_(2)//Pd)` reduces both double bond and the carbonyl group.
21797.

The sequence of bases on RNA molecules synthesized on the GCATA strand of DNA is :

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CGUAU
CGTAT
TACGC
AYCGC.

Answer :A
21798.

Which of the following is most easily hydrolysed amongst the following

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`SF_(6)`
`NF_(3)`
`C Cl_(4)`
`TeF_(6)`

SOLUTION :`TeF_(6)` undergoes hydrolysisto form `Te(OH)_(6)`. `SF_(6)` does not HYDROLYSE because ofits compact symmetrical structure.
21799.

The toal number of structural isomeric alcohols having the molecular C_(5)H_(12)O is.

Answer»


SOLUTION :Eight (8) ISOMERS are:
(i) `CH_(3)CH_(2)CH_(2)CH_(2)CH_(2)OH(1^(@)),`
(ii) `CH_(3)CH_(2)CH_(2)-CHOH-CH_(3)(2^(@))`,
(iii) `CH_(3)CH_(2)-CHOH-CH_(2)CH_(3)(2^(@)),`
(IV) `CH_(3)CH_(2)-overset(CH_(3))overset(|)(C)H-CH_(2)OH(1^(@))`
(v) `CH_(3)-overeset(CH_(3))overset(|)(C)H-CH_(2)CH_(2)OH(1^(@))`
(vi) `CH_(3)-underset(OH)underset(|)overset(CH_(3))overset(|)(C)-CH_(2)CH_(3)(3^(@))`
(vii) `CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)OH(1^(@))`
(viii) `CH_(3)-overset(CH_(3))overset(|)(C)H-overset(OH)overset(|)(C)H-CH_(3)(2^(@))`.
21800.

Which one of the following compounds is not aromatic -

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SOLUTION :Cyclooctatetraene is a tub-shaped compound and THUS it is NON -aromatic.