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21651.

Which one of the following nitro compounds does not react with nitrous acid

Answer»

`CH_3-CH_2-CH_2-NO_2`
`(CH_3)_2CH-CH_2NO_2`
`(CH_3)_3CNO_2`

ANSWER :C
21652.

Which of the following square planar complexes has two geometrical isomers ?

Answer»

`MA_(4)`
`MA_(3)B`
`MABCD`
`MA_(2)B_(2)`.

ANSWER :B
21653.

total number of isomeric alcohols (excluding stereoisomerism) with formula C_5H_12O is

Answer»

5
6
7
8

Answer :D
21654.

Which of the following carboxylic acids is most reactive towards esterification?

Answer»

`(CH_(3))_(3)"CC"OOH`
`(CH_(3))_(2)CHOOH`
`CH_(3)CH_(2)COOH`
`(C_(2)H_(5))_(2)CHCOOH`

Solution :Bulkier group the site of reaction, slows down esterification reaction.
21655.

Vitamin C is chemically known as :

Answer»

Tartaric ACID
CITRIC acid
Ascorbic acid
Aspartic acid .

ANSWER :C
21656.

The value of rate constant of a pseudo first order reaction _________.

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Independent on the concentration of reactants present in SMALL amount
Depends on the concentration of reactants present in EXCESS
Independent of the concentration of reactants
Depends only on temperature.

ANSWER :B
21657.

Write IUPAC names of the following : [Pt(NH_(3))_(6)]Cl_(4)

Answer»

SOLUTION :HEXAAMMINEPLATINUM(IV) CHLORIDE.
21658.

Which forces are involved in holding the drugs to the active site of enzymes ?

Answer»

Solution :One or more of hydrogen BONDING, ionic bonding, dipole-dipole interactions and van DER Waals. interactions are involved in binding the DRUGS to ACTIVE SITE.
21659.

Which one of the following pairs is mismatched

Answer»

Fossil fuel BURNING - release of `CO_2`
NUCLEAR power -RADIOACTIVE wastes
Solar energy -Greenhouse effect
Biomass burning -release of `CO_2`

Solution :Solar energy is not RESPONSIBLE for green house effect instead it is a source of energy for the PLANTS and animals
21660.

Write two differences between physisorption and chemisorption.

Answer»

SOLUTION :
21661.

Which gains electrons more easily :

Answer»

HYDROGEN
`NA`
`K`
`MG`

ANSWER :A
21662.

The vapour pressure of a dilute solution of a solute is NOT influenced by

Answer»

temperature of SOLUTION
melting point of solute
mole FRACTION of solute
degree of DISSOCIATION of solute

Solution :Vapour pressure of a solution INCREASEIN mole fraction of solute and decreases with degree of dissociation of solute.
21663.

Which of the following is incorrect order ?

Answer»

`CH_(3)^(-) gt CH_(3)O^(-) gt HO^(-) gt H_(2)O` ( Nucleophilicity in protic solvent )
`Cl^(-) gt CH_(3) COO^(-) gt CH_(3) O^(-) gt NH_(2)^(-)` ( Leaving group ability )

`CH_(3) - CH_(2) - F gt CH_(3) - CH_(2) - Cl gt CH_(3) - CH_(2) - Br gt CH_(3) - CH_(2) - I` ( Boiling point )

Answer :D
21664.

Which of the following is not a thermoset:

Answer»

Glyptals
Bakelite
Melamine - FORMALDEHYDE POLYMER
Styrene-butadiene rubber

Answer :D
21665.

Which one is a 1^(@) carbocation of the following

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`CH_(3)OVERSET(+)(C)H_(2)`
`CH_(3)overset(+)(C)H-C_(2)H_(5)`
`(CH_(3))_(2)overset(+)(C)H`
`(CH_(3))_(3)overset(+)(C)`

Answer :A
21666.

To prepare solution of certain substance, 300 gm is used for 25% solution and 400 gm for 40% solution, then what is the mass percentage of solute present in this solution mixture ?

Answer»

`33.57`
`66.43`
`87.23`
`19.24`

Solution :In solution - 1, mass of solute `= (25)/(100)xx300=75` gm
In solution - 2, mass of solute `=(40)/(100)xx400=160` gm
So, total mass of solute on MIXING two solution is= 235 gm
So, total mass of solution = 700 gm
So, % solute PRESENT in final solution
`= (235)/(700)xx100=33.57%`
21667.

Which compound will not give the Tollen's test ?

Answer»




Solution :Compound GIVEN in option(a) ,(b) and (d)to not have any HEMI ACETAL group so can't oxidised by TOLLEN's reagent and will not give Tollen's test.
21668.

Which of the following statementsis correct for covalent bonds

Answer»

Electrons are shared between TWO atoms
it MAY be polar or non-polar
Direction is non-polar
Valency electrons are attracted

Solution :NaH and `CaH_(2)` are ionic HYDRIDE an `B_(2)H_(6)` and `NH_(3)` covalent hydride.
21669.

The relative acidities of various organic compounds are .....

Answer»

`RCOOH GT ArOH gt H_2O gt ROH gt RC -= CH`
`RC -= CH gt ArOH gt ROH gt H_2O gt RCOOH`
`ROH gtR -= CH gt ArOH gt RCOOH gt H_2O`
`H_2O gt ROH gt RCOOH gt ArOH gt RC -= CH`

Solution :`RCOOH gt ArOH gt H_2O gt ROH gt RC -= CH`
21670.

Whichof the followingis most acidic

Answer»

`CH_(3) CHCH= CH_(2)`
`H_(3) C- underset( CH_(3))underset(|)(C H) CH_(2) C= CH`
`H_(3) C- underset(CH_(3))underset(|)(C H )HC= CH`
`H_(3)C underset(CH_(3) ) underset(| ) (C H)CH_(2) CH_(2) CH_(3)`

ANSWER :C
21671.

Which of the aldehyde is most reactive

Answer»

`C_(6)H_(5)-CHO`
`CH_(3)CHO`
`HCHO`
All the equally reactive

Solution :AMONG Carbonyl Compounds, reactivity decrease with INCREASE in alkyl groups as alkyl groups `(+I` effect) decrease positive character on C-atom. Thus, the correct order of reactivity is, `HCHO gt CH_(3)CHO gt C_(6)H_(5)CHO`
21672.

Use the relationship DeltaG^@= -nF E_(cell)^@ to estimate the minimum voltage required to electrolyse Al_2O_3 in the Half-Heroult process. DeltaG_f^@(Al_2O_3)= -1520 kJ mol^(-1) , DeltaG_f^@(CO_2)= -394 kJ mol^(-1) Show that the oxidation of the graphite anode to CO_2 permits the electrolysis to occur at a lower voltage than if the electrolysis reactions were Al_2O_3to2Al+3O_2

Answer»


Solution :1.6 V in Hall-Heroult process
Net reaction in Hall-Heroult process is :
`3C+2Al_2O_3 to 4Al +3CO_2`
or `4Al^(3+)12E^(-)to 4Al`, number of electrons (n)=12
`DeltaG^@ =3 DeltaG_f^@(CO_2)-2DeltaG_f^@(Al_2O_3)`
`=3xx394-2(-1520)=1858 kJ`
`DeltaG^@=-nFE_(cell)^@` ltbgt `-E_(cell)^@=(DeltaG^@)/(nF)=(1858xx1000)/(12xx96500)=1.60 V`
For the reaction `Al_2O_3 to 2Al+3O_2`
`DeltaG^@=`1520 kJ
`2Al^(3+)+6e^(-)to2Al, n=6`
`-E_(cell)^@=(DeltaG)/(nF)=(1520xx1000)/(6xx96500)=2.62` V
Thus Hall-Heroult process takes place at lower voltage.
21673.

Write the structures of the major organic product in each of the following: (CH_3)_3CBr + KOH underset("heat")overset("ethanol")(rarr).

Answer»

SOLUTION :`CH_3-UNDERSET(CH_3)underset(|)(C )=CH_2`
21674.

Which of the following will show geometrical isomerism :

Answer»




ANSWER :D
21675.

The solubility product of a salt having the formula M_(2)X_(2) is 1xx10^(-20). If the solubility of another salt having formula M_(2)X is twice the molar solubility of M_(2)X_(2), the solubility product of M_(2)X is:-

Answer»

`32xx10^(-12)`
`9.16xx10^(-5)`
`4.58xx10^(-5)`
`2.75xx10^(-18)`

ANSWER :A
21676.

Which out of gold sol and gelatin in water sol is a lyophilic sol?

Answer»

SOLUTION :GELATIN in WATER
21677.

Which of the following represents an E isomer?

Answer»




ANSWER :C
21678.

Which is correct for 18 crown-6

Answer»

it has FORMULA `C_12H_24O_6`
the number 18 represents the no. of carbon and OXYGEN atoms in it.
the number SIX represents the no. of oxygen ATOM
all the above

Solution :See the Nomenclature of CYCLIC ehters.
21679.

Which of the following is a primary halide?

Answer»

ISOPROPYL iodide
sec-butyl iodide
tert-butyl bromide
neohexyl chloride

Answer :D
21680.

X is

Answer»




SOLUTION :
21681.

Which of the following combination gives homocyclic unsaturated product ?

Answer»

(II)(ii)(S)
(III)(IV)(S)
(II)(iv)(S)
(IV)(iii)(Q)

SOLUTION :
21682.

To purify fluorine gas, fumes of HF are removed by

Answer»

SOLID NaF
`H_(2)` gas
Solid `KHF_(2)`
None of these

SOLUTION :Solid NaF is used to purify fluorine i.e. by removing of HF fumes.
21683.

Which among the following phenolic compounds is most acidic in nature?

Answer»

p-aminophenol
PHENOL
m-nitrophenol
p-nitrophenol

ANSWER :D
21684.

Which among the following solutions is NOT used in determination of the cell constant?

Answer»

`10^(-2)` M KCl
`10^(-1)` M KCl
1 M KCl
SATURATED KCl

SOLUTION :Saturated KCl.
21685.

Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?

Answer»

Acetyl chloride/pyridine followed by reaction with conc. `H_(2)SO_($)+conc.HNO_(3)`
ACETIC anhydride/pyridine followed by conc. `H_(2)SO_(4)+conc.HNO_(3)`.
Dil. HCL followed by reaction with conc. `H_(2)SO_(4)+conc.HNO_(3)`
Reaction with conc. `HNO_(3)+conc.H_(2)SO_(4)`.

Solution :
(c) `C_(6)H_(5)NH_(2)overset(Dil.HCl)to C_(6)H_(5) overset(+)(N)H_(3)underset(+conc.H_(2)SO_(4))overset(conc.HNO_(3))tom-NO_(2)-C_(6)H_(4)-overset(+)(N)H_(3)`
(d) With conc. `HNO_(3)+conc.H_(2)SO_(4)`, aniline is oxidised to form tarry products.
thus, options (a) and (B) are correct.
21686.

Which one of the following is used to reduce fever and prevent platelet coagulation?

Answer»

ANTIBIOTIC
ANTISEPTIC
ANTIOXIDANT
ANTIPYRETIC

Solution :antipyretic
21687.

What is the cause of a feeling of a depression in human beings? Name a drug which can be useful in treating depression.

Answer»

Solution :Low level of NORADRENALINE is RESPONSIBLE for the FEELING of depression in HUMAN beings. An important antidepressant drug is ipronizid.
21688.

What are antibiotics?

Answer»

SOLUTION :Antibiotics is a chemical SUBSTANCE PRODUCED by one microorganism, that SELECTIVELY inhibits the GROWTH of another micro organism. Example : penicillins and cephalosporins.
21689.

There are some deposits of nitrates and phosphates in earth's crust. Nitrates are more soluble in water. Nitrates are difficult to reduce under the laboratory conditions but microbes do it easily. Ammonia forms large number of complexes with transition metal ions. Hybridizatioin easily explains the ease of sigma donation capability of NH_(3) and PH_(3). Phosphine is a flammable gas and is prepared from white phosphorus. Among the following, the correct statement is

Answer»

Between `NH_(3)` and `PH_(3),NH_(3)` is a better electron donor because the Ione PAIR of electrons occupies spherical s orbital and is LESS directional
Between `NH_(3)` and `PH_(3)`, as a better electron donor because the Ione pair of electrons occupies `SP^(3)` orbital and is more directional
Between `NH_(3)` and `PH_(3),NH_(3)` is a better electron donor because the Ione pair of electrons occupies `sp^(3)` orbital and is move directional
Between `NH_(3)` and `PH_(3),PH_(3)` is a better electron donor because the Ione pair of electrons occupies spherical s orbital and is less directional.

Answer :C
21690.

Which of the following ions does not have S-S linkage ?

Answer»

`S_2O_8^(2-)`
`S_2O_6^(2-)`
`S_2O_5^(2-)`
`S_2O_4^(2-)`

ANSWER :A
21691.

What is the effect of temerature on molarity of a solution?

Answer»

Solution :Molarity DECREASES because volume of the solution INCREASES with increase in temperature but no. of MOLES of SOLUTE remains the same (assuming it to be non-volatile).
21692.

Treatement of propionaldehyde with dilute NaOH solution gives

Answer»

`CH_(3)CH_(2)COOCH_(2)CH_(2)CH_(3)`
`CH_(3)CH_(2)CH(OH)CH(CH_(3))CHO`
`CH_(3)CH_(2)CH(OH)CH_(2)CH_(2)CHO`
`CH_(3)CH_(2)COCH_(2)CHO`

ANSWER :B
21693.

Write the products obtained when benzyl phenol ether is heated with HI.

Answer»

Solution :Protonation of benzyl phenol ether gives oxononium ion in which `O-C_(6)H_(5)` has some DOUBLE bond character due to resonance between the lone pairs of electrons on the oxygen ATOM and the `sp^(2)`-hydridized carbon of the PHENYL ring. Therefore, attack by `I^(-)` ion EXCLUSIVELY breaks the weaker `O-CH_(2)C_(6)H_(5)` bond FORMING phenol and benzyl iodide.
.
21694.

Which of the following are anionic detergents?

Answer»

SODIUM salts of sulphonated long chain alcohol
Ester of STERIC acid and polythylene glycol
Quarternary ammonium salt of AMINE with acetate ion
Sodium salts of suphonated long chain hydrocarbons

Solution :Detergents are cleansing agents which have all the propeties of SOAP, but which actually to not contain any soap. They are of THREE types of which given below.
1. Anionic detergents These are sodium salts of sulphonated long chain alcohol or hydrocarbons.

2. Cationic detergents These are quartemary ammoium salts of amines with acetates chlorides or bromides an anion e.g.,

3. Non-ionic detergents it is formed by the reaction of stearic acid with polyethylene glycoi.
21695.

What happens when BaCl_2 is added to Fe(OH)_3 sol?

Answer»


Answer :`Fe(OH)_3` sol is positively charged. On adding `BaCl_2` the chloride (Cl) IONS neutralise the POSITIVE charge of `Fe(OH)_3` sol and precipitation takes PLACE.
21696.

Which of the following compound has the lowest melting point ?

Answer»

`CaCl_(2)`
`CaBr_(2)`
`CaI_(2)`
`CaF_(2)`

Solution :Covalent CHARACTER increases and melting POINT decreases :
`CaF_(2)gtCaCl_(2)gtCaBr_(2)gtCaI_(2)`
21697.

What is a 'soap' ? How is it prepared ?

Answer»

SOLUTION :Soaps : Soaps are generally mixtures of sodium and potassium salt of higher fatty acids such as stearic, palmitic and oleic acids. For effective cleansing action of soap, its fatty acid unit must CONTAINS 12 to 18 carbon atoms. Soaps with less than 12 carbaon fatty acids are COMPARATIVELY soluble in water whereas soaps containing more than 22 carbon atoms are not useful because of their insolubility in water.
Sodium soaps are hard whereas potassium soaps are soft,
PREPARATION : Shaving creams, shampoos etc., are mostly potassium soaps.
Soaps are usually obtained by the hydrolysis of oils and fats with sodium or potassium hydroxide.

Transparant soaps are prepared by dissolving ordinary soaps in alcohol and then removing the insoluble part by filtration. The solid transparent mass is obtained on evaporating off alcohol.
21698.

Which of the following is employed as antihistamine ?

Answer»

Omeprazole
Chloramphenicol
Diphenhydramine
Norethindrone

Answer :C
21699.

The tampering of steel makes it:

Answer»

Hard
Soft
Heavy
Brittle

Answer :B
21700.

What are ambident nucleophiles ? Explain with an example.

Answer»

SOLUTION :Ambident NUCLEOPHILES are the species which have two NUCLEOPHILIC centres. For example, `CN^(ʘ)("":overset(ʘ)C-=N:"")` which can attack either from carbon or NITROGEN. Actually CYANIDE ion is a resonance hybrid of two contributing structures `("":overset(ʘ)C-=N to :C=N^(ʘ))` can act as a nucleophile in two different ways, i.e., linking through carbon atom forming alkyl cyanides and through nitrogen atom forining isocyanide.