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25201.

The products expected to be formed in the wurtz reaction of a mixture of neopentyl bromide and isobutyl bromide are (i). 2,2,4-trimethylpentane (ii). 2,2,5,5-tetramethylhexane. (iii). 2,2,4,4-tetramethylhexane (iv). 2,5-dimethylhexane (v). 2,2,5-trimethylhexane.

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(II),(III) and (iv)
(ii),(iv) and (v)
(i),(iv) and (v)
(i),(iii) and (v)

Solution :Since TWO DIFFERENT alkyl halides are INVOLVED in the reaction, a mixture of three isomeric products is formed in this case.

.
25202.

The products expected from the reaction {:(CHO),("|"),(CH_(2)),("|"),(CHOH),("|"),(CHOH),("|"),(CH_(2)OH):} overset(HIO_(4))underset("excess")to

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`H-overset(O)overset(||)(C)-CH_(2)-CHO +HCOOH+HCHO`
HOOC-CHOH-CHOH-COOH+HCOOH
`HOOC-CH_(2)CH_(2)COOH+HCOOH+HCHO`
`HOOC-COOH+HCOOH+HCHO`

Solution :
(B),(c),(d) are not possible as EXPLAINED above.
25203.

The products 'C' in the following reaction is RCO OH overset(NH_(2))to(A) overset("heat")to(B) overset(P_(2)O_(5).heat)to(C)

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`RNH_(2)`
`RCN`
RNC
`RCONH_(2)`

Solution :`RCO Ohoverset(NH_(3))to RCO ONH_(4)overset(HEAT)underset(-H_(2)O)to RCONH_(2)overset(P_(2)O_(5))underset(-H_(2)O)toRCN`
25204.

The products (A), (B), and (C ) are:

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a.
b.
c.
d.

Solution :a. i. `LAH//EtOH` reduces both `(RCOCL)` and ester (here cyclic ester) to alcohols (ii) Lindlar's catalyst (`H_(2)` + POISONED Pd) reduces only `(RCOCl)` to aldehydes not esters (iii) `DIBAL-H` reduces ester to aldehyde and ALCOHOL not `(RCOCl)` GROUP.
25205.

The products (A) and (B), respectively, are:

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a.
b.
c.
d.

Solution :`(A) implies HI+P` REDUCES EPOXIDES to alkanes.
`(B) implies LAH` reduces expoxides to two DIFFERENT alcohols by CLEAVING the group from either SIDE.
25206.

the products are:

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d

Answer :D
25207.

The products A and B of the below reaction sequence are H-C=C -CH_(2)-overset(O)overset(||)C-Ch_(3) overset(HgSO_(4))underset(Dil. H_(2)SO_(4))to A overset("EtONa)underset(EtOH)toB

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SOLUTION :
25208.

The products A and B of the following reaction are two isomeric alkenes. Identify A and B

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SOLUTION :
25209.

The products 'A' and 'B' of the below reaction sequence are H-C-=C-CH_(2)-CH_(2)-overset(O)overset(||)(C)-CH_(3)underset(dil.H_(2)SO_(4))overset(HgSO_(4))rarr A underset(EtOH)overset(EtONa)rarr B

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ANSWER :B
25210.

The production potential of hydrogen half-cell will be negative if:

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`pH_(2) = 2 atm` and `[H^(+)] = 2.0 M`
`pH_(2) = 1 atm` and `[H^(+)] = 2.0 M`
`pH_(2) = 1 atm` and `[H^(+)] = 1.0 M`
`pH_(2) = 2atm` and `[H^(+)] = 1.0 M`

Solution :`E = E_(H^(+)//H_(2))^(@) - (0.059)/(n) LOG.(pH_(2))/([H^(+)]^(2))`
`= 0-(0.059)/(2) log.(pH_(2))/([H^(+)]^(2)) = - (0.059)/(2) log.(2)/(1^(2)) = -ve`
25211.

The production of an optically active compound from a symmetric molecule without resolution is termed

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WALDEN inversion
Partial racemisation
Asymmetric synthesis
Partial resolution

Solution :It is DEFINITION of asymmetric synthesis
25212.

The production of an optically active compound from a symmetric molecule without resolution is called :

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WALDEN inversion
Asymmetric synthesis
Partial racemisation
None of these

Answer :B
25213.

The product Z of the following series of reactions is :

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`CH_3CH_2-OVERSET(CH_3)overset(|)underset(H)underset(|)C-CH_2OCH_3`
`CH_3CH_2-overset(CH_3)overset(|)underset(OCH_(3))underset(|)C-CH_3`
`CH_3CH_2-overset(CH_3)overset(|)C-overset(OCH_(3))overset(|)CH_3`
`CH_3CH_2-overset(CH_3)overset(|)C-overset(OCH_(3))overset(|)CH_3`

SOLUTION :
25214.

The product Z in the following series of reaction is : CH_3CH_2 -overset(CH_3)overset(|)C=CH_2 underset((ii)NaBH_4)overset((i)Hg(OAc)_2)toY underset((ii)CH_3Br)overset((i)Na)to Z

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`CH_3 CH_2 - UNDERSET(OCH_3)underset(|)OVERSET(CH_3)overset(|)C-CH_3`
`CH_3 CH_2 - underset(CH_3)underset(|)CHCH_2OCH_3`
`CH_3 - underset(CH_3)underset(|)CH - underset(OCH_3)underset(|)(CH)-CH_3`
`CH_3 - underset(CH_3)underset(|)overset(CH_3)overset(|)C -underset(OCH_3)underset(|)CH-CH_3`

ANSWER :A
25215.

The product (z) in the following sequence of reaction is C_(6)H_(6)+CH_(2)=CHCH_(2)Cl overset(AlCl_(3))to (X) underset((ii)" "H_(2)O_(2),OH)overset((i)" "BH_(3)//THF)to (j) underset(heat)overset(HF)to C_(9)H_(10)(z)

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NONEOF the above

Answer :B
25216.

The product (Z) is ……..

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TOLUENE
ETHYL benzene
Styrene
Nitrobenzene

ANSWER :B
25217.

The product ("X") of thefollowing sequences of reactions is

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ANSWER :D
25218.

The product X on oxidation with HIO_4 gives :

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HCHO
`CH_3-CHO`
`CO_2`
HCOOH

Solution :
25219.

The product X in the following reaction is (CH_(3)CO)_(2)O+C_(2)H_(5)OH to CH_(3)COOH+X

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`C_(2)H_(5)COOH`
`CH_(3)COOCH_(3)`
`CH_(3)COOC_(2)H_(5)`
`CH_(3)COCH_(3)`

Solution :This is the characteristic reaction of ACID derivatives.
25220.

The product X is

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Solution :Phenolic group is more ACIDIC than alcoholic group, thus phenoxide formed LEADS to WILLIAMSON SYNTHESIS.

The second step is the Williamson synthesis
25221.

The product x in the following equation : 2KMnO_(4) to K_(2)MnO_(4) +MnO_(2) +x, is :

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`Mn_(3)O_(4)`
`O_(2)`
MNO
All

Solution :`2KMnO_(4) to K_(2)MnO_(4)+MnO_(2)+O_(2)`
25222.

The product which is obtained in least amount the direct nitration of aniline is

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both (2) and (3)

ANSWER :A
25223.

The product which is not obtained when ethylene reacts with KI mixed with Br_2//H_2O is -

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`BrCH_2CH_2Br`
`BrCH_2CH_2OH`
`HOCH_2CH_2OH`
`BrCH_2CH_2I`

ANSWER :C
25224.

The product U is

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SOLUTION :
25225.

How is Dacron obtained from ethylene glycol and terepthalic acid ?

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GLYPTAL
DACRON
NYLON 6, 6
Buna - S rubber

Answer :A
25226.

The product (S) in the following sequence of reaction is __________. C_2H_4 overset("HBr")to(P) overset("NaOH (aq)")to (Q) overset(Na)to (R) overset(CH_3I)to (S)

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butane
DIETHYL ETHER
PROPANE
ETHYL methyl ether

Answer :D
25227.

The product/s formed when diborane is hydrolysed is/are :

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`B_2O_3 and H_3BO_3`
`B_2O_3` only
`H_3BO_3 and H_2`
`H_3BO_3` only

Answer :A
25228.

The product p of the nuclear reaction ""_(92)^(235)U + ""_(0)^(1)n to p + ""_(36)^(92)Kr + 3 ""_(0)^(1)n is

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`""_(56)^(141)Sr`
`""_(56)^(141)La`
`""_(56)^(141)Ba`
`""_(56)^(141)Cs`

SOLUTION :U- 235 nucleus when hit by a NEUTRON undergoes the reaction.
`""_(92)U^(235) + ""_(0)^(1)n to ""_(56)Ba^(41) + ""_(36)Kr^(92) + 3 ""_(0)^(1)n`
25229.

The product p of the nuclear reaction ._(92)^(235)U + ._(0)^(1) n rarr p + ._(36)^(92)Kr + 3 ._(0)^(1)n is

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`._(56)^(141)Sr`
`._(56)^(141)La`
`._(56)^(141)Ba`
`._(56)^(141)Cs`

SOLUTION :`U - 235` nucleus when hit by a neutron undergoes the reaction.
`._(92)U^(235) + ._(0)^(1) n rarr ._(56)Ba^(141) + ._(36)Kr^(92) + 3_(0)^(1) n`
25230.

The product P may be

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ANSWER :A
25231.

The product P of the following reaction is CH_(3)-COOH overset(LiAlH_(4))to overset(SOCl_(2))to overset(Koverset(14)(C)N)to overset(H_(3)O^(o+)) to P

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ANSWER :`CH_(3)-CH_(2)-overset(14)(C)OOH`
25232.

The product "P" in the above reaction is

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SOLUTION :
25233.

The product (P) in the reaction is …….

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ANSWER :B
25234.

The product, P formed in the reaction is (AAK_MCP_36_NEET_CHE_E36_010_Q01)

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(`AAK_MCP_36_NEET_CHE_E36_010_A01`)

ANSWER :D
25235.

The product P

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is the retended FORM of (X)
is the INVERTED form of (X)
has no CHIRAL carbon
is a meso compound

Answer :B
25236.

The product of the reaction of ethyl bromide with dry silver oxide in ethanol is the functional isomer of:

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A PRIMARY alcohol
A SECONDARY alcohol
A TERTIARY alcohol
All of the above

Answer :D
25237.

The product of the reaction of P_4O_10(s) with water is .............

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<P>`PH_(4)^(+)`
`PH_(3)`
`H_(3)PO_(4)`
`HPO_(2)(AQ)`

Solution :`P_(4)O_(10) + 6H_(2)O to 4H_(3)PO_(4)`
25238.

The product of the reaction , Methanol +COoverset(Rh)to is :

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Methanal
Ethanal
Methanoic acid
Ethanoic acid.

Solution :`CH_(3)OH+COoverset(RH)toCH_(3)COOH`
25239.

The product of the reaction is

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`HOCH_(2)(CH_(2))_(3)CH_(2)COCH_(3)`
`HOCH_(2)(CH_(2))_(3)CH_(2)OCOCH_(3)`

`ClCH_(2)(CH_(2))_(3)CH_(2)OCOCH_(3)`

Solution :
`H_(2)overset(C )(CH_(2))_(3)CH_(2)OCOCH_(3)overset(ZnCl_(3)^(-))(RARR)ClCH_(2)(CH_(2))_(3)OCOCH_(3)`
25240.

The product of the reaction is

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SOLUTION :amnides REDUCES to AMINES
25241.

The product of the reactiongiven belowis :

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ANSWER :d
25242.

The product of the reaction given below is :

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SOLUTION :
25243.

The product of the reaction D-Glyceraldehyde underset(HCl)overset(Me_(2)CO)rarr overset(CH_(2)=CHMgCl)rarr overset(O_(3))rarr is/are

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SOLUTION :
25244.

The product of the reaction, D-glyceraldehyde underset"HCl"overset(Me_2CO)to overset(H_2C=CHMgCl)to overset(O_3)tois/are ?

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SOLUTION :
25245.

The product of the reaction CHO+(C_6H_5-CHCO)_2Ooverset(C_6H_5-CH_2COONa//Delta)rarr(X)will be

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`C_6H_5-CH=CH-COOH`


ANSWER :D
25246.

The product of the reaction CH_3COOH overset(P_2O_5)(to)"......." is

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ETHYL ethanoate
Formic acid
Ethanoic ANHYDRIDE
`CO_2` and water

Answer :C
25247.

The product of the reaction between one mole of XeO_(3) and two mole of XeF_(6) is :

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`XeO_(2)F_(2)`
`XeOF_(4)`
`XeO_(3)F_(2)`
`XeO_(4)`

Answer :B
25248.

The product Of the reaction, CH_3CNoverset(H_2O)rarr A overset(NH_3)rarr B undersetrarr(heat) C is:

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METHYL amine
Ammonium acetate
Ethyl amine
Acetamide

Answer :D
25249.

The productof the reaction AI_(4)C_(3)+D_(2)O rarr …..+……. are

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`C_(2)C_(3)+AI(OD)_(3)`
`AI_(2)O_(3)+C_(2)D_(2)`
`CD_(4)+AI(OD)_(3)`
`C_(2)D_(2)+AI(OD)_(3)`

Solution :`AI_(4)C_(3)+12D_(2)Orarr3CD_(4)rarr3CD_(4)+4AI(OD)_(4)`
25250.

The product of the reaction

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ANSWER :A