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25701.

The polyprotic acid is:

Answer»

HCL
`HCLO_4`
`H_3PO_4`
`HNO_3`

ANSWER :C
25702.

The polymers obtained by the addition polymerisation of two different monomers are termed as____________.

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SOLUTION :COPOLYMERS
25703.

The polymers obtained from the monomers phenol and formaldehyde are

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polythene
novolac
bakelite
polystyrene

Answer :A::B::C::D
25704.

The polymerization of ethylene to linear polyethylene is represented by the reaction nCH_2 = CH_2 to (-CH_2 - CH_2 - )_nwhere n has large integral value. Given that the average enthalpies of bond dissociation for C=C and C-C at 298 K are +590 and +331 kJ "mole"^(-1)respectively, calculate the enthalpy of polymerization per mole of ethylene at 298 K.

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SOLUTION :`DELTA H = 1 XX 590- 2 xx 331`
-72kJ
25705.

The polymerisation of ClC_(2)F_(3) will produce

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PCTFE
PTFE
PMMA
PAN

ANSWER :A
25706.

The polymer with high tensile strength and high modulus are known as ……..

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FIBRES
elastomers
THERMO PLASTIC
thermo SETTING

SOLUTION :fibres
25707.

The polymer which undergoes environment degradation by microorganism is known as

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CHAIN GROWTH polymer
chain STEP polymer
BIODEGRADABLE polymer
non- biodegradable polymer

Answer :C
25708.

The polymer used in the valve packing

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TEFLON
TERYLENE
POLYSTYRENE
POLYETHENE

ANSWER :A
25709.

The polymerwhich can be easily softeningon heating and hard on cooling is

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NEOPRENE
MELAMINE methanal
PVC
Buna-N

ANSWER :C
25710.

The polymer which can stretched easily by applying small stress and return to it'soriginal shape when stress is removed

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Buna-s
DACRON
TEFLON
BAKELITE

ANSWER :A
25711.

The polymer used in the squeze bottles is

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Polystyrene
Teflon
Polypropene
LOW DENSITY polythene

ANSWER :D
25712.

The polymer used in making blankets (artificial wool) is

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polystyrene
PAN
polyester
polythene

Solution :PAN
25713.

The polymer used in orthopedic devices and in controlled drug release is S :

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ORLON
PTFE
SBR
PHBV

Answer :D
25714.

The polymer used in the manufacture of electrical goods such as switches, plugs etc is

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Polythene
Bakelite
NEOPRENE
PHBV

Answer :B
25715.

The polymer used in making blankets(artificial wool) is

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polystyrene
PAN
polyester
polythene

Answer :B
25716.

The polymer used for making unbreakable cups and laminated sheets

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POLYSTYRENE
GLYPTAL
Bakelite
Urea-formaldelyde resin

Answer :D
25717.

The polymer PMMA is used for making ....................and its monomer is.

Answer»


Answer :eye LENSES or sky domes, METHYLMETHACRYLATE
25718.

The polymer obtained from condensation of sebacic acid and hexamethylene diammine is called:

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Terylene
NYLON`6`
Nylon-`6,10`
Dacron

Answer :C
25719.

The polymer polystyrene has the repeating unit :

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`-CH_2-UNDERSET(CN)underset(|)(CH)-`
`-CH_2-underset(C_6H_5)underset(|)(CH)-`
`-CH=CH-underset(C_6N_5)underset(|)(CH)-`
`-CH=underset(C_6N_5)underset(|)(C)-`

Answer :B
25720.

The polymer obtained by step-growth polymerization of 2-aminoethanoic acid and 6- aminohexanoic acid is called ....................

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ANSWER :NYLON -2,nylon-6
25721.

The polymer of 1,3-butadiene and acrylonitrile is called

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BUNA - s - rubber
Bruna - N rubber
ACRILAN
None of these

ANSWER :B
25722.

The polymer having strongest intemolecular forces is

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Fibres
Elastomer
Thermoplastic
Thermosetting polymer

Answer :A
25723.

The polymer formed with more than two monosaccharide unit is known as :

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DISACCHARIDE
POLYSACCHARIDE
Both (a) and (B)
NONE

ANSWER :B
25724.

The polymer containing strong intermolecular forces e.g. hydrogen bonding is

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NATURAL rubber
teflon
nylon6,6
POLYSTYRENE

ANSWER :C
25725.

The polymer containing strong intermolecular forces e.g. hydrogen bonding, is

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teflon
nylon 6,6
polystyrene
natural Rubber

Solution :Nylon-6, 6 has amide linkage and CAPABLE of FORMING HYDROGEN bonding.
25726.

The polymer containing strong intermolecular forces,

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BUNA S rubber
Nylon-6,6
Bakalite
polyethene

Solution :NA
25727.

The polymer containing strong intermolecular forces :-

Answer»

Buna S RUBBER
Nylon-6,6
BAKALITE
polyethene

ANSWER :B
25728.

The polymer containing five methylene groups in its repeating unit is

Answer»

nylon-6, 6
nylon-6
DACRON
bakelite.

Solution :(B): `-[NH-(CH_(2))_(5)-oversetoversetO(||)(c)]_(n)-`
Nylon-6
25729.

Thepolymer acrilan has the repeating unit .

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`-CH_2-OVERSET(CN)overset(|)CH-`
`-CH_2-overset(C_6H_5)overset(|)CH-`
`-CH_2-overset(CH_3)overset(|)CH-`
`-CH_2-overset(CL)overset(|)CH-`

ANSWER :A
25730.

The polymer containing an arnide group is :

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POLYTHENE
POLYSTYRENE
TERYLENE
nylon

Answer :D
25731.

The polydispersity index of a polymer containing 10 molecules with moleculer mass 1.0xx10^(4) and 10 molecules with moleculer mass 1.0xx10^(5) is approximately .

Answer»

1.67
0.59
1.55
0.83

Answer :A
25732.

Thepollution whichcomedirectly in the air from sourcesare calledprimarypollutants . Primarypollutantsaresometimesconvertedintosecondarypollutants. Whichofthe followingbelongto secondary airpollution ?

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CO
HYDROCARBON
NO
Peroxyacetyl nitrate

Answer :D
25733.

The polydentate ligand used in the treatment of lead poisoning

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EDTA
Glycinate
Oxalate
Ethylene diammine

Answer :A
25734.

The pollution in city like Delhi may be controlled to great extent

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By PROPER sewage and proper exit of chemicals from factories
By WIDE roads and factories AWAY from the city
By cleaning city and scanty use of pesticides
All of the above

Answer :D
25735.

The pollutants emitted by jet aeroplanes in outer atmosphere are known as

Answer»

Loess
Photochemical oxidants
AEROSOLS
Smog

Solution :Chemicals released in the atmosphere with force in the FORM of mist or VAPOURS are called aerosols. JET aeroplanes release aerosols which contain CFC.
25736.

The polarity of the carbon-halogen bond is responsible for the nucleophilic substitution reactions of alkyl halides which mostly occur by S_(N)1 and S_(N)2 mechanisms. The rates of S_(N)2 reactions among other things are governed by steric factors while than of S_(N)1 reactions are governed by the stability of intermediate carbocations. chirality has a profound role in undersetanding the mechanism of S_(N)1 and S_(N)2 reactions. whereas S_(N)2 reactions of chiral alkyl halides are accompanied by inversion of configuration, S_(N)1 reactions are characterised by racemisation. Q. In the solvolysis of 3-methyl-3-bromohexane, which of the followin statements is not correct?

Answer»

it involves CARBOCATION INTERMEDIATE
the intermediate invovles `sp^(2)` carbon
polar solvents accelerate the reaction
it involves INVERSION of configuration

Solution :Solvolysis means reaction with the solvent. Here, solvent ACTS as the nucleophile. 3-Methyl-3-bromohexane is a `3^(@)` alkyl halide, therefore, it undergoes solvolysis by `S_(N)1` mechanism to afford a racemic product in which both RETENTION and inversion have occurred and not only inversion.

25737.

The polarity of the carbon-halogen bond is responsible for the nucleophilic substitution reactions of alkyl halides which mostly occur by S_(N)1 and S_(N)2 mechanisms. The rates of S_(N)2 reactions among other things are governed by steric factors while than of S_(N)1 reactions are governed by the stability of intermediate carbocations. chirality has a profound role in undersetanding the mechanism of S_(N)1 and S_(N)2 reactions. whereas S_(N)2 reactions of chiral alkyl halides are accompanied by inversion of configuration, S_(N)1 reactions are characterised by racemisation. Q. An S_(N)2 reaction at an asymmetric carbon of a compound always gives

Answer»

an enantiomer of the substrate
a product with opposite OPTICAL rotation
a mixture of diastereomers
a single stereoisomer.

Solution :In `S_(N)2` reactions, inversion of CONFIGURATION occurs. Since the reactant and the product are not enantiomers, THEREFORE, the sign of optical rotation may or may not change and hence a single stereosiomerr is obtained, i.e., OPTION (d) is correct.
25738.

The polarizibility of the following compounds is/are

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`I^(-) GT Br^(-) gt Cl^(-) gt F^(-)`
`I^(-) gt Br^(-) gt F^(-) gt Cl^(-) `
`I^(-) LT Br^(-) lt Cl^(-) lt F^-`
`I^(-) lt Br^(-) lt F^(-) lt Cl^(-) `

ANSWER :A
25739.

The polarity of the carbon-halogen bond is responsible for the nucleophilic substitution reactions of alkyl halides which mostly occur by S_(N)1 and S_(N)2 mechanisms. The rates of S_(N)2 reactions among other things are governed by steric factors while than of S_(N)1 reactions are governed by the stability of intermediate carbocations. chirality has a profound role in undersetanding the mechanism of S_(N)1 and S_(N)2 reactions. whereas S_(N)2 reactions of chiral alkyl halides are accompanied by inversion of configuration, S_(N)1 reactions are characterised by racemisation. Q. S_(N)1 reaction of optically active alkyl halides leads to

Answer»

RETENTION of configuration
racemisation
inversion of configuration
none of these

Answer :B
25740.

The polarity of the carbon-halogen bond is responsible for the nucleophilic substitution reactions of alkyl halides which mostly occur by S_(N)1 and S_(N)2 mechanisms. The rates of S_(N)2 reactions among other things are governed by steric factors while than of S_(N)1 reactions are governed by the stability of intermediate carbocations. chirality has a profound role in undersetanding the mechanism of S_(N)1 and S_(N)2 reactions. whereas S_(N)2 reactions of chiral alkyl halides are accompanied by inversion of configuration, S_(N)1 reactions are characterised by racemisation. Q. Which of the following is an example of S_(N)2 reaction?

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`CH_(3)Br+OH^(-)toCH_(3)OH+Br^(-)`
`(CH_(3))_(2)CHBr+OH^(-)(CH_(3))_(2)CHOH+Br^(-)`
`CH_(3)CH_(2)OH OVERSET(-H_(2)O)to CH_(2)=CH_(2)`
`CH_(3)CH_(2)OH overset(-H_(2)O)to CH_(2)=CH_(2)`

Answer :A
25741.

The polarity is maximum in :

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N-F
C-F
O-F
F-F

Answer :B
25742.

The polarimeter readings in an experiment to measure the rate of inversion of cane sugar (1st order reaction) were as follows {:("time(min)",:,0,30,oo),("angle(degree)",:,30,20,-15):} Identify the true statement(s) ? [log2=0.3,log 3=0.48, log 7=0.84, log_e10=2.3]

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The HALF LIFE of the reaction is 75 min
The solution is optically inactive at 120 min
The equimolar mixture of the product is dextrorotatory
The ANGLE would be `7.5^@` at half time

Solution :`{:(0,30,oo),(30,20,-15):}`
`k=1/30 2.3"log"(30-(-15))/(20-(-15))=1/30"log"45/35`
`:. T_(1//2)75` min
`k=1/t2.3 "log"45/(0-(-15))`
t=120 min
`(30-(-15))/(x-(x-15))=2` at half time
`IMPLIES 45(x+15)=2 implies x+15=45/2implies x=22.5-15=7.5^@`
25743.

The poissons ratio for inert gases is :

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1.40
1.66
1.34
None

Answer :B
25744.

The points noted by arrows are melting and boiling points of the metal zinc and magnasium. Delta G^(0) as a function of temperature for some reaction of extractive metallurgy. At 1000^(@)C, which reaction is spontaneous to a maximum extent

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`MgO+C RARR Mg+CO`
`ZnO+Crarr Zn+CO`
`MgO+Zn rarr Mg+ZnO`
`ZnO+Mg rarrZn+MgO`

ANSWER :B
25745.

The poisonous gas evolved in Bhopal tragedy from the pesticide plant of union carbide was

Answer»

`CH_3NCO`
`CH_3CNO`
`CH_3CN`
`CH_3NC`

SOLUTION :MIC
25746.

The points noted by arrows are melting and boiling points of the metal zinc and magnasium. Delta G^(0) as a function of temperature for some reaction of extractive metallurgy. At what approximate temprature, zinc and carbon have equal affinity for oxygen?

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`1000^(@)`C
`1500^(@)`C
`500^(@)C`
`1200^(@)C`

ANSWER :b
25747.

The point of dissimilarity between (SO_(3) )_( 3)and (HPO_(3))_(3)(cyclic trimer) is :-

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Both have six MEMBERED ring.
Both contain CENTRAL atom in same hybridisation.
Both contain PLANAR ring.
Both are isoelectronic

Answer :C
25748.

The pOH of beer is 10.0. The hydrogen ion concentration will be

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`10^(-2)`
`10^(-10)`
`10^(-8)`
`10^(-4)`

Solution :PH + pOH = 14, pH = 4, `H^(+) = 10^(-4)` mole/litre.
25749.

What will be the pOH of 0.5xx10^(-4)M H_(2)SO_(4) solution ?

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4
8
10
2

Answer :C
25750.

The plots of triangleG versus T in the metallurgical processes are called

Answer»

HELMHOLTZ diagram
Kelvin diagram
Pauling's diagram
Ellingham diagram

Answer :D