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28451.

The manufacture of fluorine is carried out by :

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ELECTROLYSIS of aqueous HF
heating ANHYDROUS `HF and MnO_(3)`
electrolysis of anhydrous KF and `MnO_(2)`
electrolysis of anhydrous `HF` mixed with `KHF_(2)`

Answer :C
28452.

The manganate and permanganate ions are_______________in shape.

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SOLUTION :TETRAHEDRAL
28453.

The maltose and glucose can be distinguished chemically by ………………….

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MOLISCH's TEST
Barfoed's test
MILLION's test
BIURET's test

SOLUTION :Barfoed.s test
28454.

The molecular formula of saturated fatty acid is

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`C_nH_(2N)O_2`
`C_nH_(2n-2)O_2`
`C_nH_(2n+2)O_2`
`C_nH_(2n+1)O_2`

ANSWER :A
28455.

The majority of noble gas compounds are those of xenon. Explain.

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Solution :Except radon which is radioactive, Xe has the LOWEST ionization enthalpy among noble gases and HENCE can be easily oxidised by STRONG oxidising agents like `O_(2) and F_(2)`. That is why majority of noble GAS compounds are those of xenon.
28456.

The molecular formula of oxygen at ordinary temperature is .......... And that of sulfur is ...........

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SOLUTION :`O_2,S_8`
28457.

The majority of amino acids found in proteins are

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`ALPHA`-amino acids.
`beta`-amino acids.
`GAMMA-`amino acids.
`DELTA`-amino acids.

Answer :A
28458.

The major use of chloroform today is in the production of the __________ refrigerant R-22.

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ANSWER :FREON
28459.

The molecular formula of phosphorus is:

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`P_1`
`P_4`
`P_2`
`P_5`

ANSWER :B
28460.

The major substitution product that is obtained by nitration of anisole is __________.

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SOLUTION :4-nitroanisole
28461.

The major sourceof CO pollution is

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Industrialprocesscs
VEHICULAR EXHAUST
forestfires
volcanic activity

Answer :B
28462.

The molecular formula of methyl isopropyl ether may be:

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`C_4H_(10)O`
`C_3H_8O`
`C_4H_8O`
`C_3H_(10)O`

ANSWER :A
28463.

The major role of fluorspar (CaF_(2)) which is added in small amount in the electrolytic reduction of Al_(2)O_(3) dissolved in fused cryolite is :

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to act as catalyst
to make fused MIXTURE conducting
to lower the FUSION TEMPERTURE of melt
to decrease the rate of oxidation of CARBON at the anode.

Solution :Both are correct.
28464.

The molecular formula of feldspar is

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`K_(2)O.Al_(2)O_(3).6SiO_(2)`
`K_(2)O.3Al_(2)O_(3).6SiO_(2)`
`Na_(3)AlF_(6)`
`CaSO_(4).2H_(2)O`

ANSWER :A
28465.

The major products of following reactions sequence are :

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ANSWER :D
28466.

the major product(s) obtained in the following reaction is/are

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<BR>

SOLUTION :`Br_(2)` ADDITION is anti-addition.
28467.

The molecular formula of ether is:

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`C_(n)H_(2N)O`
`C_(n)H_(2n+1)O`
`C_(n)H_(2n+2)O`
`C_(n)H_(2n)OC_(n)H_(2n)`

Solution :`C_(2)H_(6)OC_(2)H_(5)-=C_(4)H_(10)O=C_(n)H_(2n+2)O`
28468.

The major product(s) obtained from the following reaction of 1 mole of hexadeuteriobenzene is//are

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SOLUTION :
28469.

The molecular formula of chloride of a metal M is MCl_3. The formula of its carbonate would be

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`MCO_(3)`
`M_(2)(CO_(3))_(3)`
`M_(2)CO_(3)`
`M(CO_(3))_(2)`

Solution :As the MOLECULAR formula of CHLORIDE of a metal M is `MCl_(3)`, it is trivalentso formula of its carbonate will be `M_(2)(CO_(3))_(3)`.
28470.

The major product (Y)in the following reaction sequency is : CH_(3) - overset( CH_(3))overset(|)(C)H - CH= CH_(2) overset( Br_(2) //H_(2)O)(rarr) X overset("conc."H_(2)SO_(4)//Delta)(rarr)Y

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`CH_(3) - overset(CH_(3))overset(|)(C)H -CH= CH-Br`
`CH_(3) - underset(H)underset(|)overset(CH_(3))overset(|)(C) -underset(Br) underset(|)(C) = CH_(2)`
`CH_(3) - overset(CH_(3))overset(|)(C)=underset(Br)underset(|)(C) - CH_(3)`
`CH_(3) - overset(CH_(3))overset(|)(C) = CH-CH_(2)- Br`

SOLUTION :`CH_(3) -overset( CH_(3)) overset(|)(C) H - CH= CH_(2) overset(Br_(2) //H_(2)O)(rarr) CH_(3) -overset(CH_(3))overset(|)(C)H-CH-CH_(2)-Br overset(Conc. H_(2)SO_(4)//DELTA)(rarr) CH_(3)-overset(CH_(3))overset(|)(C)=CH-CH_(2)-Br(Y)`
28471.

The molecular formula of dithionic acid is _________.

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`H_(2)S_(2)O_(4)`
`H_(2)S_2O_(6)`
`H_(2)S_(2)O_(5)`
`H_(2)S_(2)O_(7)`

Answer :B
28472.

The major products A and B are :

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SOLUTION :
28473.

The molecular formula of ether is

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`CH_3COCl`
`CCl_3COCl_3`
`CH_2ClCOOH`
`CCl_3COCH_3`

ANSWER :D
28474.

Themolecular formula of the chlorinated acetone formedin the distillation of acetone with bleaching powder is:

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`CH_3COCl`
`CCl_3COCl_3`
`CH_2ClCOOH`
`CCl_3COCH_3`

ANSWER :D
28475.

The major product (Y) of the following reactionsis

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ANSWER :A
28476.

The molecular formula of benzonitrile is

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`C_(6)H_(5)CN`
`C_(6)H_(5)NC`
`C_(6)H_(5)CNO`
`C_(6)H_(5)NCO`

Solution :The molecular FORMULA of benzoinitrile or phenytl CYANIDE is `C_(6)H_(5)CN`.
28477.

The molecular formula of an organic compound is C_(3)H_(6)O_(2). This compound on boiling with aqueous acidic solution produces (A) and (B) copounds. (A) gives positive test with Fehling's solution as well as with Tollen's reagent. (B) on boiling with iodine andaqueous pottasium hydroxide produces potssium formate andcompound (C ). (C ) on heating with silver produces acetylene. Identify all compounds.

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Solution :`underset((HCOOC_(2)H_(5)))(C_(3)H_(6)O_(2))OVERSET(H_(2)O)tounderset("It reduces Fehling's solution and Tollen's REAGENT")underset((HCOOH))((A))+underset((C_(2)H_(5)OH))((B))underset(KOH)overset(I_(2))tounderset((CHI_(3)))((C))overset(Ag)toHCequivCH`
28478.

The major product (X) formed in the reaction sequence is:

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`C_(6)H_(5)overset(O)overset(||)C-CH_(3)`
`C_(6)H_(5)-CO(CH_(3))_(2)`

ANSWER :C
28479.

The molecular formula of a saturated is C_(2)H_(4)Cl_(2). This formula permits the existence of two:

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FUNCTIONAL ISOMERS
position isomers
OPTICAL isomers
cis-trans isomers.

ANSWER :B
28480.

The major product X is

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ANSWER :A
28481.

The molecular formula of a non - stoichiometric tin oxide containing Sn (II) and Sn (IV) ions is Sn_(4.44) O_8. Therefore , the molar ratio of Sn (II) to Sn (IV) is approximately

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`1:8`
`1:6`
`1:4`
`1:1`

ANSWER :C
28482.

The major product U in the following reactons is overset(CH_(2)CH-CH_(3),H^(+))underset("high pressure, heat")rarr Toverset("radical initiator, O_(2))rarrU

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ANSWER :B
28483.

The molecular formula of a saturated compound is C_(2)H_(4)Br_(2). The formula permits the existence of two :

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FUNCTIONAL ISOMERS
position isomers
OPTICAL isomers
cis-trans isomers

Answer :B
28484.

The molecular formula of a saturated compound is C_2H_4Br_2. This formula permits the existence of:

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FUNCTIONAL isomers
Optical isomers
Positional isomers
Cis-trans isomers

Answer :C
28485.

The major product U in the following reaction is :

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ANSWER :B
28486.

The major product (s) obtained from the following reaction of 1 mol of hexadeuteriobenzene is /are-

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SOLUTION :
28487.

The major product P in the following reaction is CH_(3)-CH=CH_(2) underset("Peroxide")overset(HI)rarrP

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`CH_(3)CH_(2)CH_(2)I`
`underset("I")underset("|")(CH_(3)-CH-CH_(3))`
`underset("I")underset("|")CH_(2)-CH=CH_(2)`
`underset("I")underset("|")CH_(2)-underset("I")underset("|")CH_(2)`

Solution :The PRODUCT formation will be accordingly to Markownikoff.s RULE, because peroxide effect is effective only in the case of HBr and not effective in case of HI.
28488.

The molecular formula of a monobasic saturated fatty acid is:

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`C_nH_(2N)O_2`
`C_nH_(2n+1)O_2`
`C_nH_(2n+2)O_2`
`C_nH_(2n+1)O_3`

ANSWER :A
28489.

The major product (s) obtained in the following reaction is/are .

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SOLUTION :both PRODUCTS are FORMED.
28490.

The major product P of the following reaction is

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ANSWER :D
28491.

The molecular formula of a commercial resin used for exchanging ions in water softening is C_8H_7SO_3Na(Mol. Wt. 206). What would be the maximum uptake of Ca^(2+)ions by the resin when expressed in mole per gram resin ?

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`1/103`
`1/206`
`2/309`
`1/412`

Solution :`Ca^(2+) + 2C_8H_7SO_3Na to Ca (C_8H_7SO_3)_2 + 2Na `
Molecular MASS of `C_8H_7SO_3Na`
` = 12 XX 8 + 1 xx 7 + 32 xx 1 + 16 xx 3 + 23 xx 1= 206`
2 moles of `C_8H_7SO_3Na` require 1 mol of `Ca^(2+)`
` 2 xx 206 g ` of `C_8H_7SO_3 Na + 1 ` mol of `Ca^(2+)`
1g of `C_8H_7SO_3Na = 1/412 ` mol
` therefore ` maximum uptake ` = 1/412 ` mol/g
28492.

The major product of this reaction is

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ANSWER :A
28493.

The molecular formula of a commercial resin used for exchanging ions in water softening is C_(8)H_(7)SO_(3)Na (mol. Wt. 206). What would be the maximum uptake of Ca^(2+) ions by the resin when expressed in mole per gram resin?

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`(1)/(103)`
`(1)/(206)`
`(2)/(309)`
`(1)/(412)`

Solution :`{:(underset("2 moles")(2C_(8)H_(7)SO_(3)^(-)Na^(+))+underset(" 1 mole")(Ca^(2+))rarr(C_(8)H_(7)SO_(3)^(-))Ca^(2+)),(=2xx206=412g""+2Na^(+)):}`
Thus, 412 G of resin take up `Ca^(2+)` ions = 1mole
`therefore" 1 g of resin will take up "Ca^(2+) " ions"=(1)/(412)"mole"`
i.e, UPTAKE of `Ca^(2+)` ions in mole per gram resin
`=(1)/(412)`
28494.

The major product of the reaction of alcohols with carboxylic acid in presence of acid catalyst is ….

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ESTER
Ether
Anhydride
Aldehyde

Solution :Ester
28495.

The major product of the reaction is

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NONE of these

Answer :C
28496.

The molecular formula of a commercial resin used for exchanging ions in water softeningis C_(8) H_(7) SO_(3) (mol . wt. = 206) . Whatwouldbe the maximumuptake of Ca^(2+) ionsby the resin whenexpressed in mole per gram resin ?

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`(1)/(103)`
`(1)/(206)`
`(1)/(309)`
`(1)/(412`

Solution :`2 C_(8) H_(7) SO_(2)Na + Ca^(2+) to (C_(8) H_(7) SO_(3))_(2) Ca + 2Na`
28497.

The major product of the reaction overset(NaNO_(2)//H_(2)SO_(4))to is

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SOLUTION :
28498.

The molecular formula H_(2)S_(2)O_(2) represents which oxoacid among the following?

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Hydrosulphurous ACID
Thiosulphuric acid
SULPHURIC acid
Pyrosulphurous acid

ANSWER :B
28499.

The molecular formula Co(NH_(3))_(5)BrSo_(4) have two isomeric form X and Y which differ in :

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HYBRIDISATION
MAGNETIC moment
Geometry
Electrical CONDUCTIVITY

Solution :`[Co(NH_(3))_(5)Br]SO_(4),[Co(NH_(3))_(5)SO_(4)]Br,`{Electrical conductivity}
28500.

The major product of the reaction is:

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ANSWER :C