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28351.

The mass of precious stones is expressed in terms of 'carat'. Given that 1 carat = 3.168 grains and 1 gram = 15.4 grains, calculate the total mass of a ring in grams and kilograms which contains 0.500 carat diamond and 7.00 gram gold.

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SOLUTION :The unit CONVERSION factors will be :
`1=("1 carat")/(3.168" grains")=("3.168 grains")/("1 carat")`
`1=("1 gram")/("15.4 grains")=("15.4 grains")/("1 gram")`
`"0.500 carat"="0.500 carat"xx("3.168 grains")/("1 carat")xx("1 gram")/("15.4 grains")="0.10 gram"`
`THEREFORE"Total MASS of the ring"=7.00+0.10g=7.10gxx(1kg)/(1000G)=0.0071kg.`
28352.

The molecule/ion having pyramidal shape is :

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`PCl_(3)`
`SO_(3)`
`CO_(3)`
`NH_(4)^(+)`

ANSWER :A
28353.

The mass of P_(4)O_(10) produced if 440 gm P_(4)S_(3) is mixed with 384 gm of O_(2) is

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568gm
426 gm
284 gm
396 gm

Answer :B
28354.

The molecule in which one of the nitrogen bases is bonded with a sugar molecule is called …………………..

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SOLUTION :NUCLEOSIDE
28355.

The mass of potassium dichromate crystals required to oxidise 750 cm^3 of 0.6 M Mohr's salt solution is: (Given molar mass : potassium dichromate = 294, Mohr's salt = 392)

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0.45 g
22.05 g
2.2 g
0.49 g

Solution :GRAM EQUIV. of moh.s salt = gram equiv. of `K_2Cr_2O_7`
Gram equiv. of mohr.s salt in `750 cm^3` of 0.6 M solution
` = 0.6 xx 1 xx 750/1000`
= 0.45
Let the mass of `K_2Cr_2O_7 = X g `
` therefore(x)/(294//6)= 0.45`
`(becauseEq. wt of K_2Cr_2O_7 = ("mol. wt)/(6) )`
`x= (0.45 xx 294)/(6) = 22.05 g `
28356.

The molecule in which all atoms are not coplanar is

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ANSWER :C
28357.

The mass of oxygen gas which occupies 5.6 litres at STP would be

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The gram atomic mass of OXYGEN
One fourth of the gram atomic mass of oxygen
Double the gram atomic mass of oxygen
HALF of the gram atomic mass of oxygen.

Solution :22.4 L of `O_2` gas at STP has mass = 32 g
5.6 L of `O_2` gas at STP has mass ` = (32 XX 5.6)/(22.4) = 8 g `
8 g of corresponds to half of the atomic mass oxygen .
28358.

The molecule having smallest bondangle is :

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`NCl_(3)`
`AsCl_(3)`
`SbCl_(3)`
`PCl_(3)`

Solution :All the members form volatile HALIDES of the type `AX_(3)` All halides are pyramidal in SHAPE. The bond angle decreases on MOVING down the group due to decrease in bond pair-bond pair repulsion.
`{:(NCl_(3),PCl_(3),AsCl_(3),SbCl_(3)),(107^(6),109.5^(@),98^(@),98.2^(@)):}`
28359.

The mass of one molecule of oxygen is:

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32 G
`32// 6.02 xx 10^23 g `
`16 // 6.02 xx 10^23`
`0.32 g`

Solution :MASS of 1 molecule of `O_2`
` = (32)/(6.022 xx 10^23) g `
28360.

The molecule having smallest bond angle is :

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`PCl_(3)`
`NCl_(3)`
`AsCl_(3)`
`SbCl_(3)`.

SOLUTION :Bond angle decreases as electronegativity of central ATOM decreases.
28361.

The mass of one litre sample of ozonised oxygen at N.T.P. was found to be 1.5 g. When 100 mL of this mixture at N.T.P. were treated with turpentine oil, the volume was reduced to 90 mL. Calculate the molecular mass of ozone.

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Solution :As ozone is absorbed by turpentine oil, therefore, volume of ozone in 100ML of the mixture
`=100-90=10mL`
`therefore""O_(2)" in the mixture"=100-10=90mL`
As 1 L of the mixture WEIGH = 1.5 g, therefore, average MOLAR mass of the mixture (mass of 22.4 L at S.T.P.)`=1.5xx22.4=33.6"g mol"^(-1)`
`"Ratio of ozone " : "oxygen in the mixture "=10:90`
It m is the molecular mass of ozone, then
`"Average mol. mass of mixture "=(10xxm+90xx32)/(100)="33.6 (CALCULATED above)"`
`"or"m+288=336 "or"m=48`
28362.

The molecule having one unpaired electron is

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NO
CO
`CN^(-)`
`O_(2)`

ANSWER :A
28363.

The mass of Mg_(3)N_(2) produced if 48 gm metal is reacted with 34 gm NH_(3) gas isMg + NH_(3) to Mg_(3)N_(2) + H_(2)

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200/3 gm
100/3 gm
400/3 gm
150/3 gm

Answer :A
28364.

The mass of molecule A is twice the mass of molecule B. The rms speed of A is twice the rms speed of B. If two samples of A and B contain same no. of molecules, what will be the ratio of P of two samples in separate containers of equal volume.

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<P>

Solution :Given, `M_(A) =2M_(B)`
`therefore` Mol wt. of `A=2xx` mol wt. of B `"…(1)"`
`U_("rma")` of `A=2xxU_("rms")` of B `"…(2)"`
Also, the no. of molecules of A =NO. of Molecules of B `"….(3)"`
For GAS `A P_(A) V_(A) =(1)/(3) M_(A) U_("rms")^(2) A`
`(P_(A)V_(A))/(P_(B)V_(B))=(M_(A))/(M_(B))xx(U_(A))/(U_(B))".....(4)"`
Given `V_(A) =V_(B)".....(5)"`
`therefore` By equation (1) (2) (4) & (5)
`(P_(A))/(P_(B)) =2xx(2)^(2)=8`
`P_(A) =8P_(B)`
28365.

The molecule having least dipole moment (Assume benzene molecule to be a regular hexagon) :

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SOLUTION :
28366.

The mass of metal, with equivalent mass 31.75 which would combine with 8 g of oxygen is

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1
8
`3.175`
`31.75`

Solution :Equivalent mass of METAL = 31.75
Mass of metal = X
Combine with 8 g of oxygen
Equivalent mass of metal= `("mass of metal")/("mass of oxygen") XX 8`
i.e. `31.75 = (x)/(8) xx(8) Rightarrow x = 31.75`
28367.

The molecule having one and two bonds is

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`SO_2`
`SO_3`
`CO_2`
`N_2`

ANSWER :B
28368.

The mass of helium atom is 4.0026 amu, while that of the neutron and proton are 1.0087 and 1.0078 amu respectively on the same scale. Hence, the nuclear binding energy per nucleon in the helium atom is about

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<P>5 MEV
12 MeV
14 MeV
7 MeV

Solution :Mass defect of `._(2)He^(4), Delta m = [2(m_(p) + m_(n)) - m_(He)]`
`Deltam = [2(1.0087 + 1.0078) - 4.0026]`
`= 4.033 - 4.0026 rArr Delta m = 0.0304`
`:.` BINDING energy PER nucleon
`= (Deltam xx 931.5)/(4) = (0.0304 xx 931.5)/(4) = 7.01 MeV`
28369.

The molecule having largest bond angle is :-

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`H_(2)O`
`H_(2)S`
`H_(2)SE`
`H_(2)TE`

ANSWER :A
28370.

The mass of gold in an 18 carat gold ring of 4 g is :

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4G
3G
2g
1g

Solution :24 carat gold is pure gold
4g ring of 18 carat gold ` = ( 4XX 18)/(24) = 3g`
28371.

The mass of glucose that should be dissolved in 50 g of water in order to produce the same lowering of vapour pressure as produced by dissolving 1 g of urea in the same quantity of water is

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<P>1 g
3 g
6 g
8 g

Solution :`(p^(@)-p_(s))/(p^(@))=(n_(2))/(n_(1))=(w_(2)M_(1))/(w_(1)M_(2))`
As (`p^(@)-p_(s))//p^(@)` is same in the two CASES
`((w_(2)M_(1))/(w_(1)M_(2)))_("glucose")=((w_(2)M_(1))/(w_(1)M_(2)))_("urea")`
`(w_(2)xx18)/(50xx180)=(1xx18)/(50xx60) or w_(2)=3 g.`
28372.

The molecule having highest bond dissociation energy is :

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`O_(2)`
`O_(2)^(+)`
`O_(2)^(-)`
`O_(2)^(2-)`

ANSWER :B
28373.

The mass of dinitrogen in grams produced by the thermal decomposition of 2 moles of ammonium dichromate.

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Solution :`(NH_(4))_(2)Cr_(2)O_(7)OVERSET("Heat")RARR N_(2)+4H_(2)O+Cr_(2)O_(3)`
`{:("1 mole","1mole"),("2 mole","2mole"):}`
Mass of `N_(2)=` mole of `N_(2)xx` molar mass of `N_(2)`
`=2xx28=56 g`
28374.

The mass of gases evolved in Question is

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`0.06g`
`0.6g`
`6.0g`
`60g`

SOLUTION :Total mass of `C_(2)H_(6)+2CO_(2)+H_(2)-=30+88+2=120g`
`:. 2xx96500Cimplies120g`
`0.1xx965C=(120xx0.1xx965)/(2xx96500)implies0.06g`
28375.

The molecule has:

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ONE asymmetric carbon and one MESO FORM and two optically active isomers.
two asymmetric carbon and one meso form and two optically active isomers.
no asymmetric carbon and no meso form and no optically active isomers
one asymmetric caron and two optically active isomers with no meso form

Solution :
Two asterisk SHOW asymmetric carbon. It has two optically active isomers and one meso form.
28376.

The mass of glucose that should be dissolved in 50 g of water in order to produce the same lowering of vapour pressure as is produced by dissolving 1 g of urea in the same quantity of water is

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1 G
3 g
6 g
18 g

SOLUTION :`(p_(0)-p_(s))/(p_(s))=(w_(1)M_(2))/(w_(2)M_(1))`
To produce same lowering of vapour PRESSURE `((p_(0)-p_(s))/(p_(s)))` TERM will be same for both the cases (solvent is same).
`THEREFORE (w_(g)xx18)/(50xx180)=(w_(u)xx18)/(50xx60)`
(`w_(g)=`weight of glucose, `w_(u)=`weight of urea)
or,`(w_(g)xx18)/(50xx180)=(1xx18)/(50xx60)`or,`w_(g)=3`.
28377.

The mass of CO_(2) produced from 620 gm mixture of C_(2)H_(4)O_(2) & O_(2) prepared to produce maximum energy is ( combustion reaction is exothermic )

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413.33 gm
593.04 gm
440 gm
320 gm

Answer :C
28378.

Themolecule ClCH_(2)CH_(2)SCH_(2)CH_(2)Cl is commonlycalled as

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TEAR GAS
DDT
Mustard gas
Phosgene

Answer :C
28379.

The mass of carbon anode consumed (giving only carbon dioxide) in the production of 270kg of Al metal from bauxite by Hall process is:

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270kg
540kg
90kg
180kg

Solution :`underset(3xx12g)(3C)+2Al_(2)O_(3)rarrunderset(4xx27=108g)(4Al+3CO_(2))`
`because` 108g Al is produced by consuming =36G carbon
`therefore 270xx10^(3)g` Al will be produced by consuming
`=(36)/(108)xx270xx10^(3)g` of carbon
`=90xx10^(3)g`=90 kg carbon.
28380.

The mass of carbon present in 0.5 mole of k_(4)[Fe(CN)_(6)] is:

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1.8g
18g
3.6g
36g

Solution :1 mole of `K_(4)[Fe(CN)_(6)]` contains 6 mole CARBON, i.e., 72G carbon.
28381.

The molecule exhibiting maximum number of non-bonding electron pairs (l.p.) around the central atom is :

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`XeOF_(4)`
`XeO_(2)F_(2)`
`XeF_(3)^(-)`
`XeO_(3)`

Answer :C
28382.

The mass of carbon anode consumed (giving only carbondioxide) in the production of 270 kg of aluminium metal from bauxite by the hall process is

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180kg
270kg
540 kg
90kg

Solution :`(omega_(1))/(E_(1))=(omega_(2))/(E_(2)),(omega_(1))/(3)=(270)/(93),omega_(1)=90kg`
28383.

The molecule ClF_(3) has same number of lone pairs as are present in :

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`SF_(4)`
`XeF_(2)`
`IF_(5)`
`XeF_(4)`

ANSWER :D
28384.

The mass of carbon anode consumed (giving only carbon dioxide) in the production of 270 kg of aluminium metal from bauxite by Hall process is:

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180 kg
270 kg
540 kg
90 kg

Solution :`2Al_2O_3 + 3C to 3CO_2 + 4Al`
`4 xx 27` g of Al are OBTAINED when carbon ANODE consumed= `12 xx 3g`
270 g of the Al are obtained when carbon anodeconsumed ` = (12 xx 3)/(4 xx 27)xx 270 = 90 kg `
28385.

The molecularity of the reaction,6FeSO_4+3H_2SO_4+KClO_3rarrKCl+3Fe_2(SO_4)_3+3H_2O is

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6
3
10
7

Solution : The total number of reactant MOLECULES participating in a chemical reaction is KNOWN as its MOLECULARITY, hence the molecularity = 6 +3+ 1 = 10
28386.

The mass of carbon anode consumed (giving only carbon dioxide) in the production of 270 kg of aluminium metal from bauxite by Hall process is

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`180 KG`
`270 kg`
`540 kg`
`90 kg`

Solution :`2Al_(2)O_(3)+UNDERSET(3xx12g)(3C)to3CO_(2)+underset(4xx27g)(4Al)`
`4xx27g` of Al are OBTAINED when CARBON anode consumed `= 12xx3 g`
28387.

The mass of carbon anode consumed (giving only carbon dioxide) in the production of 270 kg of aluminium metal from bauxite by the Hall process is :

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90 KG
540 kg
180 kg
270 kg

Solution :`2Al_(2)O_(3)+3Crarr4Al+3CO_(2)`
PRODUCTION of `4xx27Kg=36kg`
`therefore"Production of 270 kg of Al CONSUMERS C of anode"`
`=(36)/(4xx27)xx270=90kg.`
28388.

'The molecularity of a reaction can be 0,1,3 etc.'' The statement is

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1Both the above
None of these

Answer :B
28389.

The molecularity of reaction 2NO+O_2to2NO_2is

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5
2
3
0

Answer :C
28390.

The mass of BaCO_(3) produced when excess CO_(2) is bubbled through a solution of 0.205 mol Ba(OH)_(2) is

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81 g
40.5 g
20.25 g
162 g

Solution :`BA(OH)_(2)+CO_(2) rarr BaCO_(3)+H_(2)O`
Atomic wt. of `BaCO_(3)=137+12+16xx3=197`
No. of mole `=("wt. of substance")/("mol wt.")`
`:'` 1 mole of `Ba(OH)_(2)` GIVES 1 mole of `BaCO_(3)`
`:.` 0.205 mole of `Ba(OH)_(2)` will give 0.205 mole of `BaCO_(3)`
`:.` wt. of 0.205 mole of `BaCO_(3)` will be
`0.205xx197=40.385 GM ~~ 40.5 gm`.
28391.

The molecular weight of O_(2) and SO_(2) are 32 and 64 respectively. At 15°C and 150 mm Hg pressure, one litre of O_(2)contains N molecules. The number of molecules in two litres of SO_(2) , under the same conditions of temperature and pressure will be

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N/2
N
2N
4N

Solution :If 1 L of `O_(2)` gas contains N molecules, 2L of any gas under the same conditions will contain 2 N molecules.
28392.

The mass of an electron is m, its charge e and it is accelerated from rest through a potential difference V. The Kinetic energy of the electron in joules will be:

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V
eV
MeV
None

Answer :B
28393.

The molecular weight of protein is

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lt10000
gt10000
gt1000
gt1000 and lt10000

Answer :B
28394.

The mass of an electron is 9.1xx10^(-31)kg . Ifits K.E . Is 3.0xx10^(-25)J , calculate its wavelength .

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SOLUTION :896.7 NM
28395.

The mass of an atom of carbon is:

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1G
`1.99xx10^(-23)G`
`1//12g`
`1.99xx10^(23)g`

ANSWER :B
28396.

The molecular weight of NaCl determined from colligative properties is always

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`GT 58.5`
`LT 58.5`
`= 58.5`
Cannot be measured

Answer :C
28397.

The mass of an atom of carbon is :

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1g
1/12 G
`1.99 xx 10^(-23) g `
`1.99 xx 10^23 g`

Solution :Mass of an ATOM of C
` = (12)/(6.02 xx 10^23) =1.99 xx 10^(-23)g `
28398.

The molecular weight of NaCl determined by studying freezing point depression of its 0.5% aqueous solution is 30. The apparent degree of dissociation of NaCl is:

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0.95
0.5
0.6
0.3

Answer :A
28399.

The mass of an Al block (in grams) whosedimensions are 2.0 inch x 3.0 inch x 4.0 inch having density 2.78 g cm^(-3)is

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64.8 G
8.9 g
`1.1 XX 10^3 g `
`1.1 xx 10^5 g `

SOLUTION :`1.1 xx 10^3 g `
28400.

The molecular weight of hydrogen peroxide is 34.What is the unit of the molecular weight ?

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G
MOL
g `mol^(-1)`
mol `g^(-1)`

Answer :C