This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 29051. |
The Lanthanoid contraction is responsible forthe fact that |
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Answer» Zr and Y have about the same RADIUS |
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| 29052. |
The lanthanide contraction relates to : |
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Answer» Atomic radii |
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| 29053. |
The lanthanide contraction is responsible for the fact that: |
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Answer» ZR and Y have ALMOST the same radius |
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| 29054. |
Thelanthanidecontractionisresponsiblefor thefactthat |
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Answer» ZR andZnhave thesameoxidationstate |
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| 29055. |
The lanthanide contraction is responsible for the fact that |
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Answer» ZR and YB have same size |
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| 29056. |
The lanthanide contraction is due to |
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Answer» perfect shielding of F-orbitals `s gt p gt d gt f.` Hence 4f-electrons are not able to shield perfectly the attraction between nucleus and outermost eletronic orbit. The effect of INCREASED nuclear charge is more than that of shielding effect of 4f-orbitals. hence atomic or ionic size decreases from Ce to Lu. |
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| 29057. |
The Lambda^(@) values of KNO_3 and LiNO_3 are 145.0 and 110.1S cm^(2) mol^(-1) respectively . The lambda^(@) value for K^(+) ion is 73.5 S cm^(2) mol^(-1) . Calculate lambda^(@) (Li^(+)) . |
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Answer» `= 145.0 - 73.5 = 71.5 S cm^(2) mol^(-1)` `lambda^(oo) (Li^(+)) = Lambda^(oo) (LiNO_(3)) - lambda^(oo) (NO_(3)^(-))` `= 110.1 - 71.5 = 38.6 S cm^(2) mol^(-1)` |
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| 29058. |
The langmuir adsorption isotherm is given by |
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Answer» `x/m = - KP^(1//n)` |
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| 29059. |
The Langmuir adsorption isotherm is deduced using the assumption |
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Answer» the ADSORPTION sites are EQUIVALENT in their ABILITY to adsorb the particles |
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| 29060. |
The lambda for H_alpha line of Balmer series is 6500 overset@A. Thus lambda for H_beta line of Balmer series is: |
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Answer» 4814 |
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| 29061. |
The lack of vitamin C leads to |
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Answer» beriberi |
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| 29062. |
The K_w ofneutral solution is 10^(-12) at a particular temperature. What are its pH and pOH values? |
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Answer» SOLUTION :`pK_w=pH+pOH=10^(-12)` For a NEUTRAL solution, `pH=pOH` So `pH=pOH=6`. |
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| 29063. |
The K_(sp) of Mg(OH)_(2) is 1 xx 10^(-12), 0.01 M Mg(OH)_(2) will precipitate at the limiting pH |
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Answer» 3 `K_(sp) = [Mg^(2+)] [OH^(-)]^(2)` `1 XX 10^(-12) = 0.01 [OH^(-)]^(2)` `[OH^(-)]^(2) = 1 xx 10^(-10) rArr [OH^(-)] = 10^(-5)` `[H^(+) = 10^(-14)//10^(-5) = 10^(-9)` `PH = -LOG[H^(+)] = -log[10^(-9)] = 9`. |
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| 29064. |
The K_sp of PbCO_3 and MgCO_3 are 1.5 xx 10^-15 and 1 xx 10^-15 repectively at 298 K. What is the concentration of Pb^2+ ions in saturated solution containing MgCO_3 and PbCO_3 ? |
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Answer» `1.5xx10^(-4)` M |
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| 29065. |
The K_(sp) of CuS, Ag_(2)S and HgS are 10^(-31), 10^(-44) and 10^(-54) respectively. The solubility of these hydrides are in the order : |
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Answer» `Ag_(2)S GT CUS gt HgS` |
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| 29066. |
The K_(sp)ofBaCrO_(4) is 2.4xx10^(-10)M^(2). The maximum concentration of Ba(NO_(3))_(2)possible without precipitation in a 6xx10^(-4)M K_(2)CrO_(4) solution is |
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Answer» `4xx10^(-7)M` `2.4xx10^(-10)=[Ba^(2+)](6xx10^(-4))` `therefore [Ba^(2+)]=(2.4xx10^(-10))/(6xx10^(-4))` `=4.0xx10^(-7)M`. |
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| 29067. |
The K_(sp) of Agl is 1.5 times 10^-16. ON mixing equal volume of the following solutions, precipitation will occur only with….. |
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Answer» `10^-7 M AG^+ and 10^-19 M I^-` `10^-8 M Ag^- and 10^-8 M I` Ionic PRODUCT `=10^-16=K_(sp)` |
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| 29068. |
The K_(SP) of Agl is 1.5 xx 10^(-16). On mixing equal volumes of the following solutions, precipitation will occur only with |
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Answer» `10^(-7) M AG^(+)` and `10^(-19) M I^(-)` `10^(-8)M Ag^(+)` and `10^(-8) M I^(-)` Ionic product `~~ = 10^(-16)` `K_(sp)` = Ionic product. |
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| 29069. |
The K_(sp) of AgI at 25^@C is 1.0 xx 10^(-16) mol^2 L^(-2). The solubilityof AgI in 10^(-14)N solution of KI at 25^@C is approximetely (in mol L^(-1)): |
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Answer» `1.0 XX 10^(-16)` |
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| 29070. |
The K_(sp) of Ag_(2)CrO_(4) is 1.1 xx 10^(-12) at 298 K. The solubility (in mol/L) of Ag_(2)CrO_(4) in a 0.1 M AgNO_(3) solution is |
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Answer» `1.1 XX 10^(-11)` |
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| 29071. |
The K_(sp) of Ag_(2)CrO_(4), AgCl, AgBr and AgI are respectively, 1.1 xx 10^(-12), 1.8 xx 10^(-10), 5.0 xx 10^(-13), 8.3 xx 10^(-17). Which one of the following salts will precipitate last if AgNO_(3) solution is added to the solution containing equal moles of NaCl, NaBr, NaI and Na_(2)CrO_(4) |
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Answer» AgCl `[Ag^(+)] = sqrt((1.1 xx 10^(-12))/([C]))` If we take [C] = 1 then the MAXIMUM requirement of `[Ag^(+)]` will be CASE of `Ag_(2)CrO_(4)` |
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| 29072. |
The K_(sp) " for " Cr(OH)_(3) " is " 1.6xx10^(-30). The solubility of this compound in water is : |
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Answer» `root(4)(1.6xx10^(-30))` `(s) (3s)^(3)=K_(SP)` `27S^(4)=K_(sp)` `s=((K_(sp))/(27))^(1//4)=((1.6xx10^(-30))/(27))^(1//4)` |
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| 29073. |
The K_(sp) for Cr(OH)_(3)is 1.6xx10^(-30). The molar solubility of this compound in water is : |
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Answer» `root(3)(1.6xx10^(-30))` `Cr(OH)_(s)hArr UNDERSET(s)(Cr^(3+))+underset(3S)(3OH^(-))` `K_(sp)=(s)(3s)^(3)=27s^(4)` `therefore 27s^(4)=1.6xx10^(-30)` `s= root(4)(1.6xx10^(-30)//27)` |
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| 29074. |
The K_pvalue for the reaction equilibrium:H_2(g) + I_2 (s) iff 2HI(g)is 871 at 25^@C . If the vapour pressure of iodine is 4 xx 10^(-4) atm, calculate the equilibrium constant in terms of partial pressures at the same temperature. |
| Answer» SOLUTION :0.3484 ATM | |
| 29075. |
The K_(sp) for AgCl at 298 K is 1.0xx10^(-10). Calculate E for Ag^(+)//Ag electrode immersed in 1.0 M KCl solution. Given : E^(@)Ag^(+)//Ag=0.799" V". |
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Answer» SOLUTION :`AgCl(s)HARR Ag^(+)+Cl^(-)` `K_(sp)=[Ag^(+)][Cl^(-)]` `[Cl^(-)]=1.0M` `[Ag^(+)]=(k_(sp))/([Cl^(-)])=(1xx10^(-10))/(1)=1xx10^(-10)M` `"Now,"Ag^(+)+e^(-)rarrAg(s)` `E=E^(theta)-(0.059)/(1)log.(1)/([Ag^(+)])` `=0.80-(0.059)/(1)log.(1)/(10^(-10))` `=0.80-0.059xx10=0.21V` |
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| 29076. |
The K_(p) value for a homogeneous gaseous reaction is found to vary with the change in pressure. The correct conclusion is |
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Answer» the gases behave IDEALLY |
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| 29077. |
The K_(p) of a reaction is 10atm at 300K and 4 atm at 400K. The incorrect statement about the reaction is |
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Answer» The REACTION is exothermic |
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| 29078. |
The Kp for reaction A + BhArrC + D is 1.34 at 60° C and 6.64 at 100°C. Determine the standard free energy change of this reaction at each temperature and DeltaH° for the reaction over this range of temperature ? |
| Answer» SOLUTION :`-810` J/mol , -5872 J/mol and 41.3 KJ/mol | |
| 29079. |
Theknockingwillbemainmumwhenthemixtureof fuel is : |
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Answer» Strightchained |
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| 29080. |
the Kohinoor diamond was the largest diamond ever found . How many moles of carbon atom were presnent in it , if it is weight 3300 carat. [Given :1 carrat = 200 mg ] |
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Answer» |
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| 29081. |
The Kirchhoff's equation given the effect of_____ on heat of reactions: |
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Answer» Pressure |
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| 29082. |
The king of delocalization involving sigma and orbitals is called |
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Answer» INDUCTIVE EFFECT |
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| 29083. |
The kinetically more stable alltrope of phosphorus is |
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Answer» Redphosphorus |
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| 29084. |
The kinetic study of a reaction like vA rarr P at 300 K provides the following curve, where concentration is taken in mol dm^(-3) and time in min. |
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Answer» N = 0, k = 4.0 mol `dm^(-3) min^(-1)` RATE = `k[A]_0^n` …(ii) `therefore r_0 = 16[A]_0^2` On comparing EQ. (ii) and (iii),we get, k=`16dm^3mol^(-1)min^(-1)`,n = 2 |
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| 29085. |
The kinetic molecular theory attributes an average kinetic energy of (3)/(2) kT to each particle. What rms speed would a mist particle of mass 10^(-12) g have at room temperature (27^(@)C) according to the kinetic molecular theory ? |
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Answer» Solution :KE per MOLECULE `= (3)/(2)kT` `= (3)/(2).(R)/(N).T`. If the mass of ONE molecule is m then KE of this molecule `= (1)/(2) MC^(2)`, where c is the rms SPEED. `therefore (1)/(2)mC^(2) = (3)/(2) (R)/(N).T` or `C = sqrt(3 xx (R)/(N) xx (T)/(m))` `= sqrt((3 xx 8.314 xx 10^(7) xx 300)/(6.022 xx 10^(23) xx 10^(-12))) = 0.35 cm//s` |
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| 29086. |
The kinetic gas equation for 'N' number of molecues in volume V having mass m and root mean squarevelocity mu is : |
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Answer» `PV = ( 1)/( 3) mN mu ^(2)` |
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| 29087. |
The kinetic energy of the electron emitted when light of frequency 3.5xx10^(15)Hz is made to strike on a metal surface havng threshold frequency 1.5xx10^(15)Hz is (h=6.6xx10^(-34)Js) |
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Answer» `1.32xx10^(-18J` `=6.6xx10^(-34)(3.5xx10^(15)-1.5xx10^(15))` `=1.32xx10^(-18)J` |
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| 29088. |
The kinetic energy of sub-atomic particle is 5.85 xx 10^(-25)J. Calculate the frequency of the particle wave. (Planck’s constant, h = 6.626 xx 10^(-34) Js) |
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Answer» Solution :`K.E = 1/2 MV^2 = 5.85 xx 10^(-25) J` By de-broglie equation ` lamda = (h)/(mv)` `lamda = (v)/(upsilon)` ` therefroe v/v = (h)/(mv)` or` v = (mv^2)/(h) = (2 xx 5.85 xx 10^(-25)J)/(6.626 xx 10^(-34) JS)` ` = 1.77 xx 10^9 s^(-1)` |
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| 29089. |
The kinetic energy of one mole of any gas depends upon |
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Answer» PRESSURE of the GAS |
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| 29090. |
The kinetic energy of molecules at constant temperature in gaseous state is : |
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Answer» More than those in the LIQUID state |
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| 29091. |
The kinetic energy of molecule is zero at : |
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Answer» `0^@ C` |
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| 29092. |
The kinetic energy of electrons ejected by using light having frequency equal to threshold frequency (v_(0)) is |
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Answer» `hv_(0)` |
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| 29093. |
The kinetic energy of an electron is 4.55xx10^(-28) kJ. Calculate the de Broglie's wavelength. |
| Answer» SOLUTION :`7.2xx10^(-7)m` | |
| 29094. |
The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is (a_(0) is Bohr radius) |
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Answer» `(h^(2))/(4PI^(2)ma_(0)^(2))` use `r= n^(2) a_(0) (a_(0)=r_(1))` |
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| 29095. |
The kinetic date for the given reaction A(g)+2B(g)overset(K)toC(g) is provided in the following table for three experiments at 300 K {:("Ex. No.","[A/M]","[B/M]","Initial rate" (M sec^(-1))),(1.,0.01,0.01,6.930xx10^(-6)),(2.,0.02,0.01,1.386xx10^(-5)),(3.,0.2,0.02,1.386xx10^(-5)):} ltbgt In another experiment starting swith initial concentration of 0.5 and 1 M respectively for A and B at 300 K, find the rate of reaction after 50minutes from the starting of edperiment (inM//sec). |
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Answer» `6.93xx10^(-4)` |
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| 29096. |
The kind of colloid that does not exist |
| Answer» Answer :D | |
| 29097. |
The key structural feature of protein is: |
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Answer» ETHER linkage |
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| 29098. |
The key step in cannizzaro's reaction is the intermolecular shift of |
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Answer» Proton |
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| 29099. |
The keto form of ethyl aceto acetate is indicated by |
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Answer» Sodium <BR>`NaHSO_(3)` |
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| 29100. |
The kinetic energy of the photoelectrons depends upon: |
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Answer» INTENSITY of radiation |
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