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30451.

The group satisfying the secondary valencies of a cation in a complex are called:

Answer»

Ligands
Radicals
PRIMARY valencies
None

Answer :A
30452.

The group reagment for the test of alcohol is :

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cerric AMMONIUM nitrate
Schiff s REAGENT
MOLISCH's ragment
bromine water

Solution :N//A
30453.

The group reagent for the test of alcohols is :

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Cerric AMMONIUM nitrate
Schiff's reagent
Molisch's reagent
Bromine water

Solution :N//A
30454.

The group reagent for the analysis of group IIIB is:

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NH_4Cl+NH_4OH+H_2S`
`HCI+H_2O`
`NH_4CI+NH_4OH+(NH_4)_2CO_3+H_2S`
`CaCO_3`

ANSWER :A
30455.

The group reagent for group III is:

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DIL HCL
`NH_4OH` in the PRESENCE of `H_2S`
`NH_4OH` is the presence of `NH_4Cl`
`(NH_4)_2CO_3` in the presence of `NH_4OH`

ANSWER :C
30456.

The group of molecules having identical shape is:

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`PCl_(5)IF_(5), XeO_(2)F_(2)`
`BF_(3),PCl_(3),XeO_(3)`
`SF_(4),XeF_(4),C Cl_(4)`
`CIF_(3),XeOF_(2),XeF_(3)^(+)`

Solution :`CIF_(3) to ` HYBRIDISATION `=3+(1)/(2)[7-3]=5(sp^(3)d)`
`XeOF_(2) to` Hybridisation `=3+(1)/(2)[8-4]=5(Sp^(3)d)`
`XeF_(3)^(+) to` Hybridation `=3+(1)/(2)[8-2-1]=5(sp^(3)d)`
All MOLECULES have `sp^(3)`hybridzation and 2 lone pairs. HENCE all haveidentical (T-shape).
30457.

The group of metals which is known as ferrous metals is:

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FE,Co,Ni
Ru,RH,Pd
Os,Ir,Pt
Cr,Mn,Cu

Answer :A
30458.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)Qwhich will give borax beat Test with bluebeard?

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`Cr^(3+)`
`CO^(3+)`
`Ni^(2+)`
`CD^(2+)`

Answer :b
30459.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QWhich component of KCIO, used in above reaction with HCl and given Salt

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`KCIO_(3)`
KCL
`KClO_(3)`
NASCENT oxygen

Answer :d
30460.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QWhich metal salt gives a violet coloured bead in the borax bead test?

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`FE^(2+)`
`NI^(2+)`
`Co^(2+)`
`Mn^(2+)`

Answer :d
30461.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QColour of cobalt chloride is

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pink
black
colourless
green

ANSWER :B
30462.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QWhich of the following pairs of ions cannot be separated by HS in dilute hydrochloric acid?

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`BI^(3+) Sn^(4+)`
 `AL^(3+) HG^(2+)`
`ZN^(2+). Ca^(2+)`
 `Ni^(2+)Cu^(2+)`

Answer :a
30463.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QIn above paragraph, given compound 'D' is

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 `K_4[FE(CN)_6]`
`K_4[Mn(CN)_6)`
 `K_4[CO(CN)_6]`
`K_4[Ni(CN)_6]`

ANSWER :C
30464.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QIn above paragraph, given salt 'A' is

Answer»

Coch
Zns
Cos
NİS

Answer :a
30465.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QIn above paragraph, given salt 'B' is

Answer»

ZNS
NIS
Cos
MnS

Answer :B
30466.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QFormation of a rose red precipitate when a slightly alkaline solution of Inorganic salt is treated with dimethylglyoxime confirms the presence of

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cobalt
zinc
iron
nickel

ANSWER :d
30467.

The group of four basic radicals, CO^(2+) Nl^(2+) Mn^(2+) and Żn^(2+) have group reagent hydrogen sulphide in presence of NH.OH. These radicals are precipitated as sulphides which are insoluble in NH_(4)OH. Addition of HS increases the ionization of NH_4OH due to reaction of OH and H lon. NH_4OHharrNH_(4) + OHH_2S hArr2H+S^(2-) Salt (A) of above group cations having black colour treated with above reagent and produced compound (B), (B) on treatment with HCl and KCIO, again converted into (A) with the evolution of HS gas. (A) again treated with KCN gives a buff coloured ppt. (C) which dissolved in excess KCN and produced (D)QTo avoid the precipitation of hydroxides of Ni*, Co. Mn along with those of the third group cations, the solution should be

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heated with few drops of CONC. `HNO_(3)`
heated with excess of `NH_4`CI
concentrated to SMALL volume
 NONE of the above

Answer :b
30468.

The group obtained by the removal of H-atom of the -OH group of ROH is called

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ALKYL group
alkene
alkoxy group
all of these

ANSWER :C
30469.

The group linkage present in fats is :

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PEPTIDE linkage
ESTER linkage
glycoside linkage
NONE of these

Answer :B
30470.

The group II precipitate soluble in yellow ammonium sulphide may be

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`As,SB,Sn`
`Ca,Hg,BI,Cd`
Both (a) and (B)
None of these

Solution :YELLOW ammonium sulphide is a SOLVENT for As,Sb and Sa salphides
30471.

The group in which all the elemets do not have same number of valency electron is :

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Zero
Second
First
Seventh

Answer :A
30472.

The group I elements form hydroxides, which are :

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STRONGLY acidic
strongly basic
weakly acidic
neutral

Answer :B
30473.

The 'group displacement law' was given by :

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Bacqueral
Rutherford
Madam Curie
Soddy and Fajan

Answer :D
30474.

The group displacement law was proposed by :

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SODDY and Thomson
Soddy and RUTHERFORD
Soddy and FAJAN
Rutherford.

Answer :C
30475.

The group containing oxides that cannot be reduced by carbon to give the respective metal is :

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`Cu_2o, SnO_2`
`FeO_3`
`Na_2O, AI_2O_3`
PBO,`Fe_2O_3`

ANSWER :C
30476.

The group commonly present in synthetic detergents is

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RNa
RONa
RCOONA
`RC_6H_(4)SO_3Na`

ANSWER :D
30477.

The group 15 elements are commonly known as:

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Halogens
Normal elements
Pnicogens
None

Answer :C
30478.

The ground state electronic configuration of the elements, U, V, W, X, and Y (these symbols do not have any chemical significance) are as follows: U""1s^(2)2s^(2)2p^(3) V""1s^(2)2s^(2)2p^(6)3s^(1) W""1s^(2)2s^(2)2p^(6)3s^(2)3p^(2) X""1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)3d^(5)4s^(2) Y""1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)3d^(10)4s^(2)4p^(6) Determine which sequence of elements satisfy the following statement: (i) element forms a carbonate which is not decomposed by heating (ii) Element is most likely to form coloured ionic compound (iii) element has largest atomic radius (iv) element forms only acidic oxide

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V W Y U
V X Y W
V W Y X
V X W U

Solution :(i) Alkali metal carbonates do not decompose even at red HOT `to`V
(ii) Transition metal ions having unpaired d-electrons are coloured in aq. Sol./compounds`toX`
(iii) In case of Kr VAN der Waals. RADIUS is considered, which is largest atomic radius `to`Y
(IV) Si atom has only acid `SiO_(2) to W`
30479.

The ground state magnetic property of B_(2) and C_(2) molecules will be

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`B_(2)` paramagnetic and `C_(2)` diamagnetic
`B_(2)` diamagnetic and `C_(2)` paramagnetic
both are diamagnetic
both are paramagnetic.

Solution :`B_(2)` MOLECULE
`sigma1s^(2), sigma*1s^(2), sigma2s^(2),sigma*2S^(2),pi2p_(x)^(1)~~pi2p_(y)^(1)`
(Two UNPAIRED electrons hence paramagnetic)
`C_(2)` molecule `sigma1s^(2), sigma*1s^(2),sigma2s^(2), sigma*2s^(2),pi2p_(x)^(2)~~pi2p_(7)^(2)`
No unpaired electrons hence diamagnetic.
30480.

The ground state energy of hydrogen atom is -13.6 eV. Consider an electronic state Psiof He^(+)whose energy, azimuthal quantum number and magnetic quantum number are -3.4 eV, 2 and 0, respectively. Which of the following statement(s) is(are) true for the state Psi?

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It has 3 radial nodes
It has 2 angular nodes
The nuclear CHARGE experienced by the electron in this state is LESS than 2e, where e is the magnitude of the ELECTRONIC charge
It is a 4d state

Answer :A::C::D
30481.

The ground state electronic configuration ofFe^(3+) (g)ion is:

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`[Ar]3D^(3)4S^(2)`
`[Ar]3d^(6)4s^(2)`
`[Ar]3d^(5)`
`[Ar]3d^(6)`

Solution :`[Ar]3d^(5)`
30482.

The ground state electronic configuration of the element which is isoelectronic with NO^(+) is

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`1S^(2)2s^(2)2p^(6)3S^(2)3p^(3)`
`1s^(2)2s^(2)2p^(6)3s^(2)3p^(1)`
`1s^(2)2s^(2)2p^(6)3s^(2)3p^(2)`
`1s^(2)2s^(2)2p^(6)`

ANSWER :C
30483.

The ground state electronic configuration of Cu(29) is [Ar]3d^(10) 4s^(1) and not [Ar]3d^(0)4s^(2). This is indicated by the fact that

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Completely filled sub-shell configuration is more stable than one less filled sub-shell configuration.
Cu EXHIBITS +1 IONIC state besides `+2` STATES.
Copper turnings react with hot conc. `H_(2)SO_(4)` to evolve `SO_(2)(g)`rather than `H_(2)(g)`.
`Cu^(2+)` disproportionates in aqueous solution into `Cu^(2+)` and Cu.

Answer :B
30484.

The ground state electronic configuration ofoxygen in Li_(2)O is

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`1s^(2)2s^(2)2p^(4)`
`1s^(2)2s^(2)2p^(6)`
`1s^(2)2s^(2)2p^(2)`
`1s^(2)2s^(2)2p^(3)`

Solution :In`Li_(2)O` OXYGEN eixsts as `O^(2-)`.Its configuration is `1s^(2)2s^(2)2p^(6)`.
30485.

the ground state electronic configuration of chromium can be written as

Answer»

`[AR] 3d^1 4s^1`
`[Ar] 3d^1 4s^2`
`[Ar] 3d^5 4s^1`
`[NE] 3d^4 4s^1`

ANSWER :C
30486.

The ground state electronic configuration for chromium atom (z=24) is

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`[Ar]3D^(5)4s^(1)`
`[Ar](3d^(4))4s^(2)`
`[Ar]3d^(6)`
`[Ar]4s^(1)4p^(5)`

ANSWER :A
30487.

The groun dhaving isoelectronic species is

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`O^(2-),F^(-), NA^(+), MG^(2+)`
`O^(-), F^(-), Na, Mg^(2+)`
`O^(2-), F^(-), Na, Mg^(2+)`
`O^(-), F^(-), Na^(+), Mg^(2+)`

ANSWER :A
30488.

The ground state configuration of oxygen in OF_(2) is

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`1s^(2)2s^(2)2P^(4)`
`1s^(2)2s^(2)2p^(6)`
`1s^(2)2s^(2) 2p^(2)`
`1s^(2)2s^(2)2p^(3)`

Solution :In `OF_(2)`, OXYGEN exists as `O^(2+).(1s^(2) 2s^(2) 2p^(2))`
30489.

The Grignard reagent, CH_(3)CH_(2)MgBr, can be used to prepare

Answer»

ethane
3-methyl-3-pentanol
propanoic acid
all of these.

Answer :D
30490.

The grey cast iron contains:

Answer»

IRON carbide
Silicon carbide
silicon dioxide
Graphite

Answer :D
30491.

The grey cast iron contains :

Answer»

Irion CARBIDE
SILICON carbide
Silicon DIOXIDE
Graphite

Answer :D
30492.

The green pigment chlorophyll contains ................... Ion surrounded by a modified porphyrin ligand called ..................

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ANSWER :`MG^(2+)`, corrinring
30493.

The greenhouse effect is caused by

Answer»

CO
`NO_2`
`CO_2`
NO

SOLUTION :`CO_2`
30494.

The green pigment of plants essential for the formation of carbohydrates by photosynthesisis

Answer»

Acrophyll
Lyphyll
Chlorophyll
None of the above

Answer :C
30495.

The green mass formed when copper is exposed to moist air has the same composition as that of

Answer»

Azurite
Malachite
CUPRITE
COPPER pyrites

Answer :B
30496.

The green coloured salt formed on heating (NH_(4))_(2) Cr_(2)O_(7) is "................."

Answer»


ANSWER :`Cr_(2)O_(3)`
30497.

The greatest strain is involved in cycloalkane when the bond angle is:

Answer»

`60^@`
`90^@`
`120^@`
`108^@`

Answer :B
30498.

The greatest percentage of CO is in :

Answer»

COAL gas
Producer gas
Water gas
Oil gas

Answer :C
30499.

The greater the value of r_(+)//r_(-).

Answer»

the LOWER will be the CN
the HIGHER the VALUE of CN
the higher will be the NUMBER of cations
the lower will be the number of anions

Answer :B
30500.

The greater the ionic character of the carbon metal bond:

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The more reactive is the ORGANOMETALLIC COMPOUND
The less reactive is the organometallic compound
both are correct
None is correct

Answer :A