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31351.

The correct statement regarding RNA and DNA is :

Answer»

The sugar COMPONENT RNA is ARABINOSE and sugar in DNA is ribose
The sugar component in RNA is 2'DEOXYRIBOSE and the sugar component in DNA is arabinose.
The sugar component in RNA is arabinose and the sugar component in DNA is 2' - deoxyribose.
The sugar component in RNA is ribose and sugar component in DNA is 2'- deoxyribose.

Answer :D
31352.

The correct statement regarding entropy is,

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at absolute zero TEMPERATURE, entropy of a PERFECTLY crystalline solid is zero
at absolute zero temperature, the entropy of a perfectly crystalline substance is + ve
at absolute zero temperature,the entropy of 9 all crystalline substances is zero
at `0^(@)C` the entropy of a PERFECT crystalline solid is zero

Answer :a
31353.

The correct statement regarding defects in crystalline solids is ..........

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Frenkel defects DECREASES the density of crystalline solid. 
Frenkel defect is a DISLOCATION defect. 
Frenkel defect is found in HALIDES of alkali metals. 
SCHOTTKY defects have no effect on the density of crystalline solids. 

ANSWER :B
31354.

The correct statement regarding defect in solids is

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Schottky defect has no effect on the physical properties of SOLIDS
Frenkel defect is a DISLOCATION defect
Frenkel defect is USUALLY favoured by a very small difference in the sizes of cations and anions
trapping of proton in the lattice leads to the formation of f- centers.

Solution :Schottky defect has effect on the physical properties of solids i.e., it decreases the density of crystal. (c) Frenkel defect is usually favoured by a large difference in the sizes of cations and anions. (d) Trapping of electron in the lattice SITE leads to the formation of F-centers.
31355.

The correct statement regarding [Co(C_2O_4)_3]^(3+)complex is

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It is inner ORBITAL COMPLEX and DIAMAGNETIC
It is outer orbital complex and diamagnetic
It is inner orbital complex and para MAGNETIC
It is outer orbital complex and para magnetic

Answer :A
31356.

The correct statement regarding ClO_(n)^(-) molecular ion is:

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On decreasing value of 'n', `Cl-O` BOND ORDER increases
On increasing value of 'n', Cl-O bond LENGTH increases
On increasing value of n, OXIDATION number of CENTRAL atom increases
On increasing value of n, hybrid orbitals on central atom increases

Answer :C
31357.

The correct statement regarding a carbonyl compound with a hydrogen compound with a hydrogen atom on its alphacarbon, is

Answer»

A carbonyl COMPOUND with a hydrogen atom om its alphacarbon never EQUILIBRATES with its corresponding ENOL
A carbonyl compound with a hydrogen atom on its alphacarbon rapidlyequilibrates with its corresponding enol and this process is known as aldehyde-ketone equilibration
A carbonyl compound compound with a hydrogen atom on its alphacarbon rapidly equilibrates with its corresponding enol and this process is known as carbonylation
A carbonyl compound with a hydrogen atom on its alphacarbon rapidly equilibrates with its corresponding enol and this process is known as keto-enol tautomerism

Solution :Keto-enol tautomerism
`{:("|""|"),(-._(alpha)C-C- hArr-C=C-),("|""||""|"),(" "underset("(Keto)")(._(alpha)H)" "O""underset("(enol)")(OH)):}`
31358.

The correct statement regarding a carbonly compound with a hydrogen atom on its alphacarbon is :

Answer»

a carbonly compound with a hydrogen ATOM on its alpha-CARBON RAPIDLY equilibrates with its corresponding enol and this process is KNOWN as carbonylation
a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as keto-enol tautomerism
a carbonly compound with hydrogen atom on its alpha - carbon never equilibrates with its corresponding enol
a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as aldehyde-ketone equilibration.

Answer :B
31359.

The correct statement on the isomerism associated with the following complex ions : (P) [Ni(H_(2)O)_(5)NH_(3)]^(2+) (Q) [Ni(H_(2)O)_(4)(NH_(3))_(4)(NH_(3))_(2)]^(2+) and (R ) [Ni(H_(2)O)_(3)(NH_(3))_(3)]^(2+) is :

Answer»

<P>(P) and (Q) show GEOMETRICAL and optical isomerism
(Q) and (R ) show geometrical and optical isomerism
(P) and (Q) show only geometrical isomerism
(Q) and (R ) show only geometrical isomerism

Answer :D
31360.

The correct statement on the isomerism associated with the following complex ions , (a) [Ni(H_(2)O)_(5)NH_(3)]^(2+), (b) [Ni(H_(2)O)_(4)(NH_(3))_(2)]^(2+) and ( c) [Ni(H_(2)O)_(3)(NH_(3))_(3)]^(2+) is :

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(a) and (b) SHOW only GEOMETRICAL ISOMERISM
(b) and ( C) show geometrical and optical isomerism
(b) and (c ) show only geomterical isomerism
(a) and (b) show geometrical and optical isomerism

Answer :C
31361.

The correct statement reaarding a carbonyl compound with a hydrogen atom on its alpha- carbon, is that it :

Answer»

rapidly EQUILIBRATES with its corresponding enol and this PROCESS is known as carbonylation
rapidly equilibrates with its corresponding enol and this process in known as keto-enol TAUTOMERISM
nenver equilibrates with its corresponding enol
rapidly equilibrates with its correspondingenol and this process in known as aldehyde-ketone equilibration

Answer :B
31362.

The correct statement is/are:

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Zirconium (Zr) and hafnium (HF) have almost same size
Correct ORDER of ionisation energy of coinage metals is CugtAg`ltAu`
Carbon atom in `C Cl_(4)` is more electronegative than carbon atom in `CF_(4)`
`PB^(2+)` is more stable than `Pb^(4+)`

Solution :
Since `delta GT delta.`, hence C-atom in `CF_(4)` is more electronegative than in `C Cl_(4)`.
31363.

Thecorrectstatementis

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`cu_(2)CI_(2)` and `Ag_(2)S ` arecoloured
Uponstrongheatingparamagneticgases areevolved by Na`NO_(3)` and `AgNO_(3)`
Greenvitriola andbluevitriol are isomorphus
`KMnO_(4)` and `K_(2)Cr_(2) O_(7)`are coloureddue to

Answer :B
31364.

The correct statement is:

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DOLOMITE is the ORE of zinc
Galena is the ore of mercury
Pyrolusite is the ore of iron
Cassiterite is the ore of tin

Answer :D
31365.

The CORRECT statement is ___________.

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the earlier members of lanthanoid SERIES resemble calcium in their chemical properties
the extent of actinoid contraction is almost the same as lanthanoid contraction
in general, lanthanoid and actinoids do not SHOW variable oxidation states
`CE^(+4)` in aqueous SOLUTION is not known

Answer :A
31366.

The correct statement in the following is

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The ionic crstal of AgBr has Schottky defect
The unit cell having crystal PARAMETERS, `a=b NEC,alpha=beta=90^(@),gamma=120^(@)` is hexagonal
In ionic COMPOUNDS having Frenkel defect the RATIO `(gamma_(+))/(gamma_(-))` is high
The coordination number of `Na^(+)` ion in NACl is 4.

Solution :A crystal system is hexagonal if its unit cell having `a=bnec` axial ratio and `alpha=beta=90^(@),gamma=120^(@)` axial angles.
31367.

the correct statement from the foll. Is ___

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in maltose,GLYCOSIDIC linkage is between C-1 andC-2 of `ALPHA`-D- glucopyranose units
in CELLULOSE, glycosidic linkage is between C-1 and C-4 of `BETA` -D-glucopyranose unitsin sucrose , glycosidic linkage is between C-1 and C-4 of `alpha`-D-glucopyranoseunits.

Answer :A::B::C::D
31368.

The correct statement for the molecule, CsI_(3), is

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it contains `Cs^(+), I^(-)` and LATTICE `I_(2)` molecules
it is a COVALENT moleule
it contains `Cs^(+) and I_(3)^(-)` ions
it contains `Cs^(3+) and I^(-)` ions

SOLUTION :It contains `Cs^(+) and I_(3)^(-)` ions.
31369.

The correct statement for the molecule, CsI_(3) is:

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It is a COVALENT molecule.
it contains `Cs^(+)` and `i_(3)^(-)` ions.
it contains `Cs^(3+)` and `I^(-)` ions.
It contains `Cs^(+), I^(-) and `lattice `I_(2)` molecule.

Solution :`CsI_(3)` dissociates as `CsI_(3) to Cs^(+) +I_(3)^(-)`
31370.

The correct statement for the molecule, CsI_(3), is-

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it contains `Cs^(+),I^(-)` and lattice `I_(2)` molecule
it is a COVALENT molecule
it contains `Cs^(+)andI_(3)^(-)` ions
it contains `Cs^(3+)ANDI^(-)` ions

Solution :`CsI_(3)` molecule is FORMED by making electrovalent bond between `Cs^(+)andI_(3)^(-)` ions.
31371.

The correct statement for the equilibrium is , HClO_4 + H_2O hArr H_3O^+ + ClO_4^- :

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`HClO_4` is the CONJUGATE ACID of `H_2O`
`H_2O` is the conjugate acid of `H_3O^+`
`H_3O^+` is the conjugate BASE of `H_2O`
`ClO_4^-` is the conjugate base of `HClO_4`

ANSWER :D
31372.

The correct statement among the following is

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SODIUM dodecylbenzensulphonate is used in toothpaste is a CATIONIC detergent
Sodium lauryl SULPHATE forms an insoluble scum with hard water
Cetyltrimethylammonium bromide is a popular cationic detergent used in hair conditioner
Non - ionic detergents are formed when polythene glycol reacts with adipic acid

ANSWER :C
31373.

The correct statement about the synthesis of erythritol (C(CH_(2)OH)_(4)) used in the preparation of PETN is

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The SYNTHESIS requires TWO aldol condensation and two CANNIZZARO reactions
Alpha hydrogens of ethanol and methanol are involved in this REACTION
The synthesis requires four aldol condensations between methanol and ethanol
The synthesis requires aldol condensation and one cannizzaro reaction.

Answer :D
31374.

The correct statement about the following reaction sequence is(are) Cumene (C_9H_12)underset((ii)H_3O^+)overset((i)O_2)to P overset(CHCl_3//NaOH)to Q"(major)" + "R (min or )" Q underset(PhCH_2Br)overset(NaOH)to S

Answer»

R is steam volatile
Q gives dark violet coloration with 1% aqueous `FeCl_3` solution
S gives yellow PRECIPITATE with 2,4-dinitrophenylhydrazine
S gives dark violet COLOURATION with 1% aqueous `FeCl_3` solution

Solution :
Q (not R) is steam volatile due to intramolecular HYDROGEN bonding
Q gives violet colouration due to phenolic functional group
S gives yellow precipitate due to aldehydic group with 2,4-DNP
S does not have FREE phenolic group to respond to `FeCl_3` test.
31375.

The correct statement about the following disaccharide is

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Ring (a) is PYRANOSE with `ALPHA`-GLYCOSIDIC link
Ring (a) is furanose with `alpha`-glycosidic link
Ring (b) is furanose with `alpha`-glycosidic link
Ring (b) is pyranose with `BETA`-glycosidic link

Answer :A
31376.

The correct statement about sulphur hexa fluoride

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There are 12F-S-F `90^(@)` BOND angle
S in `SF_(6)` has an expanded OCTET
With `H_(2)O, SF_(6)`on accept lonepair of electron in the empty 3d atomic orbital and gets hydrolysed
`SF_(6)` has a distorted OCTAHEDRAL geometry

Solution :`SF_(6)=` octahedral structure because, So undergo `sp^(3)d^(2)` HYBRIDIZATION. It is HIGHLY inactive.
31377.

The correct statement about orthoboric acid is

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It is a strong MONOBASIC acid
it is not a PROTON donor, but a weak LEWIS acid
It is a tribasic acid
It is harmful for eyes

Answer :B
31378.

The correct statement about d-block elements is

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they are all metals
they show VARIABLE VALENCY
they form coloured ions and complex salts
all the above STATEMENTS are CORRECT

Answer :D
31379.

The correct statement aboutbuffer solution:

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It contains a weak ACID and its CONJUGATE BASE.
it contains a weak base and its conjugate acid
it shows little change in ph on ADDING small amount of an acid or base
All of the above

Answer :D
31380.

The correct stability order of the given carbanions is

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`AGTBGTC`
`bgtcgta`
`cgtbgta`
`cgtagtb `

ANSWER :C
31381.

The correct starting material and product of different disintegration series are

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`Th^(232) , Pb^(208)`
`U^(235) , Pb^(207)`
`U^(238) , Pb^(207)`
`NP^(237) , Bi^(209)`

Solution :`U^(238) , Pb^(207) implies` not belongs to any SERIES .
31382.

The correct stability order of the following species is

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C LT a lt B
c = b lt a
c lt a = b
a = b = c

Answer :C
31383.

The correct stability order of following is :

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IgtIIgtIIIgtIV
IIIgtIVgtIIgtI
IIgtIVgtIIIgtI
IVgtIIIgtIIgtI

Solution :STABILITY `prop` RESONANCE `prop` Hyperconjugation
LENGTH of conjugation is equal in all I, II,III & IV
But Hyperconjugation is IVgtIII=IIgtI and Hyperconjugation STRUCTURE of III is more stable than II since it is more delocalised.
31384.

The correct stability order for the following species is

Answer»

(II) gt (IV) gt (I) gt (III)
(I) gt (II) gt (III) gt (IV)
(II)gt (II)gt (III) gt (IV)
(I) gt (III) gt (II) gt (IV)

Solution :Carbocation (I) is STABILIZED by + R-effectof O-atomas wellas +I -effectof TWO ` -CH_(3)`GROUPS , carbocation(II)is stabilized by +I-effectof ` -CH_(3)` and `CH_(2)CH(CH_(3))_(2)` groups, carbocation, (III)is stabilized by+ R-effectof O - atom and +I-effect of one `-CH_(3)`,group while carbocation (IV) is stabilizedby +I- effect of ` -CH_(2)CH_(2)CH(CH_(3))_(2)` group THUS , decreasing , order of stability of thesecarbocations is : ` I lt III lt II lt IV `
31385.

The correct stability order for the following species is

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(II) GT (IV) gt (I) gt (III)
(I) gt (II) gt (III) gt (IV)
(II) gt (I) gt (IV) gt (III)
(I) gt (III) gt (II) gt (IV)

ANSWER :D
31386.

The correct stability order for N_(2) and its given ions is :

Answer»

`N_(2)gt N_(2)^(+)gt N_(2)^(-)gt N_(2)^(-2)`
`N_(2)^(-)gt N_(2)^(+)gt N_(2)gt N_(2)^(-2)`
`N_(2)^(+)gt N_(2)^(-)gt N_(2)gt N_(2)^(-2)`
`N_(2)gt N_(2)^(+)= N_(2)^(-)gt N_(2)^(-2)`

SOLUTION :`Hg_(2)Cl_(2)hArr Hg_(2)^(2+)+2Cl^(-)`
`N = 3`
`ALPHA = (i-1)/(n-1)`
`0.8=(i-1)/(3-1)`
`i=2.6`
31387.

The correct solubility order is/are (I) CaCO_(3)gtSrCO_(3)gtBaCO_(3)(II)Li_(2)CO_(3)ltNa_(2)CO_(3)gtK_(2)CO_(3) (III)K_(2)CO_(3)ltRb_(2)CO_(3)ltCs_(2)CO_(3)(IV)Na_(2)CO_(3)gtK_(2)CO_(3)gtRb_(2)CO_(3)

Answer»

II, IV
I, IV
II, III, IV
I, II, III

Answer :D
31388.

The CORRECT Sidgwick structure for ferrocyanide complex is _________.

Answer»




ANSWER :B
31389.

Thecorrect solubility order is/are I. CaCO_3 gt SrCO_3 gt BaCO_3 II. Li_2CO_3 lt Na_2CO_3 lt K_2CO_3 III. K_2CO_3 lt Rb_2CO_3 lt Cs_2CO_3 IV. Na_2CO_3 gt K_2CO_3 gt Rb_2CO_3

Answer»

II,IV
I,IV
III, II, IV
I,II,III

Answer :D
31390.

The correct set of the products obtained in the following reactions RCNoverset("reduction")rarr(A),RCMunderset((ii)H_(2)O)overset((i)CH_(3)MgBr)rarr(B),overset("hydrolysis")rarr(C),RNH_(2)overset(HNO_(2))rarr(D) The answer is :

Answer»

`{:(,A,B,C,D),((A), 2^(@)"Amine","Methyl KETONE",1^(@) "Amine","Alcohol"):}`
`{:(,A,B,C,D),((B),1^(@) "Amine","Methyle ketone",1^(@) "Amine","Alcohol"):}`
`{:(,A,B,C,D),((C),2^(@)"Amine","Methyl ketone",2^(@) "Amine","ACID"):}`
`{:(,A,B,C,D),((D),2^(@)"Amine","Methyl ketone",2^(@) "Amine","Aldehyde"):}`

ANSWER :B
31391.

The CORRECT set of their indicated bond length is

Answer»

`S-S(S_(8))gt P-P (P_(4))`
`d_(N-N), NH_(2)-NH_(2)gt NF_(2)-NF_(2)`
`d_(S-Cl), SOCl_(2) gt SO_(2)Cl_(2)`
`d_(B-O), B(OH)_(3) gt [B(OH)_(4)]^(-)`

Answer :A
31392.

The correct set of the following reaction is CH_3-oversetoverset(O)(||)C-OEt to CH_3-oversetoverset(O)(||)C-CH_2-oversetoverset(O)(||)C-OEt

Answer»

<P>(I)(IV)(P)
(II)(iii)(P)
(I)(iii)(Q)
(III)(i)(R)

Solution :This is claisen EASTER CONDENSATION reaction
31393.

The correct set of the following reaction is

Answer»

<P>(I)(iv)(P)
(III)(I)(R)
(I)(iv)(Q)
(III)(iv)(R)

SOLUTION :This is intramolecular Aldol CONDENSATION and product is `alpha,BETA` - unsaturated carbonyl compound.
31394.

The correct set of the following reaction is :

Answer»

(I)(i)(Q)
(II)(i)(P)
(III)(i)(R)
NONE of these

Solution :This is perkin REACTION.
31395.

The correct set of quantum numbers (n, I and m respectively) for the unpaired electron of chlorine atom is

Answer»

`2, 1, 0`
`2, 1, 1`
`3,1,1`
`3,2,1`

Solution :`""_(17)Cl-1s^(2)2s^(2)2p^(6)3s^(2)3p_(x)^(2)3p_(y)^(2)3p_(z)^(1)`
For `3p_(1)` electron n = 3, L = 1 , m = -1 , 0 or + 1.
31396.

The correct set of quantum numbers for the valence electrons of rubidium atom (Z=37) is

Answer»

`5,0,0,+1//2`
`5,1,0,+1//2`
`5,1,1,+1//2`
`5,0,1,+1//2)`

Solution :The electronic configuration of rubiduim
(Z=37) is
`1s^(2)2s^(2)2p^(6)3S^(2)3p^(6)3D^(10)4S^(2)4p^(6)5s^(1)`
Valence electron is `5s^(1)`.
Quantum NUMBER n=5, l=0, m=0, `s=+1//2`
31397.

The correct set of quantum numbers for the unpaired electrons of chlorine atom is

Answer»

`2,0,0 + (1)/(2)`
`2,1,-1 + (1)/(2)`
`3,1,1, pm (1)/(2)`
`3,0,0 pm (1)/(2)`

SOLUTION :The electronic configuration of CI would be `rarr 1S^2,2S^2 2P^6,3S^2 3P^5`
The p-orbital has 1 UNPAIRED electron and the quantum number CORRESPONDING to it as

`n=3,1=1 , m=1,s=1//2`
31398.

The correct set of quantum number for theunpaired electron of chlorine atom is

Answer»

`2, 0, 0, +(1)/(2)`
`3, 0, 0, +-(1)/(2)`
`2,1 , -1,+(1)/(2)`
`3, 1, 1, +-(1)/(2)`

SOLUTION :Electronic configuration of CI (Z = 17) atom:
`1s^(2)2s^(2) 2P^(6) 3s^(2) 3p^(5)`
So, the unpaired electron of CL atom is in 3p-orbital.
31399.

The correct set of quantum number for the unpaired electron of chlorine atom is:

Answer»

n=2, l=1, m=0
n=2, l=1, m=1
n=3, l=1, m=1
n=3, l=0, m=0

Answer :C
31400.

The correct set of four quantum numbers for outermost electron of potassium (Z=19 ) is

Answer»

`3,1,0,1/2`
`4,0,0,1/2`
`3,0,0,1/2`
`4,1,0,1/2`

Solution :`K(Z=19),1s^(2)2s^(2)2p^(6)3s^(2)3P^(6)4S^(1)`
For OUTERMOST electron,
`n=4,l=0,m=0,s=+1/2`