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31251.

The cost of electricity required to deposit 1 g of Mg is Rs.3.00. The cost of deposit 8 g of Al is (al.mass Al = 27 , Mg = 24)

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RS.`12.00`
Rs. `24.00`
Rs. `32.00`
Rs.`42.50`

SOLUTION :`(W_(Al))/(W_(Mg)) = (E_(Mg))/(E_(Al))`
`therefore (W_(Al))/(1)= (24//2)/(27//3) = (12)/(9)`
`therefore W_(Al) = (12)/(9)` gms.
When 1 gm of Mg deposited at the same time , `(12)/(9)` gm of Al deposited by passing same quantity of ELECTRICITY
For 1 gm Mg `-=` it cost three rupees
`therefore (12)/(9) g Al -= x : x = (3 xx (12//9))/(1) = 4` rupees
`therefore` For 8 gm of Al `-= 8 xx 4 = 32` rupees
31252.

The cost of electricity required to deposit 1 g of Mg is Rs 3.00. The cost to deposit 8 g of Al is __________. )At. Mass Al = 27 , Mg = 24)

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RS 12.00
Rs 24.00
Rs 32.00
Rs 42.50

Answer :C
31253.

The cost at 5 paise/KWH of operating an electric motor for 8 hours which takes 15 amp at 110V is

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RS 66
66 paise
37 paise
Rs 6.60

Solution :`W = I.V`
31254.

The corrrect relationship between K_c and K_p is gaseous equilibrium is:

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`K_C = K_P (RT)^DELTAN (B)`
`K_p = K_C (RT)^Deltan`
`(k_c)/(RT) (K_P)^Deltan`
(K_P)/(RT) = (K_C)^Deltan`

ANSWER :B
31255.

The corrosion of iron object is not favoured by

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presence of `H^(+)` ION
presence of moisture in AIR
presence of impurities in iron object
presence of VACUUM

SOLUTION :Follow theory of corrosion .
31256.

The corrosion of iron object is favoured by

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PRESENCE of `H^(+)` ION
Presence of MOISTURE of air
Presence of impurities in iron object
All of the above

Answer :D
31257.

The corrosion of iron object is favoured by:

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PRESENCE of `H^+` ion
Presence of MOISTURE in air
Presence of imputities in IRON object
All of these

Answer :D
31258.

The correctr statement regarding electrophile is-

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electrophile is a NEGATIVELY charged species and can form a bond by accepting a pair of electrons from another electrophile
electrophiles are generally neutral speices and can form a bond by accepting a pair of electrons from a nucleophile
electrophiles can be EITHER neutral of postively charged speices and can from a bond by accepting a pair of electrons from a nucleophile
electrophile is a negatively charged species and can form a bond accepting a pair of electrons from a nucleophile

Solution :Electrophile may be neutral `(e.g.,NO_(2)^(oplus))`. They can TAKE ELECTRON from nucleophile to COMPLETE its ortet.
31259.

The correct values of ionisation energies of Si, P, Cl and S are respectivey:

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`786,1012,999,1256`
1012,786,99,1256
`786,1012,1256,999`
`786,999,1012,1256`

ANSWER :C
31260.

The correct values of ionization enthalpies (in kJ "mol"^(-1)) of Si, P, Cl and S respectively are :-

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786, 1012, 999, 1256
1012, 786, 999, 1256
786, 1012, 1256, 999
786, 999, 1012, 1256

Solution :ORDER of IE
`underset(3s^(2)3P^(2))(SI) lt underset(3s^(2)3p^(3))(P) lt underset(3s^(2)3p^(4))(S) lt underset(3s^(2)3p^(5))(Cl)`
`underset(1256)(Cl) gt underset(1012)(P) gt underset(999)(S) gt underset(786)(Si)`
31261.

The correct three dimensional presentation of ethane is

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ANSWER :A
31262.

The correct thermodynamic conditions for a non-spontaneous reaction at all temperature is

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`(delta H LT 0 and delta S GT 0)`
`(delta H lt 0 and delta S = 0)`
`(delta H gt 0 and delta S lt 0)`
`(delta H gt 0 and delta S gt 0)`

ANSWER :1
31263.

The correct thermodynamic conditions for the spontaneous reaction at all temperature is

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`DELTAHLT0 and DeltaS=0`
`DELTAHGT0 and DeltaSlt0`
`DeltaHlt0 and DeltaSgt0`
`DeltaHlt0 and DeltaSlt0`

Solution :`DeltaG=DeltaH-T.DeltaS`
For,`DeltaHlt0` and `DeltaSgt0, DeltaG=-ve` (ALWAYS)
`therefore` SPONTANEOUS at all temperatures.
31264.

The correct stucture of ethylenediaminetetraacetic acid (EDTA) is

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SOLUTION :The CORRECT STRUCTURE of EDTA is
31265.

The correct structure of the product of the following reaction will be (AAK_MCP_37_NEET_CHE_E37_009_Q01)

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`(AAK_MCP_37_NEET_CHE_E37_009_A01)`

ANSWER :C
31266.

The correct structure of trans-2-hexenal is :

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SOLUTION :
31267.

The correct structure representation of carboxylate ion is

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Solution :`R-COOH OVERSET(-H^(+))to R-COO^(-)`
is a RESONANCE HYBRID of resonating structures.
31268.

The correct structure of the product 'A' formed in the reaction

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SOLUTION :
31269.

The correct structure of the product 'A' formed in the reaction A is ……..

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SOLUTION :
31270.

The correct structure of the drug paracetamol is

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ANSWER :B
31271.

The correct structure of the drug paracetamol is ...............

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SOLUTION :
31272.

The correct structure of the drug paracetamol is :

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ANSWER :B
31273.

The correct structure of the dipeptide gly-ala is

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`NH_2overset(CH_(2))overset(|)underset(H)underset(|)-underset(O)underset(||)(C)-NH -CH_(2) -overset(O)overset(||)(C)-OH`
`H_(2)N-overset(H)overset(|)underset(H)underset(|)(C)-overset(O)overset(||)(C)-overset(H)overset(|)(N)-underset(CH_(3))underset(|)(CH)-overset(O)overset(||)(C)-OH`
`H-N-overset(H)overset(|)underset(H)underset(|)(C)-overset(O)overset(||)(C)-NH-overset(H)overset(|)underset(CH_(2))underset(|)(C)-overset(O)overset(||)(C)-OH`

Solution :
31274.

The correct structureof thedipeptide gly - ala is .

Answer»




Solution :`H_(2)N - underset("(Gly)")(CH_(2))-overset(O)overset(||)(C)- overset(H)(N) - CH - underset("(Ala)")underset(CH_(3))underset(|)(CH) - overset(O)overset(||)(C) -OH`
31275.

The correct structure of product, D formed in the following sequence of reactions is

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ANSWER :B
31276.

The correct structure of product B, formed in the reaction sequence is (AAK_MCP_35_NEET_CHE_E35_020_Q01)

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`(AAK_MCP_35_NEET_CHE_E35_020_A01)`

ANSWER :D
31277.

The correct structure of o-dihalobenzne is …….

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ANSWER :B
31278.

The correct structure of hydroquinone or quinol is

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(`AAK_MCP_36_NEET_CHE_E36_004_A01`)

ANSWER :B
31279.

The correct structure of glycine at given pH are :

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`H_(3) overset(oplus)(N)CH_(2)-underset(underset(O)(||))(C)-OH""atpH=2.0`
`H_(3)overset(oplus)(N)CH_(2)-underset(underset(O)(||))(C)-O^(Theta)""at pH=6.0`
`H_(2)NCH_(2)-underset(underset(O)(||))(C)-O^(Theta)`
`H_(2)NCH_(2)-underset(underset(O)(||))(C)-OH""atpH=12`

SOLUTION :At acidic `pH`, glycine will convert to cation and at basic `pH` glycine will convert to anion.
31280.

The correct structure of Fe(CO)_(5) is

Answer»

octahedral
TETRAHEDRAL
square pyramidal
TRIGONAL bipyramidal

ANSWER :D
31281.

The correct structure of ethylenediamineteraacetic acid (EDTA) is

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SOLUTION :is the CORRECT STRUCTURE of EDTA.
31282.

The correct structure of Fe(CO)_5 is

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octahedral
tetrahedral
square pyramidal
trigonal bipyramidal

Answer :A
31283.

The CORRECT structure of ethyldiaminetetraacetic acid (EDTA) is ____________.

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ANSWER :C
31284.

The correct structure of drug paracetamol is

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ANSWER :B
31285.

The correct structure of 4-bromo-3-methyl but-1 ene is:

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`BrCH=C(CH_(3))_(2)`<BR>`H_(2)C=C(CH_(3))CH_(2)CH_(2)Br`
`H_(2)C=CH-CH(CH_(3))-CH_(2)Br`
`CH_(3)-C(CH_(3))=CHCH_(2)Br`

Answer :C
31286.

The CORRECT structure of dipeptide gly-ala is _________.

Answer»


`NH_2- UNDERSET(H) underset(|) OVERSET(CH_2SH)overset(|)C-underset(O)underset(||)C-NH-CH_2-overset(O)overset(||)C-OH`
`H_2N-underset(H) underset(|) overset(H) overset(|)C-overset(O)overset(||)C-overset(H)overset(|)N-underset(CH_3)underset(|)CH-overset(O)overset(||)C-OH`
`H_2N-underset(H) underset(|) overset(H) overset(|)C-overset(O)overset(||)C-NH-underset(CH_2SH)underset(|) overset(H) overset(|)C-overset(O)overset(||)C-OH`

ANSWER :C
31287.

The correct structure for compound B will be:

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ANSWER :B
31288.

The correct structural formula of pyridinium chlorochromate is ……

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ANSWER :A
31289.

The correct structural formula of potassium tri oxalate aluminate (III) is

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`K_3[AL(C_2O_4)_3]`
`K_3[Al(C_2O_4)_2]`
`K_2[Al(C_2O_4)_2]`
`K_2[Al(C_2O_4)_3]`

ANSWER :A
31290.

The correct statements with respect to Ellingham's diagram among the following are I) Magnesium reduces aluminium oxide below 1700 K II) Aluminium reduces magnesium oxide above 1700 KIII)Aluminium reduces magnesium oxide below 1700 K IV) Magnesium reduces aluminium oxide above 1700 K

Answer»

I & II
II & III
III & IV
II, III & IV

ANSWER :A
31291.

The correct statemet is

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the earlier members of lanthanoid series RESEMBLE CALCIUM in theirchemicalproperties.
the extent ofactinoid contractionisalmostthe sameaslanthanoid contrction.
in general, Inathnoid and actinoids andactinoids do notshow VARIABLEOXIDATION states.
`Ce^(4+)` inaquesoussoltuion is not known.

Solution :LANTHANOIDS are placaed in the samegroup (2) inwhichtheelement Ca occupies a POSITION. Therefore, theearlier members of theseries resembleCa in theirchemical properties.
31292.

The correct statement(s) to the adsorption of a gas on a solid surface is (are)

Answer»

Adsorption is ALWAYS exothermic 
Physisorption may transform into chemisorption at high TEMPERATURE 
Physisorption INCREASES with increasing temperature but chemisorption DECREASES with increasing temperature 
Chemisorption is more exothermic than physisorption, however it is very slow due to higher ENERGY of activation

Solution :Adsorption is exothermic at high temp physisorption transfer to chemical adsorption `DetlaH` is more for chemisorption [40 - 400]
Activation energy in more
31293.

The correct statements (s) regarding, (i) HClO, (ii) HClO_(2) ,(iii) HClO_(3)and (iv) HClO_(4) is are

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The number of Cl=O bonds in (ii) and (III) together is two
The number of lone PAIRS of electrons on Cl in (ii) and (iii) together is three
The hybridization of Cl in (IV) is `sp^(3)`
AMONGST(i) to (iv), the strongest acid is (i)

Solution :
`**` Number of lonepair on Cl in (ii) & (iii) together is 3
`**` Hybridisation of Cl in (iv) is `sp^(3)`
`**` Strongest acid is `HClO_(4)` (iv)
31294.

The correct statements (s) about Cr^(2+) and Mn^(3)is(are) [Atomic numbers of Cr= 24 and Mn= 25]

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`Cr^(2+)` is a reducing agent
`Mn^(3+0` is an oxidizing agent
Both `Cr^(2+)` and `Mn^(3+)` exhibit `d^(4)`electronic CONFIGURATION
When `Cr^(2+)` is used as a reducing agent, the CHROMIUM ion attains `d^(5)` configuration

Solution :(a) `Cr^(2+)` is a reducing agent as it gets oxidizd to `Cr^(3+) ( 3d^(3)` or `t_(2g)^(3)`which is a stable half-filled configuration)
(b) `Mn^(3+)` is an oxidizing agent asitgets reduced to `Mn^(2+)( 3d^(5)`which is more stablehalf-filledconfiguration ).
(c )`Cr( 24) = 3d^(4) 4s^(2):. Cr^(2+ ) = 3d^(4)`
`Mn(25) = 3d^(5) 4s^(2):.Mn^(3+) = 3d^(4)`
Thus, both `Cr^(2+)` and `Mn^(3+)` have `d^(4)` electronic configuration .
(d) When `Cr^(2+)`is usedas a REDUCINGAGENT, it is OXIDIZED to `Cr^(3+)` which has `d^(3)` and not `d^(5)` configuration.
31295.

The correct statements regarding Mg(ClO_(4))_(2) ?

Answer»

is a SALT of hypochlorous acid
is a salt of PERCHLORIC acid
is called ANHYDRONE
is "used in dry BATTERY"

Solution :`Mg(ClO_(4))_(2) ` is a salt of perchloric acid
`Mg(ClO_(4))_(2)` is called Anhydrone
`Mg(ClO_(4))_(2)` is used an the electrolyte in dry batter.
31296.

The correct statement(s) regarding (i) HClO, (ii) HClO_(2), (iii) HClO_(3) and (iv) HClO_(4), is (are)

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The number of CL = O bonds in (II) and (iii) TOGETHER is TWO
The total number of lone pairs of electrons on Cl in (ii) and (iii) together is three
The hybridization of Cl in (IV) as `sp^(3)`
Amongst (i) to (iv), the strongest acid is (i)

Solution :(a) Statement (a) is wrong because the number of Cl = O bonds in (ii) and (iii) is 1 + 2 = 3.
(b) Statement (b) is correct because the lone pairs of electrons on Cl in (ii) and (iii) is 2 + 1 = 3.
(c) Statement (c) is also correct since hybridization of Cl in (iv) is `sp^(3)`. In fact, it is `sp^(3)` in all the four acids.
(d) Statement (d) is wrong because strongest acid is (iv) and not (i).
31297.

The correct statements regarding defects in solids are

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FRENKEL defect is usually favoured by a very small difference in the sizes of CATION an anion
Frenkel defect is a dislocation defect
trapping of an electron in the lattice leads to the FORMATION of F-center
Schottly DEFECTS have no effect on the physical properties of solids.

Solution :When an ion is missing from its normal position and occupies an interstitaial SITE between the lattice points, Frenkel defect arises, hence it is a dislocation defect.
The electrons trapped in anion vacancies are referred to as F-centers.
Schottky defects arise when some atoms or ions are missing from their normal lattice points. Due to the presence of large number of vacancies in crystals, its density (i.e. physical property) is lowered.
31298.

The correct statement(s) pertaining to the adsorption of a gas on a solid surface is(are) (i) adsorption is always exothermic (ii) physisorption may transform into chemsisorption transform into chemisorption at high temperature (iii) physisorption increases with increasing temperature but chemisorption decreases with increasing temperature . (iv) chemisorption is more exothermic than physisorption , however it is very slow due to higher energy of activation.

Answer»

(i) and (IV) only
(II) and (III) only
(i),(ii) and (iv) only
All of these.

Answer :C
31299.

The correct statement(s) pertiaining to the adsorption of a gas on a solid surface is (are)

Answer»

Adsorption is always exothermic
Physisorption may transform into chemisorption at high TEMPERATURE
Physisorption increases with INCREASING temperature but chemisorption DECREASES with increasing temperature
Chemisorption is more exothermic than physisorption, however it is very SLOW DUE to higher energy of activation.

Answer :A::B::D
31300.

The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are)

Answer»

Adsorption is always oxothermic
PHYSISORPTION may transform into chemisorption at HIGH TEMPERATURE
Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature
Chemisorption is more exothermic than physisorption, howerver it is very SLOW due to higher energy of activation

Solution :Only (C ) is incorrect because physisorption decreases with increasing temperature and chemisorption increase initially with increasing temperture.