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2851.

What is rancidity? How can we reduce the problem of rancidity?

Answer»

Rancidity: It is defined as chemical decomposition of oils and fats which in another words is spoiling food materials that difficult for consumption.It can be prevented by following methods:(i) The packing of food materials should be replaced the air with Nitrogen.(ii) The food materials should be placed at very low temperatures.(iii) Addition of antioxidants also prevents rancidity process.

2852.

Olue-4 Explain rancidity and corrosion with examples?

Answer»

Answer

Corrosion is defined as a process where materials, usually metals, deteriorate as a result of a chemical reaction with air, moisture, chemicals, etc.For example, iron, in the presence of moisture, reacts with oxygen to form hydrated iron oxide.4Fe+ 3O2+ nH2O → 2Fe2O3.nH2O

Rancidity is the process of oxidation of fats and oils that can be easily noticed by the change in taste and smell is known as rancidity.For example, the taste and smell of butter changes when kept for long.

2853.

Appreciate the role of inertness of chemicals to prevent the rancidityprocess

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Thank u for your answer

2854.

20.Explain the following terms with one example each.(a) Corrosion(b) Rancidity

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a)Corrosion: It is the process of degradation of material on continuous interaction with atmosphere. Because of Corrosion the strength of the material decreases

Ex:The materials like water pipes which are made up of metal continuously exposed to moist atmosphere will get corrode and over the time water starts leaking.The bottom layer of the boats or ships get corrode, so for every fixed period of time they will get replaced by new materials.Rusting of some of the materials in our house items.

b)When the substance containing oils and fats are exposed to air they get oxidised and become rancid due to which their smell, taste and colour change. This process is known as rancidity.

For example when a when butter is kept open for a long time then its smell and taste gets changed

2855.

CHEMISTRY IN EVERYDAY LIFEifrom drues The medicines are

Answer»

Digestion relies onchemicalreactions between food and acids and enzymes to break down molecules into nutrients the body can absorb anduse.

Soaps and detergents act as emulsifiers to surround dirt and grime so it can be washed away from clothing, dishes, and our bodies.

Drugs work because ofchemistry.

Like my answer if you find it useful!

2856.

A ANITI Siduman (TITANSWhat will happen if inflated balloon is kept in a fridge and why?

Answer»

it will burst please mark best

it will burst is the correct answer of the given question

It will be burst after sometime.

2857.

A weather balloon is inflated with helium. The balloon has a volume of 100 m3 and it must beinflated to a pressure of 0.10 atm. If 50 L gas cylinders of helium at a pressure of 100 atm areused, how many cylinders are needed? Assume that the temperature is constant.(A) 2(B) 3(C) 4(D) 1

Answer»

If the cylinders were at 1.00 atm, they would contain 50.00 L each, so at 100.0 atm they contain 5000. L each.

1 m³ = 1000 L,

so 100.0 m³ = 1.000 × 10⁵ L.

Since the pressure in the balloon is only 0.10 atm, though, the gas volume equals only 1.000 × 10⁴ L at 1 atm.

(1.000 × 10⁴ L) / (5000. L/cylinder) = 2.00 cylinders.

2858.

Give detailed note on strength of carbon nanotubes.

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2859.

) Heavy platinum

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Platinumis achemical elementwith symbolPtandatomic number78. It is adense,malleable,ductile, highly unreactive,precious, silverish-whitetransition metal. Its name is derived from the Spanish termplatino, meaning "little silver"

2860.

17.A student has performed an experiment in the laboratory. He mixed water with hexane and found twolayers separated. Second time he mixed chloroform with water and he again found two layers in thetest tube. Explain which will be upper layer and which one will be lower layer in both the experiments.

Answer»

Since hexane is non polar in nature and have lower density than water it will be upper layer.

In second case chloroform will be in the lower layer because it is more dense than water.

2861.

17. Greenhouse effect leads to global warming. Whichsubstances are responsible for green house effect ?

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The major greenhouse gases (GHG's) solely responsible for greenhouse effect are Carbon dioxide, Ozone, Methane and Water vapour.

Explanation:Greenhouse gases include water vapour, carbon dioxide, methane, nitrous oxide, and ozone. The major greenhouse gases are water vapour, which causes about 36-70% of the greenhouse effect on Earth (not including clouds); carbon dioxide, which causes 9-26%; methane, which causes 4-9%, and ozone, which causes 3-7%.

2862.

list out the green house gases explain how green house effect can cause climatic changes

Answer»

5 greenhouse gases are as follows

carbon dioxide (co2)

methane (ch4)

nitrios oxide (n2o)

sulphur florouide (sf6)

cfc-12 (ccl2f2)

Increase in the amount of green house gases in the atmosphere would lead to the warming of the atmosphere and would cause the melting of ice which would lead to rise in sea level.

greenhouse gases:carbon dioxidemethanenitrous oxidefluorinated gases

effect:Thegreenhouse effectis the process by which radiation from a planet's atmosphere warms the planet's surface to a temperature above what it would be without its atmosphere.

2863.

Name two metals which will displace hydrogen from dilute acids, andwhich will not.two metals7.

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2864.

Name two metals which are found in nature in the free state.

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2865.

What property of an element is measured by electronegativity

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ELECTRONEGATIVITY IS THE MEASURE OF TENDENCY OF AN ATOM TO ATTRACT BONDING PAIR OF ELECTRONS.

2866.

How (i) valency electrons (it) Electronegativity affect the bond formation inbetween two atoms.

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The number ofelectronsin an atom's outermostvalenceshell governs itsbondingbehaviour. They need to lose only one or twovalence electronsto form positive ions with an s²p⁶ configuration. NONMETALS. Nonmetals tend to attract additionalvalence electronsto form either ionic or covalentbonds

Intermediate differences inelectronegativitybetween covalentlybondedatoms leadtopolarity in thebond. As a rule, anelectronegativitydifference of 2 or more on the Pauling scale between atoms leadstotheformationof an ionicbond.

2867.

t 3.15 What is the basic difference between the termselectron gain enthalpy and electronegativity?

Answer»
2868.

HC CCH CH-CH Which carbon atomwill show minimum electronegativity(A) Fifth(C) First(B) Third(D) Second

Answer»

electronegativity order of hybridisation is

sp> sp2>sp3

so, here minimum electronegative atom is 5th because it is sp3 hybridised.

2869.

WAT INTILOT MATTI ITnoma (nITIODO ULIOTT17. (a) Define electronegativityOn the basis of quantum numbers justify that sixth Period of the periodic table shouldhave 32 elements

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b)Principal quantum number is number which determines the main energy level or shell in which the electron is present.It gives the average distance of the electron from the nucleus & specifies the value of the energy of the electron.

Azimuthal quantum number is the number which determines the sub shell in a principal energy shell to which an electron belongs.

In the periodic table each period begins with the filling of principal quantum number (n). The value ofnfor the sixth period is 6. For n= 6, azimuthal quantum number (l) can have values of 0, 1, 2, 3, 4.

In the 6thperiod, electrons can be filled in only 6s, 4f, 5d,and 6psubshells. Now, 6s has one orbital, 4f has seven orbitals, 5d has five orbitals, and 6p has three orbitals. Therefore, there are a total of sixteen (1 + 7 + 5 + 3 = 16) orbitals available.

According to Pauli’s exclusion principle, each orbital can accommodate a maximum of 2 electrons. Thus, 16 orbitals can accommodate a maximum of 32 electrons.

Hence, the sixth period of the periodic table should have 32 elements.

a)Electronegativity is a measure of the tendency of an atom to attract a bonding pair of electrons. The Pauling scale is the most commonly used. Fluorine (the most electronegative element) is assigned a value of 4.0, and values range down to caesium and francium which are the least electronegative at 0.7.

2870.

SP-17. () Define electronegativity(6) On the basis of quantum numbers justify that sixth Period of the periodic table shouldhave 32 elementshf

Answer»

(a) Electronegativityis a measure of the tendency of an atom to attract a bonding pair of electrons. The Pauling scale is the most commonly used. Fluorine (the mostelectronegativeelement) is assigned a value of 4.0, and values range down to caesium and francium which are the leastelectronegativeat 0.7.

(b) Principal quantum number is number which determines the main energy level or shell in which the electron is present.It gives the average distance of the electron from the nucleus & specifies the value of the energy of the electron.

Azimuthal quantum number is the number which determines the sub shell in a principal energy shell to which an electron belongs.

In the periodic table of the elements, a period indicates the value of the principal quantum number (n) for the outermost shells. Each period begins with the filling of principal quantum number (n). The value of n for the sixth period is 6. For n = 6, azimuthal quantum number (l) can have values of 0, 1, 2, 3, 4.

According to Aufbau’s principle, electrons are added to different orbitals in order of their increasing energies. The energy of the 6d subshell is even higher than that of the 7s subshell.

In the 6th period, electrons can be filled in only 6s, 4f, 5d, and 6 p subshells. Now, 6s has one orbital, 4f has seven orbitals, 5d has five orbitals, and 6p has three orbitals. Therefore, there are a total of sixteen (1 + 7 + 5 + 3 = 16) orbitals available. According to Pauli’s exclusion principle, each orbital can accommodate a maximum of 2 electrons. Thus, 16 orbitals can accommodate a maximum of 32 electrons.

Hence, the sixth period of the periodic table should have 32 elements.

2871.

s dangerous.GuessandWritetheFeasort.What is the formula given by Milliken to find the electronegativity of an element?Cold and Silver are used to make iewellery. Why?6.

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2872.

U)RberandBect12(c)RbClandMgCl(d)MgCl2a. Which of the following is insoluble in water?(a) AgF(b) Agl(c) KBr(d) CaClh. The electronegativity dig

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option 2

2873.

4. Thermometer is used to determine the density of milk. Ts Pulses provide us with protein.

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Ans :- Statement is false.

hydrometer

Ahydrometeris an instrument used for measuring the relative density of liquids based on the concept of buoyancy. They are typically calibrated and graduated with one or more scales such as specific gravity.

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2874.

01502 1 DIty 2ADIB Lokl 6L LAk12 RYiEd M3bke kltekhblyg

Answer»

इस प्रकार की मिश्रधातुओं में अवयव धातुएँ जब पिघली हुई होती हैं, तब वे एक दूसरे में घुली हुई रहती हैं, किंतु ठोस होने पर धातुओं के क्रिस्टल अलग-अलग हो जाते हैं, अर्थात्‌ धातुएँ परस्पर अविलेय हैं। इस प्रकार मिश्रधातु प्रत्येक अवयव धातु के शुद्ध क्रिस्टल कामिश्रणहोती है और ठंडा करने पर कोई एक अवयव धातु ठोस रूप में पृथक्‌ हो जाती है। उदाहरणार्थ, एक तरल मिश्रधातु, जिसमें मात्रानुसार 10 भाग सीसा और 90 भाग टिन होते हैं, जब ठंडी की जाती है तब शुद्ध टिन के क्रिस्टल प्रथम उसी प्रकार से पृथक्‌ होते हैं जिस प्रकार शुद्ध हिम के क्रिस्टल चीनी के तनु विलयन में से ठंडा करने पर पृथक्‌ होते हैं। जिस ताप पर टिन के क्रिस्टल पृथक होना प्रारंभ करते है, वह ताप शुद्ध टिन के गलनांक से कम होता है। टिन के गलनांक को जब उसमें सीसा घुला रहता है, ज्ञात कर सीसे का अणुभार उसी नियम द्वारा निकालते हैं जिस नियम से पानी में घुली वस्तओं का अणुभार निकालते हैं। इस विधि से उन कई धातुओं का अणुभार निकाला गया है, जो तनुघात्विक विलयन में अलग परमाणु के रूप में रहती है। सीसा-ऐंटीमनी मिश्रधातु मिश्रण श्रेणी की है। ऐंटीमनी भंगुर होता है और सीसा मुलायम। मुद्रण धातु सीसी, ऐंटीमनी और अत्यंत कम मात्रा में टिन की मिश्रधातु है। इस मिश्रधातु में ऐंटीमनी की कठोरता तो होती है, किंतु यह उसकी तरह भंगुर नहीं होती।

2875.

chemical test to distinguish between tertiary but chloride and but chloride

Answer»
2876.

Giveachemical test to distinguish between aniline and N-methylaniline

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2877.

give a chemical test to distinguish between c6h5ch2nh2 and c6h5nh2

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2878.

Q. 3. Give a chemical test to distinguishbetween C2H;Br and CoH5Br.

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On addition of AgNO3 in C2H5Br a yellow ppt is formed which is insoluble in NH4OH

C6H5Br will not form yellow ppt with AgNO3

thanl you

2879.

ぎ1prference betux enread phosPhouous

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Ans :- The keydifference between redand white phosphorusis that thered phosphorus appears as darkredcolored crystals whereas the whitephosphorusexists as a translucent waxy solid that quickly becomes yellow when exposed to light. Phosphorusis a chemical element that occurs in several different allotropes.

2880.

Seetion AQ. 1- The atomic number of phosphorus is 15-Give the electronic configuration of P-ion.

Answer»

We knowthatit will have 15+3= 18 electronnow

1s2 2s2 2p6 3s2 3p6

2881.

DINESH COMPANION14.54Give one chemical test to distinguish between the following pairs of compounds(i) Methylamine and dimethylamine2.

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(i)Methylamine and dimethylamine can be distinguished by the carbylamine test.

Carbylamine test: Aliphatic and aromatic primary amines on heating with chloroform and ethanolic potassium hydroxide form foul-smelling isocyanides or carbylamines. Methylamine (being an aliphatic primary amine) gives a positive carbylamine test, but dimethylamine does not.

thank-you sir

2882.

Is it possible to have an element having atomic number 1.5 placed between hydrogen and helium ?

Answer»

No, because in the modern periodic table, elements are placed in increasing order of their atomic numbers. Atomic number is always a simple whole number as half electron or half proton cannot exist. It can be either 1 or 2.So, there can be no element with atomic number 1.5.

2883.

Bull 밖do

Answer»

no they are entirely different and infact different types of conformation a crystal can aquire.

Body-Centered Cubic (BCC) or CCP StructureThe body-centered cubic unit cell has atoms at each of the eight corners of a cube (like the cubic unit cell) plus one atom in the center of the cube (left image below). Each of the corner atoms is the corner of another cube so the corner atoms are shared among eight unit cells. It is said to have a coordination number of 8. The bcc unit cell consists of a net total of two atoms; one in the center and eight eighths from corners atoms as shown in the middle image below (middle image below). The image below highlights a unit cell in a larger section of the lattice.

Face Centered Cubic (FCC) StructureThe face centered cubic structure has atoms located at each of the corners and the centers of all the cubic faces (left image below). Each of the corner atoms is the corner of another cube so the corner atoms are shared among eight unit cells. Additionally, each of its six face centered atoms is shared with an adjacent atom. Since 12 of its atoms are shared, it is said to have a coordination number of 12. The fcc unit cell consists of a net total of four atoms; eight eighths from corners atoms and six halves of the face atoms as shown in the middle image above. The image below highlights a unit cell in a larger section of the lattice

Hexagonal Close Packed (HCP) StructureAnother common close packed structure is the hexagonal close pack. The hexagonal structure of alternating layers is shifted so its atoms are aligned to the gaps of the preceding layer. The atoms from one layer nest themselves in the empty space between the atoms of the adjacent layer just like in the fcc structure. However, instead of being a cubic structure, the pattern is hexagonal. (See image below.) The difference between the HCP and FCC structure is discussed later in this section.

2884.

what does the diffusion of gasses tell us about their particles

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(a) The diffusion of gases tells us that:(1) Matter consists of tiny particles, that have space between them.(2) The particles of matter are in constant motion.Â(b) The example of diffusion of gases in liquids is:(1) Oxygen (gas) gets dissolved in blood (liquid) during the process of respiration.

2885.

If n 3,(A) 10, 110, m 0 then the possible atomic number may be(C) 12, 13(B) 11, 12(D) 13, 14

Answer»

n = 3 ... means 3rd orbit L = 0 , means S subshell

so, 3S can have either 1 or 2 electrons

=> 1s2 , 2s2, 2p6 = 10 electrons 3s1/3s2 = 1 or 2 electrons

so , the atomic numbers can be 10+1 , 10+2 = 11,12

option B

2886.

T-2けIl

Answer»

no. of moles in 1.2gm of Mg is 1.2/12 = 0.1 mol and since 1 mol carries +2 charge so, and in 1 mol , the total charge is 1 Faraday

so , in 0.1 mol the charge will be = 0.1*2*F = 0.2F and 1F = 96485C so total charge is 0.2*96845 = 19369C

2887.

b) increasesdecreasesD) becomes zero5)When a mercury drop of radius R, breaks into n droplets of equal size, the radius (t) of each droplet is71C) r = Rm1/3n1/3D)6)The surface tension of a liour. İsar1n

Answer»

Relation between big drop of Radius R and radius of small n drops of radius r is

R^3 = nr^3(volume remains equal)

r = R/n^1/3

(B) is correct option

2888.

11. If the density of a certain gas at 30°C and768 torr is 1.35 kg/m3 its density at STP would be

Answer»

Let us assume that V = 1 liter.

PV = nRT

n = PV/RT = (768/760 atm) x (1 L) / [(0.0821 Latm/mole K) x (303K)] = 0.0406 moles of gas

= 1 L x (1 m³ / 1000 L) x (1.35 kg / 1 m³ ) x (1000 g / 1 kg) = 1.35 g

Thus, MW of gas = 1.35 g / 0.0406 moles = 33.3 g/mole.

At STP,n = PV / RT = (1.0 atm) x (1 L) / [(0.0821 Latm/moleK) x (273K)] = 0.0446 moles

= 0.0446 moles x (33.3 g / mole) x (1 kg / 1000 g) = 0.00149 kg

= 0.00149 kg / 1 L x (1000 L / 1 m³) = 1.49 kg / m³

bro bt smjh nhi aaya..3rd step k bd

2889.

explain the process of titration in great details along with the knowledge that how it helps in knowing the concentration of the unknown

Answer»

titration process, two solutions are prepared. Substance to be analyzed (titrate) is taken in a conical flask and solution of known concentration (titrant) is filled in burette. Certain auxiliary agents are added in a conical flask to identify the end point of titration. Solution from burette is added to the conical flask till marked color change occurs at the completion of chemical reaction. At completion of reaction, auxiliary agent reacts with titrant and gives color change. This process is called as titration.In short, the process of determining the volume of the titrant required to react completely with a known volume of solution under analysis is called as titration.

Importance of Volumetric analysis:

High precision is obtained

Simple apparatus is required

Easy process and fast result

Different methods for different types of substance

Types of titration methods:Direct Titration:Substance is directly titrated with titrant by using simple indicator. Example: titration of strong acid (HCl, HNO3) with strong base (NaOH, KOH)Indirect Titration:Substance is not directly titrate but precipitated or removed from the reaction and the product formed has to be titrated. Back Titration:Use for the substances which are not water soluble or which are weak acids or bases.

Classification of Titrimetric Methods:Titrimetric methods are classified into various types depending on the nature of chemical reactions. 1. Acid –Base Titration 2. Redox Titration 3. Complexometric Titration 4. Precipitation Titration 5. Zeta Potential 6. Miscellaneous

2890.

(iv) Conductometric titration

Answer»

Conductometric titration is a type of titration in which the electrolytic conductivity of the reaction mixture is continuously monitored as one reactant is added. The equivalence point is the point at which the conductivity undergoes a sudden change.

2891.

Explain titration in great detail.

Answer»

titration is a technique where a solution of known concentration is used to determine the concentration of an unknown solution. Typically, the titrant (the know solution) is added from aburetto a known quantity of the analyte (the unknown solution) until the reaction is complete. Knowing the volume of titrant added allows the determination of the concentration of the unknown. Often, an indicator is used to usually signal the end of the reaction, the endpoint.

how it helps in knowing conc . help please

2892.

Determine the empirical formula of an oxide of iron which has 69.9% yon and30.1% dioxygen by mass.

Answer»
2893.

uestions1. An object has moved through adistance. Can it have zerodisplacement? If yes, supportyour answer with an example.2. A farmer moves along theboundary ofa square field of side10 m in 40 s. What will be themagnitude of displacement of thefarmer at the end of 2 minutes 20seconds from his initial position?Which of the following is true fordisplacement?3.(a) It cannot be zero(b)Its magnitude is greater thanthe distance travelled by theobject.

Answer»

1)

2)

2894.

. An object has moved through adistance. Can it have zerodisplacement? If yes, supportyour answer with an example.

Answer»

what is your question

If the distance travelled by the object is in straight path then it can have 0 displacement. For example: A car travels some distance on a straight highway and it come backs from the same highway then it displacement will be 0.

2895.

11. Delermine the order and rate constant of the reactionSO2Cl SO2+ Cl2using the following data.Time (s)1x10" | 2.5x10" | 3x10"| S():Cb] ( m ol L"). 1-0.0.0896一ㄧ一一0,08920,0577-1 0.05 I 70

Answer»

Could u repost a clear pic please once again?

2896.

он4] The IUPAC name of1SCH1) 3-Methylcyclo-l-buten-2-ol2) 4-Methylcyclo-2-buten-1-ol3) 4-Methylcyclo-l-buten-3-ol4) 2-Methylcyclo-3-buten-1-ol

Answer»

the numbering will start from -OH

so, the correct option is 2.

2897.

Why is as orbidalfilled before 3dorbidal

Answer»

this is because N+L value of 4s is less than 3d.N+L value of 4s is 4 and N+L value of 3d is 5.so 4s orbital is filled before 3d

4s is less than 3d so 4s orbital is filled before 3d

S orbit contain only 2elecrons is less then 3d orbit

2898.

Discuss iodoform test. How will you distinguish between propane-1-ol and Propane-2-olthis test ?22.

Answer»

Any compounds containing theCH3C=Ogroup or theCH3CH(OH)group give a positive result with the iodoform test. When I2 and NaOH is added to a compound containing one of these groups, apale yellow precipitate of iodoform(triiodomethane) is formed.

The iodoform test can therefore be used to identifyaldehydesandketones; is the compound is an aldehyde then it must be ethanal (this is the only aldehyde with the CH3C=O group). This occurs as three I atoms replace the H atoms of CH3C=OR, and the C-C bond breaks due to the electron withdrawing effect of the three I atoms (as I is more electronegative than C) forming CHI3 and the salt anion of a carboxylic acid (depending on the R group of the original compound, which influences the length of the carbon chain of the anion RCOO- that is formed).

This test can also be used to identifyalcohols; if the alcohol is a tertiary alcohol then it gives no result as it cannot be be oxidised. If the alcohol is a primary alcohol then it must be ethanol (as this is oxidised to ethanal, which is the only aldehyde that gives a positive result with the iodoform test). All secondary alcohols give a positive result, as they are oxidised to ketones.

propane -1-ol , doesn't contain... -CH(OH)-CH3 ( that is present in propane-2-ol)

so, it will not give iodoform test..

2899.

define pyrolysis

Answer»

Pyrolysis is the thermal decomposition of materials at elevated temperatures in an inert atmosphere. It involves the change of chemical composition and is irreversible. The word is coined from the Greek-derived elements pyro "fire" and lysis "separating".

2900.

(a) Why copper is regarded as a transition element though it has completely filled 3d orbital?(b) Discuss preparation of KMnO, from pyrolusite ore. Write down all the reactions involved.

Answer»

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