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90751.

A colloid is formed by adding FeCl_3 in excess of hot water. What will happen if excess sodium chloride is added to this colloride ?

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Solution :A positively CHARGED colloidal solution of hydrated ferric oxide is FORMED. On ADDING sodium chloride, NEGATIVELY charged chloride ions neutralise the positive charge of the colloidal solution. Coagulation of the sol takes place.
90752.

(A) Colloidal particles show Brownian Movement(R ) Brownian movement arises because of the impact of the molecules of the dispersion medium with the colloidal particles.

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Both (A) and (R ) are TRUE and (R ) is the correct EXPLANATION of (A)
Both (A)and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

Answer :A
90753.

A colloid is formed by adding FeCl, in excess of hot water. What will happen if excess sodium chloride is added to this colloid ? The

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Solution :Adding excess `FeCl_(3)` to hot water produces COLLOIDAL solution of hydrated ferric oxide which is a POSITIVELY CHARGED COLLOID. When excess NaCl is ADDED, `Cl^(-)` will coagulate the colloidal sol.
90754.

A colloid is formed by adding FeCL_(3) in excess of hot water. What will happen if excess of sodium chloride is added to this colloid ?

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SOLUTION :On ADDING `FeCl_(3)` to WATER, a colloidal sol of hydrate ferric oxide is formed which carries +ve charge due to adsorption of `FE^(3+)` ions on its surface. On adding `NACL, Cl^(-)` ions bring about coagulation of the sol.
90755.

A collision between high energy molecules overcomes the forces of repulsion and brings the formation of an unstable molecule cluster, called activated complex. The life span of an activatd complex is very small. Thus, the activated complex breaks either into reactants again or new substances, i.e. products. The activation energy (E_(a)) depends upon the nature of chemical bonds undergoing rupture and is independent of enthalpies of reactants and products. The energy changes during exothermic and endothermic versus the progress of the reaction are as shown below : When temperature is increased, the number of active molecule increases, i.e. the number of effective collisions will increase and the rate of reaction will increase. Activation energy (E_(a))=E_(("activated complex"))-E_(("ground state")) DeltaH=E_(a)(f)-E_(a)(b) The activation energy of exothermic reaction , A to B, is 80kJ. The heat of reaction is 200kJ. The activation energy for the reaction, B to A, will be

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`80KJ`
`120kJ`
`280kJ`
`200KJ`

ANSWER :C
90756.

A colloid always :

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Contains two phases
Is a true SOLUTION
Contains THREE phases
Contains only WATER soluble particles

Solution :COLLOID is hetergeneous, biphasic solution.
90757.

A collision between high energy molecules overcomes the forces of repulsion and brings the formation of an unstable molecule cluster, called activated complex. The life span of an activatd complex is very small. Thus, the activated complex breaks either into reactants again or new substances, i.e. products. The activation energy (E_(a)) depends upon the nature of chemical bonds undergoing rupture and is independent of enthalpies of reactants and products. The energy changes during exothermic and endothermic versus the progress of the reaction are as shown below : When temperature is increased, the number of active molecule increases, i.e. the number of effective collisions will increase and the rate of reaction will increase. Activation energy (E_(a))=E_(("activated complex"))-E_(("ground state")) DeltaH=E_(a)(f)-E_(a)(b) The activation energy for the forward reaction ,X to Y, is 60kJ mol^(-1) and DeltaH is -20kJ//mol^(-1), the activation energy for the reverse reaction is

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`40kJ//mol`
`60kJ//mol`
`80kJ//mol`
`20kJ//mol`

ANSWER :C
90758.

A cold, green flame can be made by passing CO_2 over warm:

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Bonze
White P
Grey Sn
Green candles

Answer :B
90759.

A codonhas a sequence of A, and specific a particular B that is to be incorporated into C. what are A,B,C

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`{:("A","B","C"),("3 BASES","AMINO acid","carbohydrate"):}`
`{:("A","B","C"),("3 acids","carbohydrate","protein"):}`
`{:("A","B","C"),("3 bases","protein","amino acid"):}`
`{:("A","B","C"),("3bases","amino acid","protein"):}`

Answer :D
90760.

A codon on the mRNA has :

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ONE base
Two base
Three base
Variable NUMBER of bases

Answer :C
90761.

A codon has a sequence of A and specifies a particular B that is to be incorporated into C what are ? A,B,C

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A-3 bases, B-amino acid, C-carbohydrate
A-3 acids, B-carbohydrate, C-protein
A-3 bases, B-protien, C-amino acid
A-3 bases, B-amino acid, C-protein

Solution :A codon is a SPECIFIC SEQUENCE of three adjacent bases on a STRAND of DNA or RNA that provides GENETIC CODE information for a particular amino acid.
90762.

(A) : CoCl_3 . 3NH_3 does not ionise in aqua solution. (R ): CoCl_3 . 3NH_3 is an example of aionic compounds.

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Both A & R are true, R is the correct EXPLANATION of A
Both A & R are true, R is not correct explanation of A
A is true, R is false
A is false, R is true

Answer :C
90763.

(A) : [Co_(2)(OH)_(3)(NH_(3))_(6)]Cl_(3) is an example of polynuclear complex compound (R) : Compound in which the number of central metal atoms is more than one is called polynuclear compound

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Both A & R are TRUE, R is the CORRECT explanation of A
Both A & R are true, R is not correct explanation of A
A is true, R is false
A is false, R is true

Answer :A
90764.

(A) : CO_(2) reacts with Grignard reagent followed by acid catalysed hydrolysis gives carboxylic acid . (R) : Alkyl halide reacts with Mg in the presence of ether gives Grignard reagent .

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Both A & R are true , R is the correct explanation of A
Both A & R are true , R is not correct explanation of A
A is true , R is false
A is false , R is true

ANSWER :B
90765.

A CO_2 molecule contains:

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2 `sigma-bonds` and 1 `pi-bond`
4 `pi-bonds`
2 `sigma` and 2 `pi-bonds`
4 `sigma-bonds`

ANSWER :C
90766.

A co -polymer ofvinyl chlorideand vinyledene chloride is called:

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Dynel
Saran
Vinylon
Oelen

Answer :A
90767.

A co -polymer ofvinyl chlorideand vinylidene chloride is called:

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Dynel
Saran
Vinylon
None of these

Answer :A
90768.

A co -polymer ofvinyl chlorideand vinyacetate is called:

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Vinyon
Saran
Dynel
Orlen

Answer :A
90769.

A co -polymer ofvinyl chlorideand vinyl acetate is called:

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Vinyon
PVCA
Dynel
Orlon

Answer :A
90770.

A co -polymer ofisobutylene and isoprene is called:

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BUTYL rubber
Buna -S
Buna -N
Thiokol

Answer :A
90771.

A co-polymer is one in which

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two monomers undergo condensation
there is excessive cross linking
extensive HYDROGEN bonding
REPEATING unit CONTAINS two different monomers

Answer :D
90772.

Assertion:Co-ordination compounds are generally formed by transition metals. Reason :Transition metals generally have partly filled d-orbitals in n^(th) shell.

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Both A & R are true, R is the CORRECT explanation of A
Both A & R are true, R is not correct explanation of A
A is true, R is false
A is false, R is true

Answer :C
90773.

A co-ordination complex has the formula PtCl_(4).2KCl. Electrical conductance measurement indicate the presence of three ion in one formula unit. Treatment with AgNO_(3) produces no precipitate of AgCl. What is the co-ordination number of Pt in this complex ?

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5
6
4
3

Solution :N//A
90774.

A closed vessel with rigid walls contains 1 mole of ._(92)^(238)U and 1 mole of air at 298K. Considering complete decay of ._(92)^(238)U to ._(82)^(206)Pbthe ratio of the final pressure to the initial pressure of the system at 298K is

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ANSWER :9
90775.

A closed vessel with rigid walls contains 1 mole of ""_(92)^(238)U and 1 mole of air at 298K. Considering complete decay of ""_(92)^(238)U to ""_(82)^(206)Pb, the ratio of the final pressure to the initial pressure of the system at 298K is…..

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SOLUTION :`""_(92)^(238)U RARR ""_(82)^(206)P + 8 ""_(2)^(4)He + 6 ""_(-1)^(0)e`
`(P_("final"))/(P_("intial"))= (8 (He) + 1 ("air"))/(1("air"))`
90776.

A closed vessel with rigid walls contains 1 mol of ._(92)^(238)U and 1 mole of air at 298K. Considering complete decay of ._(92)^(238)U " to " ._(82)^(206)Pb, the ratio of the final pressure to the initial pressure of the system at 298 K is

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Solution :Initial moles of gases = 1
`underset("Initial moles1 mole")(._(92)^(238)U rarr ._(82)^(206)Pb) + underset(8 "mole")(8_(2)^(4) He + 6 ._(-1)e^(0))`
Moles after
Total gaseous moles after decomposition `= 8 + 1 = 9` moles
Ratio of pressures `(P_(f))/(P_(i)) = (n_(f))/(n_(i)) = 9`
90777.

A closed vessel of known volume containing known amount of ideal gaseous substance 'A'was observed for variation of pressure with temperature .The expected graph was to be like as in ( i) However actual observations revealed the graph to be like. (ii) The deviation was attributed to polymerisation of gas molecules as nA(g) 1 A_(n) (g).If it is known that the above reactiongives only 50% yield. (a) Calculate the ratio of ( n_("experiment"))/( n_("theoritical")) ( where n_("exp.")= Total no. of gaseous mole actually present n_("theoretical") = Total no. of mole origianl taken ) ( b) Find the value of n to which the gas A is being polymerised into

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ANSWER :(a) 0.625 (B) 4
90778.

A closed vessel of known volume containing known amount of ideal gaseous substance 'A' was observed for variation of pressure with temperature . The expected graph was to be like as in (i) However actual observations reveal the graph to be like (ii). The deviation was attributed to polymerisation of gas molecules as nA(g)hArrA_(B)(g).If it is known that the above reaction given only 50% yield Find the value of n to which the gas A is being polymerised into

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Solution :`nArArrA_(N) V=` constant
`t=t_(eq)` moles `a_(0)-a_(0)alpha (a_(0)alpha)/(n)` ideal gases:-
PV-nRT
`P=(nR)/(V)(t^(@)+273)`
`PV_(s)t(.^(@)C) y=mx+C`where `m=(nR)/(V)`
`(m_("actual"))/(m_("theoriticl"))=(n_("actual"))/(n_("theortical"))=(a_(0)a_(0)alpha+(a_(0)alpha)/(n))/(a_(0))=(1.0375)/(1.66)=(1)/(1.6)`
`(0.5xx1.6)/(n)=0.2`
n=4
90779.

A closed system undergoes a process AtoB. If it occurs reversible, then the system absorbs q_(1) amount of heat and performs w_(1) amount of work. However, if it occurs out irreversible, then the system absorbs q_(2) amount of heat and does w_(2) amount of work. is (q_(1)+w_(1)) greater than, less than or equal to (q_(2)+w_(2)) ?

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SOLUTION :For a reversible process: `DeltaU_(1)=q_(1)+w_(1)` and for an irreversible process: `DeltaU_(2)=q_(2)+w_(2)`.
In both processes, the initial state (A) and final state (B) of the system are identical. Since U is a state function, its change in a process depends only on the initial and final STATES of the system, and not on the NATURE of the process. as the initial and final states in both processes are identical, the change in INTERNAL energy in both cases will be the same. therefore, `DeltaU_(1)=DeltaU_(2)` and `q_(1)+w_(1)=q_(2)+w_(2)`.
90780.

A closed flask contains water in all its three states, solids, liquid and vapour at 0@C. In this situation the average KE of the water molecule will be:

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MAXIMUM in VAPOUR state
Maximum in SOLID state
Greater in the LIQUID than in vapour state
Same in all the THREE states

Answer :D
90781.

A closed cylinder contains 40 g of SO_3 and 4 g of helium gas at 375 K. If the partial pressure of helium gas is 2.5 atm, then the volume of the container is (R = 0.082 L-atm K^-1 mol^-1)

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8.3 L
2.5 L
15.5 L
12.3 L

Answer :D
90782.

A clock spring is heated to redness and then plunged into cold water. This treatment will cause it to become

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SOFT and ductile
More SPRINGY than before
Strongly magnetic
Hard and brittle

Answer :D
90783.

A clock spirng is heated to a high temperature and then suddenly pluged into cold water . This treatment will cause the metal to becone :

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SOFT and DUCTILE
More SPRINGY than before
HARD and brittle
Strongly magnetic

Answer :C
90784.

A clear solution is heated in a china dish where upon a solid separates from the hot solution. It is due to the fact that

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the SOLID has a positive enthalpy of solution
the solid has a NEGATIVE enthalpy of solution
solvent has evaporated
the solute is volatile.

Solution :(a) If the solid has positive enthalpy of solution its solubility will DECREASE with INCREASE in temperature and the solid will SEPARATE out on heating .
The solid can also separate out on the evaporation of the solvent.
90785.

A clathrate is defined as:

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CAGE Compound
Liquid crystal
Mixture
Solid solution

Answer :A
90786.

A class of drugs useful to inhibit the pathogenic action of microbes are called.

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Antimicrobials
Analgesic
Antipyretics
Tranquilizers

Answer :A
90787.

(A): Cl - O bond length decreases from CIO^(-) to ClO_(4)^(-) (R): CI-O bond order increases from CIO^(-) to CIO_(4)^(-).

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Both (A) and (R ) are TRUE and (R ) is the correct EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

Answer :A
90788.

(A) cis-2-butene overset(HCO_3H)rarrI (B) trans-2-butene overset(HCO_3H)rarrII Correct statements are

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II is racemic MIXTURE by ANTI ADDITION
II is MESO compound by anti addition
I is meso compound by syn addition
II is racemic compound by syn addition

Answer :C::D
90789.

(a) Cis-1,2-cylopentanediol reacts with acetone in the presence of dry HCl of yield compound K, C_(8)H_(14)O_2, which is resistance to boiling alkali, but which is readily into the starting material by aqueous acdis. What is structure of K ? (b) Trans-1,2-Cyclopentanediol does not form an analgous compound. explain why

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Answer :`(##RES_CHM_CCAK_E01_003_A01##)`
(B) The-OH groups in the trans ISOMER are too far part to form cyclic STRUCTURE
90790.

A current of 2 ampere was passed through solution of CuSO_4 and AgNO_3 in series.0.635 g of copper was deposited .Then the weight of silver deposited will be:

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0.59g
3.24g
1.08g
2.16g

Answer :D
90791.

A chocolate brown coloured compound with acetic acid and potassium ferrocyanide is obtained from a salt solution containing :

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Cu
Cd
Sn
Hg

Answer :A
90792.

(A) Chromates and dichromates are not interconvertible in aqueous solution with charge in pH. (R) Chromates are orange in colour.

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Both (A) and (R) are TRUE and (R) is the CORRECT EXPLANATION of (A)
Both (A) and (R) are true and (R) is not the correct explanation of (A)
(A) is true but (R) is FALSE
Both (A) and (R) are false

Solution :Both (A) and (R) are false
90793.

(A): Chlorophyll contains one magnesium atom (R): Chlorophyll is useful to perform photosynthesis in plants

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Both A & R are TRUE, R is the CORRECT explanation of A
Both A & R are true, R is not correct explanation of A
A is true, R is FALSE
A is false, R is true

Answer :B
90794.

A chloroform solution of aniline is heated with KOH. Which of the following is right.

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Chloroform HYDROLYSED to give formic acid
Aniline REACTS with chloroform to give cyanides
A secondary AMINE is obtained
Foul smelling compound is obtained

Solution :carbylamine `"REA"^(n)R-NC` test
90795.

A chloro derivative (X) on treatment with Znand HCl gave a hydrocarbon with five carbon atoms in the molecule when (X) is dissolved in ether and treated with Na, the product 2,2,5,5-tetra methyl hexane is obtained. The compound (X) is

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3-chloro-2,2-dimethylpropane
1-chloropropane
1-chloro-2,2-dimethylpropane
2-chloro-2-methylbutane

Answer :C
90796.

A chloro compound (A) showed the following properties. It decolourised bromide water. It reacts with H_(2) in presence of catalyst. It gave a brick red precipitate with an ammonical Cu_(2)Cl_(2). When vaporized with 1.49g of (A) gave 448 ml of vapours at STP. on reaction with excess of hydrogen and nickel gave 'B'. calculate the molecular weight of 'B'.

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ANSWER :`0044`
90797.

A chloro compound (A) showed the followingproperties: (i) Decolorized bromine in "CCI"_4(ii) Absorbed hydrogen catalytically (iii) Gave a precipitate with amm. cuprous chloride (iv) When vaporized, 1.49 g of (A) gave 448 mL of vapour at STP. Identify (A).

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SOLUTION :`ClCH_2C -=CH`
90798.

(A) : Chlorine is gas, bromine is liquid and iodine is solid (R) : Intermolecular attraction forces increase upon increase in molecular masses .

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Both (A) and (R ) are TRUE and (R ) is the correct explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

Answer :A
90799.

(A) Chlorine dioxide is paramagnetic (R ) Chlorine dioxide molecule has odd number of electrons

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Both (A) and (R ) are TRUE and (R ) is the correct explanation of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

ANSWER :A
90800.

(A) : Chlorine acts as a bleaching agent in the presence of moisture (R) : Chlorine forms hypochlorous acid in the presence of moisture.

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Both (A) and (R ) are true and (R ) is the CORRECT EXPLANATION of (A)
Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
(A) is true but (R ) is FALSE
Both (A) and (R ) are false

ANSWER :A