This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 25901. |
The Ph of blood is (approximately ) |
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Answer» 7.4 |
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| 25902. |
The pH of blood does not appreciably change by a small addition of an acid or a base because blood |
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Answer» CONTAINS serum protein which ACTS as buffer |
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| 25903. |
The pH of blood does not appreciably change by a small addition of acid or a base because blood |
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Answer» SERUM protein present in blood acts as BUFFER |
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| 25904. |
The pH of basic buffer mixtures is given by pH = pK_(a) + log.(["Base"])/(["Salt"]), whereas pH of acidic buffer mixtures is given by : pH = pK_(1) + log.(["Salt"])/(["Acid"]). Addition of little acid or base although shows no change in pH for all practical purposes , but since the ratio (["Base"])/(["Salt"]) for (["Salt"])/(["Acid"]) changes, a slight decrease or increase in pH results. The amount of (NH_(4))_(2)SO_(4) to be added to 500 mL of 0.01 M NH_(4)OH solution (pK_(a) for NH_(4)^(+) is 9.26) to prepare a buffer of pH 8.26 is |
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Answer» 0.05 mole `[NH_(4)^(+)] = (a xx 2)/(500)`, Let a millimole of `(NH_(4))_(2)SO_(4)` are added. `:. [Salt] = [NH_(4)^(+)]`. `pH = 9.26 + log [(0.01)/(2a//500)]` `8.26 = 9.26 + log.(0.01 xx 500)/(2a):. a = 25` `:.` Mole of `(NH_(4))_(2)SO_(4)` added `= 0.025`. |
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| 25905. |
The pH of basic buffer mixtures is given by pH = pK_(a) + log.(["Base"])/(["Salt"]), whereas pH of acidic buffer mixtures is given by : pH = pK_(1) + log.(["Salt"])/(["Acid"]). Addition of little acid or base although shows no change in pH for all practical purposes , but since the ratio (["Base"])/(["Salt"]) for (["Salt"])/(["Acid"]) changes, a slight decrease or increase in pH results. A solution containing 0.2 mole of dichloroacetic acid litre solution has [H^(+)] |
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Answer» 0.05 M `{:(CHCl_(2).COONA,rarr,CHCl_(2)COO^(-),+,Na^(+)),(,,0.1,,0.1),(CHCl_(2).COOH ,hArr,CHCl_(2)COO^(-) ,+,H^(+)),(0.2,,0,,0),((0.2 - x),,(x + 0.1),,x):}` `:. K_(a) = ([CHCl_(2)COO^(-)][H^(+)])/([CHCl_(2)COOH])` or `5 xx 10^(-2) = ([0.1 + x][x])/([0.2 - x])` `:. x = 0.05`. |
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| 25906. |
The pH of basic buffer mixtures is given by pH = pK_(a) + log.(["Base"])/(["Salt"]), whereas pH of acidic buffer mixtures is given by : pH = pK_(1) + log.(["Salt"])/(["Acid"]). Addition of little acid or base although shows no change in pH for all practical purposes , but since the ratio (["Base"])/(["Salt"]) for (["Salt"])/(["Acid"]) changes, a slight decrease or increase in pH results. The ratio of pH of solution (I) containing 1 mole of CH_(3)COONa and 1 mole of acetic acid in one litre is |
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Answer» `1:2` `:. [CH_(3)COOH] = (1)/(2) =1`. `:. [H^(+)] = C alpha = C sqrt((K_(a))/(C)) = sqrt(K_(a).C) = sqrt(K_(a))` or `pH_(1) = -(1)/(2) LOG K_(a) = (1)/(2) pK_(a)` `{:(CH_(3)COOH+,CH_(3)COONa),(""1," "1):}` `:. pH = pK_(a) + log.(1)/(1) rArr pH_(2) = pK_(a) :. (pH_(1))/(pH_(2)) = (1)/(2)`. |
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| 25907. |
The pH of basic buffer mixtures is given by pH = pK_(a) + log.(["Base"])/(["Salt"]), whereas pH of acidic buffer mixtures is given by : pH = pK_(1) + log.(["Salt"])/(["Acid"]). Addition of little acid or base although shows no change in pH for all practical purposes , but since the ratio (["Base"])/(["Salt"]) for (["Salt"])/(["Acid"]) changes, a slight decrease or increase in pH results. The volume of 0.2 M NaOH needed to prepare a buffer of pH 4.74 with 50 ml of 0.2 M acetic acid (pK_(b) of CH_(3)COO^(-) = 9.26) is |
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Answer» 50 mL `{:(NaOH+,CH_(3)COO,rarr,CH_(3)COONa+,H_(2)O),(0.2 xx V,50 xx 0.2,,""0," "0),(-,[10-0.2V],,""0.2V,0.2 V):}` `:. pH = pK_(a) + LOG.(["Salt"])/(["ACID"]) = pK_(W) - pK_(b) + log.(["Salt"])/(["Acid"])` `= 14 - 9.26 + g.(["Salt"])/(["Acid"])` `= 14-9.26 + log.([(0.2V)/(50+V)])/([(10-0.2 V)/(50+V)])` `4.74 = 4.74 + log [(0.2V)/(10 - 0.2 V)] :. V = (10)/(0.4) = 25 mL`.` |
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| 25908. |
The pH of aqueous solution of 1M HCO ONH_(4), pK_(a) of HCO OH is 3.8 and pK_(b) " of " NH_(3) is 4.8 |
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Answer» 6.5 `PH=1//2 pK_(w)+ 1//2 pK_(a)- 1//2pK_(B)` `THEREFORE pH=(1)/(2)xx14+(1)/(2)xx3.8-(1)/(2)xx4.8, pH=6.5` |
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| 25909. |
The pH of an aqueous solution of Mg(OH)_(2) is 9.0. If the solubility product of Mg(OH)_(2) is 1xx10^(-11), what is [Mg^(2+)] ? |
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Answer» `1XX10^(-5)` `[OH^(-)]=(1xx10^(-14))/(10^(-9))=10^(-5)` `Mg(OH)_(2)hArr Mg^(2+)+2OH^(-)` `K_(sp)=[Mg^(2+)][OH^(-)]^(2)` `1xx10^(-11)=[Mg^(2+)][10^(-5)]^(2)` `[Mg^(2+)]=(1xx10^(-11))/((10^(-5))^(2))=10^(-1)=0.1` |
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| 25910. |
The pH of an aqueous solution of HCl is 2. Its osmotic pressure at a temperature T would be equal to |
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Answer» 0.01 RT |
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| 25911. |
The pH of an aqueous solution of a 0.1 M solution of a weak monoprotic acid which is 1% ionised is : |
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Answer» 1 `[H^(+)]= c alpha = 0.1xx(1)/(100)=10^(-3)` `therefore PH = -log [H^(+)]=3` |
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| 25912. |
The pH of an aqueous solution of 1.0M ammonium formate will be (pk_a of formic acid = 3.8 and pK_a, of ammonium hydroxide = 4.8) |
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Answer» 5.5 |
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| 25913. |
The pH of an aqueous solution is Zero. The solution is……. |
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Answer» Slightly acidic `THEREFORE [H^+]=10^(-pH)` `=10^0=1` `[H^+]=1 M` The solution is strongly acidic |
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| 25914. |
The pH of an aqueous solution having hydroxide ion concentration as 1 xx 10^(-5) is |
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Answer» 5 `pOH = -LOG[OH^(-)] = 5` `pH + pOH = 14 rArr pH = 14 - 5 = 9`. |
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| 25915. |
The pH of an aqueous solution is Zero. The solution is |
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Answer» Slighly ACIDIC `:. [H^+] = 10^(-pH)` `=10^0 = 1` `[H^+] = 1M` The solution is strongly acidic. |
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| 25916. |
The pH of an aqueous solution at 25^(@)C is 6.1 its p(OH) is : |
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Answer» `12.2` `THEREFORE pOH = 14-6.1 =7.9`. |
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| 25917. |
The pH of an aqueous solution containing [H^(+)] = 3 xx 10^(-3) M is |
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Answer» 2.471 |
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| 25918. |
The pH of an acidic buffer solution & a basic buffer solution at 25^(@)C is : |
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Answer» `gt7,lt7` |
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| 25920. |
The pH of a solution prepared by mixing 2.0 ml of HCl solution of pH 3.0 and 3.0 ml of NaOH of pH 10.0 is |
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Answer» 2.5 |
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| 25921. |
The pH of a solution resulting from the addition of 12.5mL of 0.1M HCl to 50mL of a solution containing 0.15M CH_(3)COOH & 0.2M CH_(3)COONa will be (Given : pK_(a) of CH_(3)COOH=4.74) |
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Answer» `4.74` `pH=pK_(a)=4.74` |
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| 25922. |
The pH of a solution of H_2O_2is 6.0. Some chlorine gasis bubbled into this solution. Which of the following is correct? |
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Answer» HYDROGEN GAS is LIBERATED. As HCL (a strong acid ) is produced , hence `[H^+]` of the solution increases, pH of the solution decreases. |
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| 25923. |
The pH of a solution obtained by mixing equal volumes of (N)/(10)NaOH and (N)/(20) HCl |
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Answer» 13.4 `(1)/(10) xx V -(1)/(20) xx V = N_(R)xx 2 xx V` `(0.05)/(2) = N_(R) rArr N_(R) = 0.025`. `[H^(+)] = 0.025 M` `PH = -log[0.025] = 1.6`. |
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| 25924. |
The pH of a solution obtained by mixing 50 mL of 2N HCI and 50 mL of 1 N NaOH is [log 5 = 0.7] |
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Answer» 1.7 |
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| 25925. |
The pH of a solution obtained by mixing 50 ml of 1 N HCl and 30 ml of 1 N NaOH is [log 2.5 = 0.3979] |
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Answer» 3.979 No. of milli equivalent of `HCL = 50 xx 1 = 50` `:.` No. of milli equivalent of HCl left after TITRATION = 50 - 30 = 20. Total volume of the mixture = 50 + 30 = 80 ml i.e. 20 milli equivalent or 0.02 equivalent of HCl are PRESENT in 80 ml. `:.` 250 milli equivalent or 0.25 equivalentof HCl are presentin 1000 ml or 1 litre. i.e., `0.25 N HCl ~~ 0.25 N NaOH` (Monobasic) So, `[H^(+)] = -log_(10)[2.5 xx 10^(-1)] rArr pH = 1 - log_(10)[0.25]` `pH = -log_(10)[2.5 xx 10^(-2)rArr pH = 1 - log_(10)2.5` `pH = 1 - 0.3979 rArr pH = 0.6021`. |
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| 25926. |
The pH of a solution obtained by mixing 50 mL of 1N HCl and 30 mL of 1 N NaOH is [log 2.5 = 0.3979] |
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Answer» `0.979` |
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| 25927. |
The pH of a solution obtained by mixing 50 ml of 0.4 N HCl and 50 mL of 0.2 N NaOH is : |
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Answer» 13 |
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| 25928. |
The pH of a solution obtained by mixing 50 ml of 0.4 M HCl with 50 ml of 0.2 M NaOH is |
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Answer» `-LOG 2` |
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| 25929. |
The PH of a solution obtained by mixing 50 ml of 0.4 M HCl and 50 ml of 0.2 M NaoH IS : |
| Answer» Answer :C | |
| 25930. |
The pH of a solution, obtained by mixing 50 ml of 0.4 HCl and 50 ml of 0.2 N NaOH, is |
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Answer» `1.0` |
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| 25931. |
The pH of a solution obtained by mixing 100mL of a solutionpH of =3 with 400mL of a solution of pH =4 is |
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Answer» `3- log 2.8` or `N_(3)=(0.1+0.04)/(500)=(0.14)/(500)=2.8 xx 10^(-4)M` `pH=-log (2.8 xx 10^(-4))=4=log 2.8` |
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| 25932. |
The pH of a solution is the negative logarithm to the base 10 of its hydrogen ion concentration in |
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Answer» MOLES PER LITRE |
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| 25933. |
The pH of a solution is increased from 3 to 6 , its H^+ ion concentration will be |
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Answer» reduced to half hence`[H^+]` is reducedby `10^3`times |
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| 25934. |
The pH of a solution is 6. Sufficient amount of acid is added to decrease the pH to 2. The increase in hydrogen ion concentration is : |
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Answer» 1. FOUR times |
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| 25935. |
The pH of a solution is increased from 3 to 6. Its H^(+) ion concentration will be |
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Answer» Reduced to half |
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| 25936. |
The ph of a solution is 5.0 to this solution sufficient acid is added to decreases the ph to 2.0 The increase in hydrogen ion concentration is : |
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Answer» 1000 times |
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| 25937. |
The pH of a solution is 5. Its hydrogen ion concentration is increased 100 times. Its pH will be : |
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Answer» 7 |
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| 25938. |
The pH of a solution is 2. If its pH is to be raised to 4, then the [H^(+)] of the original solution has to be |
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Answer» Doubled Then `[H^(+)] = 10^(-2) M`. If pH of any solution is just double then pH = 4 and `[H^(+)]` will be `10^(-4)`. |
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| 25939. |
The pH of a solution is 2. Its pH is to be changed to 4. Then the H^+ concentration of original solution has to be: |
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Answer» Halved |
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| 25940. |
The pH of a solution having [H^(+)]=10xx10^(-4) mol/litre will be |
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Answer» 4 |
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| 25941. |
The pH of a solution containing NH_(4)OHandNH_(4)^(+) ia 9. if [NH_(4)^(+)]=0.1MandKa" of " NH_(4)^(+) " is "5xx10^(-10)then what is [NH_(4)OH]? |
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Answer» 0.05 M |
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| 25942. |
The pH of a solution formed by mixing 40 mL of 0.10 M HCl and 10 mL of 0.45 M NaOH is: |
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Answer» 5 |
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| 25943. |
The pH of a solution at 25^@C containing 0.10 M solution acetate and 0.03 M acetic acid is……. |
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Answer» 4.09 `=4.57+log""0.10/0.03=5.09` |
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| 25944. |
The pH of a solution at 25°C containing 0.20 M sodium acetate and 0.06 M acetic acid is (pK_a for CH_3COOH = 4.74 and log 3 = 0.477) |
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Answer» 4.36 |
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| 25945. |
The pH of a solution at 25^(@)C containing 0.10 m sodium acetate and 0.03 m acetic acid is (pK_(a) for CH_(3)COOH = 4.57) |
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Answer» 4.09 |
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| 25946. |
The pH of a soloution containing 0.4 gm NaOH per litre is : |
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Answer» 2 |
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| 25947. |
The pH of a soft drink is 3.82. Its hydrogen ion concentration will be |
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Answer» `1.96 XX 10^(-2)` mol/l |
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| 25948. |
The pH of a soft drink is 3.82. Its hydrogen ion concentration will be……. |
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Answer» `1.96 TIMES 10^-2 mol//L` `THEREFORE[H^+]=1.5 times 10^-4 mol//litre` |
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| 25949. |
The pH of a simple acetate buffer is given by pH = pK_(a) + log.(["Salt"])/(["Acid"]) K_(a) of acetic acid = 1.8 xx 10^(-5) If [Salt] = [Acid] = 0.1 M, the pH of the solution would be about |
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Answer» 7 `K_(a) = 1.8 xx 10^(-5) , PH = -logK_(a) + log.(["Salt"])/(["Acid"])` `= -log 1.8 xx 10^(-5) + log.(0.1)/(0.1) = -log 1.8 xx 10^(-5)` `pH = 4.7`. |
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| 25950. |
The pH of a soft drink is 3.82. Its H^+ ion concentration will be: |
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Answer» `1.96xx10^(-2)` mol/lit |
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