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1051.

What is Zero order reaction? Give two examples.In a first order reaction the concentration of the reactant is reduced to one fourthof its initial value is 50 seconds. Calculate the rate constant of the reaction. [4]

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In somereactions, the rate is apparently independent of the reactant concentration. The rates of thesezero-order reactionsdo not vary with increasing nor decreasing reactants concentrations. This means that the rate of thereactionis equal to the rate constantthe decomposition of ammonia to form nitrogen and hydrogen

1052.

Derive an expression for the rate constant of a zero order reaction.

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1053.

An example of Zero Order Reaction isAThermal decomposition of HonoBHydrogenation of etheneDecomposition of No

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Thermal decomposition of HI on the gold surface is a zero order reaction. That means the rate of the reaction is independent of the concentration of the HI2 HI ------> H2 + I2R = K[HI]^0So R = K

Thus, for the zero order reaction rate constant = rate of the reaction

(A) is correct option

n=o means zero border reaction so option a

1054.

A reaction is found to be zero order. Will its molecularity be also zero

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It is equal to number of molecules taking part simultaneously in single step of reaction. It cannot be zero because, it would mean there is no reaction.

1055.

What is an ammeter ? Where is an ammeter placed in an electric circuit?

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An ammeter is an instrument used for measuring electric current in units of amperes. An ammeter must be connected in series with the path of the current being measured.

1056.

The compression factor (compressibility factor) for onemole of a van der Waals' gas at 0°C and 100 atm pressureis found to be 0.5. Assuming that the volume of a gasmolecule is negligible, calculate the van der Waals'constant 'a.(2001)

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We know that, Compressibility factor, Z = PV/RT

0.5 = 100 *V/0.082 *273

∴ V = 0.1117L

NOTE :Further when volume of a gas molecule is negligible, van der Waal’s equation becomes

(P + a/V²) (V - 0) = RT

Or PV = RT – a/V or a = RTV – PV²

Substituting the values

A = (0.082 * 0.1119 *273) – (100 * 0.1119 * 0.1119)

= 1.253 atm L²mol-²

1057.

If 8 mL of uncombined O, remain after explodingO2 with 4 mL of hydrogen, the number of mL ofO -2 originally were(1) 12(3) 10(2) 2(4) 4

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1058.

3.2 Trends in the Modern Periodic Table

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electronegativity,ionization energy,electron affinity,atomic radius, metallic character, ionic radius and reactivity. Periodic trends arise from the arrangement of elements in the periodic table and allow chemists to quickly and reliably predict an element's properties.

1059.

A beam of electrons is accelerated by a potential difference of 10000 volts. The wavelewave associated with it will be(A) 0.0123 A(B) 1.23 A(C) 0.123 A(D) of these

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wavelength of electon = 12.27/√v A°

so, wavelength = 12.27/√10000 = 12.27/100 = 0.1227 A°

option c

1060.

कि 1. 42, ठेके» «सके 2. लि. (५०८५५ 6.. सरल 3... e TN 3B TR :

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1061.

1. Define:-(i) Fluid ii) Latent HeatWater hyacinth floate on water en para

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In physics, a fluid is a substance that continually deforms under an applied shear stress, or external force. Fluids are a phase of matter and include liquids, gases and plasmas. They are substances with zero shear modulus, or, in simpler terms, substances which cannot resist any shear force applied to them.

The heat required to convert a solid into a liquid or vapour, or a liquid into a vapour, without change of temperature.

1062.

What is the element present on lead pencils?

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Carbon (graphite)

1063.

What is non-toxic substance!

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An example is treated boiler water. A non-toxic substance is any substance that may create a non-health hazard and is a nuisance or is aesthetically objectionable. For example, foodstuff, such as sugar, soda pop, etc.

1064.

Jeevandee2360.2. Solve the following questions. (Any er the questionsi. Study the following reaction anfive)2H,o0 electrical enerey 2H,1 +O,(Acidic Water)a. What is the above reaction called?

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the above reaction is called electrical decomposition reaction

The above reaction is electrolysis of water also termed as electrical decomposition reaction

sorry it is not electrical it is electrolytic decomposition reaction

1065.

4. Sample A can displace sample from its salt solution and sample B can displacesample C, but sample C cannot displace samples A and B. Find out the names of thesesamples and arrange them in the decreasing order of their reactivity. (Hint: Samples Aand B are placed below calcium and above hydrogen in the activity series, whereas sample C is the leastreactive metal and is placed between mercury and gold.)

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Black substance in the lead pencil is graphite is non metal but contact electricity like those of carbon brush of drills.Graphite is carbon of lead element which handle heat fire and electric contacts,soft like talc and smooth.

sorry sorry...I sending to someone else but in ur answer going

1066.

Write the six differences between thermo-plastics andthermosetting plastics.

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Thermoplastics

It can be remolded.it can be recycle.lt is renewable.it can be destroy by heat.it is apoor conductor of electricityex PVC.

thermostatting

it cannot be remolded it cannot be recycleit is not renewableit cannot be destroy by heat

1067.

What are plastics?

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They are a combination of materials, they may be synthetic or naturally occurring, that are shaped when soft and then hardened to retain the given shape. Plastics are polymers. A polymer is a substance made of many repeating units.

1068.

(9) Define compounding? Discuss compourding of plastics.-

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Compoundingis a process of melt blendingplasticswith other additives.

This process changes the physical, thermal, electrical or aesthetic characteristics of theplastic.

The final product is called acompoundor composite.Compoundingstarts with a base resin or polymer.

1069.

rare the guidelines for recycling of plastics

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Recycling centers use optical scanners to identify the type of plastic resin, so #1 and #2 plastics are separated from each other and other materials (such as paper and glass). Bottles are then crushed (where caps are removed if you haven’t already done so) and baled to be sent to a plastic recycler.

Recyclers will shred the #1 or #2 plastic into flakes, which are washed, rinsed and dried. Flakes are then melted into pellets, then transported to a manufacturer to make new plastic bottles/jugs or other products, such as lining for sleeping bags, T-shirts, carpet, or playground equipment.

1070.

Short note on Dry Ice

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Dry Ice is the common name for solid carbon dioxide (CO2). It gets this name because it does not melt into a liquid when heated; instead, it changes directly into a gas (This process is known as sublimation).

1071.

give reason Iron can displace copper from copper sulphate solution, but copper cannot displace iron from iron sulphate.

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It is because iron has higher reactivity than copper.

1072.

Give reasons for the following.(a) Aluminium foils are used to wrap food items.(b) Immersion rods for heating liquids are made up of(c) Copper cannot displace zinc from its salt soluticoSodium and potassium are stored in kerosene.

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Aluminium foils are used to wrap food items because aluminium being a soft malleable metal it can be beaten to in sheets to form thin wrapping sheets. Moreover it does not react with food items.

Immersion rods are made of metallic substances metals are good conductors of heat and electricity. They get hot very soon when electric current is passed through them and thus warm the water.

Copper can not displace zinc from its salt-solution because copper is less reactive than zinc. A less reactive metal can not displace more reactive metal from its solution.

Sodium and Potassium are stored in Kerosene since they are very reactive. They quickly react in air and water.

1073.

a)Aluminium foils(b)areusedtowrapfooditemsImmersion rods for heating liquids are made up of metallic substanw(c) Copper cannot displace zinc from its salt solution.(d) Sodium and potassium are stored in kerosene.Can you store lemon pickle in an aluminium utensil? Explain.Match the substo

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1074.

Aluminium foils are used to wrap food items.Immersion rods for heating liquids are made up of metallic substanCopper cannot displace zinc from its salt solution.Sodium and potassium are stored in kerosene.

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1075.

Example 4. Calculate the amount of work done when0.75 mol of an ideal gas expands isothermally and reversibly at27°C from a volume of 15 L to 25 L.

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1076.

write short note on markownikoffs reaction

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The rule states that with the addition of a protic acid HX to an asymmetric alkene, the acid hydrogen (H) gets attached to the carbon with more hydrogen substituents, and the halide (X) group gets attached to the carbon with more alkyl substituents. Alternatively, the rule can be stated that the hydrogen atom is added to the carbon with the greatest number of hydrogen atoms while the X component is added to the carbon with the least number of hydrogen atoms.[3]

The same is true when an alkene reacts with water in an addition reaction to form an alcohol which involve formation of carbocations. The hydroxyl group (OH) bonds to the carbon that has the greater number of carbon–carbon bonds, while the hydrogen bonds to the carbon on the other end of the double bond, that has more carbon–hydrogen bonds.

The chemical basis for Markovnikov's Rule is the formation of the most stable carbocation during the addition process. The addition of the hydrogen ion to one carbon atom in the alkene creates a positive charge on the other carbon, forming a carbocation intermediate. The more substituted the carbocation, the more stable it is, due to induction and hyperconjugation. The major product of the addition reaction will be the one formed from the more stable intermediate. Therefore, the major product of the addition of HX (where X is some atom more electronegative than H) to an alkene has the hydrogen atom in the less substituted position and X in the more substituted position. But the other less substituted, less stable carbocation will still be formed at some concentration, and will proceed to be the minor product with the opposite, conjugate attachment of X.

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give me example

1077.

80. "pH has a great importance in our daily life " explain by giving examples.

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PH plays an important role in our everyday life. A few examples are:-

1. In our digestive system - Hydrochloric acid is produced in the stomach to help in digesting food. However, when the amount of acid exceeds a certain limit it causes acidity and pain. This acidity can be neutralized by taking a mild base called as an antacid.

2. pH of soil – Plants grow only in soils that have a definite pH range. So, highly acidic soils are treated with quicklime or calcium carbonate to reduce its acidity.

3. Tarnished vessels – Copper vessels are tarnished due to the formation of a layer of basic copper oxide. This can be removed when it is rubbed with the citric acid from a lemon. Copper oxide forms copper citrate with citric acid and is washed away giving a shine to the vessels.

1078.

(4) Explain giving two examples of chemicalchange.

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1079.

Explain the reaction of metals and non-hĂŠtals With oxygen giving examples.

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1080.

Explain the reaction of metals and non-metals with oxygen giving examples.

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1081.

suggest a suitable words (a) chemical added to food preventing growth of microorganisms (b) chemical which kill or stopthe growth of parhogenh

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a) Preservatives are the chemicalsadded to food to prevent growth of microorganisms.b) Rhizobium is the nitrogen fixing bacteria present in root nodules of legumes.c) Vector is the agent which spreads pathogens from one place to another.d) Chemicals which kill or stop the growth of pathogens are called antibiotics.

1082.

why is standard entropy of an elementary substance not zero whereas standard enthalpy of formation is taken as zero...???

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thanks

1083.

calculate A, for CaCl2 and MgSO4 from the following data :avalues are Ca2+ = 119.0, Cl-= 76.3. Mg": 106.0, SO-160.0 all in Scm2mor)N.C.E.R.Τ.

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In accordance to Kohlrausch's law of independent migration of ions,we get the relation that molar conductivity for an electrolyte at infinite dilution is the sum of independent molar conductivities of both cation and anion..i.,e.

λ°=[λ+] +[λ−]

2. For CaCl2:

λ°CaCl2 =λ°Ca++λ°Cl−=119+76.3=195.3ForMgSO4, λ°MgSO4=λ°Mg2++λ°SO42− =106+160=266

1084.

The combustion of 1 mole of benzene takes place at 298 K and 1 atm.After combustion, CO,(g) and H,O(1) are produced and 3267.0 k) of heatis liberated. Calculate the standard enthalpy of formation AHºofbenzene. Standard enthalpies of formation of CO (8) and H,0(1) are-393.5 kJ mol-1 and -285.83 KJ moll respectively.

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Answer: Standard enthalpy of formation of benzene = 129.9 KJ/mol

Explanation: Enthalpy of the reaction is equal to the total sum of the standard enthalpies of the formation of products minus the total sum of the standard enthalpies of formation of reactants. It is represented by

Mathematically,

For the combustion of benzene:

The standard enthalpy of the elements present in their standard state is always zero.

Putting values in above equation, we get:

=129.9kJ/mol[/tex]

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1085.

6. During an isothermal expansion of an ideal gas, its(CBSE 1991)(a) internal energy increases(b) enthalpy decreases(c) enthalpy remains unaffected(d) enthalpy reduces to zero

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enthalpy remains unaffected

1086.

the second ionization enthalpy of alkaline earth metals is greater than the first ionization enthalpy

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the second ionization enthalpy of alkaline earth metal is greater than first

yes its was greater than first

Yes Mate, you are right✔

the second ionization enthalpy of alkaline earth metal is greater than the first ionization enthalpy of alkaline earth metal.

because of less force of attraction the second ionization enthalpy of alkaline is greater than one

the second ionization enthalpy of alkine earth metal is greater than first

Yes the second ionization enthalpy is greater than first ionization enthalpy

Second ionisation enthalpy is always greater than first because it requires more energy to remove subsequent electrons as nucleus attracts remaining electrons with greater force.(Comment if you need more help or need help on exceptions for (jee/neet)

1087.

Define the term 'lonization Enthalpy'. Discuss the factors affectingionization enthalpy and its trends in the periodic table.

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Factors on which Ionisation Enthalpy Depends:(i) Size of the atom:The larger the atomic size, smaller is the value of ionisation enthalpy. In a larger atom, the outer electrons are far away from the nucleus and thus force of attraction with which they are attracted by the nucleus is less and hence can be easily removed.Ionisation enthalpy ∝ 1/ Atomic size(ii) Screening effect:Higher the screening effect, the lesser is the value of ionisation enthalpy as the screening effect reduces the force of attraction towards nucleus and hence the outer electrons can be easily removed.Ionisation enthalpy ∝ 1/ Screening effect(iii) Nuclear charge:As the nuclear charge increases among atoms having same number of energy shells, the ionisation enthalpy increases because the force of attraction towards nucleus increases.Ionisation enthalpy ∝ Nuclear charge(iv) Half filled and fully filled orbitals:The atoms having half filled and fully filled orbitals are comparatively more stable, hence more energy is required to remove the electron from such atoms. The ionization enthalpy is rather higher than the expected value in case of such an atom.Ionisation enthalpy ∝ Stable electronic configuration(v) Shape of orbital:The s-orbital is more close to nucleus than the p-orbital of the same orbit. Thus, it is easier to remove electron from a p-orbital in comparison to s-orbital. In general, the ionisation enthalpy follows the following order(s>p> d>f) orbitals of the same orbit.Variation of ionisation enthalpy in the periodic tableln general, the ionisation energy decreases down the group due to increase in atomic size. On the other hand, the ionisation energy increases across the period from left to right, again due to decrease in atomic size from left to right.

1088.

Give reason for the following(a) F has lower electron gain enthalpy thanh(b) lonization enthalpy of N is higher than

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a)F is more electronegative and smaller size and cl has higher size and less electronegativity

1089.

5. What type of clothes should wewear in summer?

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cotton clothes because it absorbs body sweat and make body release heat

We should wearcotton clothes and light coloured clothes in summers. We sweat a lot in summers.Cottonis a good absorber ofwater . Thus, it absorbs sweat from ourbody and exposes the sweat to the atmosphere, making its evaporation faster.

1090.

The degree of dissociation is 0.4 at 400 K and1.0 atm for the gaseous reactions C2. Assuming ideal behaviour of all the gases, calculate the denr and 1.0 atmosphere. (Atomic mass of P-31.0 and Cl - 35.5)mixture

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PCI5 ⇌ PCI3 + CI2Initial moles 1 0 0Moles at eq 1 -0.4 0.4 0.4∴ Total moles at equilibrium = 1 – 0.4 + 0.4 + 0.4 = 1.4Also Normal mol. Wt. of PCI5/Exp. Mol. Wt. of PCI5 = 1 + ∝ = 1.4Or 208.5/Exp. mol. Wt. of PCI5 = 1.4∴ Exp. mol. Wt. of PCI5 or m. wt. of mixture = 208.5/1.4Now using, PV = w/m RT for mixtured = w/V = Pm/RT = 1 * 208.5/1.4 *0.082 *400 = 4.53 g/litre

1091.

8.(NCERTWrite the balanced chemical equations for the following reactions.(a) Calcium hydroxide + carbon dioxide - Calcium carbonate + water(b) Aluminium + copper chloride + Aluminium chloride + copper(c) Zinc + Silver nitrate Zinc nitrate + Silver(d) Barium chloride + Potassium Sulphate → Potassium chloride + Barium Sulphate

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1092.

volvedme yuations for these reactions..In the refining of silver, the recovery of silverPacement by copper metal. Write down the reactionharSilver from silver nitrate solutionown the reaction involved.15

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1093.

e refining of silver, the recovery of silver from silver nitrate solution inwokedinvolved dacIn thmetal. Write chemical equation involved.

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1094.

metal M forms a sulphate which is isomorphouswith MgSO, 7H,O. If 0.6538 g of metals Mdisplaced 2.16g of silver from silver nitrate solution,then the atomic weight of the metal M is(1) 32.61 (2) 56.82 (3) 65.38 (4) 74.58

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1095.

4. Suggest a method to liquejyatmospheric gases.

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The gases can be converted into liquids by bringing its particles closer so atmospheric gases can be liquefied either by decreasing temperature or by increasing pressure.

1096.

What are Halogens and Chalcogens?

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(VI A) GROUP ELEMENTS ARE KNOWN AS CHALCOGENS .....WHILE THEY HAVE SIMILAR PROPERTIES AMONG ELEMETS AND ARE ORE FORMING ELEMENTS............HALOGENS ARE (VII A) THEY FORM SALTS WITH SEVERAL ELEMENTS......AND IS ALSO A VERY IMPORTANT GROUP OF P-BLOCK ELEMENTS......I HOPE THIS MUCH IS SUFFICIENT .....I HOPE IT WILL HELP U...👍

1097.

3 ( The main constituent of marsh gas is

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Marsh gas, swamp gas and bog gas is a mixture ofmethane, hydrogen sulfide and carbon dioxide, produced naturally within some geographical marshes, swamps, and bogs

The main constituent is methane.

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1098.

what is clore alkali

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The clore alkali process is an industrial process for the electrolysis of sodium chloride. It is the technology used to produce chlorine and sodium hydroxide, which are commodity chemicals required by industry.

1099.

Mendeleev classified the elements and arranged them in the form of a table. Hydrogen whichresembles alkali metalsand halogens, was placed along with the alkali metals in the first group.Why? How does it resemble halogens? Why do you think he named it as Periodic Table?

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Hydrogen is the first element of the periodic table & often called protium. Its electronic configuration is [1s1]. Due to the presence of only one electron in its 1s shell, hydrogen exhibits a dual behaviour, i.e., it resembles both alkali metals and halogens. As a result, it is placed at the top of the alkali metals in group 1 & also along the halogens in group 17 since just like halogens, it also requires anyone electron to have the configuration of the nearest noble gas element.The dual nature of hydrogen can be justified by the following points:

Mendeleev realized that the physical and chemical properties of elements were related to their atomic mass in a 'periodic' way, and arranged them so that groups of elements with similar properties fell into vertical columns in his table.In a periodic way as rows and columns. So he called it a periodic table.

1100.

diffrerence between acid and alkali

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a liquid substance that can dissolve metal and may burn your skin or clothes. Acids have a pH value of less than 7

Acid

An acid is any chemical compound once dissolved in water produces a solution with hydrogen ion activity more than purified water

Strength relies on the concentration of the hydroxide ions

Would depend upon the temperature acids would look solid, liquid or in the form of gas. It would also have a sour taste.

Would turn litmus paper red

Alkali

A base is an aqueous substance that could absorb hydrogen ions.

Strength relies on the concentration of the hydronium ions

Bases would feel slippery and solid in nature except ammonia which is gaseous.It would have a bitter taste

Would turn litmus paper blue

a chemical substance that reacts with acid to form a salt. An alkali has a pH value of more than 7