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3751.

Which of the following reagents would distingusihcis-cyclopentane-1,2-diol from its trans-isomer?(1) Acetone(2) Ozone(3) MnO2(4) Aluminium isopropxide4.

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3752.

Write a note on quantum numbers.

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Quantum numbers are a set of values that describes the state of an electron including its distance from the nucleus, the orientation and type of orbital where it is likely to be found, and its spin. The Pauli exclusion principle states that no two electrons in an atom can have the same set of quantum numbers.

3753.

eo protons and (ii) the electroni coGive the number of t2.2728 , (electrons in the species H, H2 and O22An atomic orbital has n 3. What() List the quantum numbers (m apossible values of4) of electrons for 3d orbital.(iii) Which of thee following orbitals are possible?orfolInwing quantum numbers.

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3754.

(3) TripleFrom 200 mg of CO, when x molecules are re2.89 × 1o-moles of CO2 are left. xwill be(1) 1020 molecules2) 1010 molecules3) 21 molecules4) 1021 molecules

Answer»

We have 200 mg of carbon dioxide. The molar mass of carbon dioxide is 44g. That is there are 6.022 × 1023molecule of CO2in 44g of CO2. Thus

number of moles of CO2in 44g of CO2= 1

number of moles of CO2in 1g of CO2= 1 / 44

number of moles of CO2in 200 mg or 200 × 10-3g of CO2= (1 × 200 × 10-3) / 44

= 4.545 × 10-3moles

We are given that after removing X molecules from 200 mg of CO2, 2.89 X 10-3moles of CO2are left. Therefore, number of moles of CO2removed will be

= total number of moles of CO2- number of moles of CO2left

= 4.545 × 10-3- 2.89 × 10-3

= 1.655 × 10-3moles of CO2

Thus, 1.655 × 10-3moles of CO2were removed. The number of molecules X can be calculated by simply multiplying this quantity with Avogadro's number. So, number of CO2molecules removed will be

= 1.655 X 10-3X 6.022 X 1023

= 9.969X 1020molecules of CO2 ~ 10^20

Hence, option (a) is correct.

3755.

What are alkyl halides? How are they classified?Furnlain the nomenelature of alkyl halides4.

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Alkyl halides are formally derived fromalkanesby exchanging hydrogen for halogen (fluorine,chlorine,bromine, andiodine). Depending on the degree of substitution at thecarbon atomcarrying the halogen, alkyl halides are classified into primary, secondary and tertiary alkyl halides.

3756.

8. Alkyl halides react with lithium dialkyl copper reagents to give1) alkenes3) alkanes2) alkyl copper halides4) alkenyl halides

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In Corey House synthesis of alkane, alkyl halide reacts with lithium dialkyl cuprate.

R2CuLi + R’X → R-R’ + RCu + LiX

option c

3757.

5. Explain the nomenclature of alkyl halides.

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Ans :- Nomenclature of Alkyl Halides

Alkyl halides are formally derived from alkanes by exchanging hydrogen for halogen (fluorine, chlorine, bromine, and iodine). Depending on the degree of substitution at the carbon atom carrying the halogen, alkyl halides are classified into primary, secondary and tertiary alkyl halides.

Vinyl halides are often classified as the fourth type of alkyl halides.

In the generally accepted nomenclature of alkyl halides, the name of the alkyl residue is followed by the name of the halide,e.g.methyl iodide and ethyl chloride. The IUPAC nomenclature (shown in brackets in the illustration below), considers an alkyl halide a substituted alkane,i.e.halogens are treated the same way as alkyl groups. The name of the halogen is followed by the name of the alkane, for example, iodomethane and chloromethane. If an alkyl halide contains more than one halogen, the halogen names are noted in alphabetical order, such as 1-chloro-2-iodobutane.

In the nomenclature ofunsaturatedalkyl halides, unsaturated bonds have a higher priority than halogen substituents. This requires special attention when numbering the carbon chain.

Some commonly used chlorinated organic solvents, such as carbon tetrachloride (tetrachloromethane), chloroform (trichloromethane) and methylene chloride (dichloromethane), are known more by their trivial name than by their IUPAC name.

3758.

What are alkyl halides? How are they classified?

Answer»

Alkyl halides are formally derived fromalkanesby exchanging hydrogen for halogen (fluorine,chlorine,bromine, andiodine). Depending on the degree of substitution at thecarbon atomcarrying the halogen, alkyl halides are classified into primary, secondary and tertiary alkyl halides.

3759.

50. What is the maximum number of orbitals that can be identified with the following quantum numbers?n=3,l=1,my=0A) 1B) 2-C) 3D) 4

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option A. n= 3 , 3rd orbital l= 1 , p orbital mi = 0 , pxy subshell

its is 3pxy

3760.

b)Describetheorbitalwithfollowingquantumnumbersusings,p.dorfnotationsi) when n-2, 1 0ii) when n 4, 1 2

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3761.

2.29 Usings. p. d notations, describe the orbital with the following quantum numbers.(a) n=1. H. (b) n= 3:1 (c) n = 4: 1-2; (d) n-4; 1-3.

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3762.

What is the maximum number of orbitals that canbe identified with the following quantum numbers?n = 3, 1 = 1, m = 0[AIPMT-2014](1) 1(2) 2(3) 3(4) 4

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option I is the correct answer

1 orbital is the answet

option (3) 3 is correct answer

3763.

Problem 2.18Using s, p, d, f notations, describe theorbital with the following quantumnumbers(a) n- 2, l-1, (b) n 4, 1-0, (c) n 5,3, (d) n 3,1 2

Answer»

n=2,l=1=2pn=4,l=0=4sn=5,l=3=5fn=3,l=2=3d

a. -2p,/ b. -4s,/ c. -5f,/ d. - 3d

3764.

Q.10. Why does the colour of the oil film on thesurface of water continuously changes?

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When petrol is dropped on the road during a rainy day, a thin layer ofoilwill appearon thewater surface. Both the top and bottom surfaces of thisoil filmcan reflect light.The wavelength corresponding to the constructive interference also differs and this causes the reflected light to have variouscolours.

3765.

What happens when a strip of lead metal is placed in a solution of copper chloride? Write the balanced chemical equation for the reaction along with the colour changes observed during the reaction

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Lead is more reactive than copper. Hence, when a strip of lead is placed in a solution of copper chloride, it will displace copper from the salt and instead form lead chloride and copper metal. Following is the chemical equation for the reaction

Pb + CuCl2→ PbCl2+ Cu

3766.

Which can chemical copper metal pulled ricegrains

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Ru, Rh, Pd, Os, Ir and Pt can be applied on copper to make it attract rice grains.

3767.

IntesstQsti2 Why is sulphuric acid not used during the reaction of alcohols with K?

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3768.

\left. \begin{array} { l l } { \text { at } 4 ^ { \circ } C } \\ { 6.023 \times 10 ^ { 22 } } & { ( b ) } & { 1.338 \times 10 ^ { 22 } } \\ { 6.023 \times 10 ^ { 20 } } & { ( d ) 7.338 \times 10 ^ { 22 } } \end{array} \right.

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3769.

»Jack does not like to be contradicted. Comment.

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3770.

| (9)||५|(८)पु!|||५||If pH of solution is 13, means that it is -(1) weakly acidic (2) weakly basicयदि pH = 13, तो विलयन की प्रवृत्ति होगी -(3) strongly acidic141 strongly basic

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option 4 is correct it is strongly basic medium

(4) is correct answer

(4) is correct answer

if ph value more than 7 then tha solution is dasic . in this condition the ph value is 13 then tihis solution is strongly basic

3771.

16. The number of moles of KMnO4 that will beneeded to react with one mole of sulphiteion in acidic solution is ICBSE AIPMT 2007(a) 4/5 (b) 2/5 (c) 1(d) 3/5

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The reaction will be

2KMnO4 + 5 H2SO3 --> K2SO4 +2 MnSO4 +2 H2SO4 + 3H2O

As 5 mole of sulphite reacts with 2 mole of KMnO4

Then 1 mole will react with 2/5 mole of KMnO4

in what way you write the reaction?

thaku

3772.

In a solution the concentration H^+ ion is 10^-9 ML^-1.This solution is of type(1) Basic(3) Neutral(2) Acidic(4) Basic or acidic

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At room temperature,

Kw= [H+][OH-]=10^-14 .

It is given that[H+]=10^-9, hence [OH-]=10^-5.

So, pOH=-log[OH-]= 5. But pH+pOH=14. So pH= 9.

it will be basic

3773.

If pH of solution is 13, means that it is -(1) weakly acidic (2) weakly basic(3) strongly acidic(9strongly basic

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ph range is from 1 to 14 where 1-3 shows strong acidic nature and 12-14 shows strong basic nature

3774.

Compare LPG and wood as fuels.

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LPG is cleaner fuel as it releases much less pollutants than wood. Thus, using LPG as fuel makes our environment pollution free.

3775.

What are the advantages of using CNG and LPG as fuels

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3776.

mention the states of iron water and lpg gas withb4 reason

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Iron is solidWater is liquidLog is gasDue to intermolecular attraction

worst answer

3777.

7. Reaction A → B follows second order kinetics. Doubling the concentration of A will increasthe rate of formation of B by a factor of:(c) 2(d) 4

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rate of reaction for 2nd order is given by

R = k[A]²

so when [A] → 2[A]

R = k[2A]² = 4k[A]²

option d

3778.

Why hydrolysis of ethyl acetate with NaOH is reaction of second order while with HCl, it is of firstorder?

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The acidic hydrolysis of ethyl acetate is a first order reaction because water is present in excess and does not affect the rate of reaction and acid is present in trace amounts while the alkaline hydrolysis of esters is a second order reaction because in alkaline hydrolysis the amount of NaOH influences the rate of reaction.

3779.

SWhyhydrolysis of ethyl acetate with NaOH is reaction of second order while with HCL,it is of firstorder?

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thanku very much

can you please tell me why base is consumed fully and not h+

3780.

How many molecules are present in (2)a) 9 g of water? (Atomic mass of H-lu. O-l6u)b) 17g of NH3? (Atomic mass of N- 14u)

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Given weight = 9g molecular weigh = 2 + 16= 18g no. of molecules = 9/18=0.5

molecules

The molar mass of nitrogen is 14 g while that of hydrogen is 1g. The chemical formula for ammonia is NH3, so the molar mass of ammonia will be

= molar mass of nitrogen + 3 X (molar mass of hydrogen)

= 14 + 3 X (1) = 17 g

Thus the molar mass of ammonia is 17 g. This means that there are 6.023 X 1023molecules of ammonia present in 17 g of ammonia. That is

17 g of NH3= 6.023 X 1023molecules of ammonia

3781.

Complete the equation:Cr2O7 ( -2 ). + OH- gives

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3782.

Whatis atomicity of sucrose C12H211

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Atomicity of sucrose (C12H22O11) is = 12 + 22+11 = 45

3783.

molal concentration of 30 percent sucrose solution

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Molarity = concentration/ Molecular weightMolecular weight = 342.2965Concentration = 300g/L (30%)Therefore, Molarity = 300/342.2965 = 0.8764 moles/Litre

3784.

45. For the reaction,PCl 5 (g)>PCl 3 (g ) + Cl2(g)(AFMC 1998)(c) AH-AU(d) none of these

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3785.

how to find degree of dissociation give example

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what will be the final equation then.thanks for answering.

3786.

Calculate the pH of 0.01 (M) CH 3 COOH at 25°C.( Given dissociation constant of CH 3 COOH(ii)1.7510-5 ).

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pKa = -log(10)[Ka]

Ka for acetic acid is [H+][CH3COO-]/[CH3COOH] where [] indicates the concentration.

pKa = log(10)[CH3COOH] - log(10)[H+] - log(10)[CH3COO-]

as [H+] = [CH3COO-]

pKa = log(10)[CH3COOH] - 2*log(10)[H+]

For acetic acid pKa = 4.76 and -log(10)[H+] = pH

4.76 = log(10)(0.1) + 2*pH

=> 2*pH = 4.76 + 1

=> pH = 5.76/2

=> pH = 2.88

The required pH of 0.1 M solution of acetic acid is 2.88

3787.

At 4440 C, the equilibrium constant K for thereaction 2AB(g) A2(9) + Bag) is , Thedegree of dissociation of AB will be(A) 10% (B) 20 % (C) 30% (D) 50%12(g) B

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3788.

50. The vapour pressure of water at 20°C is 17.5 mm Hg. If18 g of glucose (C6H1206) is added to 178.2 g of water at20°C, the vapour pressure of the resulting solution will be(a) 17.675 mm Hg (b) 15.750 mm Hg(c) 16.500 mm Hg (d) 17.325 mm Hg.

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enthalpy of combustion of ethyl alcohol C2H5oH is _ 950 kj mol .how much is evolved whemn one gram of ethyl alcohol burns ?

3789.

02) Vapour pressure of chloroform (CHCL,) anddichloromethane (CH2Cl2) at 298 K are 200mm Hg and 415 mm Hg respectively.Calculate the vapour pressure of the solutionprepared by mixing 25.5 g of CHCI, and 40g of CH,Cl2 at 298 Ka) 347.9 mm Hgb) 200 mm Hgc) 147.9 mm Hgd) 501.4 mm Hg

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3790.

A gas occupies 200 ml at 25°C and 7000 mmHg pressure. If the pressure is increased to1000 mm Hg at constant temprature. Whatwill be resulting volume ?

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3791.

The decompostion NH3 gas on a heated tungsten surface gave the following results:Initial pressure (mm of Hg) 65 105Half-life (sec)Calculate approximately the values of x and y(A) x 410 sec, y 115 mm of Hg(C) x 490 sec, y 120 mm of Hg7.185y670 820290 x(B) x(D) x467 sec , y-150 mm of Hg430 sec, y 105 mm of Hg

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k = 2.5 × 10−4mol−1L s−1Order of reaction = 0Decomposition reaction of NH3Here NH3 has 2 mol then N2and H2has 1 and 3 moles respectivelyUse the formula of rate of reactionUse this formula we getAnother formula of rate, Rate = k[NH3]xGiven that order of reaction x = 0Plug the values we getPlug the value of k we getRate of production of N2= k = 2.5 × 10−4mol L-1s−1Rate of production of H2= 3k = 3 x 2.5 × 10−4mol L-1s−1= 7.5 × 10−4mol L-1s−1

ans is option B

3792.

1. The value of equilibrium constant for the reaction,N, t 20, F-2NO2 is 1 00. The equilibrium constantfor the reaction. No,一一1 N, to, willbe(a) 100(c) 0.10(b) 0.010(d) 1000[Manipal] .

Answer»

Here you can see that the 2nd equation is reverse of 1st and the coefficients is reduced by 1/2

so, if k1 = 100the k2 will be (1/100)½ = 1/10= 0.10

option C

3793.

stioli. Which of the follouwing hasinertia: (a) a rubber ballrestone of the same sizbicycle and a train? (c) aupees coin and a one rupeeand ae? (b)five-In?

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3794.

(v) Derive the relation between AGº and equilibriumconstant (K) for the reaction-A+ B=cC+d D. (Ch. 3)

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3795.

CaCo, CaO+ CO, (R Rate of forwardR,Rate of backward reaction). Which cRRate of backward reaction). Whichcfollowing is true at equilibrium?

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option 4 is correct

options 3 is correct because CaO is a solid and it is not considered so rate of forward reaction is K[CO2]

3796.

Ifequilibrium constant for reaction 2ABA, + B2, is 49, then the equilibrium constant forreactionAB-A2+-B2,will be2(2)20(4) 212(3) 49If equilibrium constants of reaction, N+02

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49 bcoz in first reaction there is two ab and product produced in 1:1 ratio and in second eqn ab is 1 it converts in 1/2:1/2

your ans is wrong

equilibrium constant for 1st is written as Keq = [A2]¹[B2]¹/[AB]²

and for 2nd reaction it is

K'eq = A2]½[B2]½/[AB]

that is K'eq = √Keq = √49 = 7

option 1

3797.

6.9 What are the characteristics of equilibriumconstant?

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Ans :- Characteristics of Equilibrium Constant: It has a definite value for every chemical reaction at a particulartemperature. It is independentof initial concentrations of the reacting species. It changes with the change in thetemperature.

3798.

The density of mercury is 13.6 g/mL. Calculate the diameter of an atom of mercuryassuming that each atom of mercury is occupying a cube of edge-length equal to thediameter of the mercury atom. (Hg200)LIT)

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3799.

What is the equilibrium constant expression for the following equilibrium reaction?2N20(g) +02(9)4NO(g)NO]

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C answer is right.

option cas the keq is given by the concentration of products raise to power there number of moles/concentration of reactants raise to power there moles

3800.

I. The relation between equilibrium constant K, and Kc is

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