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1.

`IUPAC` name of succinic acid isA. Butanedioic acidB. Oxalic acidC. PropanedioicD. None of these

Answer» Correct Answer - a
Succinic acid is `HOOC-CH_(2)-CH_(2)-COOH.`
2.

The correct `IUPAC` name of the compound A. `1-`Ethenylcyclohexa`-2,4-`dieneB. `5-`Ethenycyclohex`-1,3-`dieneC. `6-`Ethenylcyclohexa`-1,3-`dieneD. Cyclohexa`-2,4-`dienylethene

Answer» Correct Answer - b
Ring has two double bonds so name will and with ring.
3.

The `IUPAC` name of the compound `CH_(3)CH=CHC-=CH` isA. pent`-4-`yn`-2-`eneB. pent`-3-`en`-1-`yneC. pent`-2-`en`-4-`yneD. pent`1-1`yn`-3-`ene

Answer» Correct Answer - b
Follow `IUPAC` rules
`overset(5)(C)H_(3).overset(4)(C)H=overset(3)(C)H.overset(2)(C)-=overset(1)(C)H`
4.

Assertion `:` The central carbon`-`carbon bond in `1, 3-`butadiene is shorter than `n`-butane. Reason `:` In butadiene the central bond has `sp^(2)-sp^(2)` nature whereas in butane it is `sp^(3)-sp^(3)`.A. If both the assertion and reason are true and reason is the true explanation of the assertion .B. If both the assertion and reason are true bu the reason is not the correct explanation of assertion.C. If the assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - a
Both assertion and reason are true and the reason is the correct explanation of the assertion.
5.

In which of the following compound `IUPAC` numbering is correct `:`A. B. C. D.

Answer» Correct Answer - c
6.

In above compound, total number of `2^(@)` hydrogen atoms are `:`A. 3B. 18C. 6D. 9

Answer» Correct Answer - C
7.

Assertion `:` Neopentane is chain isomer of `n-`pentane. Reason `:` Molecular formula of neopentane and `n-`pentane is `C_(5)H_(12)`.A. If both assertion and reason are true and the reason is the correct explanation of the assertion.B. If both the assertion and reason are true but the reason is not the correct explanation of assertion.C. If the assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - b
8.

When an organic compound is present in aqueous medium and is less soluble in any organic solvent, then it is separated by `:`A. continuous extractionB. distillationC. chromatographyD. sublimation

Answer» Correct Answer - a
9.

What if the name of the following compound ? A. `3-(` cyclohexanecarboxamideo`)-2-`hydroxy`-6` sulphobenzoic acidB. `2-`Carboxy`-4(`cyclohexanecarboxamido`)-3-`hydroxy`-`benzene sulphonic acidC. `5-(`cyclohexanecarboxamido`)-6-`hydroxy`-2-`sulphobenzoic acidD. None of these

Answer» Correct Answer - b
10.

Which of the following has not bridgehead carbon ?A. B. C. D.

Answer» Correct Answer - d
11.

Write the `IUPAC` name of the following compound. A. `4-(`benzene carboxamide `)-6-`nitrobenzene sulphonic acidB. `4-(`benzoylamino`)-6-`nitrobenzene sulphonic acidC. `4-(`benzoylamino`)-2-`nitrobenzene sulphonic acidD. `4-(`benzamido`)-6-` nitrobenzene sulphonic acid

Answer» Correct Answer - c
12.

The systematic name of the compound isA. Bicyclo `[2,2,0]` octane`-2,6-`dieneB. Bicyclo`[2,2,2]` octane `-2,6-`dieneC. Bicyclo`[1,1,1]`octanoneD. None of these

Answer» Correct Answer - b
13.

The `IUPAC` name of the compound A. Bicyclo`[2,2,2]` octane `-3-`olB. Bycyclo`[4,2,0]` octane `-6-` olC. Bicyclo`[4,2,0]` octane `-3-` olD. Bicycle `[2,4,0]` octan `-3-` ol

Answer» Correct Answer - c
14.

The Diels `-`Alder reaction between `1,3-`cyclohexanediene and propenoic acid gives the product. It `IUPAC` name is A. `2-`carbocy bicyclo`[2.2.2]` oct`-5-`eneB. Bicyclo`[2.2.2]`oct`-5-`en`-5-`oicacidC. Bicyclo`[2.2.2]` oct `-5-`en`-2-`carboxylic acidD. `3-`carboxy bicyclo `[2.2.2]`oct`-5-`ene

Answer» Correct Answer - c
15.

The `IUPAC` name of the compound isA. `5-`Chloro oct `-2-` eneB. `7-`Chloro bicyclo`[2,2,2]` oct `-2-`eneC. `5-`Chloro bicyclo`[2,2,2]`oct `-2-` eneD. None of these

Answer» Correct Answer - c
16.

The `IUPAC` name of the spiro compound, isA. `8-`Ethyl`[4,5]`deca`-1,7-`dieneB. `2-`Ethyl spiro`[5,4]`deca`-1,6-`dieneC. `3-`Ethyl spiro `[5,4]`deca `-3,7-`dieneD. `2-`Ethyl spiro`[4,5]` deca`-2,6-`diene

Answer» Correct Answer - d
17.

If `0.228 g` of silver salt of dibasic acid gabe a residue of `0.162 g` of silver on ignition then molecular weight of the acid isA. 70B. 80C. 90D. 100

Answer» Correct Answer - c
Mass of silver salt taken`=0.228 gm`
Mass of silver left`=0.162 gm`
Basicity of acid `=2`
Step`1-` To calculate the equivalent mass of silver salt `(E)`
`=(E)/(108)=(0.228)/(0.162)=E=(0.228)/(0.162)xx108`
`=1529`(Eq. mass o f silver salt `)`
Step`2-` To calculate the eq. mass of acid.
Eq. mass of acid `-` Eq. mass of silver salt`-`Eq. mass of `Ag+` Basicity
`=152-108+1=152-109`
`=43(` Eq. mass of acid `)`
Step`3-` To determine the molecular mass of acid.
Mol. mass of acid `=` Eq. mass of acid `xx` basicity
`=45 x2=90`.
18.

The most suitable method of separation of a mixture of ortho and para nitrophenol in the ratio `1:1` is :A. ChromatographyB. CrystallisationC. steam distillationD. sublimation

Answer» Correct Answer - c
The ortho and para isomers can be separated by steam distillation `o-`Nitrophenol is steam volatile due to intramolecular hydrogen bonding while `p-`nitro phenol less volatile due to intermolecular hydrogen bonding which cause association of molecular.
19.

The best method for the separation of naphthalene and benzoic acid from their mixture isA. Chromatography CrystallisationB. DistillationC. SublimationD. sublimation

Answer» Correct Answer - b
Mixture of benzoic acid and naphthalene can be separated from hot water in which benzoic acid dissolves but naphthalene does not.
20.

The most suitable method of separation of a mixture of ortho and para nitrophenol in the ratio `1:1` is :A. distillationB. crystallizationC. sublimationD. chromatography

Answer» Correct Answer - A
Para nitrophenol has higher to `b.p.` due to `H-` bonding.
21.

A gas mixture contains `50%` helium and `50%` methane by volume. What is the percent by weight of methane in the mixture.A. `80.03%`B. `20.05%`C. `50%`D. `75%`

Answer» Correct Answer - a
Solution contain `He+CH_(4)`
Their `mol. Wt.=4+16=20`
`% wt.` of `CH_(4)=(wt. of CH_(4))/("Total wt". )xx100=(16)/(20)xx10=80%`
22.

The sodium extract on acidification with acetric acid and then adding lead acetate solution gives a black precipitate. The organic compound contains.A. nitrogenB. halogenC. sulphurD. phosphorus

Answer» Correct Answer - c
A black precipitate of `PbS` is formed.
23.

Assertion `:` Glycerol is purified by distilled under reduced pressure. Reason `:` Glycerol is a trihydric alcohol.A. If both assertion and reason are true and the reason is the correct explanation of the assertion.B. If both the assertion and reason are true but the reason is not the correct explanation of assertion.C. If the assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - b
Both assertion and reason are true but reason is not the correct explanation of the assertion.
24.

Assertion `:` The yield in organic reactinos are `100%` Reason `:` The organic reactions take place along with side reaction.A. If both assertion and reason are true and the reason is the correct explanation of the assertion.B. If both the assertion and reason are true but the reason is not the correct explanation of assertion.C. If the assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - d
The yield of organic reactions is not `100%` because they take place with side reactions.
25.

Common name of ethyl isocynide isA. PropionisonitrileB. AcetoisonitrileC. IsopropionitrileD. Propanoisonitrile

Answer» Correct Answer - A
`underset(Ethyl isocyni de IUPAC)(CH_(3)-CH_(2)-N)overset(rarr)=C` underset(Ac et oisonitril e (Common))( ) `
26.

Camphor is often used in molecular mass determination becauseA. It is volatileB. It is solvent for organic substancesC. It is readily availableD. It has a very high cryoscopic constant

Answer» Correct Answer - a
Due to its volatile nature camphor is often used in molecular mass determination.
27.

The correct `IUPAC` name of the compound is:A. `6-`Methyl`-1-`methyl`-4-`oxohept`-6-`ene`-1-`sulphonic acidB. `7-`Ethyl`-5-`oxooct `-7-`ene`-2-`sulphonic acidC. `2-`Ethyl `-7-`sulphooct `-1-`ene `-4-`oneD. `7-`Methylene `-5-`oxononane `-2-`sulphonic acid

Answer» Correct Answer - b
`-SO_(3)H` is higher in priority.
28.

What is the `IUPAC`name of the following compound ? A. `5-`bromo`-2-`heptyneB. `5-`bromo`-5-`methyl`-2-`hexyneC. `5-`bromo`-5,5-`dimethyl hexyneD. `2-`bromo`-2-`methyl`-4-`hexyne

Answer» Correct Answer - b
Triople bond has preference over alkyl and halide locants. Hence, they are given lower number.
29.

The correct `IUPAC` name of the compound A. `2-`Phenoxycarbonylbenzenecarboxylic acidB. Phenyl`-2-`carboxybenzenecarboxylateC. `2-`Benzoyloxybenzenecarboxylic acidD. `2-`Benzyloxycarbonylbenzenecarboxylic acid

Answer» Correct Answer - a
`2-`Phenoxycarbonylbenzenecarboxylic acid.
30.

What is the correct `IUPAC` name of A. Dioxy butaneB. `2,6-`dioxy butaneC. `1,2-`dimethoxy ethaneD. Dimethyl ethyl ether

Answer» Correct Answer - c
It is a diether with two methoxy groups at `C-1` and `C-2` of parent ethane.
31.

Which of the following is the best scientific method to test the presence of water in liquid ?A. Use of anhydrous copper sulphateB. Use of litmus paperC. TasteD. Smell

Answer» Correct Answer - A
Anhydrous `CuSO_(4)` is used to test presence of water in any liquid because it changes its colour white to blue.
32.

Suggest the suitable name of the following compound. `CH_(2)=CH-OH`A. Viny alcoholB. Hydroxy etheneC. Hydroxy ethyleneD. Ethene `-2-`ol

Answer» Correct Answer - a
`CH_(2)=CH-OH(`vinyl alcohol`)`
33.

The correct `IUPAC` name of the compound is A. `4-`Bromo`-1-`chloro`-2-`fluoroiodomethylbuteneB. `4-`Bromo`-2-`chloromethyl`-1-`fluoro`-1-`iodbut `-1-`eneC. `2-(2-`Bromoethyl`)-3-`chloro`-1-`fluoro`-1-`iodoprop`-1-`eneD. `1-`Bromo`-3-`chloromethyl`-4-`fluoro`-4-`iodobut`-1-`ene

Answer» Correct Answer - b
Lower number to carbon having double bond.
34.

The label of a bromobutanoic acid bottle has been washed away. Someone is trying to relabel it with correct `IUPAC` name. Whih of the following cannot be a name ?A. `2-`bromobutanoic acidB. `3-`bromobutanoic acidC. `4-`bromobutanoic acidD. `1-`bromo`-3-`butanoic acid

Answer» Correct Answer - d
In monocarboxylic acid, numbering always starts from carbon of `-COOH` group.
35.

Name of the compound given below is A. `5-`ethyl`-6-`methyloctaneB. `4-`ethyl`-3-`methylocataneC. `3-`methyl`-4-`ethyloctaneD. `2,3-`diethylheptane

Answer» Correct Answer - b
4 ethyl`,3` methyl ocatane
36.

In the estimation of sulphur organic compound on treating with conc. `HNO_(3)` is converted toA. `SO_(2)`B. `H_(2)S`C. `H_(2)SO_(4)`D. `SO_(3)`

Answer» Correct Answer - c
In Carius method sulphur of organic compound is converted in to `H_(2)SO_(4)`.
`S+H_(2)O+3Ounderset(HNO_(3))overset(Delta)rarr H_(2)SO_(4)`.
37.

Assertion `:` Refining of petroleum involves fractional distillation. Reason `:` Fractional distillation involves repeated distillation.A. If both assertion and reason are true and the reason is the correct explanation of the assertion.B. If both the assertion and reason are true but the reason is not the correct explanation of assertion.C. If the assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - B
Petroleium can be refined by fraction distillation since it separate crude petroleum into useful fractions such as gasoline, kerosene oil, lubricating oil etc.
38.

Assertion `:` Potassium can be used in Lassaigne test. Reason `:` Potassium reacts vigorously.A. If both the assertion and reason are true and reason is the true explanation of the assertion .B. If both the assertion and reason are true bu the reason is not the correct explanation of assertion.C. If the assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - d
Assertion is false but reason is true.
39.

Chromatography is a valuable method for the separation, isolation, purification and identification of the constituents of a misture and it is based on general principle ofA. Phase ruleB. Phase distributionC. Interphase separationD. Phase operation

Answer» Correct Answer - a
40.

The structure of allyl viny thioether isA. `CH_(2)=CH-CH_(2)-S-CH_(2)-CH=CH_(2)`B. `CH_(2)=CH_S-CH_(2)-CH=CH_(2)`C. `CH_(2)=CH-S-CH=CH_(2)`D. None of these

Answer» Correct Answer - b
`CH_(2)=CH-S-CH_(2)-CH=CH_(2)` Allyl vinyl thioether
41.

Which of the following compound is unsaturated hydrocarbon.A. `CH_(3)-overset(O)overset(||)(C)-CH_(3)`B. `CH_(3)-C-=N`C. D.

Answer» Correct Answer - d
According to `IUPAC` only alkene and alkyne are unsaturated hydrocarbon.
42.

Which of the following compound is unsaturated hydrocarbon.A. B. `CH_(3)-C-=N`C. D.

Answer» Correct Answer - D
According to `IUPAC` only alkene and alkyne are unsaturated hydrocarbon.
43.

In the compound `CH_(2)=CH-CH_(2)-CH_(2)-C-=CH` the `C_(2)-C_(3)` bond is ofA. `sp-sp^(2)`B. `sp^(2)-sp^(3)`C. `sp-sp^(3)`D. `sp^(3)-sp^(3)`

Answer» Correct Answer - b
The correct numbering of parent chain is
`overset(1)(C)H_(2)=overset(2)(C)H-overset(3)(C)H_(2)-overset(4)(C)H_(2)-overset(5)(C)-=overset(6)(C)H`
Double and triple bond are equidistant from teminals, numbering is done in alphabetical order, giving lower number ot ene.
Hence, `C_(2)=C_(3)` are `sp^(2)-sp^(3)` hybridised
44.

Empirical formula of a compound is `CH_(2)O` and its vapour density is 30. Molecular formula of the compound isA. `C_(2)H_(6)O_(3)`B. `C_(2)H_(4)O_(2)`C. `C_(2)H_(4)O`D. `CH_(2)O`

Answer» Correct Answer - B
Empirical formula `=CH_(2)O`
Empirical formula mass `=12+2+16=30`
Mol. Mass `2xxV.D.=2xx30=60`
`n=(Mol. mass)/("Emperical mass")=(60)/(32)=2`
Molecular formula`=(` emperical formula`)_(n)`
`=(CH_(2)O)_(2)=C_(2)H_(4)O_(2)`
45.

An organic compound contains `C,H` and `O` in the proportion of `6:1:8` by weight, respectively. Its vapour density is 30. Its molecular formula will beA. `C_(2)H_(4)O_(2)`B. `CH4O`C. `CH_(2)O`D. `C_(3)HO`

Answer» Correct Answer - a
`"Element No. of moles Simple ratio"`
`C" "6" "6//12=0.5=1" "1`
`H" "1" "1//1=1=2" "2`
`O" "8" "8//16=0.5=1" "1`
Thus, Empirical formula `=CH_(2)O`
Empiricial formula mass `=30`
Mol. Mass `2xxVD=2xx30=60`
`n=(60)/(30)=2`
Mol. formula`=(CH_(2)O)_(2)=C_(2)H_(4)O_(2).`
46.

The `IUPAC` name of the A. `4-`Oxobenzoic acidB. `4-`Formyl benzoic acidC. `4-`Formyl cyclohexane carboxylic acidD. None of these

Answer» Correct Answer - c
As `CHO` is behaving as substituent.
47.

The correct `IUPAC` name of the compound. A. `N-`Formy`-4-`chlorobenzenamineB. `N-`Formyl`-4-`chloroanilineC. `N-(4-`chlorophenyl`)` methanamideD. `N-(`Parachlorphenyl`)-N-`formylaniline

Answer» Correct Answer - c
`N-(4-`chlorophenyl`)` methanamide
48.

`IUPAC` name of A. `4-`Chlorophenyl benzoateB. Phenyl`-4-`chlorobenzenecarboxylate.C. Benzy`-4-`chlorobenzenecarboxylate.D. `4-`Chloro diphenycarboxylate.

Answer» Correct Answer - b
Phenyl`-4-`chlorobenzenecarboxylate.
49.

How many `H-` atoms are present in `0.046 g` of ethanol ?A. `6 xx 10^(20)`B. `1.2 xx 10^(21)`C. `3 xx 10^(21)`D. `3.6xx 10^(21)`

Answer» Correct Answer - D
`Mol. Wt. `of `C_(2)H_(5)OH`
`=2xx12+5+16+1=64`
`:. 48g C_(2)H_(5)OH` has `H atm =6xxN_(A)`
`:. 0.046g C_(2)H_(5)OH ` has `H atm`
`=(6xx6.02xx10^(23)xx0.046)/(46)=3.6xx10^(21)`
50.

Assertion `:` Ethanol and water mixture can be separed by simple distillation. Reason `:` Ethanol and water forms azeotropic mixture.A. If both the assertion and reason are true and reason is the correct explanation of the assertion .B. If both the assertion and reason are true bu the reason is not the correct explanation of assertion.C. If the assertion is true but reason is false.D. If assertion is false but reason is true.

Answer» Correct Answer - d
Separation of alcohol`-` water is done by adding `C_(6)H_(6)` and then using fractional distillation.