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651.

Hydrogen peroxide is used asA. Oxidising agentB. Reducing agentC. Both as oxidising and reducing agentD. Drying agent.

Answer» Correct Answer - C
Both oxidising and reducing in nature (see comprehensive review).
652.

In the laboratory, `H_(2)O_(2)` is prepared by the action ofA. cold `H_(2)SO_(4)` on `BaO_(2)`B. aqueous alkali on `Na_(2)O_(2)`C. `MnO_(2)` and cold `H_(2)SO_(4)`D. dilute HCl and `MnO_(2)`.

Answer» Correct Answer - A
Laboratory preparation
`BaO_(2).8H_(2)O+H_(2)SO_(4)toBaSO_(4)darr+H_(2)O_(2)+8H_(2)O`.
653.

The process 1/2 `H_(2)(g)+e^(-) to H^(-)(g)` is endothermic `(DeltaH=+151kJ mol^(-))`, still ionic hydrides are known. How do you accound for this:

Answer» In the formation of solid ionic hydrides, energy is released as released as enthalpy `Delta_(f)H` from the corresponding ions in the gaseous state that are involved in the hydride. This compensates the energy which is needed for the formation of `H^(-)` ions from `H_(2)` gas
654.

Difference between hard water and soft water.

Answer»

The water which contains dissolved salts of bicarbonates, sulphates and chlorides of calcium and magnesium is called hard water. Hard water does not produce lather with soap solution. 

Soft water is free from bicarbonates, sulphates and chlorides of calcium and magnesium. It produces lather with soap solution easily. e.g., distilled water, rain water.. 

655.

Metal hydride on treatment with water gives `:`A. `H_(2)O_(2)`B. `H_(2)O`C. acidD. hydrogen

Answer» Correct Answer - d
`CaH_(2)+2H_(2)O rarr Ca(OH)_(2)+2H_(2)`
656.

Calculate the strength of 20 volume solution of hydrogen peroxide.

Answer»

10 volume solution of H2O2 means that 1L of this H2O2 will give 10 L of oxygen at STP 

2H2 O2 ( l) → O2( g) +2 H2O( l) 

2×34 g       22.4 L at STP 

22.4 L of O2 at STP is produced from H2O2 = 68 g 

20 L of O2 at STP is produced from H2O2 =68X20/22.4 = 60.72 g

Therefore, strength of H2O2 in 20 volume H2O2 = 60.72 g/L

657.

Assign the reason for the following observations:(a) The temporary hardness of water is removed by boiling. (b) In the Clark’s method, only calculated amount of lime is added to hard Water for removal of hardness. (c) Regeneration of sodium zeolite is essential by brine.

Answer»

a) because calcium and magnesium bicarbonates decomposes on heating or boiling 

b) It precipitates out calcium carbonate and magnesium hydroxide which can be filtered off. 

c) Permutit/Zeolite is said to be exhausted when all the sodium in it is used up. It is regenerated for further use by treating with an aqueous sodium chloride solution. 

658.

Distinguish clearly between salt-like and covalent hydrides.

Answer»

Salt-like hydrides are also called ionic hydrides. They are formed by group 1 and 2 elements with H2. They are basic in nature. They dissolve in water forming alkali and give H2 gas, .e.g., NaH, CaH2, KH etc. Covalent hydrides are formed between less electropositive or electronegative elements. 

Ex : B2H6, AlH3, BeH2, They are insoluble in water.

659.

Discuss the position of hydrogen in the periodic table is not justified.

Answer»

Its position in periodic table is not justified because it resembles both alkali metals and halogens.

(i) Its electronic configuration is similar to alkali metals. 

(ii) It is non-metal like halogens. 

(iii) Its ionization energy is high like halogens. 

(iv) It can lose electrons to form H+ like alkali metals.

660.

Hard water is softened before using in boilers. Explain

Answer»

Hard water on boiling forms precipitates of MgCO3, CaCO3 and CaSO4 which form scales in the boilers. As a result of these scales in the boilers. The boiler gets deteriorated due to over heating. Moreover, these scales are non-conducting and therefore, more fuel is consumed. Therefore, in order to prevent the formation of scales, hard water softened before using in boilers.

661.

Write one chemical reaction for the preparation of D2O2.

Answer»

D2Ocan be prepared by the reaction of D2SO4 dissolved in water over BaO2.
BaO2 + D2SO4 → BaSO4 + D2O2  

662.

Write one chemical reactions for the preparation of D2O2.

Answer»

D2O2 can be prepared by the reaction of D2SO4 dissolved in water over BaO2.

BaO2 + D2SO4 → BaSO4 + D2O2

663.

For which work H.C. Very get Noble prize in 1934.

Answer»

Heavy hydrogen or deuterium was separated from liquid hydrogen by fractional evaporation by H.C. Urey. For this great contribution, he was awarded the Noble Prize in Chemistry in 1934.

664.

The maximum tolerable limit of degree of hardness in water required for our daily needs is approximatelyA. 10-15 ppmB. 100-150 ppmC. `10^(3)` ppmD. 700-800 ppm.

Answer» Correct Answer - B
665.

Define degree of hardness of water.

Answer» It may be defined as:
The number of parts by weight of calcium carbonate (or its equivalent) present in a million `10^((6))` parts by weights of water.
666.

What you mean by degree of hardness?

Answer»

Degree of hardness is defined as the number of parts of calcium carbonate or equivalent to various calcium and magnesium salts present in a million parts of water by mass. It is expressed in ppm.

667.

The hybrid state and oxidation state of two oxygen atoms in `H_(2)O_(2)` are respectivelyA. `sp^(2),-1`B. `sp^(3),+1`C. `sp^(3),-1`D. `sp^(2),-2`.

Answer» Correct Answer - C
Oxidation number of oxygen is -1, and hybrid state of both oxygen atom is `sp^(3)`.
668.

A `100 mL` of tap water was titrated with `M//50 HCl` with methyle orange as indicator. If `30 mL of HCl` were required. Calculate the hardness of `CaCO_(3)` per `10^(3)` parts of water. The hardness is temporary.A. `150 "ppm"`B. `600 "ppm"`C. `275 "ppm"`D. `300 "ppm"`

Answer» Correct Answer - D
Meq. of `CaCO_(3)`= Meq. of `Ca(HCO_(3))_(2)` = Meq. of HCl
`(W)/(100//2)xx 1000= (1)/(50) xx 30`
`W_(CaCO_(3))= (3 xx 100 )/(5 xx 2000) = 0.03 g`
`therefore 100 mL " of "H_(2)O " contins " Ca^(2+)= (0.03 xx 10^(6))/(100)= 300 "ppm"`
669.

The volumn strength of perhydrol isA. 20B. 30C. 100D. 10 .

Answer» Correct Answer - C
The volumn strength of perhydrol is 100
Perhydrol is `30% H_(2)O_(2)`
10 vol `H_(2)O_(2)-=3% H_(2)O_(2)`
`:. 30% of H_(2)O_(2)=-100 vol H_(2)O_(2)`
670.

What is hydride gap?

Answer»

The region of the periodic table from groups 7-9 which do not form hydrides is called the hydride gap.

671.

What is syngas? Why is it called so?

Answer»

Mixtures of CO and H2 are called syngas. It is so named because it is used for the synthesis of methanol and a number of hydrocarbons.

672.

The name of the perhydrol is given toA. solution of `Na_(2)O_(2)` in etherB. dilute solution of phenol in etherC. dilute solution of `H_(2)O_(2)` in waterD. dilute solution of `CrO_(4)` in ether.

Answer» Correct Answer - C
dilute solution of `H_(2)O_(2)` in water is known as per hydrol.
673.

Which of the following statements are not true for hydrogen ?A. It exist as diatomic moleculeB. It has one electron in the outermost shellC. It can lose an electron to from a cation which can freely existD. If from a large number of ionic compounds by losing an electron

Answer» Correct Answer - C::D
`H^(+)` does not exist freely and is always associated with other atoms or molecules. Like alkali metals, hydrogen forms oxides, halides and sulphides. However, unlike alkali metals, it has very high ionisation enthalpy and does not possess metallic characteristics under noraml conditions.
674.

High dipole moment of water `(1*03 D)` justifies thatA. it is not linear moleculeB. it is a universal solventC. it has higher density than iceD. it is neutral towards litmus.

Answer» Correct Answer - A
Had it been linear molecule the dipole moment would have been zero.
675.

Why hard water does not form lather with soap? What advantage has soap over detergents?

Answer»

It is because Ca2+ and Mg2+ ions present in hard water react with soap to form Ca2+ and Mg2+ salts of fatty acids which are insoluble in water. 

Advantages of soap over detergent; soap are biodegradable where as detergents are non-biodegradable.

676.

Reaction of steam on hydrocarbon or coke at high temperature in presence of catalyst yields a mixture of gases. (a) Name the gases produced. (b) Write a reaction of the above mentioned process. (c) What is a specific name given to the mixture of gases? (d) Write the reaction when the mixture of gases is reacted with steam in presence of iron chromate as catalyst. Also give the special name of this reaction.

Answer»

(a) Carbon monoxide and dihydrogen

(b) CnH2n+2 + nH2\(\overset{1270\,K}{\underset{Ni}{\longrightarrow}}\) nCO + (2n + 1)H2

(c) Synthetic gas or syngas or water gas.

(d) CO(g) + H2O(l) \(\overset{673\,K}{\underset{FeCrO_4}{\longrightarrow}}\) CO2(g) + H2(g)

Water-gas shift reaction is the special name of this reaction.

677.

Difference in chemical behaviour of compound of hydrogen with elements of atomic number 17 and 20.

Answer»

Atomic number 17 = Chlorine, and Atomic number 20 = Calcium. 

(b) H2 + Cl2 → 2HCl 

Cl2 is oxidizing agent, H2 is reducing agent. 

Ca + H2 → CaH2

678.

Hydrogen forms comound with elements having atomic number 9,11,12 and 17. Write their chemical formulate.

Answer» HF,NaH,`MgH_(2)` and HCl
679.

Orthohydrogen and parahydrogen haveA. Same electronic spin, physical and chemical properitesB. Parallel electronic, and nuclear spin with identical physical and chemical properties.C. Different electronic spin with differences in physical and chemical properties.D. Opposite electronic spin, different nuclear spin and with different physcial properties.

Answer» Correct Answer - D
680.

Protonic acid isA. a compound that form solvated hydrogen ion in polar solventB. an acid which accepts the protonC. a compound that forms hydride ion in polar solventD. an acid which donates the proton.

Answer» Correct Answer - A
For example HCl is a protonic acid
`HCl+H_(2)OhArr[H_(3)O]^(+)+Cl^(-)`
681.

Hydrogen peroxide isA. an oxidising agentB. a reducing agentC. both an oxidising and a reducing agentD. neither oxidising nor reducing agent

Answer» (c ) `H_(2)O_(2)` acts both as an oxidising agent and reducign agent
682.

Boron with hydrogen forms a number of hydrides which are known are boranes. These hydrides are classified into closoboranes and nidobarances. The simplest hydride of boron is diborane. Boron apart from having `(2c, 2e)` bonds also contain `(3c, 2e)` bonds. Which of the following is an electron-deficient compound ?A. `NaH`B. `CaH_(2)`C. `CH_(4)`D. `B_(2)H_(6)`

Answer» Correct Answer - D
D
683.

In all its properties, hydrogen resembles `:`A. Alkali metals onlyB. Halogen onlyC. Both alkali metals and halogensD. Neither alkali metals nor halogens.

Answer» Correct Answer - C
Hydrogen resembles both alkali metals and halogens.
684.

Hydrogen resembles in many of its properties `:`A. halogenB. Alkali metalsC. both `(a)` and `(b)`D. none of these

Answer» Correct Answer - C
C
685.

Atomic hydrogen reacts with oxygen to giveA. almost pure waterB. almost pure hydrogen peroxideC. a mixture of water and hydrogen peroxideD. None of these.

Answer» Correct Answer - B
Atomic hydrogen reacts with oxygen to give almost pure hydrogen peroxide
`2[H]+O_(2)toH_(2)O_(2)`
686.

Which of following cannot be used for the preparation of `H_(2)` ?A. Zn+HCl(dil.)B. `NaH+H_(2)Oto`C. `Zn+HNO_(3)(dil.)to`D. `HCOONaoverset(Delta)to`

Answer» Correct Answer - C
`Zn+2HCl(dil.)toZnCl_(2)+H_(2)`
`NaH+H_(2)OtoNaOH+H_(2)`
`2HCOONaoverset(Delta)tounderset("sodium oxalate")(Na_(2)C_(2)O_(4)+H_(2))` M
`4Zn+10HN_(3)(dil.)to4Zn(NO_(3))_(2)+N_(2)O+5H_(2)O`
687.

Calgon used as water softner isA. `Na_(2)[Na_(4)(PO_(3))_(6)]`B. `Na_(4)[Na_(2)(PO_(3))_(6)]`C. `Na_(2)[Na_(4)(PO_(4))_(5)]`D. None of the above

Answer» Correct Answer - A
Calgon used as water softner . The chemial compositive is `Na_(2)[Na_(4)(PO_(3))_(6)]`.
688.

Metal which does not react with cold water but evolves `H_(2)` with steam is `:`A. `Fe`B. `K`C. `Pt`D. `Na`

Answer» Correct Answer - A
`underset(Red hot)(3Fe)+4H_(2)O(v) rarr Fe_(3)O_(4)+4H_(2)`
689.

Write two reactions to explain amphoteric nature of water .

Answer» The reaction which explain the amphoteric nauture of water are:
`underset("acid")(H_(2)O(l))+NH_(3)(aq) Leftrightarrow OH^(-)(aq)+NH_(4)^(-)(aq)`
`underset("Base")(H_(2)O(l))+H_(2)S(aq) Leftrightarrow H_(3)O^(+)(aq)+HS^(-)(aq)`
690.

Give reasons for the following:(a) Hydrogen be used as a fuel?(b) Though hydrogen is lighter than air it cannot be collected by downward displacement of air.(c) A pop sound produced when hydrogen is burnt?(d) Helium replaced hydrogen in weather observation balloons?(e) Nitric acid not used for the preparation of hydrogen gas?(a) Because of its high heat of combustion, it is used as a fuel.

Answer»

(a) Coal gas, water gas and liquid hydrogen are some significant fuel.

(b) Since hydrogen is lighter than air. it is possible to collect the gas by downward displacement of air. But it is not safe to do so since a mixture of hydrogen and air can lead to an explosion.

(c) Impure hydrogen gas bums in air with a pop sound. This is because of the presence of impurities in it.

(d) If there is a small leakage of hydrogen in a balloon, it forms a mixture with air that can explode. So helium has replaced hydrogen.

(e) Hydrogen cannot be prepared by the action of nitric acid on metals because it also releases nitrous oxide and nitric oxide and oxides the hydrogen to form water.

691.

Temporary hardness of water is due the presence ofA. Magnesium bicarbonateB. Calcium chlorideC. Magnesium sulphateD. Calcium carbonate.

Answer» Correct Answer - A
Chlorides and sulphates of Mg and Ca produces permanent hardness, and bicarbonates of Mg and Ca produces temporary hardness.
692.

Which of the following is not true ?A. Hardness of water depends on its behaviour towards soapB. The temporary hardness is due to the presence of soluble `Ca` and `Mg` bicarbonatesC. Permanent hardness is due to the presence of soluble `Ca` and `Mg` sulphate , chlorides and nitratesD. Permanent hardness can be removed by boiling the water

Answer» Correct Answer - D
Permanent hhardness cannot be removed by boiling of water but temporary hardness can be removed.
693.

Temporary unstable hardness of water due to presence of :A. `CaCl_(2),MgSO_(4)`B. `Ca^(+2),Mg^(+2)`C. `K^(o+),CaCO_(3)`D. `Ca(HCO_(3))_(2),Mg(HCO_(3))_(2)`

Answer» Correct Answer - D
Temporary hardness arises due to `Ca(HCO_(3))_(2)& Mg(HCO_(3))_(2)`
694.

By which reaction formation of hard water takes place : (a) `Ca(CH)_(2)+2HCl` (b) `NaOH+HCl` (c) `KOH+HCl` (d) `NaOH+H_(2)CO_(3)`A. By only dB. By only aC. By a, b, cD. By all process

Answer» Correct Answer - B
Hardness of water arises due to presence of `CaCl_(2),CaSO_(4),MgCl_(2),MgSO_(4),Ca(HCO_(3))_(2)Mg(HCO_(3))_(2)" only "Ca(OH)_(2)+2HClrarr CaCl_(2)+H_(2)O`
695.

Which of the following will cause softening ofhard water ?A. Passing it through cation exchange resinB. Passing it through anion exchange resinC. Passing it through sandD. Passing it through alumina

Answer» Correct Answer - a
In cation exchange resin `Mg^(+2)` and `Ca^(+2)(` cations `)` are replaced by `Na^(+)` ions.
696.

Which one of the following removes temporary harness of water ?A. Slaked limeB. Plaster of ParisC. CuprousD. Hydrolith

Answer» Correct Answer - A
Slaked lime removes temporary hard ness of water.
`Ca(OH)_(2) +underset("From hard water")(Ca(HCO_(3))_(2))rarr underset(ppt.)(2CaCO_(3)darr)+2H_(2)O`
697.

Which of the following pairs produce deutronitric acidA. `NO_(2),H_(2)O`B. `NO,D_(2)O`C. `N_(2)O_(5),D_(2)O`D. `N_(2),D_(2)O`

Answer» Correct Answer - C
`N_(2)O_(5)+D_(2)Orarr underset("Deutronitric")(2DNO_(3))`
698.

The compound sodium polymetaphosphate `(Na[Na_(4)(PO_(3))_(6)])` is called calgon becauseA. It was developed by the scientistB. It was developed first in CaliforniaC. It refers to calcium goneD. It is based on the name of the company which developed it.

Answer» Correct Answer - C
It refers to calcium gone.
699.

Polyphosphates are used as water softening agents because theyA. Form soluble complexes with anioic speciesB. precipitate anionic speciesC. Form soluble complexes with cationic speciesD. Precipitate cationic species.

Answer» Correct Answer - C
700.

Polyphosphates are used for softening agents because theyA. form soluble complexes anionic speciesB. precipitate anionic speciesC. form soluble complexes with cationic speciesD. precipitate cationic species

Answer» Correct Answer - c
c