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101.

Why did Rutherford select a gold foil in his `alpha`-ray scattering experiment ?

Answer» Because nucleus is positively charged (electrostatic force of repulsion)
102.

Thickness of the foil of gold used in `alpha`-particle scattering experiment isA. `2.1xx10^(-7)` mB. `3.5xx10^(-5)` mC. `2.1xx10^(-9)` mD. `3.5xx10^(-6)` m

Answer» Correct Answer - A
103.

The mass of an `alpha-`particle is.

Answer» Alpha particle is a doubly charge Helium nucleus , so it has two neutrons and two protons.
Therefore, M`approx` 4U
104.

Most of the `alpha`-particles passed through the foil undeviated . What can be concluded from this observation ?

Answer» it can ve concluded that most of the space in an atom is unoccupied.
105.

Very thin foil of gold was used in scattering experiment. Why ?

Answer» It was done to avoid multiple scattering.
106.

Suppose you are given a chance to repeat the alpha-particle scattering experiment using a thin sheet of solid hydrogen in place of the gold foil. (Hydrogen is a solid at temperatures below 14 K.) What results do you expect?

Answer»

The nucleus of hydrogen contains only one proton. Its mass is 1.67 x 10-27 kg. The mass of an alpha-particle is 6.64 x 10-27 kg. When the alpha particles are incident on a thin sheet of solid hydrogen [in place of the gold foil], even in a head-on collision, the alpha-particle will not be scattered back. It is because the scattering particle is more massive than the target particle.

107.

A 12.5 eV electron beam is used to bombard gaseous hydrogen at room temperature. What series of wavelengths will be emitted?

Answer»

The first, second and third excited energies for hydrogen atom are
E’1 = E2 – E1 = -3.4 – [-13.6] = 10.2 eV,
E’2 = E3 – E= -1.51 – [-13.6] = 12.09 eV,
and E’3 = E4 – E1 = -0.85 – [-13.6] = 12.75 eV
It follows that when a 12.5 eV electron beam is used to bombard gaseous hydrogen at room temperature, the H – atoms at the most will be raised to n = 3 level. The H – atoms may come to ground state directly or via n = 2 level. Therefore, the wavelengths emitted will lie in Balmer series [for de-excitation from n = 3 level to n = 2 and 1 level] and Lyman series [for de­excitation from n = 2 level to n = 1 level].

108.

Is the probability of backward scattering (i.e., scattering of α-particles at angles greater than 90°) predicted by Thomson’s model much less, about the same, or much greater than that predicted by Rutherford’s model?

Answer»

Thomson’s model predicts the backward scattering of a -particles much less than that predicted by Rutherford’s model. The reason is that in Thomson’s model, positive charge is uniformly distributed over whole of the nucleus instead of being concentrated in a small part.

109.

In which model is it completely wrong to ignore multiple scattering for the calculation of average angle of scattering of α-particles by a thin foil?

Answer»

On the basis of Thomson’s atom model, the scattering angle of α-particles due to single collision will be very small. It is because, mass of atom is distributed all over it. The observed average scattering angle can be explained only by considering multiple scattering. Therefore, it is wrong to ignore multiple scattering in Thomson’ atom model.

Since the mass of the atom is concentrated in the form of nucleus in Rutherford’s atom model, most of the scattering comes through a single collision and multiple scattering can be ignored.

110.

Is the average angle of deflection of α-particles by a thin gold foil predicted by Thomson’s model much less, about the same, or much greater than that predicted by Rutherford’s model?

Answer»

Thomson’s atom model cannot explain the scattering of α -particles through large angles and particularly through 180°. It is because, the light particles like electrons cannot deflect the massive a -particles through 180°.

111.

Explain Thomson’s model of the atom. What are its drawbacks?

Answer»

The first model of the atom with a substructure was put forward in 1898 by Sir J.J. Thomson (1856-1940), a British physicist. According to this model, an atom consists of a sphere with a uniform distribution of positive charge and electrons embedded in it such that the atom is electrically neutral and stable.

Drawbacks : This model, known as the plumpudding model, failed to account for the observed scattering of α-particles and spectra of various elements.

[Note : It can be shown that the Thomson atom cannot be stable.]

112.

Assume that the de Broglie wave associated with an electron can from a standing wave between the atom arrange in a one dimensional array with nodes at each of the atomic sites. It is found that one such standing wave if the distance d between the atoms of the array is `2 A^0` A similar standing wave is again formed if d is increased to `2.5Å` . Find the energy of the electrons in electron volts and the least value of d for which the standing wave type described above can from .

Answer» Correct Answer - 150 eV , 0.5 Å
113.

Using the Rydberg formula, calculate the wavelength of the first four spectral lines in the Lyman series of the hydrogen spectrum.

Answer» The Rydberg formula is
`hc//lambda_(if)=(me^(4))/(8epsilon_(0)^(2)h^(2))((1)/(n_(f)^(2))-(1)/(n_(i)^(2)))`
The wavelengths of the first four lines in the Lyman series correspond to transitions from `n_(i)` = 2,3,4,5 to nf = 1. We know that
`(me^(4))/(8epsilon_(0)^(2)h^(2))=13.6 eV = 21.76xx10^(-19)J`
Therefore,
`lambda_(i1)=(hc)/(21.76xx10^(-19)((1)/(1)-(1)/(n_(i)^(2))))m`
`=(6.625 xx 10^(-34)xx3xx10^(8)xxn_(i)^(2))/(21.76xx10^(-19)xx(n_(i)^(2)-1))m=(0.9134n_(i)^(2))/((n_(i)^(2)-1))xx10^(-7)m`
`=913.4 n_(i)^(2)//(n_(i)^(2)-1)Å`
Substituting `n_(i)` = 2,3,4,5, we get `lambda_(21)` = 1218 `Å`, `lambda_(31)=1028 Å,lambda_(41) = 974.3 Å`, and `lambda_(51) = 951.4 Å`.
114.

Given that R is the Rydberg constant for hydrogen, the Hα line in the hydrogen spectrum has a wavelength(A) \(\cfrac1{6R}\)(B) 6R (C) \(\cfrac{5R}{36}\)(D) \(\cfrac{36}{5R}\)

Answer»

Correct option is (D) \(\cfrac{36}{5R}\)

115.

Given the value of Rydberg constant is `10^(7)m^(-1)`, the waves number of the lest line of the Balmer series in hydrogen spectrum will be:A. `0.5xx10^(7) m^(-1)`B. `0.25xx10^(7) m^(-1)`C. `2.5xx10^(7) m^(-1)`D. `0.025xx10^(4) m^(-1)`

Answer» Correct Answer - B
Given , Rydberg constant, `R=10^(7)m^(-1)`
`:.` for last line in Balmer series `n_(2)-oo,n_(1)=2`
As we know that,
`(1)/(lambda)=R((1)/(n_(1)^(2))-(1)/(n_(2)^(2)))rArr(1)/(lambda)=10^(7)((1)/(2^(2))-(1)/(oo))`
`barv=(1)/(lambda)=(10^(7))/(4)=0.25xx10^(7)m^(-1)`
116.

the wavelength of spectral line in the lyman series of a H-atom is `1028 Å`. If instead of hydrogen, we consider deuterium then shift in the wavelength of this line be `(m_p=1860m_e)`A. `1027.7Å`B. `1036Å`C. `1028Å`D. `1021Å`

Answer» Correct Answer - A
If `lambda_D` and `lambda_H` are wavelength emitted in the case of deuterium and hydrogen
`therefore (lambda_D)/(lambda_H)=(1-(m_e)/(2m_p))`
Here, `lambda_H=1028Å, m_p=1860m_e`
`therefore lambda_D=(1-(1)/(2xx1860))lambda_H=(1-(1)/(3720))lambda_H`
`lambda _D0.9997lambda_H=0.99973xx1028Å=1027.7Å`.
117.

The rydberg formula, for the spectrum of the hydorgen aotm where all terms have their usual menaning isA. `hupsilon_(if)=(me^(4))/(8epsilon_0^(2)h^2)((1)/(n_f)-(1)/(n_i))`B. `hupsilon_(if)=(me^(4))/(8epsilon_0^2h^2)((1)/n_(f)^2-(1)/(n_(i)^(2)))`C. `hupsilon_(if)=(8epsilon_0^2h^2)/(me^(4))((1)/(n_f)-(1)/(n_(i)))`D. `hupsilon_(if)=(8epsilon_0^2h^2)/(me^(4))((1)/n_(f)^(2)-(1)/(n_(i)^(2)))`

Answer» Correct Answer - B
118.

Hydrogen `(_(1)H^(1))` Deuterium `(_(1)H^(2))` singly omised helium `(_(1)He^(1))` and doubly ionised lithium `(_(1)Li^(6))^(++)` all have one electron around the nucleus Consider an electron transition from `n = 2 to n = 1` if the wavelength of emitted radiartion are `lambda_(1),lambda_(2), lambda_(3),and lambda_(4)`, repectivelly then approximetely which one of the following is correct ?A. `4lambda_(1)=2lambda_(2)=2lambda_(3)=lambda_(4)`B. `lambda_(1)=2lambda_(2)=2lambda_(3)=lambda_(4)`C. `lambda_(1)=lambda_(2)=4lambda_(3)=9lambda_(4)`D. `lambda_(1)=2lambda_(2)=3lambda_(3)=4lambda_(4)`

Answer» Correct Answer - C
`(1)/(lambda)=RZ^(2)((1)/(1^(2))-(1)/(2^(2)))`
`" " (1)/(lambda_(1))=R(1)^(2)(3//4),(1)/(lambda_(2))=R(1)^(2)(3//4)`
`" " (1)/(lambda_(3))=R(2)^(2)(3//4),(1)/(lambda_(4))=R3^(2)(3//4)`
`" " (1)/(lambda_(1))=(1)/(4lambda_(3))=(1)/(9lambda_(4))=(1)/(lambda_(2))`
So, option (c) is correct .
119.

Three energy levels `L_1,L_2` and `L_3` of a hydrogen atom correspond to increasing values of energy i.e., `E_(L_1) lt E_(L_2) lt E_(L_3)` . If the wavelength corresponding to the transitions `L_3` to `L_2, L_2` to `L_1` and `L_3` to `L_1` are `lambda_3, lambda_2` and `lambda_1` respectively thenA. `lambda_3=lambda_1+lambda_2`B. `lambda_1=(lambda_2lambda_3)/(lambda_2+lambda_3)`C. `lambda_1=lambda_2+lambda_3`D. `lambda_3=(lambda_1lambda_2)/(lambda_1+lambda_2)`

Answer» Correct Answer - B
120.

The energies of three conservative energy levels `L_3,L_2` and `L_1` of hydrogen atom are `E_0`. `(4E_0)/9` and `E_0/4` respectively. A photon of wavelength `lambda` is emitted for a transition `L_3` to `L_1` .What will be the wavelength of emission for transition `L_2` to `L_1` ?A. `(16lambda)/31`B. `(27lambda)/7`C. `19/20 lambda`D. `lambda`

Answer» Correct Answer - B
121.

The mass of `._(3)Li^(7)` is 0.042 amu less than the sum of masses of its nucleons. Find the B.E. per nucleon.

Answer» Correct Answer - 5.866 amu
122.

The atomic mass of `._(8)O^(16)` is 16.000000 amu. Calculate the binding energy of `._(8)O^(16)` in MeV per nucleon.

Answer» Correct Answer - 7.68 MeV
123.

The binding energy of `._(10)Ne^(20)` is 160.6 MeV. Find its atomic mass. Take mass of proton =1.007825 u and mass of neutron =1.008665 u.

Answer» Correct Answer - 19.9924 amu
124.

Calculate the binding energy per nucleon for a `._(6)C^(12)` nucleus. Atomic mass of `._(6)C^(12) = 12am u`, mass of a photon = 1.007825 amu, mass of a neutron = 1.008665 amu.

Answer» Correct Answer - 7.68 MeV
125.

An `alpha` particle of `K.E. 10^(-12)J` exhibits back scattering from a gold nucleus Z=79. What can be the maximum possible radius of the gold nucleus?

Answer» Correct Answer - `3.64 xx 10^(-14)m`
126.

Calculate the binding energy of a deutron. Given that mass of proton = 1.007825 amu mass of neutron = 1.008665 amu mass of deutron = 2.014103 amu

Answer» Correct Answer - 2.2 MeV
127.

The binding enrgy of `._(17)^(35)Cl` nucleus is 298 MeV. Find the atomic mass. Given, mass of a proton `(m_(P))=1.007825` amu, mass of a neutron `(m_(n))=1.008665` amu.

Answer» Correct Answer - 7.98 MeV
128.

A protom of energy 1 MeV is incident head-on on a gold nucleus (Z = 79), and is scattered through an angle of `180^(@)`. Calculate the distance of nearest approach.

Answer» Correct Answer - `11.37 xx 10^(-4) m`
129.

An `alpha`- particle accelerated through V volt is fired towards a nucleus. It distance of closest approach is r. If a proton accelerated through the same potential is fired towards the same nucleus, the distance of closest approach of the proton will be :A. rB. 2rC. `(r)/(2)`D. `(r)/(4)`

Answer» Correct Answer - A
Decreases in kinetic energy = increases in potential energy
`:. " " qV=(1)/(4piepsi_(0))*(Q*q)/(r)`
`:. " " r=(Q)/((4piepsi_(0))V)`
130.

An `alpha`-particle of kinetic energy 7.68 MeV is projected towards the nucleus of copper (Z=29). Calculate its distance of nearest approach.

Answer» Correct Answer - `1.09 xx 10^(-14) cm`
131.

Write the molecular formula of:(a) Sodium Sulphide(b) Magnesium oxide(c) Calcium hydroxide(d) Hydrogen chloride(e) Sulphuric acid(f) Iron(II) sulphide

Answer»
CompoundMolecular Formula
(a) Sodium SulphideNa2S
(b) Magnesium oxideMgO
(c) Calcium hydroxideCa(OH)2
(d) Hydrogen chlorideHCl
(e) Sulphuric acidH2SO4
(f) Iron(II) sulphideFeS

132.

Give the group number of following elements present in periodic table1. Magnesium 2. Carbon3. Sulphur 4. Neon

Answer»

1. Magnesium : IIA

2. Carbon : IVA

3. Sulphur : VIA

4. Neon : Zero

133.

The impact parameter at which the scattering angle is `90^(0) , z=79` and initial energy `10MeV` is

Answer» Correct Answer - C
Given ` theta =90^@,Z=79,e=1.6xx10^(-19)C`,
`E=(1)/(2)mv^2=10MeV=10xx10^6xx1.6xx10^(-19)J`.
`=1.6xx10^(-12)J`
`therefore b=(Ze^2cot(theta/2))/(4piepsilon_0(1/2mv^2))=(9xx10^9xx79xx(1.6xx10^(-19))^2cot45^@)/(1.6xx10^(-12))m`
`=9xx79xx1.6xx10^(-11)m=1137.6xx10^(-11)m`
`=1.1xx10^(-14)m=11fm`
134.

In the Angular process as atom makes a transition to a lower state without emitting a photon. The excess energy is transferred to an outer electron which may be ejected by the atom. (this is called an Augar elecrons ) . Assuming the nuclesu to be massive , calculate the kinetic energy of an `n=4` Augar electron emitted by chromium by absorbing the energy from a `n=2` to `n=1` transition .A. 4.6B. 7.5C. 5.38D. 3.36

Answer» Correct Answer - C
As the uncleus is massive, recoil momentum of the atom can be ignore. We can assume that the entire energy of tranition is transferred to the augar electron. As there is a single valence electron in chromium `(Z=24)` the energy states may be thought of as given by bohr model. the energy of the `n^th` stae is
`E_n=-(RchZ^2)/(n^2)` when R is hydberg constant.
In the transition form `n=2` to `n=1`, energy released ,
`DeltaE=-RhcZ^2((1)/(4)-1)=(3)/(4)RhcZ^2`
The energy rquired to eject ` n=4` electron
`=RhcZ^2((1)/4)^2=(RhcZ^2)/(16)`
`therefore` KE of augar electron `=(3RhcZ^2)/(4)-(RhcZ^2)/(16)`
`KE=RhcZ^2((3)/(4)-(1)/(16))=(11)/(16)RhcZ^2`
`(11)/(16)(13.6eV)xx24xx24=5385.6eV=5.38keV`
`[because Rhc=13.6eV]`
135.

When an electron makes transition from its stable orbit to another stable orbit of lower energy , where does the remaining energy go ?

Answer» In the form of Emission spectrum. (electromagnetic radiation)
136.

The relation between the orbit radius and the electron velocity for a dynamically stable orbit in a hydrogen atom is (where, all notations have their usual meanings)A. `v=sqrt((4piepsilon_0)/(me^2r))`B. `r=sqrt((e^2)/(4piepsilon_0v))`C. `v=sqrt((e^2)/(4piepsilon_0mr))`D. `r=sqrt((ve^2)/(4piepsilon_0m))`

Answer» Correct Answer - C
In hydrogen atom electrostatic force of attraction `(F_e)` between the revolving electrons and the nucleus provides the requisite centripetal force `(F_c)` to keep them in their orbits. Thus,
`F_e=F_(c) therefore (mv^2)/(r)=(1)/(4piepsilon_0)(e^2)/(r^2)`
or `v^2=(e^2)/(4piepsilon_0mr)rArrv=sqrt((e^2)/(4piepsilon_0mr))`
137.

In an atom the ratio of radius of orbit of electron to the radius of nucleus isA. `10^3`B. `10^4`C. `10^5`D. `10^6`

Answer» Correct Answer - C
The radius of orbit of electrons `=10^(-10)m` radius of nucleus `=10^(-15)m`
`therefore` Ratio `=10^(-10)/(10^(-15))=10^(5)`
Hence the radius of electron orbit is `10^(5)` times larger than the radius of nucleus.
138.

Energy of the beam of `alpha`-particles used by Geiger and Marsden in scattering experiment isA. 2.2 MeVB. 4.2 MeVC. 5.1 MeVD. 5.5 MeV

Answer» Correct Answer - D
139.

Given Rydberg constant as 1.097 × 10-7 m . Find the longest and shortest wavelength limit of Baler Series.

Answer»

\(\bar v=\frac{1}{λ}= R_H\Big[\frac{1}{n^2_1}-\frac{1}{n_2^2}\Big]\)

Longest wavelength n1 = 2 and n2 = 3

\(=\frac{1}{λ}= R_H\Big[\frac{1}{n^2_1}-\frac{1}{n_2^2}\Big]\) \(R_H\Big[\frac{1}{2^2}-\frac{1}{3^2}\Big]\)

λ = \(\frac{1}{R_H\Big[\frac{1}{2^2}-\frac{1}{3^3}\Big]}\) = 6563 A0

Shortest Wavelength n1 = 2 and n2 = α

\(=\frac{1}{λ}= R_H\Big[\frac{1}{n^2_1}-\frac{1}{n_2^2}\Big]\) = \(R_H\Big[\frac{1}{2^2}-\frac{1}{\alpha^2}\Big]\)

λ =\(\frac{1}{R_H\Big[\frac{1}{2^2}-\frac{1}{\alpha^2}\Big]}\) = \(\frac{1}{1.097\times10^7\Big(\frac{1}{4}\Big)}\)

= 3646 A0

140.

The energy of K-electron in tungsten is -20.0 keV and of an L-electron is -2.0 ke V. Find the wavelength of X-rays emitted when an electron jumps from L - shell to K-shell.

Answer» Correct Answer - 0.6875 Å
141.

Calculate the energy of the hydrogen atom in the states n = 4 and n = 2. Determine the frequency and wavelength of the emitted radiation in a transition from n = 4 to n=2 state. Is this radiation visible?

Answer» Correct Answer - `0.85 eV, 3.4 eV, 6.16 xx 10^(14) Hz, 4.87 xx 10^(-7)m`; yes
142.

The innermost orbit of the hydrogen atom has a diameter of `1.06Å` what is the Diameter of the tenth orbit:

Answer» Correct Answer - 106 Å
143.

In which transition of a hydrogen atom, photons of lowest frequency are emitted ?A. n=4 to n=3B. n=4 to n=2C. n=2 to n=1D. n=3 to n=1

Answer» Correct Answer - A
144.

the wavelength of radiation emitted is `lambda_0` when an electron jumps. From the third to second orbit of hydrogen atom. For the electron jumping from the fourth to the second orbit of the hydrogen atom, the wavelength of radiation emitted will beA. `(16//25)lambda_0`B. `(20//27)lambda_0`C. `(27//20)lambda_0`D. `(25//16)lambda_0`

Answer» Correct Answer - B
`(lambda)/(lambda_0)=([(1)/(2^2)-(1)/(3^2)])/([(1)/(2^2)-(1)/(4^2)])=(5)/(36)xx(16)/(3)=(20)/(27)`or `lambda=(20)/(27)lambda_0`
145.

The ground state energy of the hydrogen atom is -13.6eV. What are the kinetic and potential energies of the electron in this state?

Answer»

The potential energy (Ep) of the electron in an orbit is equal to twice its total
energy (E)
= -13.6 x 2 = -27.2eV
The kinetic energy (Ek) of the electron in an orbit is equal to negative of its total energy (E)
∴ Ek – E
= – (-13.6) = 13.6 eV.

146.

Find the Q - value for the nuclear reaction: `._(2)He^(4)+._(7)N^(14) rarr ._(8)O^(17)+._(1)H^(1)` `m(._(2)He^(4))=4.0039 "amu" m(._(7) N^(14))=14.0075 "amu" m(._(8)O^(17))=17.0045` amu `m(._(1)H^(1))=1.0082` amu

Answer» Correct Answer - `~ 1.21` MeV
147.

The binding energy of a hydrogen like atom in ground state is 217.6 eV. An electron having energy of 130 eV is incident on the atom. Then the energy of the electron emerging after interacting with this atom is(1) 217.6 eV(2) 87.6 eV (3) 130 eV (4) 347.6 eV

Answer»

Correct option : (3) 130 eV

Explanation : 

The electron undergoes an elastic collision with the concerned atom. Since 130 eV cannot raise the electron from ground state to the first excited state, the electron does not accept any energy from the electron. Hence the electron will emerge after interaction with the atom with 130 eV. 

148.

The velocity of an electron in the first orbit of H-atom is v. The velocity of an electron in the 2nd orbitA. 2 vB. vC. v/2D. v/4

Answer» Correct Answer - C
`vprop(Z)/(n)` since Z and n both have become twice, velocity of electron in second orbit of `H^(+)` will be v.
149.

X-rays of `lamda = 1Å` have frequencyA. `3xx10^(8)Hz`B. `3xx10^(18)Hz`C. `3xx10^(10)Hz`D. `3xx10^(15)Hz`

Answer» Correct Answer - B
150.

An X-ray has a wavelength of 0.010 Å. Its momentum isA. `2.126xx10^(-23) kg ms^(-1)`B. `6.626xx10^(-22) kg ms^(-1)`C. `3.456xx10^(-25) kg ms^(-1)`D. `3.313xx10^(-22) kg ms^(-1)`

Answer» Correct Answer - B
`p=(h)/(lambda)=(6.6xx10^(-34))/(0.01xx10^(-10))=6.626xx10^(-22)"kg ms"^(-1)`