InterviewSolution
This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 88701. |
A metal which has no effect on asolution of mercury chloride is : |
|
Answer» Zn |
|
| 88702. |
A metal weighing 0.43 g was dissolved in 50 mL of 1 N H_(2)SO_(4). The unreacted H_(2)SO_(4) required 14.2 mL of 1 N NaOH for neutralisation. Calculate the equivalent weight of the metal? |
|
Answer» Solution :`H_(2)SO_(4)" LEFT unreacted "-=NaOH" reacted= 14.2 mL of 1 N"` `therefore"1 N "H_(2)SO_(4)" reacted with the metal "=(50-14.2)mL=35.8mL` `"35.8 mL of 1 N "H_(2)SO_(4)="35.8 MILLIEQUIVALENTS"` If E is the EQUIVALENT wt. of the metal, milliequivalents of the metal reacted `"=(0.43)/(E)xx1000=(430)/(E)` As metal and the acid will react in equivalent amounts, `(430)/(E)=35.8 or E=(430)/(35.8)=12.01` |
|
| 88703. |
A metal surface ejects electrons when hit by blue light but not when hit by green light. When the electrons be ejected if the surface is hit by yellow light? |
|
Answer» Yes |
|
| 88704. |
A metal sulphide A gives gas B with rotten egg smell and a colourless sulphate C, when treated with dil H_2SO_4. B reacts with K_2Cr_2O_7//H^+ to form D, a white grey element. D burns in oxygen to yield E a colourless gas. If B is added to E, it gives D and a colourless liquid, which turns anhydrous CuSO_4 blue. C gives precipitate with NH_(3(aq)) or NaOH, which dissolves in excess of NaOH |
|
Answer» `CuSO_4` `H_2S + K_2Cr_2O_7 rarr underset((D))(S+Cr_2O_3)` `S+O_2 rarr underset((E)) SO_2` `H_2S + SO_2 rarr S + H_2O` `CuSO_4 + H_2O rarr underset((BLUE))(CuSO_4.) 5H_2O` `ZnSO_4 + NaOH rarr underset((white))(Zn(OH)_2darr) overset(NaOH) rarr underset("(SOLUBLE)")(Na_2ZnO_2)` |
|
| 88705. |
A metal sulphide (A) gives (B) gas with rotten egg and (C) a colourless sulphates, when treated with dil. H_(2)SO_(4) (B) reacts with K_(2)Cr_(2)O_(7)//H^(+) to form (D) a white grey element. (D) burns in oxygen to yield (E) a colourless gas. If (B) is added in (E), it gives (D) and colourless liquid, which turns anhydrous CuSO_(4) blue. (C) gives a precipitate with NH_(3(aq)) or NaOH which dissolves in excess of NaOH. E is |
|
Answer» `H_(2)S` |
|
| 88706. |
A metal sulphide (A) gives (B) gas with rotten egg and (C) a colourless sulphates, when treated with dil. H_(2)SO_(4) (B) reacts with K_(2)Cr_(2)O_(7)//H^(+) to form (D) a white grey element. (D) burns in oxygen to yield (E) a colourless gas. If (B) is added in (E), it gives (D) and colourless liquid, which turns anhydrous CuSO_(4) blue. (C) gives a precipitate with NH_(3(aq)) or NaOH which dissolves in excess of NaOH. C is |
|
Answer» `CuSO_(4)` |
|
| 88707. |
A metal sulphide (A) gives (B) gas with rotten egg and (C) a colourless sulphates, when treated with dil. H_(2)SO_(4) (B) reacts with K_(2)Cr_(2)O_(7)//H^(+) to form (D) a white grey element. (D) burns in oxygen to yield (E) a colourless gas. If (B) is added in (E), it gives (D) and colourless liquid, which turns anhydrous CuSO_(4) blue. (C) gives a precipitate with NH_(3(aq)) or NaOH which dissolves in excess of NaOH. B is |
| Answer» Solution :Due to formation of `H_(2)S` gas | |
| 88708. |
A metal solution when treated with dimethyl glyoxime and NH_(4) OH gives a rose red complex. The metal is |
| Answer» Answer :A | |
| 88709. |
A metal salt solution gives a yellow precipitate with silver nitrate.The precipitate dissolves in dilute nitric acid as well as in dilute ammonia solution.The solution contains : |
|
Answer» bromide ions `HPO_(4)^(2-) + 3Ag^(+) to Ag_(3)PO_(4) darr +H^(+)` `Ag_(3)PO_(4)+2H^(+)toH_(2)PO_(4)^(-) darr+3Ag^(+),Ag_(3)PO_(4)darr +6NH_(3) to 3[Ag(NH_(3))_(2)]^(+)+PO_(4)^(3-)` PALE yellow precipitate of `AgBr` is not soluble in dilute `HNO_(3)`,bright yellow precipitate of `Agl` is not soluble in both ,`Ag_(2)CrO_(4)` is obtained as red precipitate. |
|
| 88710. |
Ametal salt solutionforms a yellowprecipitatewith potassiumchromate in acetic acid , a whiteprecipitate with dil sulphuric acid butgives no precipitate with sodiumchloride oriodate .The whiteprecipitateabtained when sodium carbonate is added to the metal saltsolution consiste of |
|
Answer» LEAD carbonate |
|
| 88711. |
A metal rod dipped into a solution containing its own ions at unit activity at 298 K is called |
|
Answer» SINGLE electrode |
|
| 88712. |
A metal oxide is yellow when hot and white when cold. The metal oxide is |
|
Answer» ZnO |
|
| 88713. |
A metal present in insulin is |
|
Answer» aluminium |
|
| 88714. |
A metal oxide is reduced by heating it in a stream of hydrogen. It is found that after complete reduction, 3.15g of the oxide have yielded 1.05 g of the metal. We may deduce that |
|
Answer» The EQ. weight of the metal is 8. |
|
| 88715. |
A metal oxide is reduced by heating it in a stream of hydrogen it is found that after completereduction, 3.15 g of the oxide have yielded 1.05 g of the metal. We may conclude that: |
|
Answer» ATOMIC MASS of the METAL is 4 |
|
| 88716. |
A metal oxide has the formula X_(2)O_(3). It can be reduced by hydrogen to give free metal and water. 0.1596g of metal oxide requires 6 mg of hydrogen for complete reduction . The atomic mass of metal in amu is: |
|
Answer» 15.58 1MOL 3 MOL (2a+48)g 6g 0.006 g `H_(2)` is required by 0.1596 g oxide `THEREFORE 6g H_(2)` will be required by 159.6 g oxide `therefore 2a+48=159.6` a=55.8 |
|
| 88717. |
A metal oxide has the formula M_(2)O_(3). It can be reduced by H_(2) to free metal and water. 0.1596g of M_(2)O_(3) required 6 mg of H_(2) for complete reduction. The atomic mass of the metal is: |
|
Answer» 27.9 `(2x+48)G 6G` x=Atomic mass of METAL `because` 0.006 g `H_(2)` reduces 0.1596g `M_(2)_(3)`. `therefore 6g H_(2)` will reduce `(0.1596)/(0.006)xx6 g M_(2)O_(3)=159.6M_(2)O_(3)` `2x+48=159.6` `2x=11.6` `x=55.8`. |
|
| 88718. |
A metal oxide has 40% oxygen. Thepercentage of chlorine in its chloride is |
| Answer» SOLUTION :N/A | |
| 88719. |
A metal oxide has a formula Z_(2)O_(3). It can be reduced by hydrogen to give free metal and water. 0.01596g of the metal requires 6 mg of hydrogen for complete reduction. The atomic mass of the metal is |
|
Answer» 27.9 |
|
| 88720. |
A metal obtained by hydrometallurgy is : |
|
Answer» Ag |
|
| 88721. |
A metal object is to be coated with a nickel layer 0.3 mm thick. The surface areaof the object is 100 cm^2 . The density of nickel is 9.0 g//cm^3. How long will it take to pass a 3-amp current if the current yield is 90%? |
| Answer» SOLUTION :9 H 8 min 25 s | |
| 88722. |
A metal nitride on hydrolysis with steam gives |
|
Answer» `Cl_(2)` |
|
| 88723. |
A metal nitrate solution reacts with dilute hydrochloric acid to give a white precipitate which is soluble in concentrated potassium chloride.White precipitate on passing of hydrogen sulphide gas is converted into black precipitate.The black precipitate on boiling with hydrogen peroxide (3%) is converted again to a white precipitate which is soluble in ammonium acetate.The cation of the metal nitrate is : |
|
Answer» `Pb^(2+)` `PbCl_2darr +H_2StoPbSdarr`(black)+2HCl `PbS+4H_2O_2toPbSO_4`(white)+`4H_2O` `PbSO_4darr +2CH_3COONH_4to(NH_4)_2SO_4+(CH_3COO)_2Pb` |
|
| 88724. |
A metal nitrate reacts with KI to give a black precipitate which on addition of excess of Kl is converted into orange colour solution.The cation of the metal nitrate is : |
|
Answer» `HG^(2+)` |
|
| 88725. |
A metal nitrate reacts with KI to give a black precipitate which on addition of excess of KI is converted into orange colour solution. The cation of the metal nitrate is |
|
Answer» `Hg^(2+)` |
|
| 88726. |
A metal nitrate reacts with KI to give a black precipitate, which on addition of excess of KI converts to orange colour solution. The cation of metal nitrate is : |
|
Answer» `Hg^(2+) ` `BiI_3 + KI to underset("SOLUBLE")(K[BiI_4])` |
|
| 88727. |
A metalnitratereacts with Ki to give a balckprecipitatewhich on additionof excess of KIcovered to an orange colour solution .The cationof metalnitrate in |
|
Answer» `Hg^(2+)` `BiI_(3) +KI RARR underset("orange solution")(K[BiI_(4)])` |
|
| 88728. |
A metal nitrate reacts with KI to give a black precipitate which addition of excess of KI converts into orange colour solution. The cation of metal nitrate is: |
|
Answer» `Hg^(2+)` |
|
| 88729. |
A metal M which is not affected by strong acids like conc. HNO_(3), conc, H_(2)SO_(4) and conc. Solution of alkalies like NaOH, KOH. It formes MCl_3 which is used for toning in photography. The metal M is |
|
Answer» Ag |
|
| 88730. |
A metal M^(n+) having d^(4) valence electronic configuration combines with three bidentate ligands to form a complex compound. Assuming Delta_(0)gtP. (i) Write the electronic configuration of d^(4) ion. (ii) What type of hybridisation will M^(n+) ion has ? (iii) Name the type of isomerism exhibited by this complex. |
|
Answer» Solution :(i) `t_(2g)^(4)` (ii) `d^(2)sp^(3)` (one d-electron will pair up making two empty d-orbital available for hybridisation). (iii) Optical isomerism (SIMILAR to `[Co(EN)_(3)]^(3+)` or `[CR(o x)_(3)]^(3-)`. |
|
| 88731. |
A metal M with specific heat (0.16) have chlorine 68.3% then the formula of the compound is similar to |
|
Answer» MCl Equivalent mass of the metal `=("mass of metal")/("mass of chlorine") xx 35.5` `=31.7/68.3 xx 35.5 = 16.47` According to Dulong and Petit.s LAW, Approx, atomic mass of the metal `=6.4/(0.16) = 40` VALENCY `=("Approximation atomic mass")/("Equivalent mass") = 40/16.47 = 2.42 =2` Hence, the formula of the compound = `MCl_(2)` |
|
| 88732. |
A metal M which is not affected by strong acids like conc. HNO_3, conc. H_2SO_4 and conc. solution of alkalies like NaOH, KOH forms MCl_(3), which is used for toning inphotography, The metal M is : |
| Answer» Answer :C | |
| 88733. |
A metal M (specific heat 0.16) forms a metal chloride with a 65% chorine present in it. The formula of the metal chloride will be |
|
Answer» MCl Approx. at mass `XX` SP. HEAT = 6.4 (actually `6.4 +- 0.6`) `THEREFORE` At. Mass (approx) `=6.4/(0.16 = 40` Suppose, formula of the chloride `=MCl_(x)` `therefore` CHLORINE in it `=(35.5x xx 100)/(40 + 35.5 x)%` So, according to the question `(35.5x)/(40 + 35.5x) = 65/100 rArr 40/(35.5x) + 1= 100/65` `rArr 35.5 x = (40 xx 13)/7` `rArr x = 2.09 =2` `therefore` Formula of the metal chloride `=MCl_(2)` |
|
| 88734. |
A metal M readily forms water soluble sulphate MSO_(4), water insoluble hydroxide M(OH)_(2) and oxide MO which becomes inert on heating. The hydroxide is soluble in NaOH. The metal is : |
|
Answer» Be |
|
| 88735. |
A metal M reacts with N_(2) to give a compound 'A'(M_(3)N). 'A' on heating at high temperature gives back 'M' and 'A' on reacting with H_(2)O gives a gas 'B'.'B' turns CuSO_(4) solution blue on passing through it A and B can be |
|
Answer» `AL and NH_3` |
|
| 88736. |
A metal (M) produces a gas (N) on reaction with alkalies like NaOH and KOH. Same gas is produced when the metal reacts with dilute sulphuric acid. Gas (N) reacts with another toxic gas (P) to form methanol at high temperature and pressure . (N) also reacts with metals like (Q) to form electrovalent hydrides. M, N, P and Q respectively are |
|
Answer» `ZN, H_(2), CO, Na` |
|
| 88737. |
A metal "M" reacts with nitrogen gas to afford "M_3N". "M_3N" on heating at high temperature gives back "M" and on reaction with water produces gas "B". Gas "B" reacts with aqueous CuSO_4 to form deep blue compound. "M" and"B" are respectively...... |
|
Answer» Na and `NH_3` `2Li_(3)N to 6LiOH + 2NH_(3) overset(Cu^(2+)) to UNDERSET("DEEP blue")([Cu(NH_(3))_(4)]^(2+))` |
|
| 88738. |
A metal (M) produces a gas (N) on reactions with alkalies like NaOH and KOH. Same gas is produced when the metal reacts with dilute sulphuric acid. Gas (N) reacts with another toxic gas (P) to form methanol at high temperature and pressure. (N) also reacts with metals like (Q) to form electrovalent hydrides, M,N,P and Q respectivelyare |
|
Answer» <P>`Zn, H_(2), CO, Na` `Zn+H_(2)SO_(4)rarrZnSO_(4)+H_(2)` `underset((P))(CO)+2H_(2)overset(Delta,200atm)underset("catalyst")rarr CH_(3)OH` `underset((Q))(2Na)+H_(2)rarr 2NaH` |
|
| 88739. |
A metal M of molar mass 96 reacts with fluorine to form a salt that can be represeneted as MF_(x). In order to determiner x a 9.18 a sample of the salt is dissolved in 100g ofwater and its K_(b)(water 0.512 kg/mol. Assuming complete dissociation of salf. |
|
Answer» |
|
| 88740. |
A metal M of equivalent mass E forms an oxide of molecular formula M_(x)O_(y). The atomic mass of the metal is given by the correct equation: |
|
Answer» 2E(x/y) Mass of metal =`axx x` Mass of oxygen=`16xxy` EQUIVALENT mass of element`=("Mass of element")/("Mass of oxygen")XX8` `E=(ax)/(16y)xx8` `a=2E((y)/(x))` |
|
| 88741. |
A metal M of equivalent mass E forms an oxide of molecular formula M_(x)O_(y). The atomic mass of the metal is given by the correct equation |
|
Answer» `2E(y//X)` `therefore"8 g of oxygen will combine with metal"` `=(xm)/(16Y)XX8=(xm)/(2y)` ` therefore (xm)/(2y)=E"or"m=2E(y//x)` |
|
| 88742. |
A metal M of atomic mass 54.94 has a density of 7.42 g/cc. Calculate the apparent volume occupied by one atom of the metal. |
|
Answer» |
|
| 88743. |
A metal M of at. wt. 24 forms an oxide having 40% by wt. of O_2 .The probability formulae of oxide is |
|
Answer» `MO_2` |
|
| 88744. |
A metal 'M' is crystallised in F.C.C lattice. The number of unit cells in it having 2.4 xx 10^(24) atoms |
|
Answer» N |
|
| 88745. |
A metal M readily forms water soluble sulphate, and water insoluble hydroxide M(OH)_(2). Its oxide MO is amphoteric, hard and having high melting point. The alkaline earth metal M must be : |
| Answer» ANSWER :A | |
| 88746. |
A metal M forms chlorides in tis +2 and +4 oxidation state. Which of the following statement about these chlorides is correct? |
|
Answer» `MCl_(2)` more ionic than `MCL_(4)` |
|
| 88747. |
A metal ,M forms chlorides in its +2 and +4 oxidatio states . Which of the following statements about these chlorides is correct ? |
|
Answer» `MCl_(2)` is more volatile than `MCl_(4)` |
|
| 88748. |
A metal M forms chlorides in its +2 and +4 oxidation states. Which of the following statements about these chlorides is correct? |
|
Answer» `MCl_(2)` is more soluble is ANHYDROUS ETHANOL than `MCl_(4)` |
|
| 88749. |
A metal M forms an alum which contains the element potassium and is isomorphous with ordinary alum(K_2SO_4. Al_2(SO_4)_3 24H_2O) . If the alum of M contains 10.42% of M, then atomic weight of M is (at. mass of K= 39, O=16, S=32 and H=1): |
|
Answer» 52 `Al_2(SO_4)_3.24H_2O ` its FORMULA is `K_2SO_4`. `M_2(SO_4)_3 . 24 H_2O` Molecular weight = 894 + 2M Now ` (2M)/(894 + 2M) xx 100 = 10.42 ` SOLVING M = 52 |
|
| 88750. |
A metal (M) burns with dazzling brilliance in air to give a white powder.The white powder reacts with water to form a white precipitate and a colourless gas with a characteristic smell.The metal (M) decomposes hot water but not cold water, liberating the inflammable hydrogen gas. The metal (M) is: |
|
Answer» K `Mg+O_2toMgO , Mg+N_2toMg_3N_2` `Mg_3N_2+6H_2O to 3MG(OH)_2 + 2NH_3 uarr` `Mg+2H_2O("hot")toMg(OH)_2+H_2` |
|