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29751.

The incorrect statement regarding molecular orbital (s) is :

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If there is a nodal plane perpendicular to the intermoleculear axis and lying between the nuclei of bonded ATOMS then corresponding orbitals is antibonding M.O.
If a nodal plane lies in the inter-nuclear axis, then corresponing orbitals is (pi) bonding M.O.
The `sigma`- bonding MOLECULAR orbital does not contain nodal PLANES containing the internuclear axis
The `DELTA`-bonding molecular orbitals possesses three nodal planes containing the internuclear axis

Answer :D
29752.

The incorrect statement regarding froath floatation process is

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It is BASED on the DIFFERENCE in gravities of the ore
Uses Cresols as FROATH stabilizers
Uses of PINE OIL as frothing agent
Uses sodium ethyl xanthate,` C_2H_5OCS_2Na` as collector

Answer :A
29753.

The incorrect statement regarding chloral hydrate C Cl_(3)CH(OH)_(2) is :-

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It exhibits intramolecular hydrogen bonding
It has 9 LONE PAIR and 9 bond pair
It is stable inspite of COEXISTENCE of two-OH groups on a carbon atom
Compound is non-planar and polar

Answer :B
29754.

The incorrect statement regarding forth floatation process is

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It is BASED on the difference in gravities of ORE and gangue
Uses cresols as forth stabilizers
Uses PINE oil as forthing agent
Uses SODIUM ETHYL xanthate, `C_2H_5OCS_2` Na as collector

Answer :A
29755.

The incorrect statement is:

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The SECOND ionisation ENERGY of Se is greater than that of second ionisation energy of As
The FIRST ionisation energy of `C^(2+)` ion is greater than that of rist ionisation energy of `N^(2+)` ion
The THIRD ionisation energy of, F is greater than that of third ionisation energy of O
Helogens have highest I.E. in respectively period.

Solution :
29756.

The incorrect statement in the following is

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To ACCOMODATE messenger, shape of the receptor site CHANGES
The chemical messenger gives message to the cell by entering into the cell
Antagonists inhibit the natural function of receptor
The drugs that imitate the natural MESSENGERS are called agonists

Solution :No need to ENTER the cell
29757.

The incorrectstatement in respect of chromyl chloride test is

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formation of lead chromate
formation fo CHROMYL chloride
liberation of chlorine
formation of red vapours

Solution :Chromyl chloride test is used to confirm the presence of `Cl^(-)` in qualitative inorganic anaylis.
When a small amount of the substance (salt) is heated with conc. `H_(2)SO_(4)` in presence of `K_(2)Cr_(2)O_(7)`, deep red vapours of chromyl chloride are EVOLVED.
`NaCl+H_(2)SO_(4)toNaHSO_(4)+HCl`
`K_(2)Cr_(2)IO_(7)+2H_(2)SO_(4)to2KHSO_(4)+2CrO_(3)+H_(2)O`
`CrO_(3)+2HCl to underset("chromyl chloride")(CrO_(2)Cl_(2))+H_(2)O`
These vapours are passed through NaOH solution and yellow coloured solution of `Na_(2)CrO_(4)` is obtained.
`CrO_(2)Cl_(2)+4NaOHtounderset ("Yellow colour")(Na_(2)CrO_(4))+2NaCl+2H_(2)O`
This yellow solution is NEUTRALISED with acetic acid and on addition of lead acetate gives a yellow ppt. of lead chromate
`Na_(2)CrO_(4)+Pb(CH_(3)COO)_(2)tounderset("Yellow ppt.")(PbCrO_(4))+2CH_(3)COONa`
29758.

The incorrect statement for rhombic sulphur is

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It is INSOLUBLE in water
It exist as `S_8` molecules, which is puckered crown ring structure
It is white in colour
Its MELTING POINT is lower than monoclinic sulphur

Answer :C
29759.

The incorrect statement for the long form of the periodic table is

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it reflects the sequence of filling the electrons in the order of sub-energy leves s, p , d and f
it helps to predict the stable VALENCY STATES of the elements
it reflects TRENDS in physical and chemical properties of the elements
it helps to predict the relative ionic character of the bond between any two elements.

Solution :It does not help to predict the stable valency states of the elements.
29760.

The incorrect statement for aldehydes and ketones is

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Methanal, ethanal and propanone are MISCIBLE in water
All ALDEHYDES and ketones are fairly soluble in organic solvents like BENZENE, chloroform, etc.
Many NATURALLY occurring ALDEHYDE and ketones are used in the blending of perfumes
All aldehydes and ketones are fragrant

Answer :D
29761.

The incorrect statement for 14 g of CO is

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It OCCUPIES 2.24 litre at NTP
It corresponds to `1/2` mole of `CO`
It corresponds to same mole of `CO` and `N_(2)`
It corresponds to `3.01xx10^(23)` molecules of `CO`

Solution :14 G of `CO=14/28=0.5` mole
0.5 mole `=3.01xx10^(23)` molecules
The molecular WEIGHT of
`CO=(15+16)=28`
The molecular weight of
`N_(2)=14+14=28`
Therefore, the incorrect STATEMENT is that it occupies 2.24 litre at NTP.
29762.

The incorrect statement for 14 g CO is:

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It OCCUPIES 2.24L at NTP
It corresponds to `(1)/(2)` mole of CO
It corresponds to same mole of CO and `N_(2)`.
It corresponds to `3.01xx10^(23)` molecules of CO

Answer :A
29763.

The incorrect statement among the following is ________

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Reducing CHARACTER of hydrides of GROUP 15 INCREASES down the group
Basicity of hydrides of group 15 increases down the group
`NCl_(5)` does not exist
Phosphorus and arseniccan FORM `P pi - d pi` bond but not nitrogen

Answer :A::B::C::D
29764.

The INCORRECT statement among the following is ________.

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in calcination , ore decomposes to form metal oxide
zinconium is REFINED by van Arkel method
the sulphide ore galena is CONCENTRATED by froth floatation
in the metallurgy of IRON, the flux used is `SiO_(2)`

ANSWER :D
29765.

The incorrect statement among the following

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A CATALYST does not initiate the reaction 
The ACTION of catalyst in many instances is selective 
Catalyst MAY LOOSE its catalytic activity at high temperature 
The composition of catalyst changes at the end of reaction

Answer :D
29766.

The incorrect statement about the structure of H_2O_2 is

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It is non-linear and non-planar molecule
It has an OPEN BOOK TYPE structure
Dihedral angle in both gas PHASE and solid phase is 111.5deg
Dihedral angle in gas phase is 111.5deg and in solid phase is 90.2deg

Answer :C
29767.

The incorrect statement about interstitial compounds is :

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They are CHEMICALLY reactive.
They are very hard.
They RETAIN metallic conductivity.
They have HIGH MELTING point.

ANSWER :A
29768.

The incorrect statement about LDP is :

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It is obtained through the free RADICAL ADDITION of ethene .
It consists of liner MOLECULES .
It is obtained by the H-atom abstraction
Peroxide is used as an initialtor.

ANSWER :B
29769.

The incorrect set of the formal charge on different atoms in the Lewis structure of N_(3) are :

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`-1, +1, -1`
`-1, +1, 0`
`-2, +1, 0`
`0, +1, -2`

SOLUTION :In case of `N_(3)^(-)`
formal CHARGE can not be `-1, +1, 0`, because total charge BECOMES ZERO.
29770.

The correct order of the thermal stability of hydrogen halides (H-X) is

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`HI GT HBR gt HCl gt HF`
`HF gt HCl gt HBr gt HI`
`HCl gt HF gt HBr gt HI`
`HI gt HCl gt HF gt HBr`

ANSWER :B
29771.

The Incorrect order of property of the following is : (a) (Basic nature) Na_(2)O gt MgO gt Al_(2)O_(3)gt SiO_(2) (b) (2^(nd)I.P.)Na gt S gt P gt Si (c ) (Electron affinity) O gt S gt Se (d) (Size l^(-) lt l lt l^(+)

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a, C, d
B, c, d
c, d
a, b, c

Solution :`[H^(+)]_(HCl)=10^(-5)xx(1)/(1000)=10^(-8)`
`THEREFORE 10^(-7)M H^(+)` (of water) cannot be neglected
`[H^(+)]_("total")=10^(-8)+10^(-7)=1.1xx10^(-7)`
`pH=7-log 1.1 ~~ 6.98`
29772.

The incorrect order of lattice energy is :

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`AlF_(3) gt MgF_(2)`
`Li_(3)N gt Li_(2)O`
`NaCl gt LIF`
`TiC gt SCN`

Answer :C
29773.

The incorrect order of first ionization energy is:

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`Au gt Cu gt Ag`
`PT gt NI gt Pd`
`C gt Pb gt SN`
`B gt Ga gt Al`

Answer :B
29774.

The incorrect order of acidic strength is (DCE 2009)

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`HI gt HBr gt HCl`
`HIO_(4) gt HBrO_(4) gt HClO_(4)`
`HClO_(4) gt HClO_(3) gt HClO_(2)`
`HFgt H_(2)O gt NH_(3)`

Solution :The acidic strength of oxy0acids decreases DOWNWARDS in a group.
The correct order of acidic strength of oxyacids of HALOGENS is `HClO_(4) gt HBrO_(4) gt HIO_(4)`.
29775.

The incorrect order of bond angle :-

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`CO_(2) gt CO_(3)^(2-) gt CF_(2)Cl_(2)`
`NO_(2)^(+) gt NO_(3)^(-) gt NO_(2)^(-)`
`XeF_(2) gt XeO_(3) gt XeO_(4)`
`PH_(3) gt AsH_(3) gt SbH_(3)`

ANSWER :C
29776.

The incorrect order is:

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`N gt P gt As`: strength of `pi`-bond with oxygen atom
`SiF_(4) gt SiCl_(4) gt SiBr_(4) gt SiI_(4)`: Thermal stability
`H_(2)S gt H_(2)Se gt H_(2)TE`: Arrhenious acid character
`CaBr_(2) gt MgBr_(2) gt BeBr_(2)` Melting point

Solution :Correct ORDER of Arrhenious acid character
`H_(2)S LT H_(2)Se lt H_(2) Te`
the vlaue of `K_(a)` is maximum for `H_(2)Te`, due to least bond enegy among givenn hydrides.
29777.

The incorrect order is :

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Covalent character : `PbCl_(2)gtCaCl_(2)gtSrCl_(2)gtBaCl_(2)`
Thermal stability : `PbF_(4)gtPbCl_(4)gtPbBr_(4)gtPbI_(4)`
Melting point : `KFgtKClgtKBrgtKI`
BOILING point : `CHCl_(3)gtCH_(3)ClgtC Cl_(4)`

Answer :D
29778.

The incorrect order indicated against the rate of reaction , aA+bBoverset(h) to C then

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`-(d[A])/(DT)=a/b xx (d[B])/(dt) `
`-(d[A])/(dt)=b/a xx (d[B])/(dt) `
`-(d[A])/(dt)=-1/2(d[B])/(dt)=+(d[C])/(dt)`
`-(d[A])/(dt)= -b/a xx (d[B])/( dt)=- b/a xx (d[B])/(dt)`

SOLUTION :According to the EXPRESSION `- (1)/(a) xx (d[A])/(dt) = - (1)/(b) (d[B])/(dt) therefore -(d[A])/(dt) = - (a)/(b) (d[B])/(dt)`
29779.

The incorrect IUPAC name of a compounds is 3,3-diethyl butane. The correct name is :

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3,3-Dimethyl haxzne
1,1-Diethylmethyl pentane
3-Ethyl-3-methylpentane
3-Ethymethypentane.

Solution :`{:(""OVERSET(2)CH_(2)overset(1)(CH_(3))),(H_(3)overset(1)-H_(2)overset2(C)-""^(3)C-CH_(3)),(""overset(4)(CH_(2))overset(5)(CH_(3))):}`
3-Ethyl-3-methylpentane
29780.

The incorrect expression among the following is -

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In isothermal process, `w_("reversible")=-NRT"ln"V_(f)/V_(i)`
`lnK=(DeltaH^(@)-TDELTAS^(@))/(RT)`
`K=e^(-DeltaG^(@)//RT)`
`(DeltaG_("SYSTEM"))/(DeltaS_("total"))=-T`

ANSWER :B
29781.

The incorrect example is

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Keratin and Myosin - FIBROUS PROTEINS
Insulin and Albumin- Globular proteins
GLYCYLALANINE - Dipeptide
HAEMOGLOBIN - Derived protein

Solution :Haemoglobin - Derived protein
29782.

The incorrect combination is

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I,III,R
II,III,S
IV,I,R
IV,I,P

Answer :C
29783.

The incorrect among the following is:

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The FIRST IONIZATION potential of Al is less than the first ionization potential of Mg
The second ionizaztion potential of Mg is GREATER than the second ionization potential of Na
The first ionization potential of Na is less than the first ionization potential of Mg
The THIRD ionization potential of Mg is greater than the third ionization potential of Al

Answer :B
29784.

The impurties associated with minerals used in metallurgy are collectively called

Answer»

Slag
Flux
Gangue
Ore

Answer :C
29785.

The impurity of which element is present in Ruby and Sapphire respectively.

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Cd, Cr <BR>Cr, Cd 
Sr, Br 
NI, CU 

Answer :B
29786.

The impurity of sulphur makes the iron:

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FIBROUS
RED short
Cold short
Malleable

Answer :B
29787.

The impurities like As_(2)O_3 result in the poisoning of catalyst. In contact process, the impurities of arsenic are removed by

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gelantinuous `FE(OH)_(3)`
`Al(OH)_(3)`
`CR(OH)_(3)`
`Fe_(2)O_(3)`

ANSWER :A
29788.

The impurities associated with ores is……

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Flux
Slag
Gangue
Metal

Answer :C
29789.

The impurities associated with minerals are called :

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SLAG
Flux
Gangue
ORE.

ANSWER :C
29790.

The important use of Kohlrausch's law is deducing the

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`lambda_(INFTY)` value of weak ELECTROLYTE.
`lambda_(infty)` value of strong electrolyte.
`lambda_(C)` value of weak electrolyte.
`lambda_(C)` value of weak electrolyte.

Answer :A
29791.

The important step in Cannizzaro.s reaction is the intermolecular shift of:

Answer»

Proton
H-atom
Hydride ion
Hydronium ion

Answer :C
29792.

The important ore of iron is :

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Siderite
Haematite
Pyrites
Bauxite

Answer :B
29793.

The important monosaccharides are :

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Aldoses
Ketoses
Aldoses and ketoses
None

Answer :C
29794.

The important method for the fixation of nitrogen is

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HABER
Solvay
Deacon
Fischer method

Solution :Haber's PROCESS `to` industrial process
`N_(2)3H_(2) overset(Fe-Mo)UNDERSET({:(650-800K),("200-350 atm"):})HARR 2NH_(3)`
29795.

The important features of genetic code are a) It is universal b) It is commaless c) It is not degenerate d) Third base is not always specific.

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a only
b, C only
b, c and d only
a, BAND d only

Answer :D
29796.

The important component in our cell membrane is

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RETINOL
PHENOL
CHOLESTEROL
METHANOL

SOLUTION :Cholesterol
29797.

The important by product in the purification of bauxite by Serpeck's process is

Answer»

HCI
`N_(2)`
`NH_(3)`
`NO_(2)`

Answer :C
29798.

The imperfection in crystal increases with increases in temperature.

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If both Statement- I and Statement- II are true, and Statement - II is the correctexplanation of Statement– I.
If both Statement - I and Statement - II are true but Statement - II is not thecorrect EXPLANATION of Statement – I.
If Statement - I is true but Statement - II is FALSE.
If Statement - I is false but Statement - II is true.

ANSWER :A
29799.

The important advantage(s) of Lintz and Donawitz (L.D.) process for the manufacture of steel is (are)

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The PROCESS is very quick
Operation costs are low
Better quality steel is obtained
Scrap IRON can be used

Answer :A::C::D
29800.

The immiscible liquid system aniline-water boils at 98^@Cunder a pressure of760 mm. At this temperature the vapour pressure of water is 707 mm. If this system is distilled in steam, what fraction of total weight of the distillate will be aniline?

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ANSWER :0.28