Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

Boyle's law may be expressed as (one or more)

Answer»

<P>`(dP//dV)_(T)=K//V`
`(dP//dV)_(T)=-K//V^(2)`
`(dP//dV)_(T)=-K//V`
`V prop (1)/(p)`.

Solution :ACCORDING to Boyle's LAW, PV=K at constant T.
`:.` Ratio of mean SQUARE VELOCITIES, viz,
`:. "" P=K//V`
or`"" (dP//dV)=-K//V^(2)`.
Also `"" V prop 1//P`.
2.

Boyle's law for a gas of constant mass, may be expressed as

Answer»

<P>`((DP)/(dV))_(T) = K/V`
`((dP)/(dV))_(T) = -K/(V^2)`
`((dP)/(dV))_T = K/V`
`V ALPHA 1/P` at CONSTANT T

Solution :`PV = NRT, P = (nRT)/(V) , ((dP)/(dV))_(T) = (-nRT)/(V^2) = (-K)/(V^2)` .
3.

Boyle temperature of vaiour gases are given below : {:("Gas",T_(B)(K),),(H_(2),117,),(He,23,),(CH_(4),498,),(O_(2),406,):} Which gas can be liquefied most easily ?

Answer»

`H_(2)`
`CH_(4)`
`He`
`O_(2)`

SOLUTION :Boiling point, `T_(b) = (2)/(3) T_(C)` (Guldberg's rule)
`= (2)/(3) ((8a)/(27 RB)) = (16)/(81) (a)/(Rb) = (16)/(81) T_(B)`
Here `T_(B)` is Bolye temperature
Thus, more the `T_(B)` more is the b.pt and hence easy to liquify
4.

Boyle, Charle.s Law indicates ?

Answer»

SOLUTION :This LAWS indicate that system of GAS working in proper WAY for example pressure is increases when compressiblity of gas.
5.

Boverset(alc.KOH)larrC_(2)H_(5)Clunderset(C_(2)H_(5)OH)overset(Zn-Cu)rarrA Here compounds A and B are

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`CH_(4),C_(2)H_(4)`
`C_(2)H_(4),C_(2)H_(6)`
`C_(2)H_(6),C_(2)H_(4)`
`C_(2)H_(6),CH_(4)`

Answer :C
6.

Bouveault-Blanc reduction reaction involves :

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Reduction of an anhydride with `LiAlH_(4)`
Reduction of an ester with `Na//C_(2)H_(5)OH`
Reduction of a CARBONYL compound with `Na//Hg` and HCl
Reduction of an acyl HALIDE with `H_(2)//Pd`.

ANSWER :B
7.

Both temporary annd permanent hardness can be removed by using

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`CA(OH)_(2)`
`Na_(2)CO_(3)`
NaCl
`Mg(OH)_(2)`

ANSWER :B
8.

Both temporary and permanent hardness can be removed by using

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`Ca(OH)_2`
`Na_2CO_3`
`NACL`
`NAOH`

Answer :B
9.

Both temperary and permanent hardness are removed on boiling water with:

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`CA(OH)_(2)`
`NaCO_(3)`
`CaCO_(3)`
CaO.

Answer :a
10.

Both temperary ad permanent hardness in water are removed by:

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BOILING
filtration
distillation
decantation.

Answer :C
11.

Both methane and ethane may be obtained by suitable one step reaction from

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METHYL iodide
Ethyl iodide
Methyl alcohol
Ethyl alcohol

Answer :A
12.

Both lithium and magnesium displays several similar properties due to the diagonal relationship , however , the one which is incorrect is ,

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both form nitrides
NITRATES of both LI and Mg yield `NO_(2)` and `O_(2)` on heating
both form basic carbonates
both form SOLUBLE BICARBONATES

Solution :Li does not form basic carbonates but Mg does such as 3 Mg `CO_(3).Mg(OH)_(2). 3 H_(2)O` .
13.

Both lithium and magnesium display several similar properties due to the diagonal relationships, however, the one which is incorrect, is:

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both form NITRIDES
nitrates of both Li and Mg yield `NO_2 and O_2` on heating
both form BASIC carbonates
both form SOLUBLE BICARBONATES

Solution :both form basic carbonates
14.

Both lithium and magnesium display several similar properties due to the diagonal relationship, however the one which is incorrect is ......

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both form basic carbonates.
both form soluble bicarbonates.
both form nitrides.
nitrates of both LI and MG yield`NO_(2)` and `O_(2)`on HEATING.

SOLUTION :Carbonate of Mg is basic, but carbonate of Li does not have basic CHARACTERISTICS.
15.

Both Cr_(2)O_(7)^(2-) (aq) and MnO_(4)^(-) (aq) can be used ot titrate Fe^(2+)(aq) if in a given titration 24-50 cm^(3)0.1 M Cr_(2)O_(7)^(2-) were used then what volume of 0.1 M MnO_(4)^(-) solution would have been use for the same titration ?

Answer»


Solution :The balaced redox reaction involving oxidation f `Fe^(2+)` ions by `Cr_(2)O_(7)^(2-) "and" MnO_(4)^(-)` respectively are
`Cr_(2)O_(7)^(2-)+6Fe^(2+)14H^(+)rarr2Cr^(3+)+6Fe^(3)+7H_(2)O`
`MnO_(4)^(-)+5Fe^(2+)+8H^(+)rarrMn^(23+)+5Fe^(3+)+4H_(2)O`
Suppose `V_(2) cm^(3)"of"M_(2)F^(2+)` is titreated against 24.50 `cm^(3)` of 0.1 M `Cr_(2)O_(7)^(2-) "and" V_(1)cm^(3) of 0.1 M MnO_(4)^(-)`
solution then
`(24.5xx0.1)/(1)(Cr_(2)O_(7)^(2-))=(M_(2)B_(2))/(6)(Fe^(2+))`
`(V_(1)xx0.1)/(1)(MnO_(4)^(-))=(M_(2)V_(2))/(5)(Fe^(2+))`
Equating (i) and (II) `V_(1)=2.45xx6/5=29.4 cm^(3)`
16.

Both C_(2)H_(2) and CO_(3) have the same structure . Explain why.

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Solution :`H-C -= C-H` and O=C=O Both has, Linear - Molecular GEOMETRY
Zero -DIPOLE moment
sp- Hybridization of C in `C_(2)H_(2)` and `CO_(2)` Hence `C_(2)H_(2)` and `CO_(2)` have the same structure.
17.

Both C CI_4 and SiCI_4 has stable octets of the central atoms, but SiCl_4, is acidic. Why?

Answer»

Solution :`C CI_4` is saturated. The central atom carbon has no VACANT d-orbitals in its valence SHELL. `SiCl_4` is a Lewis ACID. The central atom silicon has empty d-orbitals in the VALENCY shell and excitation is easy. It ACTS as Lewis acid, by expanding its octet configuration.
18.

Both C_(2)H_(2) and CO_(2)have the same structure. Explain why.

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Solution :`{:("Molecule","concept","GEOMETRY"),(C_(2)H_(2),"Hybridisation (SQ)","LINEAR"),(CO_(2),"VSEPR"(AB_(2)),"Linear"):}`
19.

Both Be and Al become passive on reaction with concentrated. nitric acid due to

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The non-reactive nature of the metal
The non-reactive nature of the acid
The formation of an INERT layer of OXIDE on the SURFACE of the metals
Formation of active layer of oxide on the surface of metals

Answer :C
20.

Both Be and Al metals shows ...... properties.

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Acidic
Basic
Neutral
Amphoteric

Answer :D
21.

Both alkali metals and alkaline earth metals are s - block elements. They resemble each other respect but still there are certain dismilariaties in their properties due to number of eletrons in the valence shell different atomic radii, ionisation enthalpy, electronegativity etc. Which of the following statements are true for group ? electrons ?

Answer»

Lattice ENTHALPY of OXIDES, CARBONATES, fluorides from Be to Ba
All form nitrides in air
The solubility of the HYDROXIDES increase from Be to Ba
All are CORRECT

Solution :All are correct
22.

Both alkali metals and alkaline earth metals are s - block elements. They resemble each other respect but still there are certain dismilariaties in their properties due to number of eletrons in the valence shell different atomic radii, ionisation enthalpy, electronegativity etc. The correct sequence of increasing covalent character is

Answer»

`BeCI_(2)ltNaCIltLiCI`
`NaCIltLiCIltBeCI_(2)`
`BeCI_(2)ltLiCIltNaCI`
`LiCIltNaCIltBeCI_(2)`

SOLUTION :As POLARISING power incrases covalent character INCREASES
23.

Both alkali metals and alkaline earth metals are s - block elements. They resemble each other respect but still there are certain dismilariaties in their properties due to number of eletrons in the valence shell different atomic radii, ionisation enthalpy, electronegativity etc. Which is least thermally stable ?

Answer»

`LiCO_(3)`
`MgCO_(3)`
`BaCO_(3)`
`BeCO_(3)`

Solution :THERMAL STABILITY increases from `BeCO_(3)` to `BaCO_(3)`
24.

Both alcohols and phenols contain a hydroxyl group, but phenols are more acidic than alcohols. The reason being that the phenoxide ion left after the removal of a proton is resonance stabilized while alkoxide is not. Therefore, phenols dissolve in aqueous sodium hydroxide but alcohols do not. However, both are weaker acids than carbonic acid and hence do not decompose aqueous NaHCO_(3) solution evolving CO_(2). The presence of electron-donating groups in the benzene ring decrease the acid strength while the presence of electron withdrawing groups in the benzene ring increase the acid strength of phenols. The relative strength of o-, m- and p- substituted phenols, however, depends upon a combination of inductive and resonance effects of the substituent. Alcohols are very weak acids even weaker than water. Because of the +I effect of the alkyl groups, tha acidic strength of alcohols decreases in the order : 1^(@) alcohol gt 2^(@) alcohol gt 3^(@) alcohol. The strongest acid among the following is

Answer»

o-Methoxy phenol
p-Methoxy phenol
m-Methoxy phenol
Phenol

Answer :C
25.

Both alcohols and phenols contain a hydroxyl group, but phenols are more acidic than alcohols. The reason being that the phenoxide ion left after the removal of a proton is resonance stabilized while alkoxide is not. Therefore, phenols dissolve in aqueous sodium hydroxide but alcohols do not. However, both are weaker acids than carbonic acid and hence do not decompose aqueous NaHCO_(3) solution evolving CO_(2). The presence of electron-donating groups in the benzene ring decrease the acid strength while the presence of electron withdrawing groups in the benzene ring increase the acid strength of phenols. The relative strength of o-, m- and p- substituted phenols, however, depends upon a combination of inductive and resonance effects of the substituent. Alcohols are very weak acids even weaker than water. Because of the +I effect of the alkyl groups, tha acidic strength of alcohols decreases in the order : 1^(@) alcohol gt 2^(@) alcohol gt 3^(@) alcohol. The acidic strength decreases in the order

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p-Nitrophenol `GT` m-Nitrophenol`gt` o-Nitrophenol
p-Nitrophenol `gt` o-Nitrophenol`gt` m-Nitrophenol
m-Nitrophenol `gt` o-Nitrophenol`gt` p-Nitrophenol
o-Nitrophenol `gt` m-Nitrophenol`gt` p-Nitrophenol

ANSWER :B
26.

Both alcohols and phenols contain a hydroxyl group, but phenols are more acidic than alcohols. The reason being that the phenoxide ion left after the removal of a proton is resonance stabilized while alkoxide is not. Therefore, phenols dissolve in aqueous sodium hydroxide but alcohols do not. However, both are weaker acids than carbonic acid and hence do not decompose aqueous NaHCO_(3) solution evolving CO_(2). The presence of electron-donating groups in the benzene ring decrease the acid strength while the presence of electron withdrawing groups in the benzene ring increase the acid strength of phenols. The relative strength of o-, m- and p- substituted phenols, however, depends upon a combination of inductive and resonance effects of the substituent. Alcohols are very weak acids even weaker than water. Because of the +I effect of the alkyl groups, tha acidic strength of alcohols decreases in the order : 1^(@) alcohol gt 2^(@) alcohol gt 3^(@) alcohol. Which of the following is the strongest acid

Answer»

`FCH_(2)CH_(2)CH_(2)OH`
`FCH_(2)CH_(2)CH_(2)OH`
`CH_(3)CH_(2)CHFCH_(2)OH`
`CH_(3)CH_(2)CF_(2)CH_(2)OH`

Answer :D
27.

Both alcohols and phenols contain a hydroxyl group, but phenols are more acidic than alcohols. The reason being that the phenoxide ion left after the removal of a proton is resonance stabilized while alkoxide is not. Therefore, phenols dissolve in aqueous sodium hydroxide but alcohols do not. However, both are weaker acids than carbonic acid and hence do not decompose aqueous NaHCO_(3) solution evolving CO_(2). The presence of electron-donating groups in the benzene ring decrease the acid strength while the presence of electron withdrawing groups in the benzene ring increase the acid strength of phenols. The relative strength of o-, m- and p- substituted phenols, however, depends upon a combination of inductive and resonance effects of the substituent. Alcohols are very weak acids even weaker than water. Because of the +I effect of the alkyl groups, tha acidic strength of alcohols decreases in the order : 1^(@) alcohol gt 2^(@) alcohol gt 3^(@) alcohol. The correct order of reactivity of 1^(@), 2^(@) and 3^(2) alcohols towards sodium metal is

Answer»

`1^(@) GT 2^(@) gt 3^(@)`
`1^(@) gt 3^(@) gt 2^(@)`
`3^(@) gt 2^(@) gt 1^(@)`
`2 gt 1^(@) gt 3^(@)`

ANSWER :A
28.

Boron trihalides act as Lewis acids. Their Lewis acid strength is in the order

Answer»

`BF_3 GT BCl_3 gt B Br_3`
`BF_3 gt B Br_3 gt BCl_3`
`B Br_3 gt BCl_3 gt BF_3`
`BCl_3 gt B Br_3 gt BF_3`

SOLUTION :`B Br_3 gt BCl_3 gt BF_3`
29.

Boron tribromide is a stronger acid than boron trifuoride. Assign reason.

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Solution :Both of them are LEWIS acids but becaue of `p pi-p pi` BACK BONDING the elecron density on boron atom INCREASE and the Lewis acid strength of the halides . Now, 2p orbitals of boron and fluorine that are involed in back b onding have comparable energies. while p orbtials of boron and 4p orbtials of bromine differ LARGELY in energy and the b ack bonding is not so efficient. therefore, `BBr_(3)` is a stronger acid than `BF_(3)`.
30.

Boron, the first member of group 13 (p-block) is a typical non-metal. H exists in two allotropic forms. The compounds of boron are mainly electron deficient as well as Lewis acids. For example, all the trihalides of boron (BX_(3)) are Lewis acids. The expected order of acidic strength based on the electro negativity of halogen atoms is : BF_(3)gtBC l_(3)gtBBr_(3)gtBl_(3). But theactual order is the reverse. This is explained with the help of the concept of back bonding (p pi- p pi) . Among the hydrides of boron. diborane has a bridged structure. The two types of bonds in diboran e are covalent and q

Answer»

IONIC
Co-ordinate
Bridged
None of them is CORRECT.

SOLUTION :is the correct ASNWER.
31.

Boron reacts with oxygen at 700^(@)C to give (A). Compound (A) reacts with carbon and dry chlorine to give (B) an carbon monoxide. (B) on reduction with LiAlH_(4) gives (C ) along with LiCl and AlCl_(3). (C ) on reaction with ammonia at 200^(@)C gives (D).Compound (D) has B in ________ hybridised state

Answer»

SP
`sp^2`
`sp^3`
`dsp^2`

SOLUTION :`4BCl_(3) +3LiAlH_(4)rarrunderset((C))(2B_2H_6)+3LiCl+3AlCl_3`
32.

Boron reacts with oxygen at 700^(@)C to give (A). Compound (A) reacts with carbon and dry chlorine to give (B) an carbon monoxide. (B) on reduction with LiAlH_(4) gives (C ) along with LiCl and AlCl_(3). (C ) on reaction with ammonia at 200^(@)C gives (D).Compound (C ) is

Answer»

an ELECTRON - deficient compound
cation (3c, 2e) bond
has ethane LIKE structure
an ionic compound

Solution :`4BCl_(3) +3LiAlH_(4)rarrunderset((C))(2B_2H_6)+3LiCl+3AlCl_3`
33.

Boron reacts with oxygen at 700^(@)C to give (A). Compound (A) reacts with carbon and dry chlorine to give (B) an carbon monoxide. (B) on reduction with LiAlH_(4) gives (C ) along with LiCl and AlCl_(3). (C ) on reaction with ammonia at 200^(@)C gives (D).In compound (B) :

Answer»

Boron is `sp^2`hybridised
B is TRIANGULAR planar molecule
It is a Lewis base
DIMER

Solution :`4B +3O_(2)OVERSET(700^@C)rarr underset((A))(2B_(2)O_3)`
`B_(2)O_3+3C+3Cl_(2) rarrunderset((B))(2BCl_3)+3CO`
34.

Boron occurs in nature in the form of two isotopes having atomic masses 10 and 11. What are the percentage abundances of these isotopes in a simple a boron having average atomic mass of 10.8are :

Answer»

20,80
80,20
50,50
40,60

Solution :LET the percentage abundance of B-10 isotope=X
`:.` The percentage abundance of B-11 isotope = (100-x)
From the available data :
`(x xx10)/(100)+((100-x)xx11)/(100)=10.8`
or `10X + 1100 - 11X = 1080or x = 20`
Percentage abundance of B-10 isotope = 20 %
Percentage abundance of B-11 isotope = 80 %.
35.

Boron occurs in nature in the form of two isotopes having atomic masses 10 and 11. What are the percentage abundances of these isotopes in a simple a boron having average atomic mass of 10.8 ?

Answer»


Solution :Let the PERCENTAGE abundance of B-10 ISOTOPE=X
`:.` The percentage abundance of B-11 isotope = (100-x)
From the available DATA :
`(x xx10)/(100)+((100-x)xx11)/(100)=10.8`
or `10x + 1100 - 11x = 1080or x = 20`
Percentage abundance of B - 10 isotope = 20 %
Percentage abundance of B - 11 isotope = 80 %.
36.

Boron nitride which is isoclectronic and isostructural with graphite is mode of fused hexagonal rings made of boron and nitrogen atoms alternatively. The number of pi bonds in each hexagonal ring is

Answer»


ANSWER :2
37.

Boron is unable to form BF_6^(3-)ion. Explain.

Answer»

Solution :Due to non-availability of d-orbitals, boron is UNABLE to expand its OCTET. Therefore, the maximum COVALENCE of boron cannot EXCEED 4.
38.

Boron is unable to formBF_(6)^(3-)ion. Explain.

Answer»

Solution :Due to absence of d-orbitals, B at the maximumcan ammoundates 8 electrons pairs of electrons inits valencesshell. In otherwords, B can have a maximum convalency of 4. Therefore, `BF_(3)` can FORM`BF_(2)` but never `BF_(6)^(3-)`in whichthe COVALENCY of B is 6.
39.

Boron is used in glass industry for making specific type of glass.

Answer»


ANSWER :1
40.

Boron is a

Answer»

metal
non-metal
semi-metal
metalloid

Solution :semi-metal
41.

Why do boron halides form addition compounds with ammonia ?

Answer»

Solution :Boron halides act as Lewis acids and are capable of ACCEPTING a pair of ELECTRONS from AMINES (which act as Lewis BASES) to form addition compounds.
42.

Boron forms only "………….." compoundswhile aluminium forms both "………….." and "………….."compounds.

Answer»


ANSWER :COVALENT, covalent and IONIC
43.

Boron fluoride exists as BF_(3) but boron hydride does't exist as BH_(3). Give reason. In which form does it exist ? Explain its structure.

Answer»

Solution :Due to `p pi - p pi` back bonding, the LONE pair of electrons of F is donated to the B-atom. Thus delocalisation reduces the deficiency of electrons of B thereby incresing the stability of `BF_(3)` molecule

Due to absence of lone pair of electrons on H-atom, this compensation does not occur in `BH_(3)`. In other WORDS electron deficiency of B stays and hence to reduce its electron deficiency, `BH_(3)` dimerises, `BH_(3)` dimerises to form `B_(2)H_(6)`
In `B_(2)H_(6)`, FOUR terminal hydrogen atoms and two boron atoms lie in one PLANE. Above and below this plane there are two BRIDGING H-atoms. The four terminal B-H bonds are regular while the two bridge (B-H-B) bonds are three centre-two electron bonds.
44.

Boron fluoride exists as BF_3 but boron hydride doesn't exist as BF_3. Give reason. In which form, does it exist ? Explain its structure.

Answer»

SOLUTION :In `BF_3`, lone pair of fluorine gives back support of electrons to boron atom by `ppi-ppi` back bonding. This delocalization of electrons reduces the DEFICIENCY of electrons and THUS reduces Lewis acidic character and increases stability of `BF_3`.
In `BH_3`, there is no lone pair of electrons on H atom, therefore, `BH_3` dimerizes to give `B_2H_6`. 4 terminal H atoms and 2 boron atoms lie in one plane and above and below the plane. So there are TWO bridging H-atoms.
45.

Boron fibres are used in making light composite material for aircraft.

Answer»

SOLUTION :TRUE STATEMENT
46.

Boron exist in different allotropic forms .All allotropic fropm contains icosahedral units (icosahedral is a regular shape with 12 corners and 20 faces ) with boron atoms at all 12 corners and all bonds are equivalent . Calculate DeltaH (n KJ) per mole of boron atoms formating gaseous icosahedron if DeltaH_(BE)(B-B)=200KJ//mol:

Answer»

1000
600
500
250

Answer :C
47.

Boron does not form ionic compounds containing B^(2+) ions. Comment on the statement with suitable explanation.

Answer»

SOLUTION :The STATEMENT is TRUE
48.

Boron does not form [BF_6]^(3-), whereas aluminium forms [AlF_6]^(3-). Explain.

Answer»

Solution :In the ABSENCE of vacant d-orbitals, boron cannot expand its OCTET, WHEREAS aluminium POSSESSES vacant d-orbitals and can expand its octet.
49.

Boron does not form B^(3+) ions whereas Al forms Al^(3+) ions. This is because

Answer»

The SIZE of B atom is larger than that of Al
The sum of `IE_(1) + IE_(2) + IE_(3)` of B is much HIGHER than that of Al
The sum of `IE_(1) + IE_(2) + IE_(3)` of Al is much higher than that of B 
Both 1 and 2 

ANSWER :B
50.

Boron compouns act as Lewis acid because of their "………….." nature.

Answer»


ANSWER :electron-deficient