This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
N^(3-),O^(2-),F^-,Na^+, Mg^(2+),Al^(3+)Arrange them in the order of increasing ionic radii. |
| Answer» SOLUTION :Ionic radii is INVERSELY related to unclear charge for ISOELECTRONIC species. Hence the ORDER is `Al^(3+) lt Mg^(2+) lt Na^+ lt F^- lt O^(2-) gt N^(3-)`. | |
| 2. |
N_(2(s))+3H_(2(g)) hArr 2NH_3state the condition for industrial production of ammonia. |
| Answer» Solution :200 atmosphere pressure, `500^@C` temperature and presence of Iron (Fe) catalyst are SUITABLE SITUATION. | |
| 3. |
N_(2)O_(5) is more acidic than N_(2)O_(3). |
|
Answer» Solution :Since the oxidation state of N is +5 in `N_(2)O_(5)and+3" in "N_(2)O_(3)`, therefore, `N_(2)O_(5)` can accept electrons more readily than `N_(2)O_(3)` and hence `N_(2)O_(5)` is a stronger ACID than `N_(2)O_(3)`. Alternatively, `N_(2)O_(5)andN_(2)O_(3)` dissolve in `H_(2)O` forming `HNO_(3)andHNO_(2)` respectively. Due to higher oxidation state of +5 of N in `HNO_(3)` than +3 in `HNO_(2),NO_(2)` pulls the electrons of the O-H in `HNO_(3)` more strongly than NO pulls the electrons of the O-H bond in `HNO_(2)`. In other WORDS, `HNO_(3)` RELEASES a proton more releases a proton more reaidily than `HNO_(2)` and hence `HNO_(3)orN_(2)O_(5)` is a stronger acid than `HNO_(2)or N_(2)O_(3)`. |
|
| 4. |
N_(2)O_(4)(g)hArr2NO_(2)(g),K_(C)=4. This reversible reaction is studied graphically as shown in figure. Select the correct statements. |
|
Answer» REACTION quotient has MAXIMUM value at POINT `A` |
|
| 5. |
N_2O_(4(g)) hArr 2NO_(2(g)) of K_p = 0.15 atm (298 K) , so calculate K in torr and mol/L. (1 atm = 760 torr, R= 0.0821 L atm mol^(-1) K^(-1)) |
| Answer» SOLUTION :`K_p`= 114 torr, `K_c=0.00613 "MOL L"^(-1)` | |
| 6. |
N_(2)O_(4)(g) hArr 2NO_(2)(g) The equilibrium reaction shown is endothermic as written. Which change will increase the amount of NO_(2) at equilibrium? |
|
Answer» Adding a catalyst |
|
| 7. |
N_(2)O_(4) is dissociated to 33% and 50% at total pressure P_(1) and P_(2)atm respectively. The ratio of (P_(1))/(P_(2)) is : |
|
Answer» `(7)/(4)` `K_(P)=((""^(n)NO_(2))^(2))/(""^(n)N_(2)O_(4)) XX [(P)/(epsilon n)]^(1)` For 33% dissociation `K_(P)=((2 xx 33)^(2))/(67) xx [(P_(1))/(133)]^(1)` …...(1) For 50% dissociation `K_(P)=((2 xx 50)^(2))/(50) xx ((P_(2))/(150))^(1)` `:. (P_(1))/(P_(2))=(133 xx 67 xx (2 xx 50)^(2))/((2 xx 33)^(2) xx 150 xx 50)=(8)/(3)` |
|
| 8. |
N_(2)O_(4) harr 2NO_(2), N_(2)O_(4(g)) dissociates until the partial pressures of N_(2)O_(4) and NO_(2) become equal, initial pressure of N_(2)O_(4) is 9 atmosphere. What is K_(P) ? |
|
Answer» 6 atm partial pressure are EQUAL `IMPLIES a-X=2x` (`:. P prop n`) `implies x=(a)/(3) implies PNO_(2)=2 xx (9)/(3)=6 atm =P_(N_(2)O_(4))` `K_(P)=(P_(NO_(2))^(2))/(P_(N_(2)O_(4)))=(6^(2))/(6)=6`atm |
|
| 9. |
N_(2)O_(4) hArr 2NO_(2).At 300K N_(2)O_(4) at 6 atmosphere is heated to 600K where equilibrium is established witha total pressure of 16 atmospheres. What isK_(p) at 600K ? |
|
Answer» <P> Total no. of MOLES at equilibrium = `1+alpha` From ideal gas equation `underset("before equlibrium")((P_(1))/(n_(1)T_(1)))=underset("after equilibrium")((P_(2))/(n_(2)T_(2)))` `(6)/(1 xx 300)=(16)/((1+alpha)600), alpha=(1)/(3)` `IMPLIES K_(P)=(P^(2)NO_(2))/(PN_(2)O_(4))=8` |
|
| 10. |
N_2O_4 at an initial pressure of 2 atm and 300K dissociates to an extent of 20% at the same temperature by the time equilibrium is established. K_p for the reaction 2NO_2 harr N_2O_4 is |
Answer» Solution : `K_(P)=(0.8 xx 0.8)/(1.6)=0.4` `:. K_(P)` for `2NO_(2) HARR N_(2)O_(4)=2.5` |
|
| 11. |
N_(2) O_(2) hArr 2NO, K_(1) , (1)/(2) N_(2) + (1)/(2) O_(2) hArr NO. K_(2) , 2NO hArr N_(2) + O_(2). K_(3) , NO hArr (1)/(2) N_(2) + (1)/(2) O_(2). K_(4) |
|
Answer» `K_(1) xx K_(3)=1` |
|
| 12. |
N_(2)O is polar even though it is linear-why? |
| Answer» SOLUTION :The linear molecule `N_(2)O` is POLAR as it is not symmetrical. | |
| 13. |
N_(2)H_(4) loses 10 mol e^(-) and form new compound Y number of N does not change so what is the oxidation number of N in Y atom ? |
|
Answer» -1 TOTAL oxidation number is -4. `Y=-4+10=+6` `therefore` Oxidation number of N in Y is = `(+6)/2=+3` |
|
| 14. |
N_(2(g)) + O_(2(g)) hArr 2NO_((g)) , Delta_rH^(ө)=180 kJ .To increase the temperature of this reaction, what is the effect on products and value of K? |
| Answer» Solution :This reactions ENDOTHERMIC then to INCREASE the temperature the reaction will be forward, than product will be increases and if the PRODUCTS increase so K increase. | |
| 15. |
N_(2(g)) + 3H_(2(g)) underset"Fe"overset"200 Atm"hArr 2NH_(3(g)) , At which temperature this reaction will be possible ? |
| Answer» ANSWER :D | |
| 16. |
N_(2(g)) + 3H_(2(g)) hArr 2NH_(3(g)), The K_p of this reaction is 35 at 500 K temp. Calculate K_p of following reaction at this temp. (i)4NH_(3(g)) hArr 2N_(2(g)) + 6H_(2(g)) (ii)1/2N_(2(g)) +3/2H_(2(g)) hArr NH_(3(g)) |
|
Answer» Solution :Given equation x 2 `2(N_(2(g)) + 3H_(2(g)) hArr 2NH_(3(g)))(K_p=35)^2` `therefore 2N_(2(g)) + 6H_(2(g)) hArr 4NH_(3(g)) , K._p =(35)^2` Backward equation of this equation = `[4NH_(3(g)) hArr 2N_(2(g)) + 6H_(2(g)) ]` = equation (i) `therefore K_p` (i) of eq. (i) `=1/(K._p)^2=1/(35)^2=8.16xx10^(-4)` .... (Given equation x `1/2`) `=1/2(N_(2(g)) + 3H_(2(g)) hArr 2NH_(3(g)))` `=(1/2N_(2(g)) + 3/2H_(2(g)) hArr NH_(3(g)))` = eq.(II) `therefore K_p` of eq.(ii) = `"(K of given equation)"^(1/2)` `=(35)^(1/2)`=5.916 |
|
| 17. |
N_(2(g)) + 3H_(2(g)) hArr 2NH_(3(g)). If some HCl gas is passed into the reaction mixture at the equilibrium of this R reaction, |
|
Answer» Equilibrium shifts towards left |
|
| 18. |
N_(2(g)) + 3H_(2(g)) hArr 2NH_(3(g)) Ifargon introduce in this reaction than what happen ? |
| Answer» Solution :AR is INERT gas, so no EFFECT on EQUILIBRIUM. | |
| 19. |
N_(2(g)) + 3H_(2(g)) harr 2NH_(3(g)) is a gaseous phase equilibrium reaction taking place at 400K in a 5 L flask. For this |
|
Answer» <P>`K_(c)=K_(X)` `K_(c)(RT)^(Delta n_((g)))=K_(X)(P)^(Delta n_((g)))` `K_(c)=K_(X)((P)/(RT))^(Delta n_((g)))`, PV=RT `((P)/(RT))=(1)/(V)=(1)/(5), Delta n_((g))= -2` `K_(c)=K_(X)((1)/(5))^(-2), K_(c)=25K_(X)` |
|
| 20. |
N_(2(g))+3H_(2(g)) hArr 2NH_(3(g)) , For this equilibrium reaction at given temperature find relation between K_p and K_c |
|
Answer» Solution :At GIVEN temperature, this equilibrium reaction `N_(2(g)) + 3H_(2(g)) hArr2NH_(3(g))` all reactant and product in GASEOUS phase. At given temperature, Partial pressure of `N_2=p_(N_2)` Partial pressure of `H_2=p_(H_2)` Partial pressure of `NH_3=p_(NH_3)` `K_p=(p_(NH_3))^2/((p_(N_2))(p_(H_2))^3)` but p=cRT = (mol `L^(-1)` ) RT `K_p=([NH_3]^2(RT)^2)/{{[N_2]RT}[H_2]^3(RT)^3}` `THEREFORE K_p=[NH_3]^2/([N_2][H_2]^3)(RT)^2/((RT)(RT)^3)` but `[NH_3]^2/([N_2][H_2]^3)=K_c` For this equilibrium , `K_p ne K_c` may be `K_p LT K_c` `DELTAN`=2-(1+3)=-2 `K_p = K_c(RT)^(-2)` |
|
| 21. |
N_(2(g)) + 3H_(2(g)) hArr 2NH_(3(g)), DeltaH=-92.38 "kJ mol"^(-1) the reaction is exothermic. So at lowertemperature more product is obtained still why the reaction is carried out at high temperature ? |
| Answer» SOLUTION :If the temperature kept LOW than the rate of reaction decreases so equilibrium state is not obtained. Hence the temp must be kept (HIGH) `500^@C` for this reaction. | |
| 22. |
N_(2)3H_(2)hArr2NH_(3) K=4xx10^(6) "at" 298 K=41 "at" 400 K Which statements is correct? |
|
Answer» If `N_(2)` is added at equilibrium condition, the equilibrium will shift to the FORWARD direction because according to `II^(nd)` law of thermodynamics the entropy must increases in the direction of spontaneous reaction. |
|
| 23. |
N_(2)has higher order than NO. Explain . |
| Answer» Solution :BOND order of 1`N_(2) = 3 `Bond order of ` NO = 2 (1)/(2) ` | |
| 24. |
N_2 gas is present in one litre flask at a pressure of 7.6 xx 10^(-10)mm of Hg. The number of N_2 gas molecules in the flask at 0^@C are |
|
Answer» `2.68 XX 10^9` |
|
| 25. |
N_(2)gas is present in one litre flask at a pressure of 7.6 xx 10^(-10)mm of Hg. The number of N_(2)gas molecules in the flask at 0°C are |
|
Answer» `2.68 XX 10^(9)` |
|
| 26. |
N_(2) gas id added to the reaction equilibrium PCl_(5) (g) hArr PCl_(3) (g) + Cl_(2) (g) at constant temperature . If pressure is kept constant, equilibrium constant will …… and equilibrium will shift in the ………. direction. |
|
Answer» |
|
| 27. |
N_(2(g)) + 2O_(2(g)) rarr 2NO_(2) + xkJ, 2NO_((g)) + O_(2(g)) rarr 2NO_(2(g)) + ykJ. The enthalpy of formation of NO is |
|
Answer» `(2X-2Y)` |
|
| 28. |
N_2and O_2 are converted into monoanions N_(2)^(-)and O_(2)^(-) respectively, which of the following statements is wrong? |
|
Answer» In `N_(2)^(-)` N- N bond weakens |
|
| 29. |
N_2+ 3H_2 hArr 2NH_3+ Energy, in this equilibrium reaction what is the following when increase the total pressure ? |
|
Answer» CONCENTRATION of `N_2` increase |
|
| 30. |
N_(0)//2 atoms of X_((g)) are converted into X_((g))^(o+) by energy E_(1), N_(0)//2 atoms of X_((g)) are converted inot X_((g))^(ɵ) by energy E_(2). Hence ionisation potential and electron affinity of X_((g)) per atom are |
|
Answer» `(2E_(1))/(N_(0)),(2(E_(2)-E_(1)))/(N_(0))` `X_((g)) rarr X_((g))^(o+) + e^(-)` Energy required to ionise `(N_(0))/(2)` atoms of `X_((g)) = (N_(0))/(2) xx IE = E_(1)` (given) `:. IE = (2E_(1))/(N_(0))` `X_((g)) rarr X_((g))^(o+) ("Energy" = (N_(0))/(2) xx IE)`...(iii) `X_((g)) + e^(-) rarr X_((g))^(ɵ)[["Energy RELEASED to"],["add electrons to" (N_(0))/(2)],["atoms of"X_((g)) = -(N_(0))/(2) xx EA]]`...(iv) Energy for the process `X_((g))` to `X_((g))^(ɵ) = E_(2)` (given). Therefore, adding Eq. (iii) and (iv), we give `((N_(0))/(2) xx IE - (N_(0))/(2) xx EA) = E_(2)` (given)...(v) SUBSTITUTE the value of `IE` from Eq. (ii) in Eq. (v). `(CANCEL(N_(0))/(cancel(2)) xx (cancel(2)E_(1))/(cancel(N_(0))) -(N_(0))/(2) xx EA) = E_(2)` `-(N_(0))/(2) xx EA = E_(2) - E_(1)` `:. -EA = (2(E_(2)-E_(1)))/(N_(0))` `:. IE = (2E_(1))/(N_(0))"atom"^(-1)` and `-EA = (2(E_(2)-E_(1)))/(N_(0))` |
|
| 31. |
In the formation of a chemical bond between Na^(+) and Cl^(-),they attain the stable configuration of ………………. |
|
Answer» |
|
| 32. |
n-Propylmagnesium bromide on hydrolysis gives propane. Is there another Grignard reagent which also gives propane ? If so, give its name , structure and equation for the reaction. |
| Answer» SOLUTION :isopropylmagnesium BROMIDE , `(CH_3)_2CHMgBr` <BR> `(CH_3)_2CHMgBr + H_2O to CH_3CH_2 CH_3 + MG (OH)Br` | |
| 33. |
n-propylamine containing no secondary and tertiary amines as impurities is prepared by |
|
Answer» HOFFMAN synthesis |
|
| 34. |
n - Propyl chloride and isopropyl chloride mixture is subjected to the Wurtz reaction, which one of the following compounds is not formed |
|
Answer» HEXANE |
|
| 35. |
n-Propyl alcohol on treatment with excess hot conc. H_(2)SO_(4) gives compounds X. X on treatment with HBr in the presence of benzoyl peroxide give Y. Y when dissolved in ether and treated with sodium gives |
|
Answer» n-Hexane |
|
| 36. |
n-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent |
|
Answer» `PCl_(5)` |
|
| 37. |
n-Octane when heated to 773 K under a pressure of 10-20 atm and in presence of a mixture of Cr_2O_3, V_2O_5 and Mo_2O_3 supported over Al_2O_3 as catalyst, gives |
|
Answer» o-xylene |
|
| 38. |
n' number of alkenes yields 2,2,3,4,4- pentamethyl-pentane on catalytic hydrogenation and 'm' number report your answer as (n+m) |
|
Answer» `H_(3)C-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-underset(CH_(2))underset(||)(C)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-CH_(3) overset(H_(2)//"Catalyst")toH_(3)C-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-underset(CH_(3))underset(|)(CH)-overset(CH_(3))overset(|)underset(CH_(3)underset(|)(C)-CH_(3)` Three MONOCHLORO isomers are possible as it has three DIFFERENT types of 'H' atoms,. |
|
| 39. |
n-Octane in presence of Cr_2O_3 // Al_2O_3 ultimately changes into |
|
Answer»
|
|
| 40. |
n mole each of H_(2)O(g),H_(2)(g) "and" O_(2)(g) are mixed at a suitable high temperature to attain the equilibrium 2H_(2)O(g)hArr2H_(2)(g)+O_(2)(g). If y and mole of H_(2)O(g) are the dissociated and the total pressure maintained is P, calculate the K_(P). |
|
Answer» |
|
| 41. |
'n' moles of an ideal gas at temperature ‘T’ occupy ‘V’ litres of volume, exerting a pressure of ‘p’ atmospheres. What is its concentration in mole lit^(-1) (R = gas constant) |
|
Answer» <P>`(RT)/(R)` |
|
| 42. |
n, l and m values of the 2p_(z) orbital are |
|
Answer» 3,2,1 |
|
| 43. |
n hexane passsed over chromic oxide supported on alumina at 873 k will give …………….. |
| Answer» SOLUTION :BENZENE | |
| 44. |
n-Hexane on heating to 773 K at 10-20 atmospheric pressure in the presence of oxides of vanadium supported over alumina, yields |
|
Answer» 1-hexene |
|
| 45. |
n-hexadecane has cetane number |
|
Answer» 90 |
|
| 47. |
n g of substance X reacts with mg of substance Y to form p g of substance R and q g of substance S . This reaction can be represented as , X + Y = R + S . The relation which can be establish in the amounts of the reactants and the products will be |
|
Answer» n-m=p-q |
|
| 48. |
n-factors for Cu_(2)S and Cus when they react with KMnO_4 in acidic medium are (neglecting the further oxidation of released SO_2 |
|
Answer» 7,7 ii) `CU^(2+)` does not change only `S^(2-)` changes to `SO_2 `hence n = 6 |
|
| 49. |
N-factor for the following reaction is FeS_(2)toFe_(2)O_(3)+SO_(2) |
|
Answer» 8 `underset(2x=4)(2FE^(2+))overset(0)tounderset(2x=6)(Fe_(2)^(3+)+2e^(-)]n=(2)/(2)=1` `{:(underset(2x=-2)(S_(2)^(2-))toundersetunderset(2x=18)(2x-8=0)(2SO_(2))+10e^(-)]n=10` Total n factor `=10+1=11` |
|