Explore topic-wise InterviewSolutions in .

This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.

28601.

The major product in the reaction of 2-butyne will Li/Liq.NH_3 is

Answer»



`CH_3CH_2CH_2CH_3`
`H_2C=CH-CH_2-CH_3`

SOLUTION : REDUCTION of dialkylacetylenes with sodium INI LIQUID ammonia products the TRANS alkene.
28602.

The major product in the reaction is ……………….. {:(""CHO),("|"),(" "(CHOH)_(4)),("|"),(""CH_(2)OH):}overset((i)HCN)underset((ii)H_(3)O^(+))rarroverset(HI)rarr

Answer»

Heptanoic ACID
n-hexane
Hexanedioc acid
Saccharic acid

SOLUTION :Heptanoic acid
28603.

The molarity of a solution obtained by mixing750 mL of 0.5 (M) HCl with 250 mL of 2(M) HCI will be:

Answer»

0.875 M
1.00 M
1.75 M
0.975 M

Solution :`M_("final") V_("final") = M_1V_1 + M_2V_2`
`M_("final") = (0.5 xx 750 + 2xx 250)/(1000)`
` = (375 + 500)/(1000) = 0.875 M`
28604.

The major product in the reaction is …….

Answer»




Solution :cis-alkene with anti-addition GIVES OPTICALLY active DIHALIDE. WHEREAS trans - alkene gives meso COMPOUND.
28605.

The major product in the reaction is ……

Answer»




SOLUTION :
28606.

The major product in the reaction is …….

Answer»




SOLUTION :
28607.

The major product in the reaction, CH_(3)CH_(2)NH_(2)+Cl-overset(O)overset(||)C-CH_(3) is

Answer»

N - Methylaminoethane
Propionamide
N - Ethylacetamide
N - Methylacetamide.

Solution :`CH_(3)CH_(2)NH_(2)+CL overset(O)overset(||)C CH_(3)rarr CH_(3)CH_(2)NH underset(O)underset(||)C CH_(3)`
28608.

The major product in the given reaction is ….. CH_(3)-CH_(2)-underset("I")underset("|")("C")H-CH_(2)-CH_(3)overset(NaOH)underset(H_(2)O)rarr

Answer»

`CH_(3)-underset("OH ")underset("| ")("C ")H-CH_(2)-CH_(2)CH_(3)`
`CH_(3)-CH_(2)-underset("OH ")underset("| ")("C ")H-CH_(2)CH_(3)`
`CH_(3)-CH=CH-CH_(2)-CH_(3)`
`CH_(2)=CH-CH_(2)-CH_(2)CH_(3)`

Solution :The reaction takes place by `S_(N)1` path.
28609.

The molarity of a NaOH solution by dissolving 4 g of it in 250 ml water is

Answer»

0.4 M
0.8 M
0.2 M
0.1 M

SOLUTION :MOLARITY `=4/40 XX 1000/250 = 0.4 M`
28610.

The major product in the reaction :

Answer»

a HEMIACETAL
an ACETAL
an ETHER
an ester

Solution :N//A
28611.

The molarity of a glucose solution containing 36 g of glucose per 400 ml of the solution is :

Answer»

1
0.5
2
0.05

Answer :B
28612.

The major product in the given reaction will be ….. CH_(3)-overset("Br ")overset("| ")("C ")H-CH_(2)CH_(3)+CH_(3)-overset(CH_(3))overset("|")underset(CH_(3))underset("|")("C ")-O^(-)K^(+)rarr

Answer»

`CH_(3)-CH=CH-CH_(3)`
`CH_(2)=CH-CH_(2)CH_(3)`

`CH_(3)-CH=CH-CH_(3)` and

Solution :Base is BULKY. Thus, Hofmann ALKENE will be MAJOR.
28613.

Calculate the molality of a 9.8% (w/w) solution of H_2SO_4.

Answer»

1M
0.55 M
0.1 M
1.1 M

ANSWER :D
28614.

The major product in the following reaction is having how many pi electrons here ?

Answer»


ANSWER :2
28615.

The molarity of a 100 mL solution containing 5.1 g of hydrogen peroxide is:

Answer»

0.15 M
1.5 M
3.0 M
50.0 M

Answer :B
28616.

The major product in the following reaction is CH_(3)-underset(H)underset(|)overset(CH_(3))overset(|)(C)-CH_(2)Br underset(CH_(3)OH)overset(CH_(3)O^(-))to

Answer»

`CH_(3)-UNDERSET(H)underset(|)overset(CH_(3))overset(|)(C)-CH_(2)OCH_(3)`
`CH_(3)-underset(OCH_(3))underset(|)(C)H-CH_(2)CH_(3)`
`CH_(3)-overset(CH_(3))overset(|)(C)=CH_(2)`
`CH_(3)-underset(OCH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(3)`

Solution :Since `CH_(3)O^(-)` is a strong nucleophile as well as a strong base, therefore, it can either bring about substitution or ELIMINATION. Now, the `CH_(3)` group at `BETA`-carbon causes steric hindrance to nucleophiolic substitution `(S_(N)2)`, therefore, elimination `(E_(2))` occurs preferentially to form 2-methylpropene
28617.

The molarity of 98 % H_(2)SO_(4) (d = 1.8 g/mL) by wt.is

Answer»

6 M
18 M
10 M
4 M

ANSWER :b
28618.

The majorproduct in the following reaction is :

Answer»




ANSWER :A
28619.

The molarity of a 10% NaOH solution is

Answer»

2.5
0.5
0.25
0.05

Solution :100 ml contains 10 G. Hence ` 1 dm ^(3)` will CONTAIN 100g.
`"Molarity"= ("Mass"//dm^(3))/"MOLAR mass"=100/40=2.5 M`
28620.

The major product in the following reaction is :

Answer»




ANSWER :A
28621.

The major product from the reaction of Br_(2) with Z-3-hexene is:

Answer»

optically ACTIVE racemic MIXTURE
racemic mixture
MESO form
both racemic mixture and meso form.

Answer :B
28622.

The molarity of 900 g of water is

Answer»

50 M
55.5 M
5 M
cannot be calculated

Solution :Molarity is NUMBER of moles per LITRE
`"900 g "H_(2)O=(900)/(18)"moles = 50 moles"`
`"900 g"H_(2)O="900 ML of "H_(2)O`
`THEREFORE"Molarity "=(50)/(900)xx100x=55.5M`
28623.

The major product 'H' of the given reaction sequence is CH_(3)-CH_(2)-CO-CH_(3) overset(.^(Theta)CN)to G underset("Heat")overset(95%H_(2)SO_(4))toH

Answer»

`CH_(3)-CH=UNDERSET(CH_(3))underset(|)(C)-COOH`
`CH_(3)-CH=underset(CH_(3))underset(|)(C)-CN`
`CH_(3)CH_(2)-underset(CH_(3))underset(|)overset(OH)overset(|)(C)-COOH`
`CH_(3)CH=underset(CH_(3))underset(|)(C)-CONH_(2)`

Solution :`underset("Butan-2-one")(CH_(3)CH_(2)-CO-CH_(3)) overset(.^(Theta)CN)to underset("BUTANONE cyanohydrin (G)")(CH_(3)CH_(2)-underset(CH_(3))underset(|)overset(OH)overset(||)(C)-CN)underset(("Dehydration"))overset(95%H_(2)SO_(4),Delta)to underset("2-Methylbut-2-e-1-nitrile (H)")(CH_(3)CH=underset(CH_(3))underset(|)(C)-CN)`
Please note that hydrolysis of cyanides to carboxylic acids requries addition of amolecule of `H_(2)O`.95% `H_(2)SO_(4)` cannot SUPPLY `H_(2)O`, therefore, dehydration of (G) occurs to give (H).
28624.

The molarity of 98% H_2SO_4(d = 1.8 g/mL) by weight is

Answer»

6 M
18 M
10 M
4 M

SOLUTION :98% `H_2SO_4` MEANS 98g `H_2SO_4` is in 100 g solution
volume of 100 g solution ` = (100)/(1.8) = 55.55 ml `
Molarity`= ("number of MOLES of " H_2SO_4)/("volume of solution ") xx 1000`
` = (98)/(98 xx 55.55) xx 1000 = 18 M `
28625.

The major product H in the given reaction sequence is CH_(3)-CH_(2)-CO-CH_(3)overset(.^(Theta)CN)rarr G overset(95% H_(2)SO_(4))underset("Heat")rarr H

Answer»

`CH_(3)-CH=underset(" "CH_(3))underset(|)(C )-COOH`
`CH_(3)-CH=underset(" "CH_(3))underset(|)(C )-CN`
`CH_(3)-CH_(2)-OVERSET(OH)overset(|)underset(" "CH_(3))underset(|)(C )-COOH`
`CH_(3)-CH=underset(" "CH_(3))underset(|)(C )-CO-NH_(2)`

Solution :
28626.

The molarity of 90% H_(2)SO_(4) solution is [density = 1.8 gm/ml]

Answer»

`1.8`
`48.4`
`91.83`
`94.6`

Solution :The density of solution = 1.8 gm/ml
Weight of one litre of solution = 1800 gm
`therefore` Weight of `H_(2)SO_(4)` in the solution `=(1800xx90)/(100)=1620 gm`
`therefore` Weight of solvent = 1800 - 1620 = 180 gm
`therefore` MOLALITY `=(1620)/(98)XX(1000)/(180)=91.83`
28627.

The major product in the acid catalysed dehydration of 2-pentanol is :

Answer»

4-pentene
3-pentene
2-pentene
1-pentene

Answer :C
28628.

The major product formed when aniline reacts with concentrated H_2SO_4 followed by heating with H_2SO_4 at 453-473k is

Answer»




ANSWER :A
28629.

The molarity and molality of a solution are M and m respectively. If the molecular weight of the solute is M', calculate the density of the solution in terms of M, m and M'

Answer»


ANSWER :`[D=M((1)/(m)+(M')/(1000))]`
28630.

The major product formed when alcoholic AgNO_2 reacts with ethyl chloride is

Answer»

ETHYL NITRITE
Ethyl NITRATE
NITROETHANE
Ethyl dinitrate

Answer :C
28631.

The molarity of 0.006 mole of NaCl in 100ml solution is

Answer»

`0.6`
`0.06`
`0.066`
NONE of these

Solution :`M=(N)/(V(L))=(0.006)/(0.1)=0.06`
28632.

The major product formed when 1, 1, 1-trichloro-propane is treated with aqueous potassium hydroxide is:

Answer»

Propyne
1-Propanol
2-Propanol
Propionic acid

Solution :`Cl_(3)C-CH_(2)CH_(3)+KOHoverset("Heat")(to)(OH)_(3)C-CH_(2)CH_(3)+3KCL to CH_(3)CH_(2)CO-OH`
28633.

The molar volumes of ice and water are respectively 0.0196 and 0.0180 litres per mole at 273 K. If DeltaH for the transition of ice to water is 1440 calories per mole at 1 atm pressure, find Delta u.

Answer»


ANSWER :(1440 CAL)
28634.

The major product formed in the reaction is (AAK_MCP_35_NEET_CHE_E35_014_Q01)

Answer»


`(AAK_MCP_35_NEET_CHE_E35_014_A01)`

ANSWER :B
28635.

The molar volume of liquid benzene (density =0.877g//mL) increases by a factor of 2750 as it vaporises at 20^(@)C and that of liquid toluene (density =0.867g//mL) increases by a factor of 7720 at 20^(@)C. A solution of benzene and toluene at 20^(@)C has a vapour pressure of 46 torr. Find the mole fraction of benzene in the vapour above the solution

Answer»

<P>

Solution :The volume of 1 mole of `C_(6)H_(6)` (liquid) `=(78)/(0.877)mL`
The volume of 1 mole of `C_(6)H_(6)` (VAPOUR) `=(78)/(0.877)xx2750mL`
`=244.58` LITRES
for 1 mole of `C_(6)H_(6)` vapour at `20^(@)C`
`p_(b)^(0)V=RT`
`p_(b)^(0)=(0.0821xx293)/(244.58)`atm`=74.75mm`
Similarly for 1 mole of `C_(6)H_(5)CH_(3)` vapour at `20^(@)C`
`p_(t)^(0)=(0.0821xx293)/(((92)/(0.867)xx(7720)/(1000)))"atm"=22.32mm`
Now,
`(1)/(p)=(x_(b).)/(p_(b)^(0))+((1-x_(b).)/(p_(t)^(0)))`
`(1)/(46)=(x_(b).)/(74.75)+(1-x_(b).)/(22.32)`
`x_(b)^(.)=0.7336`
28636.

The major product formed in the reaction is, Et – S-CH_2 -CH(CI)CH_3 overset( aq.KOH )(to)

Answer»




Solution :`ET + S - CH_2 - undersetoverset(|)(CL)(C )H -CH_3 underset(KOH)OVERSET(OS)(to)Et-S -CH_2 - undersetoverset(|)(OH)(C )H - CH_3 + KCl`
28637.

The molar volume of methane , CH_(4). At 819^(@)C and 760mm pressure is :

Answer»

<P>22.4L
44.8L
89.6L
5.6L

Solution :`V_(1) = 22.4L`
`p_(1) = 760 mm HG `
`T_(1) = 273K`
`V_(2) = ?`
`p _(2) `= 760mm Hg
`T_(2) = ` 1092 K
`( V_(2))/( T_(2)) = ( V_(1))/( T_(1))`
or `V_(2) = ( V_(1) T_(2))/( T_(1)) = ( 22.4 xx 1092)/( 273) = 89.6L`
28638.

The major product formed on nitration of N, N - dimethylaniline with conc. H_2SO_4,NHO_3 mixture is

Answer»




ANSWER :A
28639.

The major product formed in the reaction:

Answer»




ANSWER :C
28640.

The molar volume of liquid benzene (density =0.877 g ml^(-1)) increases by a factor of 2750 of it vaporises at 20^(@)C At 27^(@)C when a non-votalite solute (that does not to be 98.88 mm Hg. Calculate the freezing point of the solution. Given Enthalphy f vaporization of benzene (f) 394.57 J g^(-1) Enthalpy of fusion constant for benzne =5.0 kg "mol"^(-1)

Answer»

SOLUTION :LET moles of benzene vaproises, at `20^(@)C=n_(1)`
volume of `n_(1)` mole of benzene `(f)=(78n_(1))/(0.877)`
Volume of `n_(1)` mole of benzene `(g)=2750 ((78n_(1))/(0.877))`
`PV=nRT`
`P^(@)=((78n_(1))/(0.877))((2750)/(1000))=n_(1)xx0.082xx293`
`P_("Benzene")=0.0982` atm.
`=74.63 mm Hg`
`P_("Benzene")^(@)` at `27^(@)C` can be CALCULATED as
`log((P_(2))/(P_(1)))=(DeltaH_("vap"))/(2.303R)[(T_(2)-T_(1))/(T_(1)T_(2))]`
`log ((P_(2))/(74.63))=(394.57xx78)/(2.303xx8.314)[(7)/(300xx293)]`
`P_("Benzene")^(@) ("at"27^(@)C)=100.2` mm Hg
Molality of the solution `=(X_("solvent")xx1000)/(X_("solvent")xx78)=(((100.2-98.88)/(98.88))xx10000)/(0.98xx78)=0.17`
`Deltat_(f)=K_(f)m=5xx0.17=0.85`
We known that `K_(f), =[(RT_(f)^(2))/(1000DeltaH_(f))]M`
`5=((8.314xxT_(1)^(2))/(1000xx10060))78, T_(f)-278.5K`
28641.

The major product formed in the reaction:

Answer»




ANSWER :A
28642.

The major product formed in the reaction is :

Answer»




ANSWER :A
28643.

The molar volume of X(l)(d=0.9g/mL) increases by a factor of 3000 as it vaporises at 27^(@)C and that of Y(l)(d=0.88 g/mL) increases by a factor of 8000 at 27^(@). A miscible liquid solution of X and Y at 27^(@)C has a vapour pressure of 50 torr. The mole fraction of Y in solution is : ( Given : 0.082 atm/L/mol/K, Molar mass of X=75, Molar mass of Y=88)

Answer»

0.48
0.52
0.62
0.247

Answer :A
28644.

The major product formed in the folowing reaction is

Answer»



50 : 50 MIXTURE of above two compounds

SOLUTION :(a) It is stereospecific REACTION
28645.

The major product formed in the following reaction is …… CH_(3)CH(Cl)CH_(2)-CH_(2)OH overset(" aq. KOH ")rarr

Answer»

`CH_(3)CH=CHCH_(2)OH`
`CH_(2)=CH-CH_(2)CH_(2)OH`
`CH_(3)-UNDERSET(O-CH_(2))underset("||")(CH-CH_(2))`
`CH_(3)-underset("OH ")underset("| ")("C ")H-CH_(2)CH_(2)OH`

Solution :With aq. KOH hydrolysis occurs i.e., option (D) is correct.
28646.

The major product formed in the following reaction is : CH_3-overset(CH_(3))overset(|)underset(H)underset(|)C-CH_2Broverset(CH_3O^(-))underset(CH_3OH)to

Answer»

`CH_3-overset(CH_(3))overset(|)underset(H)underset(|)C-CH_2OCH_3`
`CH_3-underset(OCH_(3))underset(|)CH-CH_2CH_3`
`CH_3-overset(CH_(3))overset(|)CH=CH_2`
`CH_3-underset(OCH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3)`

Solution :The nucleophile `(CH_3-overset(-)O)` cannot attack carbon atom bearing Br RADICAL BEACAUSE of a bulky isopropyl radical ATTACKED to it. Therefore elimaination should be major reaction.
28647.

The molar volume of liquid benzene (density = "0.877 g mL"^(-1)) increases by a factor of 2750 as it vaporises at 20^(@)C and that of liquid toluene (density "0.867 g mL"^(-1)) increases by a factor of 7720 at 20^(@)C. A solution of benzene and toluene at 20^(@)C has a vapour pressure of 46.0 torr. Find the the mole fraction of benzene in the vapour above the solution.

Answer»

Solution :In vapour phase,
`"1 MOLE of benzene, i.e., 78 g has volume at "20^(@)C=(78)/(0.877)xx"2750 mL"`
`"1 mole of toluene, i.e., 92 g has volume at "20^(@)C=(92)/(0.867)xx"7720 mL"`
`"Applying , PV = N RT"`
`"For benzene vapour, "(P^(@))/(760)"(atm)"xx(78xx2750)/(0.877xx1000)(L)=1xx"0.0821 L atm K"^(-1)"mol"^(-1)xx293 K`
`"or"P_(B)^(@)=74.74mm`
`"For toluene vapour, "(P^(@))/(760)xx(92xx7720)/(0.867xx1000)=1xx0.0821xx293`
`"or"P_(T)^(@)=22.37mm`
`""P_("total")=x_(B)xxP_(B)^(@)+x_(T)xxP_(T)^(@)=x_(B)P_(B)^(@)+(1-x_(B))xxP_(T)^(@)`
`THEREFORE""46=x_(B)=(74.74)+(1-x_(B))(22.37)`
This on solving gives `x_(B)=0.45` (in the liquid phase)
`therefore""x_(T)=1-0.45=0.55` (in the liquid phase)
`"In vapour phase,"P_(B)=x_(B)P_(B)^(@)=0.45xx74.74=36.63mm`
`""P_(T)=x_(T)P_(T)^(@)=0.55xx22.37=12.30 mm`
`"Mole fraction of benzene in vapour phase "(y_(B))=(P_(B))/(P_(B)+P_(T))(36.63)/(36.63+12.30)=0.75`
28648.

The major product formed in the following reaction is (AAK_MCP_37_NEET_CHE_E37_002_Q01)

Answer»

4-methoxy acetophenone
2-methoxy acetophenone
2-methoxy anisole
4-methoxy anisole

Answer :A
28649.

The major product formed in the following reaction CH_(3)CH(Cl)CH_(2)-CH_(2)OH overset(Aq. KOH)tois

Answer»

`CH_(3)CH=CH-CH_(2)OH`
`CH_(2)=CH-CH_(2)-CH_(2)OH`
`CH_(3)-underset(O)underset(|)CH-underset(CH_(2))underset(|)CH_(2)`
`CH_(3)-underset(OH)underset(|)CH-CH_(2)-CH_(2)OH`

SOLUTION :Nucleophilic SUBSTITUTION to give DIOL.
28650.

The major product (ester) of the following reaction is

Answer»

A single STEREOISOMER (optically ACTIVE)
A MIXTURE of DIASTEREOMERS (both optically active)
A racemic mixture (optically inactive)
A mixture of four stereoisomers (TWO racemic mixtures)

Answer :A