Explore topic-wise InterviewSolutions in .

This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.

451.

Equal weights of methane and oxygen are mixed in an empty container at `25^(@)C`. The fractin of the total pressure exerted by oxygen isA. `(1)/(3)`B. `(1)/(2)`C. `(2)/(3)`D. `(1)/(3) xx (273)/(298)`

Answer» Correct Answer - A
Let `32 g` of each be present.
Moles of `O_(2) = (32)/(32) = 1`
Moles of `CH_(4) = (32)/(16) = 2`
Mole fraction of `O_(2) = (1)/(1 + 2) = (1)/(3)`
which is same as the fraction of pressure.
452.

The temperature at which molarity of pure water is equal to its molality is `:`A. `273K`B. `298K`C. `277K`D. None

Answer» Correct Answer - 3
At `4^(@)C` density of water is `1 g//ml.`
453.

Why is limiting reactant so named ?

Answer» Limiting reactant i.e, the reactant present in fixed amount is so because it limits the participation of other reactants even if present in excess in particular reaction.
454.

`K_(2)Cr_(2)O_(7)+C_(2)O_(4)^(2-)+H_(2)SO_(4)rarr K_(2)SO_(4)+CO_(2)+Cr_(2)(SO_(4))_(3)+H_(2)O` In above reaction, identify the elements which do not undergo change in their oxidation state `:`A. `C`B. `S & C`C. `K,O,S & H`D. `C & O`

Answer» Correct Answer - 3
455.

In the balanced equation `FeS+MnO_(4)^(-)overset(H^(+))rarrFe^(3+)+SO_(4)^(2-)+Mn^(2+)` the stoichiometric coefficients of `FeS` and `MnO_(4)^(-)` are in the ratio `:`A. `8:5`B. `5:8`C. `9:5`D. `5:9`

Answer» Correct Answer - 4
456.

The modern atomic mass unit if based on the mass of ………

Answer» Correct Answer - A::B::C
The modern atomic mass unit is based on the mass of `C - 12`.
457.

Which of the following `is//are` correct? The following reaction occurs: `Na_(2) CO_(3) + 2HCl rarr 2NACl + CO_(2) + H_(2) O` `106.g "of" Na_(2) CO_(3)` reacts with `109.5 g "of" HCl`.A. The `HCl` is in excess.B. `117.0 g` of `NaCl` is formed.C. The volume of `CO_(2)` produced at 1 bar and `273 K` is `22.7 L`D. The volume of `CO_(2)` produced at 1 bar and `298 K` is `24.7 L`

Answer» Correct Answer - A::B::C::D
`(Mw "of" Na_(2) CO_(3) = 106 "of" HCl = 36.5, Mw "of" NaCl = 58.5)`
Mole of `Na_(2) CO_(3) = (106)/(106) = 1.0 "mol"`
Moles of `HCl = (109.5)/(36.5) = 3.0 "mol"`
a. Since for a mol of `Na_(2) CO_(3)`, 2 mol of `HCl` is required.
So, `HCl` is in excess `(3 - 2) = 1.0 "mol"`
Therefore, `Na_(2) CO_(3)` is the limiting quaintity.
b. weight of `NaCl` formed
`= (1.0 "mol" Na_(2) CO_(3)) ((2 "mol" NaCl)/("mol" Na_(2) CO_(3)))((58.8 g NaCl)/("mol" NaCl))`
1 mol of `Na_(2) CO_(3) = 1` mol of `CO_(2) = 22.7 L` at 1 bar,
`273 K`
1 mol of `Na_(2) CO_(3) = 1` mol of `CO_(2) = 24.7 L` at 1 bar,
`298 K`
458.

Salt cake `(Na_(2)SO_(4))` is prepared as follows: `2NaCl + H_(2) SO_(4) rarr Na_(2)SO_(4) + 2HCl` How much 80% pure salt cake could be produced form `100.0 g` of 90% pure salt in the above reaction?A. `43.92 g`B. `68.62 g`C. `87.84 g`D. `137.25 g`

Answer» Correct Answer - D
Weight of `Na_(2) SO_(4) = (109.8 g Na_(2) SO_(4)) xx`
`((100 g "new mixture")/(80.0 g Na_(2)SO_(4)))`
`= (109.8 xx 100)/(80)`
`= 137.25 g` mixture
459.

Silver (atomic weight `108 g mol^(-1))` has a density of `10.5 g cm^(-3)`. The number of silver atoms on a surfaces of area `10^(-12) m^(2)` can be expressed in scientific notation as `Y xx 10^(-x)`, The value of `x` is …….

Answer» Density `= 10.5 g c c^(-1)`
This measn `10.5 g` silver is present in `1 cm^(3)`.
`(10.5)/(108)` mol silver is present in `1 cm^(3)`.
`(10.5)/(108) N` silver atoms present in `1 cm^(3)`
`.^(3)sqrt((10.5)/(108) N)` silver atoms present in `1 cm`
`(.^(3)sqrt((10.5)/(108) N))^(1//2)` silver atoms present is `1 cm^(2)`.
`10^(-12)` is equal to `10^(-8) cm^(2)`.
`(.^(3)sqrt((10.5)/(108) N))^(1//2) xx 10^(-8)` silver atoms present in `10^(-12) m^(2)`.
On solving, we get `1.5 xx 10^(-7) = Y xx 10^(-x)`
`:.x = 7`
460.

Which of the following `is//are` correct. The following reaction occurs: ltrgt `CS_(2) + 3Cl_(2) overset(Delta)rarr C Cl_(4) + S_(2) Cl_(2)` `1.0 g` of `CS_(2)` and `2.0 g` of `Cl_(2)` reacts.A. `0.714 g CS_(2)` is used in the reaction.B. `0.286 g CS_(2)` is in formed.C. `1.45 g of C Cl_(4)` is formedD. `0.8 g Cl_(2)` is in excess

Answer» Correct Answer - A::B::C
`(Mw "of" CS_(2) = 76, Mw "of" Cl_(2) = 71, Mw "of" C Cl_(4) = 154 g mol^(-1))`
Weight of `Cl_(2)` needed
`=(1.0 g CS_(2)) ((1 "mol" CS_(2))/(76 g CS_(2)))((3 "mol" CS_(2))/("mol"CS_(2)))((71 g Cl_(2))/("mol" Cl_(2)))`
`= (1 xx 3 xx 71)/(76) = 2.8 g Cl_(2)` needed
Since there is `2.0 g Cl_(2)` is the limiting quantity
a. Weight of `Cs_(2)` used
`= (2.0 g Cl_(2))((1 "mol" Cl_(2))/(71 g Cl_(2))) ((1 "mol" CS_(2))/(3 "mol" Cl_(2)))((76 g CS_(2))/("mol" CS_(2)))`
`= (2 xx 1 xx 1 xx 76)/(71 xx 3) = 0.714 g CS_(2)` used.
b. Weight of `CS_(2)` excess or formed
`= (1.0 g CS_(2)` present) - `(0.714 g` used)
`= 0.286 g CS_(2)` formed
c. Weight of `C Cl_(4)` formed
`= (2.0 g Cl_(2)) ((1 "mol" Cl_(2))/(71 g Cl_(2)))((1"mol" CCl_(4))/(2"mol"Cl_(2)))`
`((154 g C Cl_(4))/("mol" C Cl_(4)))`
`= (2 xx 1 xx 154)/(71 xx 3) = 1.45 g C Cl_(4)`
d. Wrong
461.

Among the following, what is the number of elements showing only one non-zero oxidation state?

Answer» Correct Answer - B
`O,Cl,underline(F),N,P,Sn,Tl,underline(Na),Ti`
`Na` shows only + 1
`F` shows only - 1
462.

The total number of electrons present in `18 mL` of water is ……

Answer» Correct Answer - A::B::C::D
The total numbe of electrons present in `18 mL` of water is `6.023 xx 10^(24)`.
Number of electron in one molecules of `H_(2) O` is `2 + 8 = 10`
Denisty = 1
`18 mL` means `18 g`
Moles `= (18)/(18) = 1`
Moles `= 6.023 xx 10^(23)`
Electrons `= 6.023 xx 10^(23) xx 10 = 6.023 xx 10^(24)`
463.

`2.66 g` of chloride of a metal when treated with silver nitrate solution, gave `2.87 g` of silver chloride `3.37 g` of another chloride of the same metal gave `5.74 g` of silver chloride when treated with silver nitrate solution. Show that the results illustrate the law of multiple proportions.

Answer» `AgNO_(3)+MClrarrMNO_(3)+underset(("white ppt"))(AgCl)`
Molecular mass of `AgCl=(108+35.5)=143.5g`
In the first sample
`143.5 g` of `AgCl` contain `Cl = 35.5 g`
`2.87 g` of `AgCl` contain `Cl=((35.5g))/((143.5g))xx(2.87g)=0.71g`
Now, chlorine `(Cl)` present in `AgCl` has actually been obtained from metal chloride
`:.` Mass of metal (M) in the sample `= (2.66-0.71) = 1.95 g`
In the second sample
`143.5 g` of `AgCl` contain `Cl = 35.5 g`
`5.74 g` of `AgCl` contain `Cl=((35.5g))/((143.5g))xx(5.74g)=0.42g`
Mass of metal (M) in the sample `= (3.37 - 1.42) = 1.95 g`
From the above data, it is clear that in both the samples of metal chlorides, mass of metal `(M) = 1.95 g`
`:.` Ratios of the masses of chlorine `(Cl)` which combine with a fixed mass of metal `= 0.71 : 1.42 or 1:2`. As the ratio is a simple whole number ratio therefore, the law of multiple proportions is illustrated.
464.

Which of the following statements `is//are` correct" The following reaction occurs: `2Al + 3MnO overset(Delta)rarr Al_(2) O_(3) + 3 Mn`. `108.0 g` of `Al` and `213.0 g` of `MnO` was heated to initiate the reaction. `(Mw "of" MnO = 71`, atomic weight of `Al = 13)`A. `Al` is present in excessB. `MnO` is present is excess.C. `54.0 g` of `Al` is requiredD. `159.0 g` of `MnO` is in excess.

Answer» Correct Answer - A::C
Moles of `Al = (108)/(27) = 4.0 "mol"`
moles of `MnO = (213)/(71) = 3.0 "mol"`
a. Since 2 mol of `Al` requires 3 mol of `MnO`, therefore `Al` is in excess.
b. Wrong
Weight of `Al` required
`= (3.0 "mol" MnO) ((2 "mol" Al)/(2 "mol" MnO))((27 g Al)/("mol" Al))`
`= (3 xx 2 xx 27)/(3) = 54.0 g` of `Al`
d. Weight of `Al` in excess `= (108 - 54) = 54.0 g`
465.

In the reaction: `2Al + Cr_(2) O_(3) rarr Al_(2) O_(3) + 2 Cr`, `4.98 g` of `Al` reacted with `20.0 g Cr_(2)O_(3)`. How much grams of reactant ramains at the completion of the reaction?

Answer» (Atomic weight of `Al` and `Cr = 27` and 52, `Mw` of `Cr_(2)O_(3) = 152)`
Moles of `Al = (4.98)/(27 Al) = 0.184 "mol"`
`= (0.184)/(2) = 0.92 "mol of" Cr_(2) O_(3)`
Since 2 mol `Al` is required for 1 mol of `Cr_(2)O_(3)`.
So, `Al` is the limiting reagent and `Cr_(2)O_(3)` is excess.
Moles of `Cr_(2)O_(3)` in excess `= (0.131 - 0.092) = 0.039`
`~~ 0.04 "moo"`
Weight of `Cr_(2) O_(3)` is excess `= 0.04 xx 150 ~~ 6 g Cr_(2) O_(3)`
466.

A mixture of a mol of `C_(3) H_(8)` and `b` mol of `C_(2) H_(4)` was kept is a container of `V L` exerts a pressure of 4.93 atm at temperature `T`. Mixture was burnt in presence of `O_(2)` to convert `C_(3) H_(8)` and `C_(2) H_(4)` into `CO_(2)` in the container at the same temperature. The pressure of gases after the reaction and attaining the thermal equilirium with atomsphere at temperature `T` was found to be 11.08 atm. The mole fraction of `C_(2)H_(4)` in the mixture isA. 0.25B. 0.75C. 0.45D. 0.55

Answer» Correct Answer - B
`chi_(C_(2)H_(4))` or `chi_(b) = 1 - 0.25 = 0.75`
467.

What is the percentage of aluminium in `Al_(2)O_(3)`? `(Al = 27, O = 16)`

Answer» `Mw of Al_(2) O_(3) = 27 xx 2 + 16 xx 3 = 102 g`
`% of Al = (54 xx 100)/(102) = 52.94%`
468.

Suppose elements `X` and `Y` combine to form two compounds `XY_(2)` and `X_(3)Y_(2)` when 0.1 mole of former weigh `10 g` while 0.05 mole of the latter weigh `9g`. What are the atomc weights of `X` and `Y`.A. 40,30B. 60,40C. 20,30D. 30,20

Answer» Correct Answer - A
`X + 2Y rarr XY_(2)`
0.1 mol of `XY_(2) = 10 g`
1 mol of `XY_(2) rarr 100 g`
ii. `3X + 2 Y rarr X_(3) Y_(2)`
0.05 mol of `X_(3)Y_(2) = (9)/(0.05) = 180 g`
` {:( :. X + 2 Y = 100),(3X + 2Y = 180):}] {:(MwXY_(2) = 100),(MwX_(2)Y_(3) = 180):}`
Solve of `X` and `Y`
`X = 40 g`
`Y = 30 g`
469.

Equal weight of Aluminium and Oxygen are allowed to combine with each other to produce `Al_2O_3`.Identify the correct statement. `(4Al+3O_2to2Al_2O_3)`(At. Wt. of Al=27, O=16)A. Aluminium metal is the limiting reagentB. The fraction of excess reagent left unreacted is `1/9`C. The mass of `Al_2O_3` produced is `51/27` times the mass of oxygen taken initially.D. The mass of aluminium and oxygen is left unreacted and the mass of `Al_2O_3` produced is double the mass of aluminium taken initially.

Answer» Correct Answer - A::B::C
470.

If 1/2 moles of oxygen combine with aluminium to form `Al_(2)O_(3)` then weight of Aluminium metal used in the reaction is (Al = 27 )A. 27 gB. 18 gC. 54 gD. 40.5 g

Answer» Correct Answer - B
471.

The molarity of `H_(2)SO_(4)` is `18 M`. Its density is `1.8 g mL^(-1)`.A. 36B. 200C. 500D. 18

Answer» Correct Answer - C
Use formula
`d = M ((Mw_(2))/(1000) + (1)/(m)) implies 1.8 = 18 ((98)/(1000) + (1)/(m))`
solve for `m:`
`:. M = 500`
472.

Molarity of `H_(2)SO_(4)` is `18 M`. Its density is `1.8 g//cm^(3)`, hence molaity is :A. `18`B. `100`C. `36`D. `500`

Answer» Correct Answer - D
molarity
`(Mxx1000)/(1000d-MM_(w))=(18xx1000)/(1000xx1.8-18xx98)=500`
473.

If `1 1/2` moles of oxygen combine with Al to form `Al_(2)O_(3)` the weight of Al used in the reaction is (Al=27)A. `27 g`B. `54 g`C. `40.5 g`D. `81 g`

Answer» Correct Answer - B
`{:(3O_(2)+4Alrarr2Al_(2)O_(3)O),(3rarr4),(1rarr(4)/(3)xx(3)/(2)),((3)/(2)rarr=2molxx27=54 g):}`
474.

If `1 1/2` moles of oxygen combine with Al to form `Al_(2)O_(3)` the weight of Al used in the reaction is (Al=27)A. 27gB. 54gC. 40.5gD. 81g

Answer» Correct Answer - B
475.

A solution contains 4 g of NaOH and 16.2 g of water. The mole fraction of solute and solvent are respectively.A. 0.1,0.9B. 0.2,0.8C. 0.5,0.5D. 0.4,0.6

Answer» Correct Answer - A
`n_(B)=((4g))/(("40 g mol"^(-1)))=0.1` mol
`n_(A)=(("16.3g"))/(("18 g mol"^(-1)))=0.9` mol
`X_(B)=(n_(B))/(n_(B)+n_(A))=(0.1)/((0.1+0.9))=0.1` mol
`X_(A)=1-0.1=0.9`.
476.

A compound contains 28% N and 72% of a metal by weight . Three atoms of metal combine with two atoms of N . Find the atomic weight of metal.

Answer» Correct Answer - 24
477.

Which has maximum number of molecules among the following ?A. 44 g of `CO_(2)`B. 48 g of `O_(3)`C. 8 g of `H_(2)`D. 64 g of `SO_(2)`

Answer» Correct Answer - C
No. of moles of `CO_(2)=((44g))/(("44 g mol"^(-1)))=1` mol
No. of moles of `O_(3)=((48g))/(("48 g mol"^(-1)))=1` mol
No. of moles of `H_(2)=(8g)/(("2g mol"^(-1)))=4` mol
No. of moles of `SO_(2)=((64g))/(("64g mol"^(-1)))=1` mol
`:.` 4 moles or 8g of `H_(2)` have max. no of molecules.
478.

If 1.5 moles of oxygen combine with Al to form `Al_(2)O_(3)`. The mass of Al in grams. (Atomic mass of Al = 27) used in the reaction is :A. 2.7B. 54C. 40.5D. 81

Answer» Correct Answer - B
`underset("2 mol")(2Al+)3//2underset("1.5 mol")(O_(2)rarr)underset("1 mol")(Al_(2)O_(3))`
Mass of Al in grams used `=2xx27=54` g
479.

Methyl-t-butel ether, `C_5H_12O` is added to gasoline to promote cleaner burning How many moles of oxygen gas. `O_2` are required to burn 1.0 mol of this compound completeley to form carbon dioxide and water ?A. 4.5 molB. 6.0 molC. 7.5 molD. 8.0 mol

Answer» Correct Answer - C
480.

Calcualate the molarity and molality of 20% aqueous ehtanol `(C_(5) H_(5) OH)` solution by volume. (density of solution `= 0.96 g mL^(-1)`)

Answer» Correct Answer - C::D
`C_(2) H_(5) OH` is 20% by volume, i.e., `20 mL of C_(2) H_(5) OH` is dissolved in `100 mL` of solution
Volume of `H_(2) O = 100 - 20 = 80 mL`
Weight of `H_(2) O = 80 xx 1 = 80 g (d_(H_(2)O) = 1)`
Weight of solution `= 100 xx 0.96 = 96 g`
weight of `C_(2) H_(5) OH = 96 - 80 = 16 g`
`(Mw of C_(2) H_(5) OH = 12 xx 2 + 5 + 16 + 1 = 46)`
`:. M = (W_(2) xx 1000)/(Mw_(2) xx V_(sol)) = (16 xx 1000)/(46 xx 100) = 3.48`
`m = (W_(2) xx 1000)/(Mw_(2) xx W_(1)) = (16 xx 1000)/(46 xx 80) = 4.35`
481.

2.7 gm of Al is heated with 100 mL of `H_(2)SO_(4)` (29.4% w/w density 1 gm/mL) following reaction takes place: `Al+H_(2)SO_(4) rarr Al_(2)(SO_(4))_(3)+H_(2)` The volume of `H_(2)` gas evolved at 273 k and 1 atm:A. 3.36 LB. 2.24 LC. 4.48 LD. 11.2 L

Answer» Correct Answer - A
482.

2.7 gm of Al is heated with 100 mL of `H_(2)SO_(4)` (29.4% w/w density 1 gm/mL) following reaction takes place: `Al+H_(2)SO_(4) rarr Al_(2)(SO_(4))_(3)+H_(2)` The hydrogen gas obtained in the reaction is mixed with `1.2 xx 10^(24)` molecules of `O_(2)` . The molecular weight of gaseous mixture is :(Assuming gases are not reacting `N_(0)=6 xx 10^(23))`A. 29.9B. 30.6C. 17D. None of these

Answer» Correct Answer - A
483.

`5 mL` of a gaseous hydrocarbon was exposed to `30 mL` of `O_(2)`. The resultant gas, on cooling, is formed to measure `25 mL` of which `10 mL` is absrobed by `NaOH` and the remainder by pyrogallol. Determine the molecular formula of hydrocation. All measurements are made at constant pressure and temperature.

Answer» Let the formula of hydrocarbon `= C_(x) H_(y)`
`:. C_(x) H_(y) + (x + (y)/(4)) O_(2) rarr xCO_(2) + (y)/(2) H_(2) O`
`"Initial" 1 mL (x + (y)/(4)) mL 0 0` ltbgt `"Final" 5 mL 5 (x + (y)/(4)) mL 5x mLm -`
`CO_(2) = 10 mL`
`:. 5 x = 10 implies x = 2 mL`
Volume of `O_(2)` left `= 15 mL`
Volume of `O_(2)` used `= 30 - 15 = 15 mL`.
`:. 5 (x + (y)/(4)) = 15 implies y = 4`
Formula of hydrocarbon `= C_(2) H_(4)`
484.

Which of the following reactions represents disproportionation ?A. `CrO_(5) rarr Cr^(3+)+O_(2)`B. `IO_(3)^(-)+I^(-)+H^(+)rarr I_(2)`C. `CrO_(2)Cl_(2)+NaOHrarr Na_(2)CrO_(4)+NaCl+H_(2)O`D. `Na_(2)S_(2)O_(3)+H_(2)SO_(2)rarr Na_(2)SO_(4)+SO_(2)+S_(8)+H_(2)O`

Answer» Correct Answer - 4
`Na_(2)S_(2)O_(3)+H_(2)SO_(4)rarr Na_(2)SO_(4)+SO_(2)+S_(8)+H_(2)O`
Oxidation No. of `S` in `Na_(2)S_(2)O_(3)=+2`
Oxidation No. of `S` in `H_(2)SO_(4)=+6`
Oxidation No. of `S` in `SO_(4)=+4`
Oxidation No. of `S` in `Na_(2)SO_(4)=+6`
Oxidation No. of `S` in `S_(8)=0`
So, Sulphur can oxidise from `+2` to `+4` as well as reduce to `0(S_(8))`.
485.

The population of India based on 1981 census figure was 684 millions. Express the results in scientific notation and calculate the number of significant figures.

Answer» 1 Million `= 10^(6)`
684 Millions `= 684 xx 10^(6)`
The value in terms of scientific notation may be expressed `6.84 xx 10^(8)`
The number of significant figures = three.
486.

Which of the statement are true?A. Law of constant compositon is true for all types of compounds.B. Molar volume of a gas at standard conditions is `22.4 L`.C. vapour density of a gas is twice of its molecula mass.D. Atomic masses of most elements are fractional.

Answer» Correct Answer - D
a. Not applicable if the elements exists in different isotopes which may be involved in the formation of compound.
b. At 1 atm, `25^(@)C` molar volume `= 22.7 L`
c. `Mw = 2 xx VD`,
Due ot existance of isotopes.
487.

The largest number of molecules inA. `36 g` of waterB. `28 g` of carbon monoxideC. `46 g` of ethly alcoholD. `54 g` of nitrogen pentoxide

Answer» Correct Answer - A
The number of molecules in `36 g` of water is
`(36)/(18) N = 2 N`
The number of molecules in `28 g` of `CO` is
`(28)/(28) N = N`
The number of molecules in `46 g` of `C_(2) H_(5) OH` is
`(46)/(46) N = N`
The number of molecules in `54 g` of `N_(2)O_(5)` is
`(54)/(108) N = (1)/(2) N`
488.

Which of the statement are true?A. The equivalent weight of `Ca_(3)(PO_(4))_(2)` is `Mw//6`.B. The equivalent weight of `Na_(3)PO_(4).12H_(2)O` is `Mw//3`.C. The equivalent weight of `K_(2) SO_(4)` is `Mw//2`.D. The equivalent weight of potas alum `K_(2)SO_(4)Al_(2)(SO_(4))_(3).24H_(2) O` is `Mw//8`

Answer» Correct Answer - A::B::C::D
a. Valency factor `= 6 [overset(+ 2 xx 3)(Ca_(3)) overset(-3 xx 2)((PO_(4))_(2))]`
b. Valency factor `= 3 [overset(+1 xx 3)(Na_(3)) overset(-3)((PO_(4)))]`
c. Valency factor `= 2 [overset(+1 xx 2)(K_(2)) overset(-2)(SO_(4))]`
d. Valency factor `= 8 [overset(+ 1 xx 2)(K_(2)) overset(-2)(SO_(4)) overset(+3 xx 2)(Al_(2)) overset(-2 xx 3)((SO_(4)))]`
489.

A 50 gm oleum sample contains `(400/49)` gm of combined `SO_(3).` Find percent label of the oleum sample.

Answer» Correct Answer - 118
490.

An oleum sample has `SO_(3)` and `H_(2)SO_(4)` in 2:3 mass ratio. Select the correct statement(s).A. % labelling of sample is 109%B. % labelling of sample is 118%C. If 9 gm `H_(2)O` is added to200 gm of above sample, new labelling would be 104.5%D. If 9 gm `H_(2)O` is added to 200 gm of above sample, new labelling would be 104.3%

Answer» Correct Answer - A::D
491.

The `Ew` of an element is `13`. It forms an acidic oxide which `KOH` forms a salt isomorphous with `K_(2)SO_(4)`. The `Aw` of element is a. `13`, b. `26`, c. `52`, d. `78`A. 13B. 26C. 52D. 78

Answer» Correct Answer - D
`K_(2) MSO_(4)` and `K_(2)SO_(4)` are isomorphous. Valency of `S` and `M` should be same `= 6`
Atomic weight `= Ew xx` Valency `= 13.00 xx = 78`
492.

The vapour density of a mixture containing equal number of moles of methane and ethane at `STP` isA. `11.5`B. `11.0`C. 23D. `12.0`

Answer» Correct Answer - A
Molar mass of mixture will be
`M_(mix)=(nxx"Molar mass of "CH_(4)+nxx"Molar mass of "C_(2)H_(6))/(n+n)`
`M_(mix)=(n(16+30))/(2n)=23`
Vapour density `rArr (M_(mix))/(2)=(23)/(2)=11.5`
493.

For a reaction, `N_(2)(g) + 3H_(2)(g) to 2NH_(3)(g)` , identify dihtdrogen `(H_(2))` as a limiting reagent in the following reaction mixtures.A. `14g of N_(2) + 4g of H_(2)`B. `28g of N_(2) + 6g of H_(2)`C. `56g of N_(2) + 10g of H_(2)`D. `35g of N_(2) + 8g of H_(2)`

Answer» Correct Answer - C
494.

A mixture of gases liberated upon decomposition of 33.1 gm of lead (II) nitrate is dissolved in 10 ml of water. What is the mass (in g) of 0.1 M KOH solution with density of 1.05 g/ml required to neutralize this acid. The reactions are: `2Pb(NO_(3))_(2)rarr2PbO+4NO_(2)+O_(2)` `KOH+HNO_(3)rarrKNO_(3)+H_(2)O` [Atomic mass of Pb=207]

Answer» Correct Answer - 2100
495.

The measured density at STP of He is 0.1762 g/L. What is the weightof one mole of He?

Answer» Correct Answer - 4
496.

Calculate the number of moles of ammonia required to produce 2.5 moles of `[Cu(NH_(3))_(4)]SO_(4).`

Answer» Correct Answer - 10
497.

Preparation of `Na_(2)SnO_(2)` involves the following set of reactions : `[Sn=119]` `(P) Sn+2HClrarrSnCl_(2)+H_(2)` `(Q)SnCl_(2)+2NaOHrarrSn(OH)_(2)+2NaCl` `(R)Sn(OH)_(2)+2NaOH rarrNa_(2)SnO_(2)+2H_(2)O` If `%` yield of reaction `(P),(Q),(R) 25 %,50 %,40 %` respectively. Calculate the mass of Sn (in kg required to produce 19.7 kg of `Na_(2)SnO_(2)`.

Answer» Correct Answer - 238
498.

A `6.90 M` solution of `KOH` contains 30% by weight of `KOH`. Calculate the density of the solution.

Answer» `M = (% "by weighy" xx 10 xx d)/(Mw_(2))`
`6.9 = (30 xx 10 xx d)/(56)`
`d = 1.288 g mL^(-1)`
499.

In 2.6 gm of `FeSO_(4).6H_(2)O` (At wt of fe =56):A. No. of atoms of O are `100 xx N_(A)`B. Moles of H atoms are `120 xx N_(A)`C. Molecules of water are `60 xx N_(A)`D. Moles of `e^(-)` present in `SO_(4)^(2-)` are 500

Answer» Correct Answer - A::C::D
500.

Calculate the volume of `O_(2)` and volume of air needed for combustion of `1 kg` carbon at `STP`.

Answer» `underset(12 g)(C) + underset(32 g)(O_(2)) rarr CO_(2)`
`12 g` of `C implies g` of `O_(2) = 1 mol` of `O_(2) = 22.4 L` at `STP`
`1000 g` of `C = (22.4 xx 1000)/(12) = 1866.67 L "of" O_(2)`
Air contains `= (20 % "of" O_(2) + 80% "of N_(2))`
Volume of air = 5 times volume of `O_(2) = 5 xx 1866.67`
`= 9333.33 L`