This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
The best combination of reagents for carrying out the conversion RCH_(2)CH_(2) OH rarr RCH_(2)CH_(2)COOH is |
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Answer» `PBr_(3), KCN, H_(3)O^(+)` |
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| 2. |
The best and latest technique for isolation, purification and separation of organic compound is : (a) Crystallisation (b) Distillation (c) Sublimation (d) Chromatography |
| Answer» SOLUTION :CHROMATOGRAPHY. THUS, OPTION (d) is CORRECT. | |
| 3. |
The best and latest technique for isolation, purification, and separtion of organic compounds is |
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Answer» crystallisation |
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| 4. |
The best and latest technique for isolation, purification and separation of organic compound is: |
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Answer» CRYSTALLISATION |
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| 5. |
The behaviour of temporary gases like CO_(2) approaches that of permanent gases like N_(2), O_(2), as we go |
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Answer» Below CRITICAL temperature |
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| 6. |
The benzene molecule has two different carbon - carbon bond lengths, corresponding to alternate single and double bonds. |
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Answer» |
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| 7. |
Thebelow configuration is not correct as it violates . |
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Answer» Only Hund's RULE |
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| 8. |
The behaviour of temporary gases like CO_(2)approaches that of permanent gases like N_(2), O_(2)etc. as we go |
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Answer» Below critical temperature |
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| 9. |
The behaviour of matter in different states is governed by various physical laws. According to you what are he factors that determine the state of matter ? |
| Answer» Solution :TEMPERATURE, pressure, mass and VOLUME are the factors which FOLLOWS the different STATES of matter. i.e., solid, liquid and gas. | |
| 10. |
The behaviour of ideal gas is goverened by various gas laws which are described by mathematical statements as given below: (i) PV=k (constant) at constant n and T (ii) V//T=k_(2) (constant) at constant n and P (iii) V//n=k_(3) (constant) at constant T and P (iv) PV=nRT (v) P//T=k_(4) (constant) at constant n and V Answer the following The value of k_(2) is |
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Answer» <P>INDEPENDENT of nature and AMOUNT of gas |
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| 11. |
The behaviour of matter in different states is governed by various physical laws. According to what are the factors that determine the state of mater? |
| Answer» SOLUTION :The factors that determine the state of MATTER are pressure, TEMPERATURE, MASS and volume. | |
| 12. |
The behaviour of an electron in an atom is described mathematically by a wave function, or orbital.Spin of the electron produce angular momentum equal to S= sqrt(s(s+1)) (h)/(2pi)where S= +1/2. Total spin of an atom=+ n/2orh/2 Where n is the number of unpaired electron. The substance which contain species with unpaired electrons in their orbitals behave as paramagnetic substances. The paramagnetism is expressed in terms of magnetic moment the magnetic moment of an atom mu_s sqrt(s(s+1)) (eh)/(2pi mc) = sqrt((n/2)(n/2+1)) (eh)/(2pi mc) s = n/2 impliesmu_s = sqrt(n(n+2)) B.M n = number of unpaired electrons 1 B.M. (Bohr magneton) = (eh)/(4pi mc) If magnetic moment is zero the substances is di-magnetic. If an ion of ""_(25)Mn has a magnetic of 3.873 B.M. Then Mn is in which state. |
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Answer» SOLUTION :`sqrt(n(n+2)) = 3.813 B.M.` n= 3, no. of unpaired `E^-` =3 |
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| 13. |
The behaviour of an electron in an atom is described mathematically by a wave function, or orbital.Spin of the electron produce angular momentum equal to S= sqrt(s(s+1)) (h)/(2pi)where S= +1/2. Total spin of an atom=+ n/2orh/2 Where n is the number of unpaired electron. The substance which contain species with unpaired electrons in their orbitals behave as paramagnetic substances. The paramagnetism is expressed in terms of magnetic moment the magnetic moment of an atom mu_s sqrt(s(s+1)) (eh)/(2pi mc) = sqrt((n/2)(n/2+1)) (eh)/(2pi mc) s = n/2 impliesmu_s = sqrt(n(n+2)) B.M n = number of unpaired electrons 1 B.M. (Bohr magneton) = (eh)/(4pi mc) If magnetic moment is zero the substances is di-magnetic. Which of the following ion has lowest magnetic moement. |
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Answer» `Fe^(2+)` |
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| 14. |
The behaviour of an electron in an atom is described mathematically by a wave function, or orbital. It turns out that each wave function contains three variables, called quantum numbers, which are represented as n, l and m_1. These quantum numbers describe the energy level of an orbital and define the shape and orientation of the region in space where the electron will be found.Radial nodes are maximum in |
| Answer» Solution :RADIAL NODES = n-l-1 | |
| 15. |
Which quantum number describes the orientation of the orbital in space ? |
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Answer» PRINCIPAL |
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| 16. |
The beauty of Tajmahal is getting destroyed due to |
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Answer» GLOBAL wanning |
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| 18. |
The basis of modern periodic law is |
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Answer» ATOMIC NUMBER |
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| 19. |
The basis building unit of silicates is "………….." . |
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Answer» |
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| 20. |
The basic structural unit of silicates is |
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Answer» `SiO_(3)^(2-)` |
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| 21. |
The basic structural unit in silicates is |
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Answer» `SiO_(2)` |
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| 22. |
The basic reaction involved in the synthesis of linear silicones is |
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Answer» the HYDROLYSIS of TRIMETHYL CHLOROSILANE |
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| 23. |
The basic principle of Cottrel's precipitator is |
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Answer» neutralization of charge on COLLOIDAL particles |
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| 24. |
The basic chartacter of the alkaline earth metal hydroxides is as follows: |
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Answer» `Mg(OH)_(2)gtBa(OH)_(2)gtCa(OH)_(2)gtSr(OH)_(2)` |
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| 25. |
The basic character of oxides MgO, SrO, K_(2)O, NiO, Cs_(2)O increase in the order |
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Answer» `MGO gt SRO gt K_(2)O gt NIO gt Cs_(2)O` |
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| 26. |
The band formed from atomic orbitals of lower energy is called ___________ while that formed from atomic orbitals of higher energy is called ________ |
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Answer» |
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| 27. |
The Balmer series in the hydrogen spectrum corresponds to the transition from n_(1) = 2 " to " n_(2) = 3, 4... This series lies in the visible region. Calculate the wave number of line associated with the transition in Balmer series when the electron moves to n = 4 orbit (R_(H) = 109677 cm^(-1)) |
| Answer» Solution :`bar(v) = 109677 cm^(-1) ((1)/(n_(1)^(2)) - (1)/(n_(2)^(2))) = 109677 XX ((1)/(2^(2)) - (1)/(4^(2))) = 109677 ((1)/(4) - (1)/(16)) cm^(-1) = 20564.4 cm^(-1)` | |
| 28. |
The Balm er series in the hydrogen sp ectru m corresponds to the transition from n_(1) = 2 to n_(2) = 3, 4,........This series lies in th e visible region. Calculate the wave num ber of line associated with the tran sitio n in Balm er series w hen the electron m oves to n = 4 orbit. (R_(H) = 109677 cm^(-1) ) |
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Answer» Solution :`barv=109677 [(1)/(n_(i)^(2))-(1)/(n_(f)^(2))]cm^(-1)` so `n_(i) =2 to n_(f) =4` TRANSITION in BALMER series `=109677 (1/4-1/16)cm^(-1) =20564.44 cm^(-1)` |
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| 29. |
The balanced equation for a reaction is given below 2x + 3y rarr 41 +m When 8 moles of x react with 15 moles of y, then Which is the limiting reagent ? (b) Calculate the amount of products formed. Calculate the amount of excess reactant left at the end of the reaction. |
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Answer» Solution :2X + y `RARR` 41 + m (i) 2x reacts with 3y to give products. 8x reacts with 15Y means, y is the excess because 8 moles of x should react with `4 xx 3y = 12y` moles of y to give products. Therefore, 3 moles of y is excess and x is the limiting agent. When 8 moles of x react with 12 moles of y, the product formed will be `4 xx 4l` i.e. 161 and 4m as product. `8x + 2y rarr 161 + 4m` At the end of the REACTION, the excess reactant left is 3 moles of y. |
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| 30. |
The balanced equation for a reaction is given below 2x + 3y rarr 4l + m When 8 moles of x react with 15 moles of y, then(i) Which is the limiting reagent?(ii) Calculate the amount of products formed.(iii) Calculate the amount of excess reactant left at the end of the reaction. |
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Answer» Solution :`2x + 3y rarrt 41 + m` (i) 2x reacts with 3y to give products. 8X reacts with 15y means, y is the excess because 8 moles ofx should react with 4 `XX` 3y = I2y moles of y to give products. In this reaction 15y moles are used. Therefore, 3 moles of y is excess and x is the limiting agent. (II) When 8 moles of x react with 12 moles of y, the PRODUCT formed will be 4 `xx` 41 i.e. 161 and 4m as product. 8x + 12y `rarr` 161 + 4m (iii) At the end of the reaction, the excess reactant left is 3 moles of y |
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| 31. |
The azetrophic mixture of water (b.pt. 100^(@)C) and HCl (b.pt. 85^(@)C) boils at 108.5^(@)C. What this mixture is distilled, it is possible to obtain : |
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Answer» PURE HCL |
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| 32. |
The azimuthal quantum number for the last electron in sodium atom is |
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Answer» 1 |
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| 33. |
The azimuthal quantum number indicates …..of the orbital |
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Answer» Size |
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| 34. |
The average velocity of nitrogen at 27^@C is 0.3ms^(-1). At what temperature it will be 0.6 ms^(-1)? |
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Answer» Solution :Average VELOCITY is given as `bar(C) = sqrt((8RT)/(PI M))` The RATIO of velocities at two different temperatures for the same GAS is given as`(bar(C_1))/(bar(C_2)) = sqrt((T_1)/(T_2))` Substituting the values, the ratio is `= (0.3)/(0.6) = sqrt((300)/(T_2)) = 1/2` The TEMPERATURE, `T_2 = 2^2 xx 300 = 1200 K = 927^@C`. |
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| 35. |
Theaverage velocity ofgas molecules is 400 m//sec. Calculate its rms velocity at the same temperature . |
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Answer» Solution :Average SPEED , `v=sqrt((8 RT)/(pi M))` Root mean square speed, `u=sqrt((3 RT)/(M))` `:. (u)/(v)=sqrt((3 RT)/(M)XX(PIM)/(8 RT))=sqrt((3pi)/(8))=sqrt((3xx3.143)/(8))=1.085` `:. u=1.085xxv=1.085xx400 m s^(-1)=434 m s^(-1)`ordirectly, v=0.921 u, i.e., `u=1.085xxv` |
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| 36. |
The average velocity of gas is 2.9 xx 10^4 cms^(-1).Calculate the RMS and most probable velocities of the gas. |
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Answer» |
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| 37. |
Theaverage velocity of an ideal gas molecule at 300 K is 2 m//s. The average velocity at 1200 Kwill be |
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Answer» Solution :(B) `v_(av)=sqrt((8RT)/(PIM))rArrv_(av)propsqrtT` `(2)/(V_(2))=sqrt((300)/(1200))=sqrt((1)/(4))=(1)/(2)rArrv_(2)=4 m//s` |
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| 38. |
Isotherms of carbon dioxide at various temperatures are repersented in figure. Answer the following questions based on this figures. (i) In which state will CO_(2) exist between the points a and b at temperature T_(1) ? (ii) At what point will CO_(2) start liquefyinh when temperature is T_(1) ? (iii) At what point will CO_(2) be completely liquefued when temperature is T_(2) ? (iv) Will condensation take place when the temperature is T_(3) ? (v) What portion of the isotherm at T_(1) represent liquid and gaseous CO_(2) at equilibrium ? |
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Answer» `BARU =sqrt((8RT)/(piM))` In the present case, `baru =9.0xx10^4 " cm " s^(-1)`, `R=8.314xx10^7 " erg " K^(-1) mol^(-1)` `T=T_1 (?) and M=44` `:. "" 9.0xx10^4=sqrt((8xx8.314xx10^7xxT_1)/(3.14xx44))` HENCE, `T_1 = 1682.5 K`. The most probable velocity is given by `ALPHA = sqrt((2RT)/M)` `:. "" 9.0xx10^4=sqrt((2xx8.314xx10^7xxT_2)/(44))` Which gives `T_2 = 2143.3 K`. |
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| 39. |
The average person can see the red colour imparted by the complex [Fe(SCN)]^(2+) to an aqueous solution if the concentration of the complex is 6xx10^(-6) M or greater.What minimum concentration of KSCN would be required to make it possible to detect 1 ppm (part per million) of Fe(III) in a natural water sample ? The instability constant for Fe(SCN)^(2+)hArrFe^(3+)+SCN^(-) "is"7.142xx10^(-3) |
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Answer» `0.0036 M` |
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| 40. |
The average speed at T_1 K and most probable speed at T_2K of CO_2 gas is 9 xx 10^4 cm/sec. The values of T_1 and T_2 are |
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Answer» 2143K, 1694K |
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| 41. |
The average particle mass in colloidal solutions can be determined by |
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Answer» elevation in boiling point |
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| 42. |
The average oxidation number of iron in Fe_(3)O_(4) (ferrousferic oxide) is ____ |
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Answer» `+2` `therefore3(FE)+4(O)=0` `therefore3(X)+4(-2)=0` `therefore3x-8=0` `therefore3x=8` `thereforex=8/3` OXIDATION of Fe |
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| 43. |
The average molecular velocity in a gas sample at 300K is 500m/s. The temperature of this gas is increased until the average velocity of its molecules is 1000m/s. what is the new temperature? |
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Answer» 420K |
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| 44. |
The average life of a excited state of hydrogen atom is of the order of 10^(-8)sec. the number of revolutions made by an electron when it returns from n=2 to n=1 is: |
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Answer» `2.28xx10^(6)` |
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| 45. |
The average kinetic energy of one molecule of an ideal gas at 27^(@)C and 1 atm pressure is: |
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Answer» `900 cal K^(-1) mol^(-1)` `= (3)/(2) xx (8.314)/(6.023 xx 10^(23)) xx 300` `= 6.21 xx 10^(-21) J K^(-1) "molecule"^(-1)` |
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| 46. |
The average kinetic energy of gas molecules is directly proportional to the……………….. |
| Answer» SOLUTION :KELVIN TEMPERATURE | |
| 47. |
The average kinetic energies of helium (mol.wt.4), methane (mol.wt.16) and sulphurdioxide (mol.wt.64), at certain temperature are respectively x, y and z kJ mol^(-1) . The ratio of x, y and z is |
| Answer» Answer :C | |
| 48. |
The average kinetic energy of a gas molecule at 0^(@)C is 5.621xx10^(-27)J. Calculate Boltzman constant. Also calculate the number of molecules present in one mole of the gas. |
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Answer» Solution :Average kinetic ENERGY `KE=3/2kT` `:.k=2/3xx(KE)/^=2/3xx(5.621xx10^(-21)J"MOLECULE"^(-1))/(273K)=1.373xx10^(-23)JK^(-1)"molecule"^(-1)` No. of molecules in 1 mole of the gas (Avagadro.s no.) `=R/k` `:.R/k=(8.314JK^(-1)"MOL"^(-1))/(1.373xx10^(-23)JK^(-1)"molecule"^(-1))=6.05xx10^(23)"molecules mol"^(-1)` |
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| 49. |
The average kinetic energy of a gas molecule is given by |
| Answer» Answer :B | |