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27501.

The normality of 10% (weight/volume) acetic acid is

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1 N
10 N
1.7 N
0.83 N

Solution :`N=(w xx1000)/(Eq.wt. XX "VOLUME")=(10xx1000)/(60xx100)=1.66 N`.
27502.

The molal elevation/depression constant depends on

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NATURE of SOLVENT
nature of solute
temperature
Delta H solution

Solution :It is a CHARACTERISTICS of GIVEN solvent.
27503.

The normality of 10 mL of a 20 V H_(2)O_(2) is

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`1.79`
`3.58`
`60.86`
`6.086`

ANSWER :B
27504.

The molal elevation constant of water is …………… while that of benzene is ………………. .

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SOLUTION :`"0.52 K KG MOL"^(-1)," 2.53 K kg mol"^(-1)`
27505.

The normality of 10% ( weight/volume) acetic acid is :

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1 N
1.7 N
0.83 N
10 N

SOLUTION :Wt. of ACETIC ACID `=10G`.
Equivalents of acetic acid `=10/60`,
Vol. of solution `=100 ml`
Molarity `=(10xx1000)/(60xx100)=1.7` N
27506.

The molal elevation constant of water is 0.51. The boiling point of 0.1 molal aqueous NaCl solution is nearly:

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`100.05^@C`
`100.1^@C`
`100.2^@C`
`101.0^@C`

ANSWER :A
27507.

The Normality of 0.98% (w/v) H_2SO_4 solution is

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`0.1MN`
`0.2N`
`0.4N`
1N

Answer :B
27508.

The normality of 10 lit. volume hydrogen peroxide is

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`0.176`
`3.52`
`1.78`
`0.88`

SOLUTION :`H_(2)O_(2)to H_(2)O+(1)/(2)O_(2)`
`1 M H_(2)O_(2)` solution = 2N = 34 gm/litre = 11.2
So Normality `=(2XX10)/(11.2)=17.8`
27509.

The normality of 0.3 M phosphorus acid (H_(3)PO_(3)) is

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0.1
0.9
0.3
0.6

Answer :D
27510.

The molal elevation constant of water = 0.52^(@)C kg mol^(-1). The boiling point of 1.0 molal aqueous KCl solution (assuming complete dissociation of KCl), therefore, should be

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`100.52^(@)C`
`101.04^(@)C`
`99.48^(@)C`
`98.96^(@)C`

Solution :`Delta T_(B) =imk_(b)=0.52xx1xx2=1.04`.
`THEREFORE T_(b)=100+1.04=101.04^(@)C`.
27511.

The normal boiling point of watr is 373 K (at 760 mm), vapour pressure of water at 298 K is 23 mm. If entyalpyof vaporization is 40.656 kj//mol.the boiling point of water at 23 mm pressure will be :

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<P>250 K
`294.4 K`
`51.6 K`
`12.5 K`

Solution :From Clausius- CLAPEYRON equation.
`"log" (P_(2))/(P_(1))=(DeltaH_(v))/(2.303R)[(T_(2)-T_(1))/(T_(1)T_(2))]`
`rArr"log" (760)/(23)=(40656)/(2.303xx8.314)[(373-T_(1))/(373xxT_(1))]`
`:.T_(1)=294.4K`.
Hence, (B) is the correct answer.
27512.

The molal elevation constant of water = 0.52 K, molality^-1. The boiling point of 1.0 molal aqueous KCl solution (assuming complete dissociation of KCl), should be:

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`100.52^@C`
`101.04^@C`
`99.48^@C`
`98.96^@C`

ANSWER :B
27513.

The normal K_a for carboxylic acids is of the order of:

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`10^-5`
`10^-8`
`10^-3`
`10^-2`

ANSWER :A
27514.

The molal elevation constant is the ratio of the elevation in B.P. to

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MOLARITY
MOLALITY does not CHANGE with TEMPERATURE
Mole fraction of solute
Mole fraction of solvent

Solution :`Delta T_(B)=K_(b)xx m` or `K_(b) = Delta T_(b)//m`
27515.

The normal boiling point of water is 373K . Vapour pressure of water at temperature T is 19 mmHg . If enthalpy of vaporization is 40.67 kJ//"mol", then temperature T would be

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250 K
291.4 K
230 K
290 K

ANSWER :B
27516.

The molal elevation constant is the ratio of the elevation in boliing point to

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Lmolarity
MOLALITY
MOLE FREACTION of solute
Mole FRACTION of solvent

Answer :B
27517.

Thenormalboilingpointofpurewateris373 K. Calculatetheboilingpoint ofthe solutioncontaining2.0 xx 10^(-2)kg ofglucosein 0.5 kg of water(K_(3) for wateris 0.52 k kg mol^(-1))

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SOLUTION :373 .0116K
27518.

The normal boiling point of a liquid 'X' is 400 K.Which of the following statement is true about the process X(l)toX(g) ?

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At 400 K, and 1 atm pressure `DeltaG=0`
At 400 K, and 2 atm pressure `DeltaG=+ve`
At 400 K, and 1 atm pressure `DeltaG=0`
At 400 K, and 1 atm pressure `DeltaG=0`

Solution :Boiling of a liquid at normal boiling point is a equilibrium process and on decreasing the pressure equilibrium will go FORWARD and `DeltaG` will be NEGATIVE and vice-versa.
27519.

The molal elevation constant for water is 0.52 K. "molality"^(-). The elevation caused in the boiling point of water by dissolving 0.25 mole of a non volatile solute in 250 g of water will be :

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`52^(@)`
`5.2 ^(@)C`
`0.52^(@)C`
`0.052 ^(@)C`

Solution :`(Delta T_(f)=1000 XX K_(f))/W_(1) xx W_(2)/M_(2)=(1000 xx K_(f))/W_(1)xx n`
`Delta T_(f) = (1000 xx 0.52)/250 xx 0.25 =0.52^(@)C`
27520.

The molal depression constant of water is …………….while that of benzene is ……………… .

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SOLUTION :`"1.86 K KG MOL"^(-1),"5.12 K kg mol"^(-1)`
27521.

The normalboilingpoint of a liquild'A' is350 K.DeltaH_(vap) to benormal pointis35kJ//mole. Pick outthe correctstatement(s).(Assume DeltaH_(vap) to beindependentof pressure ).

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`DeltaS_("vaporisation")gt 10 J//K "MOLE" "at350 K and 0.5 atm"`
`DeltaS_("vaporisation")lt 10 J//K "mole" "at350 K and 0.5 atm"`
`DeltaS_("vaporisation")lt 10 J//K "mole" "at350 K and 2 atm"`
`DeltaS_("vaporisation")=10 J//K "mole" "at350 K and 2 atm"`

Solution :N//A
27522.

The molal elevation constant for water is 0.52 K.molality^-1. The elevation caused in the boiling point of water by dissolving 0.25 mole of a non-volatile solute in 250 g of water will be:

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`52^@C`
`5.2^@C`
`0.52^@C`
`0.052^@C`

ANSWER :C
27523.

The normal boiling point of a liquid ‘A’ is 350 K. DeltaH_("vap") at normal boiling point is 35 kJ/mole. Pick out the correct statement (s). (Assume DeltaH_("vap") to be independent of pressure).

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`DeltaS_("VAPORISATION")gt100` mole at 350 K and 0.5 atm
`DeltaS_("vaporisation")lt100` J/K mole at 350 K and 0.5 atm
`DeltaS_("vaporisation")lt100` J/K mole at 350 K and 2 atm
`DeltaS_("vaporisation")=100` J/K mole at 350 K and 2 atm

Answer :A::C
27524.

The molal depreesion constant of water is 1.86^(@)C//m. Then find out the freezing point of 0.1 m NaCl solution.

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`-1.86^(@)C`
`0.372^(@)C`
`-0.372^(@)C`
`-0.186^(@)C`

SOLUTION :For NACL, i = 2
`Delta T_(f)=2K_(f).m`
`= 2xx1.86xx0.1=0.372`
`T_(s)=T-Delta T_(f)=0-0.372=-0.372^(@)C`.
27525.

The molal depression constant for a solvent is 4.9. The depression in freezing point for a millimolal solution of a non-electrolyte in the solvent is

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0.49
4.9
4.9 + 0.001
0.0049.

Solution :`DELTA T_(f) = K_(f) XX m=4.9 xx 10^(-3)=0.0049`
27526.

The normal amount of glucose in 100 mL of blood (8-12hours after a meal) is:

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8 mg
80 mg
200 mg
800 mg

Answer :B
27527.

The no.of statements is// are correct ?

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SOLUTION :a ,b , d are correct . In C species can be inside or outside the COORDINATION sphere to satisfy the oxidation STATE .
27528.

The no.of chloride ions co-ordinated to Fe^(+3) ion is hydrated FeCl_3. 6H_2O

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SOLUTION :`[FE(H_2O)_4Cl_2]Cl.2H_2O`
27529.

The molal cryoscopic for water is 1.86 "K mol"^(-1). When 3.42 g of sugar ( molar mass = 342) is dissolved in 100 g of water, the solution will freeze at

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`1.86^(@)C`
`0.186^(@)C`
`-0.186^(@)C`
`0.914^(@)C`

Solution :`DeltaT_(F)=(K_(f)xx W_(B)xx1000)/(W_(A)xxM_(B))`
`=(1.86xx3.42xx1000)/(100xx342)=0.186`
Freezing point of solution `=0-0.186`
`=-0.186^(@)C`
27530.

The molal cryoscopic constant for water is:

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1.86 K `molality_(-1)`
5.26 K `molality_(-1)`
55.5 K `molality_(-1)`
0.52 K `molality_(-1)`

ANSWER :A
27531.

The molal cryoscopic constant for water is

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`1.86 K "molality"^(-1)`
5.26 K `molality_(-1)`
`55.5 K "molality"^(-1)`
`0.52 K "molality"^(1)`

Solution :It is the numerical VALUE of molal CRYOSCOPIC constant for WATER. It CHANGES with change of solvent.
27532.

The non-fusible impurities of ores are removed by adding :

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Flux
Slag
Gangue
None

Answer :A
27533.

The molal boiling point constant for water is0.513^(@)C kgmol^(-1). When 0.1mole of sugar is dissolved in 200ml of water , the solution boils under a pressure of one atmosphere at

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`100.513^(@)C`
`100.0513^(@)C`
`100.256^(@)C`
`101.025^(@)C`

Solution :`DELTA T_(B)=K_(b)xx m =0.513xx((0.1)/(200)xx1000)`
`=0.2565^(@)C, T_(b)=100.256^(@)C`
27534.

The non - stoichiometric iron oxide has a composition Fe_(0.94) O. Find the ratio of ferrous and ferric ions present in it.

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Solution :SAY one hundred ions of each `Fe^(2+) and O^(2-)` present in the stoichiometric `FEO`. Some of `Fe^(2+)`ions (x) are REPLACED by `Fe^(3+)`ions (y).
In view of the conservation of ions in an ionic crystal,
`x+y=94 ""…(1)`
In view of the conservation of positive charge of cations in a crystal,
`2x+3y = 200""...(2)`
Solving, for .x. and for .y.,
`y=12 and x=82`
The ration of `Fe^(2+) and Fe^(3+)` ions present in `Fe_(0.94) O =82 : 12`
`= 41:6`
27535.

The non-viable particulate among the following is

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DUST
bacteria
moulds
fungi

Solution :Dust
27536.

The molal boiling point constant of water is 0.53^@C. When 2 mole of glucose are dissolved in 4000 g of water, the solution will boil at:

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`100.53^@C`
`101.06^@C`
`100.265^@C`
`99.47^@C`

ANSWER :C
27537.

The non-proteinaceous substances which certain enzymes require for their activity are called:

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Catalysts
Inhibitors
Co-enzymes
Epimers

Answer :C
27538.

The Mn_3O_4formed on strong heating of a sample of MnSO_4 . 4H_2Owas dissolvedin 100 cm of 0.1 N FeSO_4containing dilute H_2SO_4 . The resulting solution reacted completely with 50 cm^3of KMnO_4solution. 25 cm^3of this KMnO_4solution required 30 cm^3of 0.1 N FeSO_4solution for complete reaction. Calculate the amount of MnSO_4 . 4H_2Oin the sample.

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SOLUTION :1.338 G
27539.

The non-protein component in enzymes which is necessary for its biological activity is :

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LIPIDS
COENZYMES
Nucleic acid
Phosphoric acid.

Answer :B
27540.

The modern basis of atomic weight is

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Isotope `H^(1) = 1.000`
Oxygen `= 16.000`
Isotope `O^(16) = 16.000`
Isotope `C^(12) = 12.000`

Solution :Isotope `C^(12)` is the MODERN basis of atomic weight.
27541.

The MnO_(4)^(-) ion is coloured though Mn(+7) has a d^(0) configuration due to the _________ of electrons from __________ to __________.

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SOLUTION :TRANSFER, OXYGEN, MANGANESE
27542.

The non-nutritive sweetener is

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saccharine
sucrose
fructose
glucose

Answer :A
27543.

The non-metallic element whose molecules contain maximum number of its atom is:

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O
Si
As
P

Answer :D
27544.

The non-metal whose oxide is a good dehydrating agent is:

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S
Cl
N
P

Answer :D
27545.

The mixtureof n-hexane and n-heptane is an example of :

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IDEAL SOLUTION
None-ideal solution
Dilute solution
Real solution

Answer :A
27546.

The non-metal which is not affected ny NaOH:

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C
Si
P
S

Answer :A
27547.

The mixture that forms maximum boiling azeotrope is :

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HEPTANE + Octane
WATER + Nitric acid
Ethanol + Water
Acetone + Carbon disulphide

SOLUTION :Negative DEVIATED mixture from IDEAL behaviour can form maximum boiling azeotrope.
Water + Nitric acid shows negative deviation.
27548.

The non-metal that usually occupies tetrahedral voids in the formation of interstetial compounds

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HYDROGEN
Boron
Carbon
Sulphur

Answer :A
27549.

The mixture of which of the following is called "Matte"?

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`FeO and SiO_2`
`PbS and Zns`
`Cu_2S and FeS`
`Cu_2S and SO_2`

ANSWER :C
27550.

The non metal which exists in liquid state at room temperature is:

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Na
Br
Mg
Ga

Solution :Bromine is non METAL which EXISTS in liquid STATE at room TEMPERATURE.