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28901.

The lowest degree of paramagnetism per mol of the compound in the following will be shown by :

Answer»

`MnSO_4cdot4H_2O`
`ZnSO_4cdot7H_2O`
`FeSO_4cdot7H_2O`
`NiSO_4cdot6H_2O`

ANSWER :B
28902.

The lowest bond energy exist in the following bonds for:

Answer»

C-C
N-N
H-H
O-O

Answer :D
28903.

The lowering of vapour pressure of the solvent takes place

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only when the solute is non-volatile
only when the solute is volatile
only when the solute is a non-electrolyte
in all the above THREE cases.

Solution :Lowering of V.P. of SOLVENT TAKES place-the solute MAY be volatile, non-volatile or electrolyte or non-electroyte.
28904.

The lowering of vapour pressure in a saturated aq. Solution of salt AB is found to be 0.108 torr. If vapour pressure of pure solvent at the same temperature is 300 torr, find the solubility product of salt AB.

Answer»

`10^(-8)`
`10^(-6)`
`10^(-4)`
`10^(-5)`

ANSWER :C
28905.

The lowering of vapour pressure of a solvent by the addition of a non-volatile solute to it , is directly proportional to :

Answer»

The STRENGTH of the SOLUTION
The nature of the solute in the solution
The ATMOSPHERIC pressure
All

Answer :A
28906.

The lowering of vapour pressure of 0.1M aqueous solutions of NaCl, CuSO_4, and K_2SO_4 are:

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All equal
In the RATIO of 1 : 1 : 1.5
In the ratio of 3 : 2 : 1
In the ratio of 1.5 : 1 : 2.5

Answer :B
28907.

The lowering in vapour pressure when a solute is added

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Will depend uponthe nature of the SOLUTE
Will be the same irrespective of the solvent TAKEN
Will be DIFFERENT when different solvent are taken
Will depend on the form IDEAL solution

Solution :Explanation : (a) `Delta P=oP_(A)^(@)x_(B)`
(a) Hence, `Delta F` depends upon i which is dependent on nature of solute (Hence, choice (a) is correct).
(c ) `Delta F` depends upon `P_(A)^(@)`. If `P_(A)^(@)` changes then `Delta F` changes. Hence when different solvents are taken `Delta F` value is different. Choice (c ) is also correct.
(d) Is also correct. `Delta F` changes with mole fraction of solute. `Delta F` also changes with TEMPERATURE.
(b) Is wrong because `Delta F` depends upon solvent.
28908.

The low solubility of BaSO_(4) in water is due to

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Low DISSOCIATION ENERGY
Ionic bonds
High VLAUE of LATTICE energy
NONE of these

Answer :C
28909.

The low solubility of BaSO_4 in water is due to:

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Ionic BOND in `BaSO_4`
LOW lattice ENERGY of `BaSO_4`
High lattice energy of `BaSO_4`
Dissociation energy of `BaSO_4`

ANSWER :C
28910.

The low bond energy of F_(2) is explained by :

Answer»

the attainment of noble gas configuration `(F^(-))`
the low electron AFFINITY of F
repulsion by electron PAIRS on F
the SMALL size of F.

Answer :C
28911.

The longest lambda for the Lyman series is…. (Given R_H=109678 cm^(-1)):

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1215
1315
1415
1515

Answer :A
28912.

The long form of periodic table is based on

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SHAPE of the atom
Mass of the atom
Atomic NUMBER of the atom
Electronegativity

ANSWER :C
28913.

The long form of periodic table has

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Eight horizontal ROWS and seven VERTICAL columns
Seven horizontal rows and EIGHTEEN vertical columns
Seven horizontal rows and seven vertical columns
Eight horizontal rows and eight vertical columns

Answer :B
28914.

The lone pair present on N family hydrides more easily participates in bond formation in:

Answer»

`AsH_3`
`PH_3`
`NH_3`
`SbH_3`

ANSWER :C
28915.

Thelogarithmof rateconstant of areaction

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decreaseslinearlywithincreasein inverseoftemperature
INCREASES linearlywithincreasesin INVERSE oftemperature
increases linearlywithincreasesin TEMPERATURE
Decreaseslinearly withincreases in temperature

Solution :STATEMENT
28916.

The lisat product (B) formed in the following reaction is

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`CH _3-CH_2-Br+ Mg ---rarr( ^dry ETHANOL) A --rarr(^CH_3COOH) B `
`CH_3- CH_2-OH`
`CH_3- CH_3`
`CH_3 -- CH_2 -- COOH`

ANSWER :C
28917.

The liquids A and B have vapour pressure 500 and 200 torr respectivelyat a certain temperature . In an ideal solution of the two , the mole fraction of A in vapour state, at which two liquids have equal partial pressure is

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0.5
0.2
0.286
0.714

Answer :A
28918.

The liquid which has the highest rate of evaporation is

Answer»

petrol
nail-polish remover
water
alcohol

Solution :As intermolecular forces are least in case of petrol. THUS, it has highest rate of EVAPORATION.
28919.

The liquid is in equlibrium with its vapoursat its boiling point. On the average, the molecules in the two phases have equal

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POTENTIAL energy
total energy
KINETIC energy
intermoleclar forces

Solution :At the boilding POINT the liquid and its vapiour have EQUAL kinetic energies.
28920.

The liquid hydrazinium is denoted as

Answer»

`N_2H_4`
`N_2H_5^+`
`N_2H_3^-`
`N_2H_3^+`

ANSWER :B
28921.

The liquefaction behaviour of temporary gases like CO_(2) approaches that of permanent gases like N_(2),O_(2) etc, as we go to

Answer»

below CRITICAL temperature
above critical temperature
above ABSOLUTE zero
below absolute zero

Answer :B
28922.

The linkage present in two nucleotide is

Answer»

AMIDE linkage
peptide linkage
phosphodiester linkage
glycosidic linkage

Answer :C
28923.

The linkage between the two monosaccharide units in lactose is

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`C_(1)`of `BETA`-D-glucose and `C_(4)` of `beta`-D-glactose
`C_(1)` of `beta`-D-galactose and `C_(4)` of `beta-`D-glucose
`C_(1)` of `alpha`-D-galactose and `C_(4)`of `beta`-D-glucose
`C_(1)` of `beta`-D-glactose and `C_(4)` of `alpha`-D-glucose

Solution :Lactose is obtained by the condensation of one molecule of `beta`-D-glactopyranose (`C_(1)-beta)` unit and one molecule of `beta`-D-glycopyranose `(C_(4)-beta)` units.
28924.

The liner structure is not assumed by:

Answer»

`SnCl_2`
`CS_2`
`NO_2^+`
HCN

Answer :A
28925.

The line at 434nm in the Balmer series of the hydrogen spectrum corresponds to a transition of an electron from the n^(th) to second Bohr orbit. What is the value of n?

Answer»


ANSWER :n=5
28926.

The line spectrum observed when electron falls from the higher level into L level is known as :

Answer»

BALMER series
Paschen series
Bracket series
None of these

Answer :A
28927.

The limiting molar conductivity of an electrolyte is obtained by adding the limiting molar conductivities of cation and anion of the electrolyte. What is meant by limiting molar conductivity ?

Answer»

SOLUTION :The MAXIMUM or limiting VALUE of molar conductivityof an electrolyte when its concentration approaches zero is CALLED the limiting molar CONDUCTIVITY `(^^_m^@)`of the electrolyte.
28928.

The limiting radius ratio for tetrahedral voids has the range:

Answer»

`0.414` to `0.732 `
`0.225` to `0.414 `
`0.155` to `0.225 `
0 to `0.155 `

ANSWER :C
28929.

The limmiting molar conductivites ^^ ^(@) for NaCl_(2)Kbr and KCl are 126,152 and 150 S cm^(2) respectively the ^^ ^(@) for NaBr is

Answer»

`128Scm^(2)"mol"^(-1)`
`302Scm^(2)"mol"^(-1)`
`278S CM^(2)"mol"^(-1)`
`176Scm^(2)"mol"^(-1)`

SOLUTION :`^^_(NaBr)^(@)=^^_(NaCl)^(@)+^^_(KBr)^(@)-^^_(KCL)^(@)`
`=126+152-150=128 S cm^(2)"mol"^(-1)`
28930.

The limiting radius ratio for tetrahedral shape is

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`0" to "0.155`
`0.155-0.225`
`0.225-0.414`
`0.414-0.732`

ANSWER :C
28931.

The limiting molar conductivities of KCl, NaCl and KNO_3 are 150, 126 and 109 S cm^2mol^(-1)respectively. What is the limiting molar conductivity of NaNO_3 ?

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`385 S Cm^2 MOL^(-1)`
`167 S Cm^2 mol^(-1)`
`85 S Cm^2 mol^(-1)`
`133 S Cm^2 mol^(-1)`

ANSWER :C
28932.

The limiting molar conductivity of an electrolyte is obtained by adding the limiting molar conductivities of cation and anion of the electrolyte. Name of the above law

Answer»

SOLUTION :Kohlrausch.s LOW
28933.

The limiting molar conductivities of HCl, CH_(3)COONa and NaCl are respectively 425, 90 and 250 mho cm^(2)mol^(-1) at 25^(@)C.t he molar conductivity of 0.1 M CH_(3)COOH solution is 7.8 mho cm^(2)mol^(-1) at the same temperature. The degree of dissociation of 0.1 M acetic acid solution at the same temperature is

Answer»

`0.10`
`0.02`
`0.15`
`0.03`

SOLUTION :`wedge_(CH_(3)COOH)^(@)=wedge_(CH_(3)COONa)^(@)+wedge_(HCL)^(@)-wedge_(NaCl)^(@)`
`=90+425-125=390" MHO "cm^(2)mol^(-1)`
`alpha=(wedge_(m)^(@))/(wedge_(m)^(@))=(7.8)/(390)=.02`
28934.

The limiting molar conductivities of HCl, CH_(3)COONa and NaCl are respectively 425,90 and 125 mho cm^(2)mol^(-1) at 25^(@)C. The molar conductivity of 0.1 M CH_(3)COOH solution is 7.8 mho cm^(2)mol^(-1) at the same temperature. The degree of dissociation of 0.1 M acetic acid solution at the same temperature is

Answer»

0.1
0.02
0.15
0.03

Solution :`WEDGE^(@)` for `CH_(3)COOH=lamda_(CH_(3)COO^(-))^(@)+lamda_(Na^(+))^(@)`
`lamda_(H^(+))^(@)+lamda_(Cl^(-))^(@)-lamda_(Na^(+))^(@)-lamda_(Cl^(-))^(@)`
`=lamda_(CH_(3)COO^(-))^(@)+lamda_(H^(+))^(@)`
`=90+425-125=390mho" "cm^(2)mol^(-1)`
DEGREE of DISSOCIATION`(alpha)=(wedge_(m)^(@))/(wedge_(m)^(@))=(7.8)/(390)=0.02`
28935.

The limiting molar conductivities of HCl, CH_(3)COONa and NaCl are respective 425, 190 and 150 mho cm^(2)mol^(-1) at 25^(@)C. The molar conductivity of 0.1 M acetic acid is 9.2 mho cm^(2)mol^(-1). The degree of dissociation of 0.1 M acetic acid is

Answer»

`0.10`
0.02
0.19
0.03

Solution :`wedge_(CH_(3)COOH)^(@)=wedge_(CH_(3)COONA)^(@)+wedge_(HCl)^(@)-wedge_(NaCl)^(@)`
`""=190+425-150=465`
`alpha=wedge_(m)^(C)/wedge_(m)^(@)=9.2/465=0.19`
28936.

The limiting molar conductivities (Lambda^(0)) for NaCl, KBr and KCl are 126, 152 and 150 S.cm^(2) "mol"^(-1) respectively. Then A for NaBr is

Answer»

`128 S cm^(2) MOL^(-1)`
`302 S cm^(2) mol^(-1)`
`278 S cm^(2) mol^(-1)`
`176 S cm^(2) mol^(-1)`

Answer :A
28937.

The limiting molar conductivities ^^ for NaCl, KBr and KCl are 126,152 and 150 S cm^(2)mol^(-1) respectively. The ^^ for NaBr is

Answer»

278 S `cm^(2)mol^(-1)`
176 S `cm^(2)mol^(-1)`
128S `cm^(2)mol^(-1)`
302 S `cm^(2)mol^(-1)`

Solution :`(126s" "cm^(2))wedge_(NaCl)^(o)=wedge_(Na^(+))^(o)+wedge_(Cl^(-))^(o)` . . .(i)
`(152s" "cm^(2))wedge_(KBr)^(o)=wedge_(K^(+))^(o)+wedge_(Br^(-))^(o)` . . . (II)
`(150s" "cm^(2))wedge_(KCL)^(o)=wedge_(K^(+))^(o)+wedge_(Cl^(-))^(o)` . . .(iii)
by EQUATION (i)+(ii)-(iii)
`because wedge_(NABR)^(o)=wedge_(Na^(+))^(o)+wedge_(Br^(-))^(o)` ltBrgt `=126+152-150=128s" "cm^(2)mol^(-1)`.
28938.

The limiting molar conductances wedge^(infty) for NaCl, KBr and KCl are 126, 152 and 150 Scm^(2) mol^(–1) respectively. The wedge^(infty) for NaBr will be:

Answer»

302 S `CM^(2) MOL^(–1)`
176 S `cm^(2) mol^(–1)`
278 S `cm^(2) mol^(–1)`
`128 S cm^(2) mol^(–1)`

ANSWER :D
28939.

The limiting molar conductance of sodium chloride, potassium chloride and potassium bromide are 126.45 , 149.86 and 151.92 ohm^(-1) cm^(2) mol^(-1) respectively . Calculate limiting molar ionic conductance of Na^(+) given that limiting molar ionic conductance of Br^(-) ion is 76.34 ohm^(-1) cm^(2) mol^(-1)

Answer»

Solution :This can be calculated with the help of Kohlrausch's law because limiting MOLAR IONIC conductance are additive
`Lambda_(m) ^(@) (KBr) = lambda_(m)^(@) (K^(+)) + lambda_(m)^(@) (Br^(-))`
`Lambda_(m)^(@) (KBr) = 151.92 ohm^(-1) cm^(2) mol^(-1)`,
`lambda_(m)^(@) (Br^(-)) = 76.34 ohm^(-1) cm^(2) mol^(-1)`
`therefore lambda_(m)^(@) (K^(+)) = Lambda_(m)^(@) (KBr) - lambda_(m)^(@) (Br^(-))`
= 151.92 - 76.34
=` 75.58 ohm^(-1) cm^(2) mol^(-1)`
Now , `Lambda_(m)^(@) (KCl) = lambda_(m)^(@) (K^(+)) + lambda_(m)^(@) (Cl^(-))`
`Lambda_(m)^(@) (KCl) = 149.86 ohm^(-1) cm^(2) mol^(-1)` ,
`lambda_(m)^(@) (K^(+)) = 75.58 ohm^(-1) cm^(2) mol^(-1)`
`therefore lambda_(m)^(@) (Cl^(-)) = Lambda_(m)^(@) (KCl) - lambda_(m)^(@) (K^+)`
`= 149.86 - 75.58`
`= 74.28 ohm^(-1) cm^(2) mol^(-1)`
Now `Lambda_(m)^(@) (NACL) = lambda_(m)^(@) (NA^(+)) + lambda_(m)^(@) (Cl^(-))`
`Lambda_(m)^(@) (NaCl) = 126.45 ohm^(-1) cm^(2) mol^(-1)`
Now `Lambda_(m)^(@) (NaCl) = lambda_(m)^(@) (Na^(+)) + lambda_(m)^(@) (Cl^(-))`
`Lambda_(m)^(@) (NaCl) = 126.45 ohm^(-1) cm^(2) mol^(-1)`
`lambda_(m)^(@) (Cl^(-)) = 74.28 ohm^(-1) cm^(2) mol^(-1)`
`therefore lambda_(m)^(@) (Na^(+)) = Lambda_(m)^(@) (NaCl) - lambda_(m)^(@) (Cl^(-))`
`=126.45 - 74.28`
`=52.17 ohm^(-1) cm^(2) mol^(-1)`
28940.

The limit of a particular detection system is 0.002 dps for 1g sample. Find the maximum t_((1)/(2)) that this system could detect in a 1-g sample of a nuclide of mass number 200.

Answer»

SOLUTION :We know, N= no. of ATOMS= moles `xx` Av. Const.`=(1)/(200) xx 6.022 xx 10^(23)`
`-(d(N))/(dt)= lamda (N)`
`0.002 = (0.6932)/(t_((1)/(2)))xx (1)/(200) xx 6.022 xx 10^(23)`
`therefore t_((1)/(2))=1.0436 xx 10^(24)` SECONDS
`=3.334 xx 10^(16)` years.
28941.

The limiting line in Paschen series corresponds to

Answer»

`n_(1)=2,n_(2)=3`
`n_(1)=3,n_(2)=4`
`n_(1)=3,n_(2)=10`
`n_(1)=3,n_(2)=OO`

Answer :D
28942.

The limiting density of hydrogen bromide is 3.6108 at 0^(@)C. The exact atomic weight ofbromine is (At. wt. of H = 1.008)

Answer»

80.92
79.92
89.29
79.29

Solution :This can be calculated by limiting density method which is BASED on the fact that at LIMIT of zero pressure the ideal gas equation hecomes exact for all gases i.e.,
PV=nRT
Molecular weight of HBr on this BASIS is
`M=RT(p/P)_(Pto0)`
`M=0.0821xx273.15xx3.6108[0^(@)C=273.15K]=80.93`
`therefore` 80.93 = atomic weight of hydrogen+ atomic weight of bromine
=1.008 + atomic weight of bromine
or atomic weight ofbromine= 80.93 - 1.008 = 79.92
28943.

The lightning bolts in atmosphere cause the formation of:

Answer»

`NO`
`O_2`
`CO_2`
`H_2O_2`

ANSWER :A
28944.

The lightest, non-inflammable gas is:

Answer»

`H_2`
He
`N_2`
Ar

Answer :B
28945.

The lightest particle is:

Answer»

Electron
Proton
Neutron
`BETA`-particle

Answer :A
28946.

The lightest metal in the periodic table is :

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H
Mg
Ca
Li

Answer :D
28947.

The lightest metal is :

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Li
Mg
Ca
Na

Answer :A
28948.

The lightest metal I

Answer»

Li
Mg
Ca
Na

ANSWER :A
28949.

The light yellow compound produced when actone reacts with iodine and alkali, is

Answer»

`CH_(3)COCH_(2)I`
`CH_(3)I`
`CHI_(3)`
None of these

Answer :C
28950.

The lightest gas is:

Answer»

Nitrogen
Helium
Oxygen
Hydrogen

Answer :D