This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Eq. wt ("Mol wt")/x What is x for acetaldehyde converted into acetic acid. |
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Answer» `underset("Acetaldehyde")overset((-1))(C_(2)H_(4)O)rarrunderset("acetic acid")overset((0))(C_(2)H_(4)O_(2))` EQ. wt = `("Mol wt")/(2)` |
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| 2. |
Equivalent weight of X is 9. The vapour density of chloride salt is 66.75 state vulency of X. |
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Answer»
`=2xx 66.75 = 133.50` `:. "Valency"=("Molecular mass")/("Equivalent weight")` `=(133.50)/(9+35.5) = (133.50)/(44.5)=3` |
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| 3. |
Equivalent weight of the reaction is same as its formula weight or molecular weight in case of the conversion__________ |
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Answer» `Na_(2)S_(2)O_(3)` into `Na_(2)S_(4)O_(6)`<BR>`FeSO_(4)` into `Fe_(2)(SO_(4))_(3)` `Na_(2)SO_(3)rarrNa_(2)S_(4)O_(6),n-f=0.5xx2=1` `FeSO_(4)rarrFe_(2)(SO_(4))_(3),n-f=1xx1=1` `KBrrarrBr_(2),n-f=1xx1=1` `Br_(2)rarrKBr,n-f=1xx2=2` |
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| 4. |
Equivalent weight of Pyrophosphoric acid is (H_(4)P_(2)O_(7)) |
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Answer» `M.W//1` |
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| 5. |
Equivalent weights of K_(2)Cr_(2)O_(7) in acidic medium is |
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Answer» 24.5 |
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| 6. |
Equivalent weight of K_(2)Cr_(2)O_(7) as oxidant in acidic medium is |
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Answer» 24.5 |
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| 7. |
Equivalent weight offerrous ion when it acts as salt is X and as reductant is Y. What is the ratio of X and Y? |
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Answer» Solution :X is 55.8/2. When ferrous ION acts as reductant , ITIS oxidised to FERRIC. Y is 55.8/1. THUS X:Y is 1:2 |
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| 8. |
Equivalent weight of element X is 3. If vapour density of volatile chloride of X is 77, Find out the moleculer formula of chloride. |
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Answer» SOLUTION :Equivalent weight of chloride of X= Equivalent weight of Cl +equivalent weight of X = 35.5+3=38.5 Moleculer weight of chloride = vapour density `xx2=77xx2=154` `"Valency of the element" X=(154)/(38.5)=4` Chlorine is taken as monovalent, SINCE it is chloride MOLECULAR formula of chloride of X is `XCl_(4)` |
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| 9. |
Equivalent weight of Ba(MNO_4)_2 in acidic medium ( M = molar mass) |
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Answer» M |
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| 10. |
Equivalent weight of As_(2)O_3 in the following equation As_(2)O_3 +2I_(2) + 2H_(2)O rarr As_(2)O_(5) +4HI [arsenci at wt. = 75] |
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Answer» 49.5 |
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| 11. |
Equivalent weight of a metal chloride is 75.5. How many moles of NaOH is required to completely precipitate one mole of metal hydroxide. Atomic weight of the metal is 120. |
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Answer» 75.5 = E + 35.5 E = 40 VALENCY = `(120)/(40)=3` `THEREFORE` Formula of metal chloride = `MCl_(3)` `MCl_(3)+3NaOHrarrM(OH)_(3)darr+3NaCl` |
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| 12. |
Equivalent masses ofNH_3in the reactions are (i) 4NH_(3) +5O_(3)rarr4NO + 6H_(2)O |
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Answer» `5:6` `E_1=M/5,overset(-3)(2NH_3)rarroverset(0)N_2` `E_2=M/3,E_1/E_2=3:5` |
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| 13. |
Equivalent mass of oxidising agent in the reaction SO_(2)+2H_(2)Srarr3S+2H_(2)O is |
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Answer» 321 Inthis reaction , `SO_(2)` acts as oxidising agent `overset(+4)SO_(2)rarroverset(0)S` `SO_(2)+4e^(-)rarrS` therefore Eq mass of `SO_(2)`=`("MOLECULAR mass")/(4)` `=(32+32)/(4) =16` |
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| 14. |
Equivalent weight and formula weight of reactants are same in the conversions |
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Answer» `AgNO_(3)rarrAg` metal `AgNO_(3),n-f=1` `CUO,n-f=1` `H_(2)O_(2),n-f=2` `Na_(2)S_(2)O_(3),n-f=1` |
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| 15. |
Equivalent mass of N, in the change N_(2)- NH_3is |
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Answer» 28/6 |
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| 16. |
Equivalent mass of KMnO_(4) when it is converted to MnSO4 is equal to molar mass divide by………. |
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Answer» 6 `KMnO_(4) + 5e^(-) to MnSO_(4)` So, EQUIVALENT mass of `KMnO_(4)=("molar mass of" KMnO_(4))/5` |
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| 17. |
Equivalent mass of KMnO_(4), when it is converted to MnSO_(4), is : |
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Answer» `M//5` |
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| 18. |
Equivalent mass of KMnO_(4) in acidic medium, concentrated alkaline medium and dilute basic medium respectively are M, M, M. Reduced products can be |
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Answer» `MnO_(2), MnO_(4)^(-) , Mn^(2+)` `MnO_(4)^(-) + 4H^(+) + 3e^(-) to MnO_(2) + 2H_(2)O`(CONCENTRATED basic medium) `MnO_(4)^(-) + e^(-) to MnO_(4)^(2-)`(DILUTE basic medium) |
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| 19. |
Equivalent mass of H_(3)PO_(2) when it disproportionates into PH_(3) " and" H_(3)PO_(3) is (Molecular mass=M) : |
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Answer» M (Change in OXIDATION number=2) `overset(+1)(H_(3)PO_(2) to overset(-3)(PH_(3)), " Eq. wt." = (M)/(4)` (Change in oxidation number=4) The EQUIVALENT mass of `H_(3)PO_(2)` in the PROCESS of disproportionation`=(M)/(2)+(M)/(4)=(3M)/(4)` |
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| 20. |
Equivalent mass of C_(2)O_(4)^(2-) ion in the reaction, C_(2)O_(4)^(2-)to2CO_(2)+2e^(-), is |
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Answer» 11 |
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| 21. |
Equivalent mass of FeC_(2)O_4in the change, FeC_(2)O_(4) rarrFe^(3+) + CO_(2)is |
| Answer» Solution :`FeC_2O_4 ""{:(FE^(2+),overset((1))rarr,Fe^(3+)),(overset(+3)(C_(2))O_(4)^(2-),overset((2))rarr,2overset(+4)(CO_2)):}}3e^(-)` | |
| 22. |
Equivalent mass of an organic base can be determined by: |
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Answer» SILVER SALT method |
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| 23. |
Equivalent mass of an organic acid can be determined by : |
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Answer» SILVER SALT method |
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| 24. |
Equivalent mass of a substance may be calculated as, Equivalent mass=("Molecular mass")/("n-factor")=("Atomic mass")/(n-factor") n-factor= Basicity of acid or acidity of base n-factor= Number of moles of electrons gainted or lost per mole of oxidising or reducing agents n-factor= Total positive or negative valency of a salt n-factor= Valency of an ion. Concept of n-factor is very important for redox as well as for non-redox reactions. Equivalentmass of H_(3)PO_(2) when it undergoes disporportionation to PH_(3) " and " H_(3)PO_(3) will be : |
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Answer» `M.w.//2` `H_(3)PO_(2)+H_(2)O to H_(3)PO_(3)+2H^(+)+2e^(-) "" n_(2)=2` N-factor`=(n_(1)xxn_(2))/(n_(1)+n_(2))=(2xx4)/(2+4)=(8)/(6)=(4)/(3)` E.w. `M.w.//(4)/(3)=(3M.w.)/(4)` |
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| 25. |
Equivalent mass of a substance may be calculated as, Equivalent mass=("Molecular mass")/("n-factor")=("Atomic mass")/(n-factor") n-factor= Basicity of acid or acidity of base n-factor= Number of moles of electrons gainted or lost per mole of oxidising or reducing agents n-factor= Total positive or negative valency of a salt n-factor= Valency of an ion. Concept of n-factor is very important for redox as well as for non-redox reactions. BrO_(3)^(-) ion reacts with Br^(-) to form Br_(2), in acid medium. The equivalent mass of Br_(2) in this reaction is : |
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Answer» `(4 M.w.)/(6)` `2Br^(-) to Br_(2)+6e^(-) "" n_(2)=2` N-factor`=(n_(1)xxn_(2))/(n_(1)+n_(2))=(10xx2)/(10+2)=(20)/(12)=(5)/(3)` `E.w.=(M.w.)/(5//3)=(3M.w.)/(5)` |
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| 26. |
Equivalent mass of a substance may be calculated as, Equivalent mass=("Molecular mass")/("n-factor")=("Atomic mass")/(n-factor") n-factor= Basicity of acid or acidity of base n-factor= Number of moles of electrons gainted or lost per mole of oxidising or reducing agents n-factor= Total positive or negative valency of a salt n-factor= Valency of an ion. Concept of n-factor is very important for redox as well as for non-redox reactions. When KMnO_(4) is titrated against ferrous ammonium sulphate in acid medium then equivalent mass of KMnO_(4) will be : |
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Answer» `("Molecular mass")/(10)` |
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| 27. |
Equimotal aquous solutions ofNaCl and KCl are prepared If the freezing point ofNaClis -2^(@) Cthe freezing point of KCI solution is expectedtobe |
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Answer» `-2^(@) C ` |
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| 28. |
Equimolar solutions of the following were prepared in water separately. Which one of the solutions will record the highest pH ? |
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Answer» `SrCl_2` |
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| 29. |
Equimolar solutions of the following substances were prepared separately. Which one of these has highest pH value? |
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Answer» `BaCI_(2)` are: `BaCI_(2) : BA(OH)_(2) +2HCI` `AICI_(3) , AI(OH)_(3) + 3HCI` `LiCI : Li(OH) + HCI` `BeCI_(2) : Be(OH)_(2) + 2HCI` Since `Ba(OH)_(2)` is the strongest base , `BaCI_(2)` solution has the maximum pH VALUE. |
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| 30. |
Equimolarsolution of non-electrolyte in the same solvent have |
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Answer» same BOILING POINT and same FREEZING point |
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| 31. |
Equimolar concentration of H_(2) and I_(2) are heated to equilibrium ina 1 liter flask. What percentage of initial concentration of H_(2) has reacted at equilibrium, the rate constant for the forward reaction is 25xx10^(2) and the equilibrum constant is 50. The rate constant for the reverse reaction is, |
| Answer» ANSWER :A | |
| 32. |
Equimolar concentraions of H_2 and I_2 are heated to equilibriumin a 1 litre flask. What percentage of initial concentration of H_2 has reacted at equilibrium if rate constant for both farward and reverse reactions are equal |
| Answer» Solution :0.33 | |
| 33. |
Equimolar amounts of H_(2) and I_(2) were taken in a bulb maintained at 500 ^(@) C. Dark violet colour faded to light violet which does not change further. This shows that the bulb contains ………….. amounts of …………. . |
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Answer» |
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| 34. |
Equimolar aqueous solutions of NaCl and KCl are prepared. If the freezing point of NaCl is -2^(@)C, the freezing point of KCl solution in expected to be ………… |
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Answer» 1) `-2^(@)C` |
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| 35. |
Equilmolar concentrations of H_(2) and I_(2) are heated to equilibrium in a 2 litre flask . At equilibrium , the forward and the backward rate constants are found to be equal . What percentage of intial concentration of H_(2) has reacted at equilibrium ? |
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Answer» `33 %` ` K= (x^(2))/((1-x)/2 xx (1-x)/2 )=(4 x^(2))/(1-x)^(2) approx4x^(2)` But `K= (k_(f))/(k_(b))=1` `:. 4"" x^(2)=1 or x^(2) = 1//4 or x = 1//2 , i.e., 50%` |
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| 36. |
Equilibrium state can be achieved if a reversible reaction is carried out in closed or open container. |
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Answer» |
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| 37. |
Equilibrium constants are given (in atm) for the following reactions at 0^(@)C : SrCl_2 . 6H_2O(s) hArr SrCl_2 . 2H_2O(s)+4H_2O(g) K_p=5xx10^(-12) Na_2HPO_4 . 7H_2O(s)+5H_2O(g) K_p=2.43xx10^(-13) Na_2SO_4 . 10H_2O(s) hArr Na_2SO_4(s)+10H_2O(g) K_p=1.024xx10^(-27) The vapour pressure of water at 0^@C is 4.56 torr. At what relative humidities will Na_2SO_4 be deliquescent (i.e. absorb moisture) when exposed to the air at 0^@C ? |
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Answer» above 33.33% |
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| 38. |
Equilibrium existing in the hydrolysis of an ester is ....... |
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Answer» Gaseous HOMOGENEOUS `CH_3COOC_2H_(5(l)) + H_2O_((l)) OVERSET(H^+)hArr CH_3COOH_((l)) + C_2H_5OH_((l))` |
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| 39. |
Equilibrium constants are given (in atm) for the following reactions at 0^(@)C : SrCl_2 . 6H_2O(s) hArr SrCl_2 . 2H_2O(s)+4H_2O(g) K_p=5xx10^(-12) Na_2HPO_4 . 7H_2O(s)+5H_2O(g) K_p=2.43xx10^(-13) Na_2SO_4 . 10H_2O(s) hArr Na_2SO_4(s)+10H_2O(g) K_p=1.024xx10^(-27) The vapour pressure of water at 0^@C is 4.56 torr. At what relative humidity will Na_2SO_4 . 10H_2O be efflorescent when exposed to air at 0^@ C? |
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Answer» above 33.33% |
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| 40. |
Equilibrium constants are given (in atm) for the following reactions at 0^(@)C : SrCl_2 . 6H_2O(s) hArr SrCl_2 . 2H_2O(s)+4H_2O(g) K_p=5xx10^(-12) Na_2HPO_4 . 7H_2O(s)+5H_2O(g) K_p=2.43xx10^(-13) Na_2SO_4 . 10H_2O(s) hArr Na_2SO_4(s)+10H_2O(g) K_p=1.024xx10^(-27) The vapour pressure of water at 0^@C is 4.56 torr. Which is the most effective drying agent at 0^@C ? |
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Answer» `SrCl_2 . 2H_2O` |
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| 41. |
Equilibrium constant of following reaction is 0.5. CO_((g)) + 2H_(2(g)) hArr CH_3OH_((g)) at equilibrium [CO]=0.18 mol L^(-1) and [H_2] = 0.22 mol L^(-1)Calculate the concentration of CH_3OH. |
| Answer» SOLUTION :`4.356xx10^(-3) ("mol L"^(-1))^(-2)` | |
| 42. |
Equilibrium constant value depends on _________ . |
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Answer» TEMPERATURE |
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| 43. |
Equilibrium constant K_(X), for the reaction H_(2)(g)+I_(2) (g) Leftrightarrow 2HI(g), is 49. What is the value of K_(C) for the reaction 1/2 H_(2)(g)+1/2I_(2) (g) Leftrightarrow HI(g) and 2HI (g) Leftrightarrow H_(2) (g)+I_(2) (g)? |
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Answer» SOLUTION :`H_(2) (g)+I_(2) Leftrightarrow 2HI(g)` `K=([HI]^(2))/([H_(2)] [I_(2)])=49` `1/2 H_(2) (g)+1/2 I_(2) (g) Leftrightarrow HI (g), K_(1)=?` `K_(1)=K^(1/2)=sqrt(K)=sqrt(49)=7` `2HI (g) Leftrightarrow H_(2) (g)+I_(2) (g), K_(2)=?` `K_(C)` for the REACTION `2HI(g) Leftrightarrow H_(2)(g)+I_(2)(g)` is `K_(2)=1/K =(1)/(49)=2.04 xx 10^(-2)` |
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| 44. |
Equilibrium constant of a reaction does not change with ……… but changes with …………… |
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Answer» |
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| 45. |
Equilibrium constant, K_(c) the reaction N_(2)(g)+3H_(2) (g) Leftrightarrow 2NH_(3) (g)" is "2 xx 10^(-2) mol^(-2) lit^(2). What is the value of K_(c) for the reaction 2NH_(3) (g) Leftrightarrow N_(2) (g)+3H_(2)(g)? |
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Answer» SOLUTION :`N_(2)(G)+3H_(2) (g) Leftrightarrow 2NH_(3) (g)`, `K_(C)= ([NH_(3)]^(2))/[N_(2)][H_(2)]^(3)=2 xx 10^(-2)" mol"^(2) lit^(2)` `NH_(3) (g) Leftrightarrow N_(2) (g)+3H_(2)(g), K_(2)=?` `K_(2)=([N_(2)] [H_(2)]^(3))/([NH_(3)]^(2))=(1)/(K_(C)0=(1)/(2 xx 10^(-2))=50 mol^(2) lit^(-2)` |
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| 46. |
Equilibrium constant K_(p)for following reaction MgCO_(3(s))hArrMgO_((s))+CO_(2(g)) |
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Answer» `K_(p)=P_(CO_(2))` |
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| 47. |
Equilibrium constant K_(C) for the reaction, N_(2(g))+3H_(2(g))hArr2NH_(3(g)) at 500K is 0.061. At particular time, the analysis shows that the composition of the reaction mixture is 3.0" mol L"^(-1) of N_(2),2.0" mol L"^(-10 of H_(2),0.50" mol L"^(-1) of NH_(3).is the reaction at equilibrium ? |
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Answer» Solution :The given REACTION is `N_(2(g))+3H_(2(g))hArr2NH_(3(g))` According to available data `N_(2)=(3.0)H_(2)=(2.0)NH_(3)=(0.50)` `Q_(C)=((NH_(3(g)))^(2))/([N_(2(g))][H_(2(g))]^(3))` `=([0.50]^(2))/((3.0)(2.0))=(0.25)/(24)=0.0104` |
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| 48. |
Equilibrium constant, K_c for the reaction N_(2(g)) + 3H_(2(g)) hArr 2NH_(3(g)) at 500 K is 0.061 At a particular time, the analysis shows that composition of the reaction mixture is 3.0 mol L^(-1) N_2, 2.0 mol L^(-1) H_2,and 0.5 mol L^(-1) NH_3. Is the reaction at equilibrium ? If not in which direction does the reaction tend to proceed to reach equilibrium ? |
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Answer» SOLUTION :`{:("Equilibrium reaction :",N_(2(G))+ , 3H_(2(g)) HARR , 2NH_(3(g))),("At t time composition :",3.0,2.0,0.5):}` At t time the reaction quotient Q of composition of reaction MIXTURE is, `Q_c=[NH_3]^2/([N_2][H_2])^3=(0.5)^2/((3.0)(2)^3)`=0.0104 `therefore (Q_c=0.0104) lt (K_c=0.061)` Here, `Q_c lt K_c` , the reaction will proceed in the direction of the products (Forward reaction till = `Q_c=K_c`) . |
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| 49. |
Equilibrium constant K_(c) for the reaction , N_(2) (g) + 3 H_(2) (g) hArr 2 NH_(3) (g) at 500 K is 0.061, At particular time ,the analysis shows that the composition of the reaction mixture is 3.0 mol L^(-1) of H_(2), 0.50 mol L^(-1) of NH_(3) .Is the reaction at equilibrium ? |
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Answer» SOLUTION :The given reaction is `: N_(2) (g) + 3 H_(2) (g) hArr 2 NH_(3) (g)` According to available data `N_(2) = [3.0] , H_(2) = [2,0] , NH_(3) = [0.50]` `Q_(C) = ([NH_(3) (g)]^(2))/([N_(2) (g)] [H_(2) (g)]^(3)) = ([0.50]^(2))/([3.0][2.0]) = (0.25)/(24) = 0.0104` |
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| 50. |
Equilibrium constant, K_(c) " for the reaction" , N_(2) (g) + 3 H_(2) (g) hArr 2 NH_(3) (g) " at " 500 K " is " 0*061. At a particular time, the analysis shows that composition of the reaction mixture is 3*0" mol "L^(-1) N_(2), 2*0 " mol "L^(-1) H_(2)and5*0 "mol " L^(-1) NH_(3).Is the reaction at equilibrium ? If not , in which direction does the reaction tend to reach equilibrium ? |
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Answer» Solution :`Q_(C)= ([NH_(3)]^(2))/([N_(2)][H_(2)]^(3) )=(0*5)^(2)/((3*0)(2*0)^(3))=0*0104` As ` Q_(c)!=K_(c) `, REACTION is not in equilibrium As ` Q_(c) ltK_(c)`, reaction willproceed in the forwarddirection. |
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