This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
If n=6, the correct sequence for filling of electrons will be, |
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Answer» `ns RARR (n - 2) f rarr (n -1)d rarr np` |
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| 2. |
If N_(2) + 3 H_(2) hArr 2NH_(3) ... (1) & N_(2) + 3H_(2) overset(Fe)(hArr) 2NH_(3)....(II) are in equilibrium at same temperature. Then |
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Answer» `K_c` of `I=K_c` of II |
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| 3. |
If n+l =6 , then total possible number of subshells would be |
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Answer» 3 |
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| 4. |
If n is equal to 3, what are the values of quantum number l and m ? |
| Answer» Solution :`L = 0, 1, 2 m = -2, -1, 0, + 1, +2 and s = +1//2 and -1//2` for each value of m | |
| 5. |
The quantum numbers n , l , m , m_s respectively of the electron 3d^1 are |
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Answer» `sum_(l=0)^(l=n) 2(2l+1)` |
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| 7. |
If n = 5, how many electrons can have m_(l) = +1? |
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Answer» Solution :When N = 5, l = 0, 1, 2 , 3 and 4 When l = 0, `m != +1` When l = 1, 2, 3, or 4, in each CASE, there is ONE orbital which has `m_(l) = +1` `(l = 1, m = -1, 0 +1, l = 2, m = -2, -1, 0 +1, +2`, etc) Hence, there are four orbitals which will have `m_(l) = +1` EAch orbital can have maximum TWO ELECTRONS. Hence, electrons with n = 5 and `m_(l) + 1` will be 8 |
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| 8. |
If n = 6, the correct sequence sequence of filling of electrons will be |
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Answer» `ns RARR NP rarr (n - 1) d rarr (n -2) f` |
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| 9. |
If n = 3, l = 0, m = 0 then atomic number is |
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Answer» 12, 13 `:. E.C. " will be " 1s^(2) 2s^(2) 2p^(6) 3s^(1 -2)` Atomic no. is 11 or 12 |
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| 10. |
If most probable velocity is represented by 'a' and fraction possessing it by 'f' , then with increase in temperature which one of the following is correct? |
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Answer» a increases/DECREASES |
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| 11. |
If more than one phase is present in the reversible reaction then it is said to be heterogenous system. Example: CaO(s)+CO_(2)(g) Expression of equilibrium constant for the above reaction can be taken as : K=([CaO(s)][CO_(2)(g)])/([CaO(s)])."".....(i) Now concentration of CaO(s)=[CaO(s)] =("moles of CaO")/("volume of CaO") as density of CaO[rho_(CaO(s))] and molar mass of CaO[M_(CaO(s))]are a fixed quantity therefore concentration of pure solid and liquid term is uncharge with respect to time. Hence, equilibrium constant for the equation (i) can be written as : K_(C)=[CO_(2)(g))] K_(P)=P_(CO_2) As K_(p) and K_(c) is not containing solid terms therefore, addition or removel of pure solid and pure liquid has no effect on the equilibrium process. CaCO_(3)(s)hArr+CaO(s)+CO_(2)(s) At equilibrium in the above case, 'a' moles of CaCO_(3), 'b' moles of CaO and 'c' moles of CO_(2) are found then identify the wrong statement: |
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Answer» a' will decrease with the additon of inert gas at constant pressure. |
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| 12. |
If more than one phase is present in the reversible reaction then it is said to be heterogenous system. Example: CaO(s)+CO_(2)(g) Expression of equilibrium constant for the above reaction can be taken as : K=([CaO(s)][CO_(2)(g)])/([CaO(s)])."".....(i) Now concentration of CaO(s)=[CaO(s)] =("moles of CaO")/("volume of CaO") as density of CaO[rho_(CaO(s))] and molar mass of CaO[M_(CaO(s))]are a fixed quantity therefore concentration of pure solid and liquid term is uncharge with respect to time. Hence, equilibrium constant for the equation (i) can be written as : K_(C)=[CO_(2)(g))] K_(P)=P_(CO_2) As K_(p) and K_(c) is not containing solid terms therefore, addition or removel of pure solid and pure liquid has no effect on the equilibrium process. K_(p) for the reaction NH_(4)I(s)hArrNH_(3)(g)+HI(g)is 1//4 at 300K.If above equilibrium is established by taking 4 moles of NH_(4)I(s) in 100 litre contanier, then moles of NH_(4)I(s) left in the container at equilibrium is ["Taken R=1/12Lt.atm mol"^(-1)K^(-1)]. |
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Answer» 1 |
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| 13. |
If more than one phase is present in the reversible reaction then it is said to be heterogenous system. Example: CaO(s)+CO_(2)(g) Expression of equilibrium constant for the above reaction can be taken as : K=([CaO(s)][CO_(2)(g)])/([CaO(s)])."".....(i) Now concentration of CaO(s)=[CaO(s)] =("moles of CaO")/("volume of CaO") as density of CaO[rho_(CaO(s))] and molar mass of CaO[M_(CaO(s))]are a fixed quantity therefore concentration of pure solid and liquid term is uncharge with respect to time. Hence, equilibrium constant for the equation (i) can be written as : K_(C)=[CO_(2)(g))] K_(P)=P_(CO_2) As K_(p) and K_(c) is not containing solid terms therefore, addition or removel of pure solid and pure liquid has no effect on the equilibrium process. 200g of CaCO_(3)(g) taken in 4Ltr container at a certain temperature. K_(c) for the dissociation of CaCO_(3) at this temperature is found to be 1//4 mole Ltr^(-1)then the concentration of CaO in mole/litre is : [Given :rho_(CaO)=1.12gcm^(-3)][Ca=40,O=16] |
| Answer» ANSWER :C | |
| 14. |
If molecular weight of Na_(2)S_(2)O_(3) and I_(2) are M_(1) and M_(2) respectively then what will be equivalent weight of Na_(2)S_(2)O_(3) and I_(2) in the following redox reaction ? 2s_(2)O_(3)^(2-)+I_(2)rarrS_(4)O_(6)^(2-)+2I^(-) |
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Answer» Solution :` 2Na_(2)S_(2)O_(3)=Na_(2)S_(4)O_(6)` TOTAL INCREASE is O.N of S for molecules of `Na_(2)S_(2)O_(3)=4xx2.5-2[2(+2)]=2` `therefore` Totalincrease in O.N of S PER molecule of `Na_(2)S_(2)O_(3)=1` `therefore` Eq mass =`M_(1)//1=M_(1)` now `I_(2)^(2)rarrr2I^(-1)` Total DECREASE is O.N per molecule of `I_(2)=0-2(-1)=2` `therefore` Eq mass of `I_(2)=M_(2)//2` |
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| 15. |
If molecular mass of solute base (M) & equivalent weight (E) are given the relation between Molarity (X) and Normality (Y). |
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Answer» `Y=(X XX M)/(E)` `:.` Acidity `= M/E` NORMALITY of a base `=` MOLARITY `xx` Acidity `Y = (X xx M)/(E)` |
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| 16. |
Compute the heat of formation of liquid methyl alcohol in kilojoules per mole, using the following data. Heat of vapourisation of liquid methyl alcohol= 38 kJ/mol. Heat of formation of gaseous atoms from the elements in their standard states, H= 218kJ/mol, C= 715 kJ/mol, O= 249 kJ/mol. Average bond energies, C-H = 415 kJ/mol, C-O = 365 kJ/mol, O-H= 463 kJ/mol |
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Answer» `(1)/(2) H_(2) rarr H, Delta H_(2) = 218` `(1)/(2) O_(2) rarr O, Delta H_(3) = 249` `C_((s)) + 2H_(2) + (1)/(2) O_(2) rarr C_((g)) + 4H_((g)) + O_((g)), Delta H_(4) = 1836` `C_((g)) + 4H_((g)) + O_((g)) rarr CH_(3)OH_((L)), Delta H = 1836 - [1 xx (C - O) + 3 xx (C - H) + 1 xx (O-H)] - Delta H_("VAP")` `=1836 - (365 + 3 xx 415 + 463 + 38)` `= 1836 - 2111 = -275` KJ/mole `rArr - 55 xx 5` |
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| 17. |
If magnetic quantum number of a given electron is represented -3, then what will be its principal quantum number ? |
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Answer» 2 |
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| 18. |
Ifmagneticquantumnumberis -3then the principlequantumnumbercan be |
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Answer» 1 so totalvaluesof N are 4 . |
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| 19. |
If m = magnetic quantum number and l = azimuthal quantum number then :- |
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Answer» `m=L+2` |
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| 20. |
If M is element of group 2 and X is elements of group 17, then which type of compound will be formed ? |
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Answer» `MX_(2)` eg. `MG to Mg^(2+) " or " M to M^(2-)` An Element of group-17 gains 1 electron and - 1 state is ATTAINED in compounds of it. eg. `CL to Cl^(-) " or " X to X^(-)` The compounds formed between `M^(2+) " and " X^(-) " are " MX_(2)` |
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| 21. |
If low pressure and low temperature are the favourable conditons for the reaction: aA+bBhArr cC+dD then the true statements will be : |
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Answer» (a+b) lt (C+d) and `DeltaH=+X` |
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| 22. |
If law of constant composition is true, what weights of calcium, carbon and oxygen are present in 1.5 g of calcium carbonate ? Given that the sample of calcium carbonate from another sample contains Ca = 40.0 %, C = 12.0 % and O = 48.0 % |
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Answer» Weight of `Ca=((1.5g)xx40)/(100)=0.6g` , Weight of C `=((1.5g)xx12)/(100)=1.18g` and Weight of `O=((1.5g)xx48)/(100)=0.72g`. |
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| 23. |
If lambda_L , lambda_Mand lambda_N an are the wave lengths of electron in L, M, N energy levels of H-atom respectively. What is their decreasing order: |
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Answer» `lambda_L gt lambda_M gt lambda_N` |
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| 24. |
If lambda = C_2 [(n^2)/(n^2 - n^2)] for Balmer series , what is the value of C_2? |
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Answer» `2/(R_H)` `=(2^2)/(C_2) [1/(2^2) -1/(n_2^2)] , R_H = (2^2)/(C_2) impliesC_2 = 4//R_H` |
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| 25. |
If lambda_1 and lambda_2 denote the de-Broglie wavelength of two particles with same masses but charges in the ratio of 1 : 2 after they are accelerated from rest through the same potential difference, then |
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Answer» `lambda_1 = lambda_2` |
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| 26. |
If K_(sp) = Q_(sp) than what it indicate ? |
| Answer» SOLUTION :If `K_(sp) = Q_(sp)` than it indicate the starting of PRECIPITATION of reaction and equilibrium state of CONCENTRATED solution and sparingly soluble SALT. | |
| 27. |
If K_(sp) of CaSO_4. 5H_2O is 9xx10^(-6) . Find the volume of 1 gm CaSO_4. (M.M = 136u) |
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Answer» 2.45 litre `K_(SP)=S^2=9xx10^(-6)` `S=3xx10^(-3)` mole/litre mg/litre = M.M x S `=136xx3xx10^(-3)` `=408xx10^(-3)` GM/litre In 1 litre `408xx10^(-3)`gm `CaSO_4` `therefore` 1 gm `CaSO_4 = 1/(408xx10^(-3))`=2.45 litre |
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| 28. |
If kinetic energy of an electron is increased by nine times, the wavelength associated with it would become ........... |
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Answer» `1/3` times `THEREFORE V=(h)/(lambdav)` and `v^(2) =(h^(2))/(lambda^(2)m^(2))` `therefore KE ALPHA (1)/(lambda^(2))` If KE is INCREASED by nine times `therefore 9=(lambda_(1)^(2))/(lambda_(2)^(2))` `therefore 3=(lambda_(1))/(lambda_(2))` and `(lambda_(2))/(lambda_(1))=1/3` |
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| 30. |
If K_(c)/(K_(p))-"log"1/(RT)=0 then above is ture for the following equilibrium reaction : |
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Answer» `NH_(3)(g)hArr(1)/(2)N_(2)+(3)/(2)H_(2)(g)` |
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| 31. |
If K_(c) for reactionCH_(3)COOH(1) + C_(2)H_(5)OH hArr CH_(3)COOC_(2)H_(5)(1)+H_(2)O(1) is 4. Then Q_(c) " and :K_(c) are ……… |
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Answer» |
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| 32. |
If K_c = [CO_2]then which is the following equilibrium ? |
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Answer» `C_((s)) + O_(2(g)) hArr CO_(2(g))` |
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| 33. |
If K_b and K_f for a reversible reactions are 0.8xx10^(-5) and 1.6xx10^(-4) respectively , the value of the equilibrium constant is………………. . |
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Answer» 20 `K_f = 1.6xx10^(-4)` `K_(eq) = (K_f)/(k_b) =(1.6xx10^(-4))/(0.8xx10^(-5)) = 20` |
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| 34. |
If K_b and K_f for a reversible reactions are 0.8 xx 10^(-5) and 1.6 xx 10^(-4) respectively, the value of the equilibrium constant is, |
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Answer» 20 `K_f = 1.6 xx 10^(-4)` `k_(AQ)= K_f/K_b = (1.6 xx 10^(-4))/(0.8 xx 10^(-5))= 20` |
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| 35. |
If K_(b) and K_(f) for a reversible reactions are 0.8xx10^(-5) and 1.6xx10^(-4) respectively, the value of the equilibrium constant is, |
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Answer» 20 |
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| 36. |
If K_(a_(1)),K_(a_(2)) are the first, second and third ionization constants of H_(2)PO_(4) respectively and K_(a_(1)) gtgt K_(a_(2)) gtgt K_(a_(3)). Which is/are correct: |
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Answer» `[H^(+)] = sqrt(k_(a_(1))[H_(3)PO_(4)])` |
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| 37. |
If K_(a_(1)) and K_(a_(2)) are thedissociation constantsof two acids HA_(1) and HA_(2), then the ratio of strengths of their solutionswith equimolar concentration is .............. |
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| 38. |
If K_(a) is theionizationconstant of a weak acid and K_(b) is that of the conjugate base,then pK_(a)+pK_(b)=.......... |
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| 39. |
If Ka of weak acid is found to be 1.78xx10^(-5) What is the PK_(a) value? |
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Answer» SOLUTION :`Ka=1.78xx10^(-5)` `PK_(a)=-logKa=-log(1.78xx10^(-5))=-log1.78+5log10=-0.2504+5=4.7496` |
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| 40. |
If K_(1) is ionization constant of H_(2)S(aq)hArr2H^(+)(aq)+S^(2-)(aq) and K_(2) is that for H_(2)S(aq)hArr H^(+)(aq)+HS^(-)(aq), then ionization constant of HS^(-)(aq)hArr H^(+)(aq)+S^(2-)(aq) will be equal to .......... . |
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Answer» |
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| 41. |
If K_(2)Cr_(2)O_7is source of Cr_(2)O_7^(2-) , what is the normality of solution containing 4.9 g of K_(2)Cr_(2)O_7in 0.1 litre of solution ? |
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Answer» `=(4.9)/(294//6xx0.1)=1N` `( :. E_(K_2Cr_(2)O_(7))=M/6)` |
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| 42. |
If K_(1) is equilibrium constant at temperature T_(1) and K_(2) is the equilibrium constant at temperature T_(2), and if T_(2)gtT_(1) and reaction is endothermic then |
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Answer» `K_(2)gtK_(1)` |
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| 43. |
If K lt1.0, what will be the value of DeltaG^(@) out of the following ? |
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Answer» `1.0` |
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| 44. |
If K lt 1, Delta G^(@) = ….... |
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Answer» `+ve` |
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| 45. |
If K gt 1 then what is the value of DeltaG ? |
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Answer» Positive |
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| 46. |
If Ionic product(IP) lt K_("sp") for a salt solution of AB, then addition of AB further ........... lead to precipitation initially. |
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Answer» |
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| 47. |
If increase in temperature and volume of air ideal gas is two times, then intitial pressure of P changes to: |
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Answer» 4P |
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| 48. |
If in Hydrogen atom, an electron jumps from n_(2) = 2 to n_(1) = 1 in Bohr.r orbit, then the value of wave number of the emitted photon will be (R = 109700 cm^(-1)) |
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Answer» `54850 CM^(-1)` |
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| 49. |
If in Bohr.s model, for uni electronic atom following symbols are used : r_(n,z) toRadius of n^(th) orbit with atomic number z. U_(n.z) to Potential energy of e^-K_(n.Z) toKinetic energy of e^- T_(n.Z) toTime period of revolution |
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Answer» |
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| 50. |
If in Bohr.s model, for uni electronic atom following symbols are used : r_(n, Z) rarr Radius of n^(th) orbit with atomic number z U_(n, Z) rarr Potential energy of e^(-) K_(n, Z) rarr Kinetic energy of e^(-) V_(n,Z) rarr Velocity of e^(-) T_(n, Z) rarr Time period of revolution |
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Answer» |
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