This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
An element with mass number 81 contains 31.7% more neutrons as compared to protons.Assign the sysmbol to the element. |
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Answer» Solution :An element can be identified by its atomic NUMBER only.Let us find the number.<BR>Let the number of protons=x `:.`Number of neutrons `=x+(x xx32.7)/(100)=(x+0.317x)` Now,mass no of element=NO. of protons+ No. of neutrons `81=x+x+0.317x=2.317x` or x=(81)/(2.317)=35 `:.`NO.of protons=35,No.of neutrons=81-35=46 The element with atomic number(Z)35 is `"BROMINE"_(35)^(81)Br.` |
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| 2. |
An element with mass number 81 contains 31.7% more neutrons as compared to protons. Assign the atomic symbol |
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Answer» Solution :Mass NUMBER = 81, i.e., `p + N = 81` If PROTONS = x, then neutrons `= x + (31.7)/(100) XX x = 1.317 x` `:. x + 1.317 x = 81 or 2.317 x = 81 or x = (81)/(2.317) = 35` Thus, Protons = 35, i.e., ATOMIC no. = 35 Hence, the symbol is `._(35)^(81)Br` |
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| 3. |
An element with electronic arrangement as 2, 8, 18, 1 will exhibit the following stable oxidation states |
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Answer» `+2 & +4` |
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| 4. |
An element with density 11.2 g cm^(-3) forms a f.c.c. lattice with the edge length of 4xx10^(-8) cm. Calculate the atomic mass of the element. (Given :N_A=6.022xx10^23 "mol"^(-1)) |
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Answer» `THEREFORE M=(rhoxxa^3xxN_A)/Z=((11.2 g CM^(-3))(4XX10^(-8) cm)^3xx(6.022xx10^23 mol^(-1)))/4=107.9 "g mol"^(-1)` |
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| 5. |
An element with density 11.2g cm^(-3)forms a f.c.c lattic with edge lengh of4 xx 10^(-8)cm. calculate the ofatoms mass of the element( Given :N_(A) = 6.022 xx 10^(23) mol^(-1) |
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Answer» <P> `M = ( p xx a^(3) xx N_(A))/ Z = (( 11.2 " G cm"^(-3)) ( 4xx 10^(-8) "cm")^(3) xx ( 6.022 xx 10^(23) "mol"^(-1)))/4 = 107.9 " g mol"^(-1)` |
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| 6. |
An element with atomic number 20 will be placed in which period of the periodic table? |
| Answer» ANSWER :A | |
| 7. |
An element with atomic number 106 has beendiscovered recently. Which of the following electronic configuration will it posses |
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Answer» `[Rn]5f^(14)6d^(5)7S^(1)` |
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| 8. |
An elementwith atomic number106has beendiscoveredrecently. Which of the followingelectronicconfigurationwill itposses ? |
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Answer» `[Rn ] 5f^(14) 6D^(4)6d^(4) 7s^(2) ` |
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| 9. |
An element with atomic no.20 will be placed in which period of the periodic table ? |
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Answer» 4 |
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| 10. |
An element with a mass number of 81 contains 31.7% more neutrons as compared to protons. Identify the element |
| Answer» Answer :C | |
| 11. |
An element with 1s^2 2s^2 2p^6 3s^2 electronic arrangement will be forming |
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Answer» ACIDIC oxide |
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| 12. |
An element which lies in the same group of the periodic table as mercury is |
| Answer» ANSWER :A | |
| 13. |
An element which is recently discovered is placed in 7th period and 10th group. IUPAC name of the element will be |
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Answer» Unnilseptium |
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| 14. |
An element of I^(st) transition series X^(+3) have highest magnetic moment in series and X^(+2) have non mangnetic nature as low spin complex. If atomic number of X is 'a' and number of unpaired e^(-) in free state X^(+2) and X^(+3) is 'b' and 'c' then calculate a+b+2c. |
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Answer» |
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| 15. |
An element of group 2 forms covalent oxide which is amphoteric in nature and dissolves in water to give an amphoteric hydroxide . Identify the element and write chemical reactions of the hydroxide of the element with an alkali and an acid . |
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Answer» Solution :Because of small size and comparatively high electronegativity of Be , BeO is covalent . It is INSOLUBLE in water . It is amphoteric in nature and DISSOLVES in acids as well as alkalies . `BeO + 2 HCL to BeCl_(2) + H_(2)O` `BeO + 2NaOH to underset("Sod. beryllate")(Na_(2)BeO_(2) +) H_(2)O` |
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| 16. |
An element of group-2 forms covalent oxide which is amphoteric in nature and dissolves in water to give an amphoteric hydroxide. Identify the element and write chemical reactions of the hydroxide of the element with an alkali and an acid. |
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Answer» Solution :In group 2, Be is the only ELEMENT which gives COVALENT oxide Bel, which is AMPHOTERICIN nature. The rest elements of this group give ionic oxides which are BASIC in nature. Beo dissolves in water and gives sparingly soluble hydroxide which reacts with acid and base to give salt `BeO+H_(2)O to underset("Beryllium hydroxide")(Be(OH)_(2))` `Be(OH)_(2)`is AMPHOTERIC hydroxide. So it is soluble in both acid and base. In produces tetra hydroxide beryllate `(Z^(-))` ionon salublizing in NaOH like alkali solution. `2NaOH_((aq)) +Be(OH)_(2(s)) to underset("hydroxidoberyllate")underset("Sodium tetra")(Na_(2)Be(OH)_(4(aq)))` It produces beryllium salt on reaction with acid. `Be(OH)_(2) +H_(2)SO_(4) underset("Beryllium sulphate")(to BeSO_(4)+2H_(2)O)` |
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| 17. |
An element of group 14 forms two oxides one of which is highlty poisionous and neutral. Other oxide can be easily liquefied and compressed to give a solid which is used as a refrigerant under the name of drikold. The element and the oxides are |
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Answer» `Si,SiO,SiO_(2)` |
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| 20. |
An element occupies group number 1 and period number 3. This element heated in air gives compound A. With water it gives compound B - a strong base. With ammonia gives compound C, which is used as a reducing agent in organic chemistry. Identify the element A,B and C. |
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Answer» Solution :(i) As per the position in the PERIODIC table this element occupying group NUMBER 1 and period number 3 is sodium. (ii) When heated in air, it forms sodium peroxide (A) `4 Na +O_2 rArr 2 Na_2O_2` (iii) With water, sodium gives sodium hydroxide (B) `2Na +2H_2O rArr 2NaOH +H_2` (iv) With ammonia, sodium gives sodamide (I) `2Na + 2NH_(3) overset(570-670 K)rarr 2 NaNH_2 +H_2` The element is sodium. The compound A is sodium peroxide. The compound B is sodium hydroxide. The compound C is sodamide. |
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| 21. |
An element occupies group no.13 and period number 2 is an representative element of that group reacts with carbondioxide and forms an oxide (A). (A) reacts with CuSO_(4) give blue beads (B). Identify the element compound (A) and (B). Write the reaction. |
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Answer» Solution :As per the position in the periodic table this element which occupies group number 13 and period number 2 is BORON and it reacts with `CO_(2)` to form boric oxide 1) `3CO_(2)+4Brarr2B_(2)O_(3)+3C` `therefore` the COMPOUND A is `B_(2)O_(3)` 2) `B_(2)O_(3)` reacts with `CuSO_(4)` to form `underset(("Red"))((CuBO_(2))_(2))` `CuSO_(4)+B_(2)O_(3)rarrCu(BO_(2))_(2)+SO_(3)` `therefore` the compound B is copper BEAD. `Cu(BO_(2))_(2)` |
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| 22. |
An element M reacts with chlorine to from a compound X. The bond angle in X si 120^(@). What is M? |
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Answer» Be |
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| 23. |
An element M has an atomic number 9 and atomic mass 19. Its ion will be represented by (1) M (2) M^(2+) (3) M^(-) (4) M^(2-) |
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Answer» |
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| 25. |
An element having electronic configuration [Rn]6s^(1) will: |
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Answer» Form BASIC oxide Due to larger size and low ionisation enthalpy of `[Rn]6s^(1)` (i.e. Cs). |
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| 26. |
An element having electronic configuration- [Ar] 3d^(3) 4s^(2)belongs to ........ |
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Answer» s-block "Elements in which the last electron is FILLED in d-orbital are known as d-block element. |
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| 27. |
An element has nine positive charges in its nucleus. Its common oxidation state is |
| Answer» ANSWER :C | |
| 28. |
An element has electronic configuration 1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(4). Predict their period , group and block : |
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Answer» <P>Period = `3^(rd)`, block = p, group = 16 By observing PRINCIPAL quantam NUMBER (n), Orbital (s,p, d,F)and equating no. of `e^(-)`, s we are able to find the period, block and group of element in periodic table. |
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| 29. |
An element has atomic mass 93 "g mol"^(-1) and density 11.5 "g cm"^(-3). If the edge length of its unit cell is 300 pm, identify the type of unit cell |
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Answer» HENCE, the type of unit cell is BCC. |
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| 30. |
An element has atoic mass93 " g mol" ^(-1)and density11.5 " g cm" ^(-3). If the edge length of its unit cell is 300 pm,identify the type of unit cell. |
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Answer» Hence, the TYPE of unit cell in BCC. |
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| 31. |
An element has a body-centred cubic (bcc) structure with cell edge of 288 pm. The density of the element is 7.2 g//cm^3 . How many atoms are present in 208 g of the element ? |
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Answer» Solution :For the BCC structure, Z=2 EDGE of the unit cell , a=288 pm , DENSITY of the element , `rho=7.2 g//cm^3` Subtituting the values in the expression `rho=(ZxxM)/(a^3xxN_0)` `7.2 g cm^(-3) =(2xxM)/((288xx10^(-10) cm)^3 XX(6.02xx10^23 mol^(-1))) "or" M=51.8 g mol^(-1)` By mole concept, 51.8 g of the element contains =`6.02xx10^23` atoms `therefore` 208 g of the element contains =`(6.02xx10^23)/51.8xx208` atoms =`24.17xx10^23` atoms |
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| 32. |
An element has 2 electrons in its K-shell. 8 electrons in L-shell, 13 electrons in M-shell and one electron in N-shell. The element is |
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Answer» Cr |
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| 33. |
An element has 18 electrons in the outer most shell. The element is |
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Answer» Transition METAL |
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| 34. |
An element forms two oxides containing 50% and 40% of the element by mass. Prove that the results are in agreement with the law of multiple proportions. |
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Answer» Solution :In the first oxide, the PERCENTAGE of element is 50. This means that 50 g of element combine with 100 - 50 = 50 g of oxygen. Let us calculate the amount of oxygen that combines with a fixed amount (say 100 g) of the element. The amount of oxygen that combines with 100 g of element = `50/50 XX 100 = 100 g` In the second oxide, the percentage of the element is 40. This means that 40 g of element combine with 60 g of oxygen. `therefore`The amount of oxygen that combines with 100 g of element `=60/40 xx 100 = 150 g` Now, the amounts of oxygen that combine with 100 g of element in the TWO cases are respectively 100 g and 150 g. The ratio in these amounts is 2 : 3 which is a simple whole number ratio. Thus, the results are in agreement with the LAW of multiple proportions. |
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| 35. |
An element (density 6.8 g cm^(-3)) occurs in the BCC structure with cell edge of 290 pm. Calculate the number of atoms present in 200 g of the element. |
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| 36. |
An element (density 6.8 gcm^(-3)and the length of the side of the unit cell is 316 pm. The unit cell in the most important crystalline form of tungsten is the body centred unit cell. How many atoms of theelementdoes 50 gof the element contain ? |
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| 37. |
An element crytallizes in the cubic lattice and the edge of the unit cell is 430 pm. Calculation the number of atoms in a unit cell. [ Atomic mass of Na = 23.0amu. Density of sodium = 0.9623 gcm^(-3) ,N_(A)= 6.023 xx 10^(23)mol^(-1) |
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| 38. |
An element crystallizes into a structure which may be described by a cubic type of unit cell having one atom on each corner of the cube and two atoms on one of its body diagonals. If the volume of this unitis24 xx 10^(-24)"cm"^(3)and density of element is7.2 g cm ^(-3),calculate the number of atoms present in 200 g of the element. |
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Answer» Solution :No. of atoms per unit cell ` = 8 XX 1/8 + 2 = 3 ,i.e. , Z =3 ` Volume of the unit cell = ` a^(3) = 24 xx 10^(-24) " cm" ^(3)` ` p = ( Z xx M)/ ( a^(3) xx N_(0))` ` 7.2 = (3xx M) / (( 24 xx 10^(-24) ) xx ( 6.023 xx 10^(23)) )or M = 34.69` Thus, 34.69g of the element have to atoms =`6.023 xx 10^(23)` 200 G of the element will have atoms ` = ( 6.023 xx 10^(23))/(34.69) xx 200 = 3.4722 xx 10^(24)` atoms |
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| 39. |
An element crytallizes in fcc lattice having edge length 400 pm. Calculate the maximum diameter which can be placed in interestital sites without disturing the structure. |
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Answer» Solution :Interstitial sites can be either tetrahedral or orctahdral or octahedral voids. As octahedral voids are bigger than tetrahedral voids, maximum diameter can fit into octahedral voids. If R is the R is the size of atoms in the fcc packing and r is the size of the octahedral void , r= 0.414 R. if fcc lattice, face diagonal =` SQRT2 a ` As in fcc, atoms along the face diagonal are tourching each other. ` 4R =sqrt2 a or R = (sqrt2a)/4` Required diameter of the interestitial site = 2R = ` 2xx 0.414 R = 2 xx 0.414 xx sqrt2/4 xx 400`pm. 117.1 pm. |
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| 40. |
An element crystallizes into a structure which may be described by a cubic type of unit cell having one atom on each corner of the cube and two atoms on one of its body diagonals. If the volume of this unit cell is 24xx10^(-24) cm^3 and density of element is 7.2 g cm^(-3) , calculate the number of atoms present in 200 g of the element. |
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Answer» Solution :No. of ATOMS PER unit cell =`8xx1/8+2=3` i.e., Z=3 VOLUME of the unit cell =`a^3 = 24xx10^(-24) cm^3` `RHO=(ZxxM)/(a^3xxN_0)` `therefore 7.2=(3xxM)/((24xx10^(-24))xx(6.023xx10^23))` or M=34.69 Thus , 34.69 g of the element have atoms =`6.023xx10^23` `therefore` 200 g of element will have atoms =`(6.023xx10^23)/34.69xx200=3.4722xx10^24` atoms |
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| 41. |
An element crystallizes in fcc lattice having edge length 400 pm. Calculate the maximum diameter which can be placed in interstitial sites without disturbing the structure . |
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Answer» Solution :Interstitital sites can be either tetrahedral or octahedral voids. As octahedral voids are bigger than tetrahedral voids, MAXIMUM diameter can fit into octahedral voids. If R is the size of atoms in the fcc packing and r is the size of the octahedral void, r=0.414 R In fcc lattice, face diagonal =`sqrt2a` As in fcc, atoms along the face diagonal are touching each other . `4R=sqrt2a "or" R=(sqrt2a)/4` REQUIRED diameter of the interstitial site =2 r =2 x 0.414 R =2 x 0.414 x `sqrt2/4` x 400 PM =117.1 pm (`because` a=400 pm ) |
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| 42. |
An element crystallizes in a f.c.c. lattice with cell edge of 250 pm. Calculate the density if 300 g of this element contains 2 xx 10^24 atoms |
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Answer» Density`(RHO)=(ZxxM)/(a^3xxN_0)=(4xx90.3)/((250xx10^(-10))^3xx(6.02xx10^23))=38.4 g cm^(-3)` |
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| 43. |
An element crystallize in f.c. lattice with cell edge of 250 pm. Calculate the density if 300 g of this element contains2 xx 10^(24)atoms. |
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Answer» Density `(p)= (Z xx M)/(a^(3)xxN_(0))= (4xx90.3)/((250xx10^(-10))^(3) xx (6.02 xx 10^(23))) = 38.4 " g mol" ^(-3)` |
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| 44. |
An element crystallises in a faces centered cubic lattice. Hence, its unit cell contains |
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Answer» 14 ATOMS of the ELEMENT and 8 of them belong to the unit cell |
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| 45. |
An element belongs to 3^(rd) period and group 13 of the periodic table. Which of the following properties will be shown by the element ? |
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Answer» GOOD conductor of electricity Being metallic in nature, ALUMINIUM behaves as a good conductor of electricity |
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| 46. |
An element belongto 3rdperiodand group- 13 of theperiodictable. Which of thefollowingproperties will beshown by theelement gt |
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Answer» Goodconductor of electricity |
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| 47. |
An element (atomic mass=250 u) crystallizes in a simple cubic. If the density of the unit cell is 7.2 g cm^(-3),what is the radius of the element ? |
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Answer» `1.93times10^(-3)CM` or`a^(3)=57.6times10^(-24)` or`a=3.86times10^(-8)` For simple cubic, `r=a//2=1.93times10^(-8)` cm |
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| 48. |
An element ("atomic mass"=100 g//mol)having BCC structure has uniti cell edge 400 pm. The density of the element is |
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Answer» 2.144g`CM^(-3)` `=(2times100)/((400)^(3)times6.02times10^(23)times10^(-30))` `= 200/(64times6.02times10^(-1))= 5.188 cm^(-3)` |
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| 49. |
An element A in conmpound ABD has an oxidation no. A^(n-). It is oxidisides by Cr_(2)O_(7)^(2-) in acid medium. In an experiment 1.68xx10^(-3) mole of K_(2) Cr_(2)O_(7) was required for 3.26xx10^(-3) moel of the compound ABD. Calculate new oxidation state of A. |
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Answer» |
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| 50. |
An element A in a compound AB has oxidationnumber -n. IT is oxidized by Cr_(2)O_(7)^(2-) in acid medium. In the experiment 1.68xx10^(-3) moles of K_(2)Cr_(2)O_(7) was usedfor 3.36xx10^(-3) moles of AB. The new oxidation number of A after oxidation is |
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Answer» 3 `A^(n-)OVERSET(+n)rarrA^(X)` `1/(x+n)` moles `A^(n-),` `overset(+12)(Cr_2)overset(2-)(O_7)overset((6))rarr2cv^(3+)` `-=1/6` moles `Cr_(2)O_(7)^(2-)=1.68 xx10^(-3)` `(x+n)Cr_(2)O_(7)^(2-)-=6A^(n-)` `1.6 8810^(-3)""?` `=(1.68 xx10^(-3)xx6)/(x+n)=3.26xx10^(-3)` x = 3 - n |
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