InterviewSolution
This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 93501. |
0.2 gm of fine animal charcoal is mixed with ahlf litre of acetic acid (-SM) solutioin and shaken for 30 minutes |
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Answer» The CONCENTRATION of the solution decreases |
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| 93502. |
0.2 gm of a mixture of NaOH and Na_(2)CO_(3) and inert impurities was first titrated with phenolphthalein and n/10HCl, 17.5 ml of HCl was required at the end point. After this methyl organge was added and 2.5 ml of same HCl was again required for next end point. Find out percentage of NaOH and Na_(2)CO_(3) in the mixture. |
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Answer» Solution :Let , `W_(1)` gm NaOH and `W_(2) gmNa_(2)CO_(3)` was present in MIXTURE . At phenophthaiein end point , `(W_(1)/40 + 1/2xx W_(2)/53 ) = 1/10 xx 17.5 xx 10^(-3)` At SECOND end point following reaction takes place Eq. of `NaHCO_(3) = Eq`. of HCL used (in second titration ) ` = 1/2 " Eq. of " Na_(2)CO_(3)` ` 1/2 xx W_(2)/53 =25 xx 1/10 xx 10^(-3) ` `W_(2) = 0.0265` gm Putting the value of `W_(2) ` in Eq. (1) , we get `W_(1) = 0.06` gm Percentage of NaOH = `(0.06)/(0.2) xx 100 = 30 %` Percentage of `NaCO_(3) = (0.0265)/(0.2) xx 100 = 13.25 %` |
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| 93503. |
0.2 g of a sample of H_(2)O_(2) required 10 mL of N KMnO_(4) in a titration in the presence of H_(2)SO_(4) .Purity of H_(2)O_(2) is |
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Answer» 0.25 |
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| 93504. |
0.2g of an organic compoundcontaningC, Hand O on combustion gave 0.147 g of CO_(2)and0.12g of water . Thepercentage content ofoxygen in the compoundis : |
| Answer» ANSWER :A | |
| 93505. |
0.2 g of an organic compound containing C, Hand O ,on combustion yielded 0.147 g Co_2 and 0.12 g water .The percentage of oxygen in it is : |
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Answer» 73,29% |
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| 93506. |
(0.1M "urea")/((A)),(0.1M NaCl)/((B)),(0.1MBaCl_(2))/((C)) |
| Answer» Solution :`{:("ORDER of" PI,CgtBgtA),("order of" R.L.V.P,C GT B gt A),("order of" V.P,Agt B gt C),("order of" DeltaT_(B),C gt B gt A),("order of" T_(B) "of solution", C gt B gt A),("order of" DeltaT_(F),C gt B gt A),("order of" T_(F) " of solution",A gt B gt C):}` | |
| 93507. |
0.1M solution of which of the following compounds will have the lowest freezing point ? |
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Answer» `FeSO_(4).(NH_(4))_(2)SO_(4).6H_(2)O` |
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| 93508. |
0.1m solution of KCI and BaCI_(2) are preparred. The freezing point of KCI solution is found to be- 4.0^(@)C.What will be the freezing point of BaCI_(2) solutionassuming that both KCI and BaCI_(2) solution are sompletely ionised in solution ? |
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Answer» `-3^(@)C` `DeltaT_(f)=(0.0.4^(@)C)=4^(@)C` `4K=2xxK_(f)xxm` `"For " BaCI_(2),DeltaT_(f)=iK_(f)xxm` `=3xxK_(f)xxm` Both `K_(f)` and m are same for the SOLUTE, `DeltaT_(f)=(BaCI_(2))=3` FREEZING POINT of `BaCI_(2)=0-3=-3^(@)C` |
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| 93509. |
0.1m K_(2)SO_(4) ionises to 10 x% to boil at same temperature as 0.2 glucose. What is x ? |
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| 93510. |
0.1M CH_(3)COOH(aq.) Is mixed with 0.1M NaOH(aq.). The pH of solution on mixing will be (K_(a) ofCH_(3)COOH is 1.8xx10^(-5) |
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Answer» `4.74` |
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| 93511. |
0.1g of an unknown substance was dissolved in 5g of camphor and it was found that the melting point of camphor was depressed by 5.3^(@)C. If K_(f) is 39.7, find the weight of 1 mole of the solute. |
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| 93512. |
0.1978 g of copper is deposited by a current of 0.2 ampere in 50 minutes. What is the electrichemical equivalent of copper ? |
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Answer» Solution :Here, t = 50 minutes `=50xx60` seconds , I = 0.2 AMPERE Quantity of electricity used is `Q=Ixxt=0.2xx50xx60=600" coulomb"` AMOUNT of COPPER deposited by 600 COULOMBS = 0.1978 g Amount of copper deposited by 1 coulomb `=(0.1978)/(600)g=0.0003296g` Electrochemical EQUIVALENT of copper `=0.0003296=3.296xx10^(-4)gc^(-1)` `=3.206xx10^(-7)kgc^(-1)` |
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| 93513. |
0.1914g of an organic acid is dissolved in approx. 20 ml of water. 25 ml of 0.12 N NaOH required for the complete neutralization of the acid solution. The equivalent weight of the acid is |
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Answer» 65 NORMALITY`=(wt)/(eq.wtxxvolume)implies0.12=(0.1914xx1000)/(Exx25)` eq.wt.`=(0.1914xx1000)/(0.12xx25)=63.8`. |
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| 93514. |
0.1890g of an organic compound gave 0.2870g of silver chloride by Carius method. Find the percentage of chlorine in the compound |
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| 93515. |
0.189 g of an organic substance gave in a carius determination 0.287 g of silver chloride. What is the % of Cl in the given compound? |
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Answer» SOLUTION :W= 0.189g WT. AgCl= 0.287 G % of Cl `+(35.5xx0.287xx100)/(143.5xx0.189) =37.57%` |
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| 93516. |
0.188gm of silver bromide is obtained from x gm of an organic compound and percentage of bromine in the compound is 4. Then the x value is |
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Answer» <BR> Solution :`% Br = (80 xx "weight of AGBR" xz 100)/(188 xx "weight of compound")` , valancy of x is 2 |
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| 93517. |
0.188 g of silver bromide is obtained from 4 g of an organic compound. Calculate the percentate of bromine in the compound |
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Answer» <BR> Solution :`%Br=(80 xx "weight of AgBr" xx 100)/(188 xx "weight of a organic COMPOUND")` |
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| 93518. |
0.170 g of a volatile liquid displaced 69.1 mL air in Victor Meyor's method. The atmospheric temperature was 15^@ C and pressure was 755 mm. (Aqueous tension at 15^@C = 12.7 mm ). Find the molecular weight of the liquid. |
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| 93519. |
0.16g of N_(2)H_(4) are dissolved in water and the total volume made upto 500 mL. Calculate the percentage of N_(2)H_(4) that has reacted with water in this solution. The K_(b) for N_(2)H_(4) is reacted with water in this solution. The K_(b) for N_(2)H_(4) is 4.0 xx 10^(-6) M |
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Answer» `K_(B) = (C alpha^(2))/((1-alpha)) RARR K_(b) = C alpha^(2)` (`because alpha` is very small, so `1-alpha ~~ 1`) `[N_(2)H_(4)] = C = (0.16 xx 1000)/(32 xx 500) = 0.01` `:. alpha^(2) = (4 xx 10^(-6))/(0.01) = 4 xx 10^(-4) "" (because = K_(b) = 4 xx 10^(-6)M)` `:. alpha = 2 xx 10^(-2) = 0.02` or 2%. |
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| 93520. |
0.16g of an organic compound, on complete combustion, produced 0.44g of CO_(2) and 0.18g of H_(2)O. Calcuate the percentage of carbon and hydrogen in the organic compounds |
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Answer» Solution :Moles of C in `CO_(2)=1 xx` moles of `CO_(2)` `=1 xx (0.44)/(44)= 0.01` Weight of C= moles of C `xx` at. Wt . of C `=0.01 xx 12 = 0.12g` Moles of H in `H_(2)O=2 xx` moles of `H_(2)O` `=2 xx (0.18)/(18)= 0.02` weight of H= moles of `H xx` at. wt. of H `= 0.02 xx 1 = 0.02g` `THEREFORE` % of `C= (0.12)/(0.16)xx 100= 75%` and % of `H= (0.02)/(0.16) xx 100= 12.5%` |
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| 93521. |
0.16 gm of organic acid required 25 ml of (N)/(10) NaOH for complete neutralization. (M. wt of acids is 128). Then the basicity of acid is |
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Answer» `(wt)/("Gewt")= 25 XX 0.1 xx 10^(-3)` `(0.16)/("Gewt") = 25 xx 0.1 xx 10^(-3)` valancy(basicety) = `("Mol.wt")/("Gewt")=2` |
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| 93522. |
0.16 gm of a dibasic acid require 25 ml of decinormal NaOH solution for complete neutralization. The moleucular weight of the acid |
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Answer» 32 MOL. Wt.=`64xx2=128`. |
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| 93523. |
0.16 g of methane was subjected to combustion at 27^(@)C in a bomb calorimeter. The temperature of Calorimeter system (including water) was found to rise by 0.5^(@)C. Calculate the heat of combustion of methane at (i) constant volume (ii) constant pressure. The thermal capacity of Calorimater system is 17.7" kJ K"^(-1). (R=8.313" J mol"^(-1) K^(-1)) |
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Answer» Total energy relesed `=17.7xx0.5=8.85` Energy released by one MOLE `CH_(4)=8.85/0.16 xx16=-885" kJ/mol"` `DeltaH=DeltaU+Deltan_(G) RT rArr Deltan_(g) =-1 rArr DeltaH=-889.95" kJ/mol"` |
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| 93524. |
0.16 g of N_2H_4are dissolved in water and the total volume made upto 500 mL. Calculate the percentage of N_2H_4that has reacted with water in this solution. K_b( N_2H_4) = 4.0 xx 10^(-6) M |
| Answer» SOLUTION :`N_2H_4 + H_2O to N_2H_5OH IFF N_2H_5^(+) + OH^-`2% | |
| 93525. |
0.16 g of methane was subjected to combustion at 27^@Cin a bomb calorimeter. The temperature of the calorimeter system (including water) was found to rise by 0.5^@C . Calculate the heat of combustion of methane at (i) constant volume, (ii) constant pressure. The thermal capacity of the calorimeter system is 17.7 kJ K^(-1) (R = 8.31 JK^(-1) "mol"^(-1)) |
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Answer» SOLUTION :`DELTA E= (17.7 xx 0.5)/(0.16//16) KJ "mol"^(-1)` -885 kJ, -889.986 kJ |
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| 93526. |
0.16 g of a dibasic organic acid required 25vm^(3)of 0.1 M NaOH for complete neutralization. Thre molecular mass of the acidof the acid is : |
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Answer» 45 |
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| 93527. |
0.15g of an organic compound gave 0.12g of silver bromide by the Carius method. The percentage of bromine in the compound is : |
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Answer» `42.06`<BR>`38.96` `188g` of `AgBr` CONTAIN bromine `=80G` `0.12g` of `AgBr` contain bromine `=(80)/(188)xx0.12` `=0.051g` PERCENTAGE of bromine `=(0.051)/(0.15)xx100` `=34.04%` |
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| 93528. |
0.15g of an organic compound (A) gave 0.33g of CO_(2) and 0.18g of H_(2)O. The molecular weight of (A) is 60. The compound (A) on dehydration gave a hydrocarbon (B) containing 85.7% of C. (B), on successive treatment with hydriodic acid and silver hydroxide gave a product (C ), isomeric with (A). Find structural formula of (A), (B) and (C ) |
| Answer» Solution :`[((A) CH_(3)CH_(2)CH_(2)OH),((B) CH_(3)CH= CH_(2)),((C ) CH_(3)CH(OH)CH_(3))]` | |
| 93529. |
0.15 mole of pyridinium chloride has been added into 500 cc of 0.2 M pyridinesolution. Calculate the pH and hydroxyl-ion concentration in this resulting solution assuming no change in volume. K_b for pyridine = 1.5 xx 10^(-9) M . |
| Answer» SOLUTION :`5, 10^(-9)`M | |
| 93530. |
0.15 molalsolutionof NaCIhas freezingpoint -0.52 ^(@)C Calculatevan'tHofffactor.(K_(f)= 1.86 K kg mol^(-1) ) |
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Answer» Freezingpoint of THESOLUTION=- 0.52 `.^(@)C` `K_(f)= 1.86K kg MOL^(-1)` `:. T_(f) =273 + (-0.52)= 272 .48 K` `T_(o)= 273 K` `:.` Depressionin freezingpoint `=DeltaT_(f(OBS))=T_(o) -T_(f)` `=273- 272.48` `= 0.52K` Theoreticaldepression infreezingpoint `= Delta T_(f_(th))` `Delta _(f_(th)) = K_(f)xx m =1.86 xx 0.15 = 0. 279 K` van't Hofffactori is `i= (Delta _(f(ob)))/(Delta_(T_(f_((th)))))=(0.52)/(0.279) = 1.864` |
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| 93531. |
0.146g of an acid requires 20 ml of 0.1 N NaOH for complete neutralization. The equivalent weight of the acid is |
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Answer» 45 volume`=20ml=(20)/(1000)` litre Normality`=0.1N,` EQUIVALENT weight=? Equivalent weight`=("Weight of acid")/(NxxV)` `=(0.126xx1000)/(0.1xx20)=63` |
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| 93532. |
0.12g of organic compound containing sulphur on treatment with Conc. HNO_(3) in a carius tube and then with excess of BaCl_(2) produced 0.233g of BaSO_(4). % of 'S' in compound ........... |
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Answer» |
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| 93533. |
0.126g of an acid requires 20 ml of 0.1N NaOH for complete neutralization. Equivalent weight of the acid is |
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Answer» 45 |
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| 93534. |
0.126 g of an acid requires 20 mL of 0.1 N NaOH for complete neutralisation . Eq.wt of the acid is |
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Answer» 45 |
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| 93535. |
0.126 g of an acid is needed to completely neutralise 20 mL 0.1 N NaOH solution. The equivalent weight of the acid is |
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Answer» 53 `=(NV)/1000 =(0.1 XX 20)/1000 = 2 xx 10^(-3)` No. of gram equivalents `=("mass")/("Equivalent mass")` `2 xx 10^(-3) = 0.126/("Equivalent mass")` Equivalent mass `=0.126/(2 xx 10^(-3)) = 126/2 = 63` |
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| 93536. |
0.123g of an organic compound produced 0.099g of CO_(2) and 0.0507g of H_(2)O. 0.185g of the same compound produced 0.319g of AgBr. Find the percentage of carbon, hydrogen and bromine in the compound |
| Answer» SOLUTION :`21.96%, 4.48%, 73.36%` | |
| 93537. |
0.1 mole of N_(2)O_(4(g)) was sealed in a tube under one atmospheic conditions at 25^(@)C. Calculate the number of moles of NO_(2(g)) present, if the equlibrium N_(2)O_(4(g))hArr2NO_(2(g))(k_(p)=0.14) is reache3d after some time |
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Answer» <P>`1.8xx10^(2)` `(.1-alpha)""2ALPHA` `thereforeP prop0.1` If V and T are constant `(Pprop0.1+alpha)P=(0.1+alpha)//0.1` `K_(p)=([2alpha]^(2))/([0.1-alpha])xx[(P)/(0.1+alpha)]or K_(p)=(40alpha^(2))/([0.1-alpha])=0.14` `alpha=0.017` `NO_(2)=0.017xx2=0.034` MOLE |
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| 93538. |
0.1 mole of sugar is dissolved in 250 g of water. The freezing point of the solution is [K_(f) "for" H_(2)O = 1.86^(@)C "molal"^(-1)] |
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Answer» `-0.460^(@)C` |
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| 93539. |
0.1 mole of XeF_(6) is treated with 1.8 g of water.The product obtained is |
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Answer» `XeO_(3)` `XeF_(6) + H_(2)O to XeOF_(4) + 2HF` |
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| 93540. |
0.1 mole of CH_(3)NH_(2)(K_(b)=5xx10^(-4)) is added to 0.08 mole of HCl and the solution is diluted to one litre. The resulting [H^(+)] is |
| Answer» Solution :The resulting solution is a buffer solution. | |
| 93541. |
0.1 mole of CH_(3)NH_(2)(K_(b) = 5 xx 10^(-4)) is mixed with 0.08 mole of HCl and diluted to one litre. What will be the H^(+) concentration in the solution |
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Answer» `8 xx 10^(-2)M` As it is a BASIC buffer solution. `pOH = pK_(b) + log.(0.08)/(0.02) = - log5 xx 10^(-4) + log 4` `= 3.30 + 0.602 = 3.902` `PH = 14 - 3.92 = 10.09`, `[H^(+)] = 7.99 xx 10^(-11) = 8 xx 10^(-11) M` |
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| 93542. |
0.1 mole of CH_(3)NH_(2) (K_(b) = 5 xx 10^(-4)) is mixed with 0.08 mole for HCl and diluted to one litre. What will be the H^(+) concentration in the solution |
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Answer» `8 xx 10^(-2)M` (Basic buffer solutions) `[OH^(-)] = K_(b) xx ("Base")/("Salt") = 5 xx 10^(-4) xx (0.02)/(0.08) = 1.25 xx 10^(-4)` `:. [H^(+)] = (10^(-14))/([OH^(-)]) = (10^(-14))/(1.25 xx 10^(-4)) = 8 xx 10^(-11) M`. |
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| 93543. |
0.1 mol of sugar was dissolved in 1 kg of water. The freezing point of the solution was found to be 272.814 K. What conclusion would you draw about the molecular state of sugar? K_(f) for water is "1.86 K kg mol"^(-1). |
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| 93544. |
0.1 molal aqueous solution of sodium bromide freezes at -0.335^(@)C at atmospheric pressure. K_(f) for water is 1.86^(@)C. The percentage of dissociation of the salt in solution is |
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Answer» 90 `alpha = (i-1)/(n-1) = (i-1)/(2-1)` For NABR `i = 1 + alpha or alpha = 0.80 = 80%` |
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| 93545. |
0.1 mole of a carbohydrate with empirical formula CH_(2)O contains 1 g of hydrogen. What is its molecular formula? |
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Answer» `C_(5)H_(10)O_(5)` `therefore "1 mole of carbohydrate will contain hydrogen"` = 10 g = 10 g atoms In `CH_(2)O`, g atomic RATIO of `C:H:O=1:2:1` `therefore" With 10 g ATOM of H, g atoms of C combined"` `="5 and g atoms of O combined = 5. Hence, actual formula (molecular formula) will be "C_(5)H_(10)O_(5)`. |
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| 93546. |
0.1 mole Ni is obtained on electrolysis of NiSO_(4) solution in neural solution, how much faraday electricity should be pass through the cell ? |
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Answer» 1F `Ni^(2+)+2e^(-) to Ni` So, 1 mole Ni is OBTAINED by 2F Then 0.1 mole Ni is obtained by `=(0.1" mole"xx2F)/(1" mole")=0.2F` |
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| 93547. |
0.1 mol of MnO_(4)^(-) in acidic medium can oxidize |
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Answer» `0.5 " MOL of " Fe^(2+)` |
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| 93548. |
0.1 mol of CH_(3)NH_(2)(K_(b)=5.0xx10^(-4)) is mixed with 0.08 mol of HCl and diluted to one litre. What will be the H^(+) ion concentration in the solution ? |
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Answer» `8xx10^(-2)M` For basic buffer `pOH=pK_(b)+"LOG"(0.08)/(0.02)` `pK_(b)=-log(5xx10^(-4))=3.30` `therefore pOH=pK_(b)+0.602` `=3.30+0.602=3.902` `pH=-log(3.902)=10.09` `[H^(+)]=-log(10.09)=7.99xx10^(-11)` or`=8xx10^(-11)M` |
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| 93549. |
0.1 mol HCl is dissolved in distilled water of volume V, then, at underset(Vtooo)(lim) (pH)_("solution") is equal to : |
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Answer» zero |
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| 93550. |
0.1 M solution of two electrolytes P and Q have specific conductance 4 times 10^(-4)" S "cm^(-1) " and " 6 times 10^(-6)" S "cm^(-1) respectively. Which among the following will have greater resistance to the flow of current? Give reason. |
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Answer» Solution :Specific CONDUCTANCE `K=C(l/a)` `""k=1/R(l/a)` That is `k ALPHA 1/R` Therefore Q will have greater resistance. |
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