This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 28751. |
The main product of the following reaction is C_(6)H_(5)CH_(2)CH(OH)CH(CH_(3))_(2)overset("conc. H_(2)SO_(4))to |
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Answer»
Trans is major product due to thermodynamically more stable as well as carbocation show anti elimination. |
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| 28752. |
The molar conductances of NaOH, NaCl and BaCl_(2) at infinite dilution are 2.481xx10^(-2), 1.265xx10^(-2) and 2.800xx10^(-2)" S "m^(2)mol^(-1) respectively. Calculate wedge_(m)^(@)Ba(OH)_(2). |
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| 28753. |
The main product of the following reactions is C_6H_5CH_2CH( OH) CH(CH_3) _2 overset( conc. H_2SO_4) to |
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Answer» ` (##AKS_NEO_CAO_CHE_XII_V02_P03_APP_E02_044_O01.png" WIDTH="30%"> |
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| 28754. |
The molar conductivitiesLambda_(NaOAc)^(0) and Lambda_(HCl)^(0) at infinitedilute in water at25^(@) Care 91.0 S cm^(2)//"mol" and 426.2 S cm^(2)//"mol" respectively . To calculate Lambda_(HOAc)^(0) the additional value required is |
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Answer» `Lambda_(NaCl)^(@)` |
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| 28755. |
The molar conductances of NaCl,HCl and CH_(3)COONa at infinite dilution are 126.45, 426.16 and 91ohm^(-1)cm^(2)mol^(-1) respectively. The molar conductance ofCH_(3)COOH at infinite dilution is:- |
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Answer» `201.28ohm^(-1)cm^(2)mol^(-1)` `=(^^)^(@)(CH_(3)COONA)+(^^)^(@)(HCL)-(^^)^(@)(NaCl)` `=91+426.16-126.45=390.71ohm^(-1)cm^(2)mol^(-1)` |
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| 28756. |
The main product of the following reaction R-COOH+CH_(2)N_(2)toProduct |
| Answer» Solution :`RCOOH+CH_(2)N_(2) overset)(ether)toRCOOCH_(3)+N_(2)` | |
| 28757. |
The molar conductance of NzCl varies with the concentration as shown in the following table and all values follows the equation lamda_(m)^(C)=lamda_(m)^(infty)-bsqrt(C) where lamda_(m)^(C)= molar specific conductance lamda_(m)^(infty)= molar specific conductance at infinite dilution C= molar concentration When a cenrtain conductivity cell (C) was filled with 25xx10^(-4)(M) NaCl solution. The resistance of the cell was found to be 1000 ohm At infinite dilution, Conductance of Cl^(-) and SO_(4)^(-2) are 80ohm^(-1)cm^(2)"mole"^(-1) and 160ohm^(-1)cm^(2)"mole"^(-1) respectively. Q. If the cell (C) is filled with 5xx10^(-3)(N)Na_(2)SO_(4) the observed resistance was 400 ohm. what is the molar conductance of Na_(2)SO_(4) |
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Answer» `19.25ohm^(-1)cm^(2)"mole"^(-1)` `K=((l)/(a))xx(1)/(R)=(0.1925)/(400)=4.81xx10^(-4)ohm^(-1)cm^(-1)` `lamda_(m)=(Kxx1000)/(M)=(4.81xx10^(-4)xx1000)/((5)/(2)xx10^(-3))` `lamda_(m)(Na_(2)SO_(4))=192.4ohm^(-1)cm^(2)"mole"^(-1)` |
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| 28758. |
The main product of the following reaction is C_6H_5CH_2CH(OH)CH(CH_3)_2 overset("conc". H_2SO_4)to ? |
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| 28759. |
The molar conductance of NaCl varies with the concentration as shown in the following table. And all values follows the equation lambda_m^C=lambda_m^oo-bsqrtC Where lambda_m^C=Molar specific conductance lambda_m^oo=Molar specific conductance at infinite direction C=Molar concentration {:("Molar Concentration of NaCl","Molar Conductance inohm"^(-1)cm^(2)"mole"^(1)),(4xx10^(-4),107),(9xx10^(-4),97),(16xx10^(-4),87):} When a certain conductivity cell (C ) was filled with 25xx10^(-4) (M) NaCl solution.The resistance of the cell was found to be 1000 ohm.At infinite dilution, conductance of Cl^(-) and SO_(4)^(-2) are 800 "ohm"^(-1) cm^(2)"mole"^(-1) and 160 "ohm"^(-1) cm^(2)"mole"^(-1) respectively. If the cell ( C) is filled with 5xx10^(-3) (N)Na_2SO_4 the observed resistance was 400 ohm. What is the molar conductance of Na_2SO_4 ? |
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Answer» `19.25 ohm^(-1) cm^(2) "mole"^(-1)` `K=(l/a)xx1/R=0.1925/400=4.81xx10^(-4) ohm^(-1)cm^(-1)` `lambda_m=(Kxx1000)/M=(4.81xx10^(-4)xx1000)/(5/2xx10^(-3))` `lambda_m(Na_2SO_4)=192.4 ohm^(-1) cm^2 "mole"^(-1)` |
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| 28760. |
The main product of the following reaction is C_(6)H_(5)CH_(2)CH(OH)CH(CH_(3))_(2) overset("conc. "H_(2)SO_(4))to? |
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Answer»
Dehydration occurs in such a way that the DOUBLE bond comes in conjugation with the `C_(6)H_(5)` group and further tans-alkenes are more stable than the cis-alkenes, therefore, OPTION (c) is correct. |
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| 28761. |
The molar conductance of NaCl varies with the concentration as shown in the following table. And all values follows the equation lambda_m^C=lambda_m^oo-bsqrtC Where lambda_m^C=Molar specific conductance lambda_m^oo=Molar specific conductance at infinite direction C=Molar concentration {:("Molar Concentration of NaCl","Molar Conductance inohm"^(-1)cm^(2)"mole"^(1)),(4xx10^(-4),107),(9xx10^(-4),97),(16xx10^(-4),87):} When a certain conductivity cell (C ) was filled with 25xx10^(-4) (M) NaCl solution.The resistance of the cell was found to be 1000 ohm.At infinite dilution, conductance of Cl^(-) and SO_(4)^(-2) are 800 "ohm"^(-1) cm^(2)"mole"^(-1) and 160 "ohm"^(-1) cm^(2)"mole"^(-1) respectively. What is the cell constant of the conductivity cell ( C) ? |
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Answer» `0.385 CM^(-1)` `lambda_m=lambda_m^oo-bsqrtC` `lambda_m=127-10^3(25xx10^(-4))^(1//2)` `lambda_m=127-10^(3)xx5xx10^(-2)` `lambda_m=77` But `lambda_m=(Kxx1000)/M " " K=(l/a)xx1/R` `lambda_m=(l/a)xx1/Rxx1000/M` `lambda_m`=[Cell CONSTANT]`xx1000/(RxxM)` `implies `77=[Cell constant]`xx1000/(1000xx25xx10^(-4))` Cell constant `=77xx25xx10^(-4)=0.1925 cm^(-1)` |
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| 28762. |
The main product of the following reaction is |
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Answer» `C_6H_5-OVERSET(OH)overset(|)CH_2CI` |
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| 28763. |
The molar conductance of NaCl varies with the concentration as shown in the following table and all values follows the equation lambda_m^( C)=lambda_m^(oo)-bsqrtC where lambda_(m)^( C)=molar specific conductance lambda_(m)^(oo)=molar specific conductance at infinite dilution C=molar concentration {:("Molar Concentration of NaCl","Molar Conductance" "In" "ohm"^(-1)cm^(2)"mole"^(-1)),(4xx10^(-4),107),(9xx10^(-4),97),(16xx10^(-4),87):} When a certain conductivity cell (C) was filled with 25xx10^(-4)(M) NaCl solution.The resistance of the cell was found to be 1000 ohm.At Infinite dilution, conductance of Cl^(-) and SO_4^(-2) are 80 ohm^(-1) cm^(2) "mole"^(-1) and 160 ohm^(-1) cm^2 "mole"^(-1) respectively. If the cell ( C) is filled with 5xx10^(-3)(N)Na_(2)SO_(4) the obserbed resistance was 400 ohm.What is the molar conductance of Na_(2)SO_(4). |
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Answer» `19.25 "OHM"^(-1)cm^2"mole"^(-1)` `lambda=((1000xx0.1925)/(5XX10^(-)3))/2xx400=192.5` |
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| 28764. |
The main product of following reaction will be: |
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| 28765. |
The molar concentration of HCl (aq.) is 10^(-5)M. Which of the following statement are correct (d_("solution") = 1 gm/cc) |
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Answer» The MOLE fraction of `HCl ~= 1.8 xx 10^(-7)` |
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| 28766. |
The main product of the following reaction is |
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Answer» `C_6H_5-overset(OH)overset(|)CH-overset(NHCH_(3))overset(|)CH_2` |
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| 28767. |
The molar conductance at infinite dilution of AgNO_(3), NaCland NaNO_(3)are 116.5, 110.3 and 105.2 ohm^(-1)cm^(2)"mole"^(-1) respectively. The molar conductance of at infinite dilution is |
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Answer» 111.4 |
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| 28768. |
The main product of reduction of nitrobenzene with lithium aluminium hydride is |
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Answer» Azoxybenzene
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| 28769. |
The molality of a urea solution in which 0.0100 g of urea, [(NH_(2))_(2)CO] is added to 0.3000 dm^(3) of water at STP is : |
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Answer» `5.55xx10^(-4)m` VOLUME of water `=0.3xx1000=300` mL Mass of water `=300xx1=300g` Moles of urea `=(0.01)/(60)` MOLALITY `=(0.01xx1000)/(60xx300)=5.55xx10^(-4)`m |
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| 28770. |
The main product of bromination of acetanilide in glacial acetic acid is |
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Answer» o-bromoaniline |
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| 28771. |
The molality of a sulphuric acis solution in which the mole fraction of water is 0.86 is |
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Answer» Solution :Mole FRACTION of `H_(2)SO_(4)` in the solution `=1-0.86=0.14` `(n_(2))/(n_(1)+n_(2))=0.14` MOLALITY is `n_(2)` in 1000 g of water, i.e., in `n_(1)` `=1000//18=55.55` moles `THEREFORE (n_(2))/(55.55+n_(2))=0.14"or"n_(2)=0.14n_(2)+7.777` `"or"0.86n_(2)=7.777 or n_(2)=9.0` |
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| 28772. |
The molality of a sulphuric acid solution is 0.6 'mol//kg'. The total weight of the solution which contains 1 kg of solvent. |
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Answer» 1000 g |
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| 28773. |
The main product obtained when a solution of sodium carbonate reacts with mercuric chloride is |
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Answer» `Hg(OH)_(2)` `HgCl_(2)+Na_(2)CO_(3)toHgO+2NaCl+CO_(2)` |
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| 28774. |
The molality of a 1 molarsolution will be (Given, density of solvent = 1.5 kg .dm^(-3) |
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Answer» 1.5 |
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| 28775. |
The molality of a sulphuric acid aqueous solution in which the mole fraction of water is 0.85 is |
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Answer» 9.8 `(n_(H_(2)SO_(4)))/(n_(H_(2)O)) = (0.15)/(0.85 XX 18)` Molality `= (0.15 xx 1000)/(0.85 xx 18) = 9.8 M` |
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| 28776. |
The molality of a solution containing 0.1 mol of a substance in 100g of water is : |
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Answer» 0.5 m |
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| 28777. |
The main product obtained by the electrolysis of the aqueous ethanolic solution of potassium bromide and sodium carbonate, is |
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Answer» ETHYL bromide |
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| 28779. |
The main product in the reactionHCONHRoverset (POCl_3) underset ("pyridine") rarr? |
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Answer» RCN |
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| 28780. |
The molality of 3M solution os mehtanol if thedensity of the solution is 0.9g cm^(-3), is |
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Answer» 3.73 `"Mass of the solution "=vxxd ` `= (1000CM(3)) xx (0.9 g cm^(3))=900 g` `"Mass of methanol"(CH_(3)OH)=(3 molxx32 "g mol"^(-1))=96 g` `"Mass of solvent" =(900-96g)=804 g=0.804 KG ` `"Molality of solution"=("No. of moles of methanol")/("Mass of solvent in kg")` `(3mol)/(0.804kg)=0.373"mol kg"^(-1)` =.373 MOLAL |
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| 28781. |
The main product in the dehydration of : (CH_(3))_(3) C underset(OH)underset(|)(CH)CH_(2)CH_(3) in the presence of conc. H_(2)SO_(4) at 170^(@)C is : |
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Answer» `(CH_(3))_(3) C CH = CHCH_(3)` `CH_(3) - underset(CH_(3))underset(|)OVERSET(CH_(3))overset(|)(C) - underset(oplus)(CH) - CH_(2) - CH_(3) overset("Rearrangement")harr CH_(3) - underset(oplus)overset(CH_(3))overset(|)(C) - underset(CH_(3))underset(|)(CH) - CH_(2) - CH_(3)` This carbonium ion loses `H^(+)` to form `(CH_(3))_(2) C = underset(CH_(3))underset(|)(C) - CH_(2) - CH_(3)` as the MAIN product. |
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| 28782. |
The molal freezing point depression constant of benzene (C_(6)H_(6)) is "4.90 K kg mol"^(-1). Selenium exists as a polymer of the type Se_(x). When 3.26 g of selenium is dissolved in226 g of benzene the obsereved freezing point is 0.112^(@)C lower than for pure benzene. Deduce the molecular formula of selenium ("At. mass of Se =78.8 g mol"^(-1)). |
| Answer» SOLUTION :`Se_(8)` | |
| 28783. |
The main product in the following reaction is C_(6)H_(5)NH_(2) underset(H^(+))overset(Na_(2)Cr_(2)O_(7))(rarr) ? |
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Answer» `C_(6)H_(5)CHO`
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| 28784. |
The molal freezing point constant of water is 1.86^(@)C//M. Therefore the freezing point of 0.1 M NaCl solution in water is expected to be |
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Answer» `-1.86^(@)C` `DeltaT_(f)=iK_(f)m=2xx1.86xx0.1=0.372^(@)C`, `T_(f)=-0.372^(@)C`. |
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| 28785. |
The main product in the reaction of : CH_(3) - CH_(2) - underset(C1)underset(|)(CH) - CH_(3) + underset((alc.))(KOH) is : |
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Answer» `CH_(3) - CH = CH - CH_(3)` |
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| 28786. |
The molal freezing point constant of water is 1.86C/M. Therefore the freezing point of 0.1 M NaCl solution in water is expected to be |
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Answer» `-1.86^@C` |
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| 28787. |
The main process for the manufacture of sodium carbonate is : |
| Answer» Answer :A | |
| 28788. |
The molal freezing point constant for water is 1.86^(@)C//m. Therefore, the freezing point of 0.1 M NaCl solution in water is expected to be |
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Answer» `-272.628K` |
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| 28789. |
The main problem encountered during electrophilic subsitution reactions of aromatic amines is that they have __________. |
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Answer» |
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| 28790. |
The molal freezing point constant for water is 1.86^(@)C//m. Therefore, the freezing point of 0.1 M NaCl solution in water is expected to be: |
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Answer» `-1.86^(@)C` |
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| 28791. |
The molal freezing point constant for water is 1.86 K . Kg "mole"^(-1). The freezing point of 0.1 m NaCl solution is |
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Answer» `-1.86^(@)C` |
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| 28792. |
The main point of difference between buna-N and buna-S is |
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Answer» the formeris homopolymerwhereas the later is copolymer |
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| 28793. |
The main point of difference between DNA and RNA is : |
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Answer» PRESENCE of THYMINE in DNA and RNA |
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| 28794. |
The main oxides formed on combustion of Li,Na and K in excess of air respectively are |
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Answer» `Li_(2)O, Na_(2)O_(2) and KO_(2)` |
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| 28795. |
The main ore of zinc is: |
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Answer» ZINC blende |
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| 28796. |
The main group elements i.e. representative elements complete their electron configuration using s and p electrons in the periodic table. These elements range from the most metallic to the most non-metallic with intermediate properties, the semi-metals, in between .The elements which occur at the two extremes of the periodic table are highly reactive and therefore, these highly reactive elements do not occur in free state : they usually occur in the combined forms. Beryllium and aluminium exhibit many properties which are similar, but, the two elements differ in : |
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Answer» FORMING covalent HALIDES |
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| 28798. |
The main ore of iron is: |
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Answer» Chloride |
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| 28799. |
The main group elements i.e. representative elements complete their electron configuration using s and p electrons in the periodic table. These elements range from the most metallic to the most non-metallic with intermediate properties, the semi-metals, in between .The elements which occur at the two extremes of the periodic table are highly reactive and therefore, these highly reactive elements do not occur in free state : they usually occur in the combined forms. Select the correct statement (this is with respect to the elements of main group). |
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Answer» Chemical reactivity of the elements is generally lowest in the centre of a period (B)Generally the elements found in the centre of period for main group elements are metalloids.They generally FORM amphoteric oxides. (C )Down the group size of ATOM increases and ELECTROPOSITIVE character increase.So metallic character increases. ACROSS the period , size of atom decreases and electropositive character decreases.So metallic character decreases and non-metallic character increases. |
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| 28800. |
The main function of the salt bridge is: |
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Answer» To allow IONS to GO from ONE cell to another |
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