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1.

The equation of a sound wave is `y=0.0015sin(62.4x+316t)` the wavelength of this wave isA. 0.2 unitB. 0.1 unitC. 0.3 unitD. None of these

Answer» Correct Answer - B
General equation of plane prograssive wale is given by
`y=a sin (kx+omegat)" "…(i)`
Given equation
`y=0.0015sin (62.4x+316t)" "…(ii)`
Comparing Eqs. (i) and (ii), we get
`k=62.4`
`therefore (2pi)/(lamda)=62.4`
`lamda=(2pi)/(62.4)=0.1` unit
2.

If the temperature increases, then what happens to the frequency of the sound produced by the organ pipe ?A. unchangedB. decreasesC. increasesD. not definite

Answer» Correct Answer - C
Due to rise in temperature, the speed of sound increases. Since frequency `n=v/lamda and lamda` remains unchanged. Hence frequency n increases.
3.

In a resonance tube the first resonance with a tuning fork occurs at 16 cm and second at 49 cm . If the velocity of sound is 330 m/s , the frequency of tuning fork isA. 500B. 300C. 330D. 165

Answer» Correct Answer - A
For closed pipe `l_(1)=(v)/(4n)and l_(2)=(3v)/(4n)`
`v=2n(l_(2)-l_(1))`
`n=(n)/(2(l_(2)-l_(1)))=(330)/(2xx(0.49-0.16))=500Hz`
4.

The differential equation whose solution is `(x-h)^2+ (y-k)^2=a^2` is (a is a constant)A. `[1+((dy)/(dx))^(2)]^(3)=a^(2)(d^(2)y)/(dx^(2))`B. `[1+((dy)/(dx))^(2)]^(3)=a^(2)((d^(2)y)/(dx^(2)))^(2)`C. `[1+((dy)/(dx))]^(3)=a^(2)((d^(2)y)/(dx^(2)))^(2)`D. None of the above

Answer» Correct Answer - B
Given, `(x-h)^(2)+(y-k)^(2)=a^(2)" (i)"`
`implies2(x-h)+2(y-k)(dy)/(dx)=0`
`implies(x-h)+(y-k)(dy)/(dx)=0" "...(ii)`
Again differentiating
`(y-k)=-(1+((dy)/(dx))^(2))/(d^(2)y//dx^(2))`
Putting in Eq. (ii), we get
`x-h =-(y-k)(dy)/(dx)=([1+((dy)/(dx))^(2)](dy)/(dx))/((d^(2)y)/(dx^(2)))`
Putting in Eq. (i), we get
`([1+((dy)/(dx))^(2)]^(2)((dy)/(dx))^(2))/(((d^(2)y)/(dx^(2)))^(2))+([1+((dy)/(dx))^(2)]^(2))/(((d^(2)y)/(dx^(2)))^(2))=a^(2)`
`implies[1+((dy)/(dx))^(2)]^(2)[((dy)/(dx))^(2)+1]=a^(2)((d^(2)y)/(dx^(2)))^(2)`
`implies[1+((dy)/(dx))^(2)]^(3)=a^(2)((d^(2)y)/(dx^(2)))^(2)`
5.

Find the differential equation of all the circleswhich pass through the origin and whose centres lie on y-axis.A. `(x^(2)-y^(2))(dy)/(dx)-2xy=0`B. `(x^(2)-y^(2))(dy)/(dx)+2xy=0`C. `(x^(2)-y^(2))(dy)/(dx)-xy=0`D. `(x^(2)-y^(2))(dy)/(dx)+xy=0`

Answer» Correct Answer - A
Equation of a circle is
`x^(2)+(y-a)^(2)=a^(2)" "...(i)`
`2x+2y(dy)/(dx)-2a(dy)/(dx)=0" "...(ii)`
From Eqs. (i) and (ii)
`(dy)/(dx)=(2xy)/(x^(2)-y^(2))`
`implies(x^(2)-y^(2))(dy)/(dx)-2xy=0`
6.

From point `P(8,27)` tangents PQ and PR are drawn to the ellipse `(x^(2))/(4)+(y^(2))/(9)=1.` Then, angle subtended by QR at origin isA. `tan ^(-1)""(2sqrt6)/(65)`B. `tan ^(-1)""(4sqrt6)/(65)`C. `tan^(-1)""(8sqrt2)/(65)`D. None of these

Answer» Correct Answer - D
Equation of chord of contact QR is
`8*x/4+27*y/9=1`
`implies2x+3y=1" "...(i)`
Now, equation of the pari of lines passing through origin and points Q, R given by
`((x^(2))/(4)+(y^(2))/(9))=(2x+3y)^(2)`
`implies9x^(2)+4y^(2)=36(4x^(2)+12xy+9y^(2))`
`implies135x^(2)+432xy+320y^(2)=0`
`therefore` Required angle is
`=tan ^(-1)""(2sqrt((216)^(2)-135*320))/(455)`
`=tan ^(-1)""(8sqrt(2916-2700))/(455)`
`=tan ^(-1)""(8sqrt216)/(455)`
`=tan ^(-1)""(48sqrt6)/(455)`
7.

In the following sequence of reactions `CH-underset(NH_(2))underset(|)(CH)-CH_(3)overset(HNO_(3))toAoverset("Oxidation")toBunderset((ii)H^(+)//H_(2)O)overset((i)CH_(3)MgI)toC` The compound C formed will beA. butanol-1B. butanol-2C. 2-methyl propanol-1D. 1, 1-dimethyletanol

Answer» Correct Answer - D
`Ch_(3)-underset(NH_(2))underset(|)CH-CH_(3)overset(HNO_(2))toCH_(3)-underset((A))underset(OH)underset(|)CH-CH_(3)`
`overset([o])toCH_(3)-underset((B))underset(O)underset(||)C-Ch_(3)underset((ii)H^(+)//H_(2)O)overset((i)CH_(3)Mgl)tounderset("1,1-dimethylethanol")((CH_(3))_(3)COH)`
8.

The equation of the common tangents to the circle`(x-3)^(2)+y^(2)=9` and the parabola `y^(2)=4ax` the x-axis, isA. `sqrt2y=3x+1`B. `sqrt3y=-(x+3)`C. `sqrt3y=x+3`D. `sqrt3y=-(3x+1)`

Answer» Correct Answer - C
Let the common tangent to the parabola
`y^(2)=4xbe,`
`y=mx+1/m`
It should be also touch the circle
`(x-3)^(2)+y^(2)=9`
Whose centre is (3,0) and radius =3, then
`(|em+1//m|)/(sqrt(1+m^(2)))=3`
`implies3m^(2)=1`
`impliesm=pm(1)/(sqrt3)`
But `m gt 0,` then equatio of common tangent is
`y=(1)/(sqrt3)*x+sqrt3`
`or sqrt3*y=x+3`
9.

The most common oxidation states of cerium areA. `+2,+4`B. `+3,+4`C. `+3,+5`D. `+2,+3`

Answer» Correct Answer - B
The electronic condiguratin of Ce is as
`Ce: [Xe]4f^(2)5d^(0)6s^(2)`
The most common oxidation states shown by cerium are +3 and +4.
10.

In a sim,le slit differection pattern intensisty and width of fringes areA. unequal widthB. equal widthC. equal width and equal intensityD. unequal width and unequal intensity

Answer» Correct Answer - D
In single slit diffraction pattern intensity and width of fringes are unequal width and unequal intensity.
11.

A plane wave front of wavelength `lamda` is incident on a single slite of width b. What is the angular width for secondary maximum ?A. `(lamda)/(db)`B. `lamda/b`C. `(2lamda)/(b)`D. `(b)/(lamda)`

Answer» Correct Answer - B
`beta=(lamdaD)/(d)and theta=(beta)/(D)`
`therefore theta=(lamda)/(d)`
Width of single slit = b
SO, `theta=(lamda)/(b)`
12.

If the body is moving in a circle of radius r with a constant speed v , its angular velocity isA. `v^(2)//r`B. `vr`C. `v//r`D. r/v

Answer» Correct Answer - C
Linear velocity `v=r omega`
`omega=v/r`
13.

A ball of mass 0.25 kg attached to the end of a string of length 1.96 m is moving in a horizontal circle. The string will break if the tension is more than 25 N . What is the maximum speed with which the ball can be movedA. 14 m/sB. 3 m/sC. 3.92 m/sD. 5 m/s

Answer» Correct Answer - A
Tension of string `T=(mv^(2))/(r) `
`25=(0.25xxv^(2))/(1.96)`
`v=14m//s`
14.

An acid solution of `pH=6` is diluted `1000` times, the `pH` of the final solution isA. `6.01`B. 9C. `3.5`D. `6.99`

Answer» Correct Answer - D
`because pH=6`
`therefore[H^(+)]=10^(-6)M`
After dilution `[H^(+)]=(10^(-6))/(1000)=10^(-9)M`
`therefore [H^(+)]`from `H_(2)O` cannot be neglected.
Total `[H^(+)]=10^(-9)+10^(-7)`
`=10^(-7)(10^(-2)+1)`
`=10^(-7)(1.01)`
`pH=-log (1.01xx10^(-7))`
`=7-0.0043=6.9957`
15.

The solubility product of `Ag CrO_(4)` is `32xx10^(-12).` What is the concentration of `CrO_(4)^(2-)` ions in that solution ?A. `2xx10^(-4)`B. `16xx10^(-4)`C. `8xx10^(-4)`D. `12xx10^(-4)`

Answer» Correct Answer - A
`Ag_(2)CrO_(4)tounderset(2s)2Ag^(+)+underset(s)(CrO_(4)^(2-))`
`K_(sp)=[Ag^(+)]^(2)[CrO_(4)^(2-)]`
`=(2s)^(2)(s)`
`K_(sp)=4s^(3)`
`s=((K_(sp))/(4))^(1//3)`
`=((32xx10^(-12))/(4))^(1//3)=2xx10^(-4)M`
16.

Which of the following salts will not undeergo hydrolysis ?A. `NH_(4)Cl`B. `KCN`C. `KNO_(3)`D. `Na_(2)CO_(3)`

Answer» Correct Answer - C
Potassium nitrate `(KNO_(3))` is a salt of strong base and strong acid and hence, will not undergo hydrolysis.
17.

An aqueous solution of urea containing 18 g urea in 2500 `cm^(3)` of the solution has a density equal to 1.052. if the molecular weight of urea is 60, the molality of the solution isA. `0.200`B. `0.192`C. `0.100`D. `1.200`

Answer» Correct Answer - B
1500 cc. solution `=1500xx1.052g =1578g`
Weight of solvent `=1560g`
Weight of solute =18 g
Molality `=("weight of solute")/("molecular weight of solute"xx)`
weight of solvent in kg
`=(18xx1000)/(60xx1560)=0.192` m
18.

S34.2 g of cane sugar is dissolved in 180 g of water. The relative lowering of vapour pressure will beA. `0.0099`B. `1.1597`C. `0.840`D. `0.9901`

Answer» Correct Answer - A
`(P^(@)-Ps)/(P^(@))=((w_(2))/(m_(2)))/((w_(1))/(m_(1))+(w_(2))/(M_(2)))`
`=((34.2)/(342))/((34.2)/(342)+(180)/(18))`
19.

What volume of `2MH_(2)SO_(4)` is required to from 0.2 N of 100 mL of solution ?A. 5 mLB. 20 mLC. 10 mLD. 50 mL

Answer» Correct Answer - A
`because M-H_(2)SO_(4)=2N-H_(2)SO_(4)`
`because2M-H_(2)SO_(4)=4N-H_(2)SO_(4)`
`N_(1)V_(1)=N_(2)V_(2)`
`4xxV_(1)=0.2xx100`
`V_(1)=(0.2xx100)/(4)=5mL.`
20.

Bactericidal antibiotic anoung the following is :A. ofloxachinB. chloroamphenicolC. erythromycinD. tetracycline

Answer» Correct Answer - A
Bactericidal antibiotic kills the organism in the body. e.g., penicillin, ofloxacin etc.
21.

If X follows the binomial distribution with parameters n=6 and p and 9p(X=4)=P(X=2), then p isA. `1//4`B. `1//3`C. `1//2`D. `2//3`

Answer» Correct Answer - A
Given, `9P(X=4)=P(X=2)`
`therefore9*""^(6)C_(4)p^(4)(1-p)^(2)=""^(6)C_(2)p^(2)(1-p)^(4)`
`implies((1-p)^(2))/(p^(2))=9`
`implies(1-q)/(p)=3`
`impliesp=1//4`
22.

Unit of decay constant of radiocative disintegration isA. timeB. `min^(-2)`C. `time^(-1)`D. time `mol^(-1)`

Answer» Correct Answer - C
For a radioactive disintegration,
`k=(2.303)/(t)log ""(N_(0))/(N)`
where, k is know as decay constant or disintegration constant.
The unit for decay constant is `"time"^(-1).`
23.

In the production of beats by two waves of same amplitude and nearly same frequency, the maximum intensity to each of the constituent waves isA. sameB. 2 timesC. 4 timesD. 8 times

Answer» Correct Answer - C
Beats formation in a case of superposition for which the maximum intensity is 4 time the intensity of either source.
24.

A glass slab of thickness `4 cm` contains the same number of waves as `5 cm` of water, when both are traversed by the same monochromatic light. If the refractive index of water is `4//3,` then refractive index of glass isA. `5//3`B. `5//4`C. `16//15`D. `3//2`

Answer» Correct Answer - A
`""_(a)n_(g)=""_(a)n_(w)xx""_(a)n_(g)`
`""_(a)n_(g)=4/3xx(lamda_(w))/(lamda_(g))`
`""_(a)n_(g)=4/3xx5/4`
`""_(a)n_(g)=5/3`
25.

3-methylpentan-3-ol will be prepared fromA. ethyl formate and methyl magnesium bromideB. ethyl ethanoate and ethyl magnesium bromideC. ethyl propanoate and methyl magnesium bromideD. ethyl formate and ethyl magnesium bromide

Answer» Correct Answer - B
`{:(CH_(3)-C=O+ C_(2)H_(5)MgBrto),(" "| " ""ethyl magnesium"),(" "OC_(2)H_(5) " ""bromide"),(" ""ethyl ethanoate"):}`
`{:(" "CH_(2)H_(5) " "CH_(2)CH_(3)),(" "|" "|),(CH_(3)-C-OHgBrunderset(-Mg(OC_(2)H_(5))Br)toCH_(3)C=O),(" "|),(" "OC_(2)H_(5)):}`
`{:(" "CH_(2)CH_(3)),(" "|),(overset(C_(2)H_(5)MgBr)toCH-C-OHgBr),(" "|),(" "CH_(2)-CH_(3)):}`
`{:(" "CH_(2)CH_(3)),(" "|),(overset(H.OH)toCH_(3)-C-OH),(" "|),(" "CH_(2)CH_(3)),(" ""3-methylpentan-3-ol"):}`
26.

`int_(pi//2)^(pi//2)(cosx)/(1+e^(x))dx` is equal toA. 1B. 0C. -1D. None of these

Answer» Correct Answer - A
`I-int _(-pi)^(pi//2)(cos x)/(1+e^(x))dx" (i)"`
`I=int _(-pi)^(pi//2)(cos (pi//2-pi //2-x))/(1+e^((x//2-pi//2-x)))dx`
`=int _(-pi)^(pi//2)(cos (-x))/(1+e^(-x))dx`
`=int _(-pi)^(pi//2)^(e^(x)cos x)/(1+e^(x))dx`
`=int _(-pi)^(pi//2)(e^(x)cos x)/(1+e^(x))dx" "(ii)`
On adding Eqs. (i) and (ii), we get
`2I=int_(-pi//2)^(pi//2)((1+e^(x))cos )/((1+e^(x)))dx`
`int _(-pi//2)^(pi//2)cos x dx`
`=2int _(0)^(pi//2)cos x dx`
[Since, cos x is an even function.]
`therefore 2I=2[sin x]_(0)^(pi//2)=2(1-0)=2`
`impliesI=1`
27.

A particle moves along a straight line according to the law `s=16-2t+3t^(3)`, where `s` metres is the distance of the particle from a fixed point at the end of `t` second. The acceleration of the particle at the end of `2s` isA. `3.6m//s^(2)`B. `36m//s^(2)`C. `36km//s^(2)`D. `360 m//s^(2)`

Answer» Correct Answer - B
Given, `s=16-2t+3t^(3)`
`implies(ds)/(dt)=-2 +9t^(2)`
`implies(d^(2)S)/(dt^(2))=18t`
Now, the acceleratio of the particle at the end of `t=2` s is
`f=(d^(2)s)/(dt^(2))=18xx2=36m//s^(2)`
28.

If `x+y=k`is normal to `y^2=12 x ,`then `k`is3 (b) 9(c) `-9`(d) `-3`A. 3B. 9C. -9D. -3

Answer» Correct Answer - B
Let `x+y=k` be normal to
`y^(2)=12xx at p(alpha,beta)" "...(i)`
`thereforebeta^(2)=12 alpha" "...(ii)`
Also, slope of normal at `P(alpha, beta)` is -1 From, Eq. (i),
`(dy)/(dx)=6/y`
`implies((dy)/(dx))_(p)=(6)/(beta)`
`therefore -1 =(-1)/(6//beta)`
`impliesbeta=6,alpha =3`
`thereforeP` is (3,6) which lies on `x+y=k`
`therefore 3+6=k`
`impliesk=9`
29.

`int[sqrt(cotx)+sqrt(tan x)]dx` ज्ञात कीजिए!A. `sqrt2tan^(-1)((tanx)/(sqrt(2 tan x)))+C`B. `sqrt2tan^(-1)((tanx-1)/(sqrt(2 tan x)))+C`C. `(tanx)/(sqrt2)*tan^(-1)((cot x+1)/(sqrt(2 tanx)))+C`D. `(tanx)/(sqrt2)*tan^(-1)((cotx+1)/(sqrt(tanx)))+C`

Answer» Correct Answer - B
Let `I=int((sin x+cosx))/(sqrtsinx*cos x)dx`
`=int(sqrt2(sinx+cos x))/(sqrt(2sin x*cos x))dx`
`=sqrt2 int(sin x+cos x)/(sqrtsin 2x)dx`
Put `sinx -cos x=t`
`implies(cos x+sin x)dx=dt`
Also, `sin 2x=(1-t^(2))`
`thereforeI=sqrt2int(dt)/(sqrt(1-t^(2)))`
`=sqrt2sin ^(-1)t+c`
`=sqrt2sin ^(-1)(sinx-cos x)+c`
`=sqrt2 tan ^(-1)((tan x-1)/(sqrt(2 tan x)))+c`
30.

x,के सभी वास्तविक मानों के लिए `(1-x+x^2)/(1+x+x^2)` का न्यूनतम मान है :

Answer» Correct Answer - B
Let `y=(1-x+x^(2))/(1+x+x^(2))=1-(2x)/(1+x+x^(2))`
`=1-(2)/((1)/(x)+1+x)`
`impliesy=1-2/t`
where `t=1/x+1+x`
Now, y is minimum, where `2/t` is max `implies` is min.
`therefore (dt)/(dx)=-(1)/(x^(2))+1=0`
`impliesx=pm1`
`(d^(2)t)/dx^(2)=(2)/(x^(2))gt0,` for `x=1`
`therefore` Minimum value of y is
`1-(2)/(1+1+1)=1-2/3=1/3`
31.

`int(x^(2))/((x sinx+cosx)^(2))dx` is equal toA. `(sin x+cos x)/(xsin x+cos x)+C`B. `(x sin x-cos x)/(x sin x+cos x)+C`C. `(sin x-x cos x)/(x sin x+cos c)+C`D. None of these

Answer» Correct Answer - C
Since, `(d)/(dx)(x sin x+cos x)=x cos x`
`therefore I =int (x^(2)dx)/((xsin x+cos x)^(2))`
`=int (x)/(cos x).(x cos x)/(cos x(x sin x+cos x)^(2))dx`
`=(x)/(cos x)((-1)/(x sin x+cos x))`
`-int(cos x-x(-sin x))/(cos ^(2)x)*(-1)/((x sin x+cos x))dx`
`=(-x)/(cos x(x sin x+cos x))+int sec^(2)dx`
`=(-x)/(cos x(xsin x+cos x))+tan x+C`
`=(-x+sin x(x sin x+cos x))/(cos x(x sin x+c os x))+C`
`=(-xcos ^(2)x+sin x*c os x)/(cos x(x sin x+cos x))+C`
`=((sin x-xcos x)/(cos x+xsin x))+C`
32.

`y=logtan(x/2)+sin^(-1)(cosx)`, then `dy/dx` isA. `cosec x-1`B. `cosec x`C. `cosec x+1`D. x

Answer» Correct Answer - A
`(dy)/(dx)=(1)/(tan x//2)sec ^(2)""(x)/(2)*(1)/(2)+ (1)/(sqrt(1 - cos^(2) x))"(-sin x)"`
`(1)/(2sin ""(x)/(2)*cos ""(x)/(2))1=cosecx-1`
33.

If ` x = 2 cos t - cos 2t , y = 2 sin t - sin 2t`, then the value of ` |(d^(2) y)/(dx^(2))|_(t= pi//2 ) `isA. `3//2`B. `5//2`C. `5//2`D. `-3//2`

Answer» Correct Answer - D
`(dx)/(dt)=2cost-2 cos 2t`
`therefore (dy)/(dx)=(2 cos t-2 cos 2t)/(-2 sin t+2sin 2t)`
`=(cos -cos 2t)/(-2sin 2t-sin t)`
`=(cos t-cos 2t)/(sin 2t-sin t)`
`implies(2 sin""(3t)/(2)*sin""(t)/(2))/(2cos ""(3t)/(2)*sin ""(t)/(2))`
`=tan ""(3t)/(2)`
`(d^(2)y)/(dx^(2))=sec ^(2)""(3t)/(2)*3/2*(dt)/(dx)`
`=3/2sec^(2)""(3t)/(2)(1)/((2 sin 2t-2sin t))`
`implies(d^(2)y)/(dx^(2))|_(t=pi//2)=-3//2`
34.

If `x^(p) y^(q) = (x + y)^((p + q)) " then " (dy)/(dx)=` ?A. `y//x`B. `py//qx`C. `x//y`D. `qy//px`

Answer» Correct Answer - A
Given, `x^(p)y^(q)=(x+y)^(p+q)`
Thinking log on both sides, we get
`p log x+q log y=(p+q)log (x+y)`
`implies(p)/(x)+(q)/(y)(dy)/(dx)=((p+q))/((x+y))(1+(dy)/(dx))`
`implies((p)/(x)-(p+q)/(x+y))=((p+q)/(x+y)-(q)/(y))(dy)/(dx)`
`implies(dy)/(dx)=y/x`
35.

If a, b, c and d are positive then `lim_(x to oo)(1+(1)/(a+bx))^(x+dx)` is eqqualA. `e^(d//b)`B. `e^(c//a)`C. `e^((c+d)//(a+b))`D. e

Answer» Correct Answer - A
`L=underset(xtooo)lim(1+(1)/(a+bx))^(c+dx)" "["from"(1)^(oo)]`
`=e^(underset(x tooo)lim(c+dx)/(a+bx))=e^(underset(x tooo)lim(c//x+d)/(a//x+b))`
`=e^((0+d)/(0+d))=e^(d//b)`
36.

Let ` f(x) = {{:({1+|sin x|}^(a//|sin x|)", " pi/6 lt x lt 0),(" b, " x = 0 ),(e^(tan 2x//tan 3x) ", "0ltx ltpi/6):}` Determine a and b such that f(x) is continous at x = 0.A. `3//2,^(3//2)`B. `-2//3,e^(-3//2)`C. `2//3,e^(2//3)`D. None of these

Answer» Correct Answer - C
We have, `underset(x to 0^(-))limf(x)`
`=underset(c to 0)lim{1+|sinx|}^((a)/(|sin x|))`
`=e^(underset(x to 0)lim|sinx|.(a)/(|sin x|))=e^(a)`
and `underset(xto0^(-))limf(x)=underset(xto0)lime^((tan 2x)/(tan3x))`
`e^(underset(xto0)lim(tan 2x)/(2x)(3x)/(tan3x)xx2/3)`
`e^(2//3)`
For f (x) to be continous at x=0, we must have
`underset(x to 0^(-))limf(x)=underset(xto0^(+))limf(x)`
`=f(0)`
`impliese^(a)=e^(2//3)=b`
`implies a=2//3`
and ` b=e^(2//3)`
37.

A gas is compressed at constant temperature. Its molecules gainA. speedB. kinetic energyC. internal energyD. None of these

Answer» Correct Answer - D
38.

Ziegler-Natta cattalyst catalyse preparation of which of the following compounds ?A. preparation of Ti-metalB. Preparation of low density plasticC. Preparation of high resistance plasticD. Preparation of high density plastic

Answer» Correct Answer - D
High density polythene (or plastic) is prepared by heating ethylene at about 330-250 K, under a pressure of 1-2 atm and in the presence of Ziegler-Natta catalyst.
`nCH_(2)=CH_(2)underset("Ziegler-Natta catalyst")overset(330-350 K, 1-2 atm)to(CH_(2)-CH_(2))n` high density polythen
39.

The value of `(1+Delta)(1-Delta)` is

Answer» Correct Answer - C
We have, `(1+Delta)(1-grad)f(x)`
`=(1+Delta){(1-grad)f(x)}`
`=(1+Delta)[f(x)-{f(x)-f(x-h))]`
`=(1+Delta)f(x-h)=Ef(x-h)`
`[because (E=1+Delta)]`
`=f(x)=1*f(x)`
Thus, `(1+Delta ) (1-grad)f(x)=1*f(x),` for any function `f (x).
`therefore (1+Delta)(1+grad)=1`
40.

When Zn is treated with excess of NaOH, the product obtained isA. `Zn(OH)_(2)`B. ZnOHC. `Na_(2)ZnO_(2)`D. None of the above

Answer» Correct Answer - C
When Zn is reacted with excess of NaOH, sodium zincate is obtained.
`Zn+2NaOH+2H_(2)Oto Na_(2)underset("soluble")([Zn(OH)_(4)])+H_(2)`
or `An+2NaOHto Na_(2)ZnO_(2)+H_(2)`
41.

The heat of neutralisation of a strong acid and a strong alkali is `57.0kJ mol ^(-1).` The heat released when 0.2 mole of `HNO_(3)` soluton is mixed with 0.2 mole of KHO isA. `57.0` kJB. `11.4` kJC. `28.5` kJD. `34.9` kJ

Answer» Correct Answer - C
`because0.2` mole will neutralised `0.2` mole of `HNO_(3).`
`therefore` Heat evoled `=57xx0.2=11.4kJ`
42.

The standard reduction potential for `Fe^(2+) //Fe` and `Sn^(2+) //Sn` electrodes are `-0.44` and `-0.14 ` volt respectively. For the given cell reaction `Fe^(2+) + Sn rarr Fe + Sn^(2+) `, the standard ` EMF` is.A. `+0.30V`B. `-0.58 V`C. `+0.58V`D. `-0.30V`

Answer» Correct Answer - D
`Fe^(2+)+SntoFe+Sn^(2+)`
`E^(@)=E_(red)^(@)(Fe) +E_(oxi)^(@)(Sn)`
`=-0.44+(0.14)`
`=-0.30V`
43.

The heat of combustion of carbon is `-393.5kJ//mol.` The heat released upon the formation of 35.2 g of `CO_(2)` from carbon and oxygen gas isA. `+135` kJB. `-31.5` kJC. `-315` kJD. `+31.5` kJ

Answer» Correct Answer - C
`C+O_(2)to CO_(2)`
`DeltaH=-393.5kJ`
`therefore` Heat released upon the formation of 1 g of
`CO_(2)=(-393.5)/(44)kJ`
`therefore` Heat released upon the formation of 1 g of
`CO_(2)=(-393.5)/(44)xx35.2`
`~~-315kJ`
44.

As par Bohr model, the minimum energy (in `eV`) required to remove an electron from the ground state of doubly ionized `Li` atom `(Z = 3)` isA. `1.51`B. `13.6`C. `40.8`D. `122.4`

Answer» Correct Answer - D
`E=-2^(2)xx13.6eV`
`E=-9xx1.6eV`
`E=-122.e eV`
So, inization energy is `+122.4` eV
45.

The multiplicative inverse of `A = [(cos theta,-sin theta),(sin theta,cos theta)]`isA. `[{:(-cos theta, sin theta),(-sin theta, -cos theta):}]`B. `[{:(cos theta, sin theta),(-sin theta, cos theta):}]`C. `[{:(-cos theta, -sin theta),(sin theta, -cos theta):}]`D. `[{:(cos theta, sin theta),(sin theta, -cos theta):}]`

Answer» Correct Answer - B
`|A|=cos ^(2)+sin^(2)theta=1`
`adj(A)=[{:(cos theta,sintheta),(-sin theta, cos theta):}]`
`A^(-1)=(adj(A))/(|A|)=[{:(cos theta, sin theta),(-sin theta, cos theta):}]`
46.

The value of a for which system of equation , `a^3x+(a+1)^3y+(a+2)^3z=0, ax+(a+1)y+(a+2)z=0, x+y+z=0,` has a non-zero solution is:A. 1B. 0C. `-1`D. None of these

Answer» Correct Answer - C
For non-zero solution,
`|{:(a^(3), (a+1)^(3), (a+2)^(3)),(a, (a+1),(a+2)),(1,1,1):}|=0`
`implies-|{:(1,1,1),(a,(a+1),(a+2)),(a^(3),(a+1)^(3),(a+2)^(3)):}|=0`
`-(a-a-1)(a+1-a-2)(a+2-a)xx(a+a+1+a+2)=0`
`implies-2(3a+3)=0`
`impliesa=-1`
`[because|{:(1,1,1),(x,y,z),(x^(3),y^(3), z^(3)):}|=(x-y)(y-z)(z-x)(x+y+z)]`
47.

If one of the lines of the pair `ax^(2)+2hxy+by^(2)=0` bisects the angle between positive direction of the axes, then a, b and h satisfy the relation.A. `a+b=2|h|`B. `a+b=-2h`C. `a-b=2|h|`D. `(a-b)^(2)=4h^(2)`

Answer» Correct Answer - B
y=x, should satisfy `ax^(2)+2hxy+bt^(2)=0`
`impliesa+b=-2h`
48.

Find the angle between the following pair of lines: A lines with direction ratios 2,2,1 A line joning (3,1,4)to (7,2,12)A. `cos ^(-1)(2//3)`B. `cos ^(-1)(3//2)`C. `tan^(-1)(-2//3)`D. None of the above

Answer» Correct Answer - A
Direction ratios of the line joining the point
`(3,1,4) and (7,2,12)` are
`=lt7-3,2-1,12-4gt`
`=lt4,1,8gt`
`=lea_(1),a_(2),a_(3)gt (let)`
Ant the directin ratio of given line is
`=lt2,2,1gt` lt brgt `=ltb_(1),b_(2),b_(3)gt` (let)
Let Q be the and between the lines,
then `cos theta=(a_(1)b_(1)+a_(2)b_(2)+a_(3)b_(3))/(sqrt(a_(1)^(2)+a_(2)^(1)+a_(3)^(2))sqrt(b_(1)^(2)+b_(2)^(2)+b_(3)^(2)))`
`impliescos theta=((4)(2)+(1)(2)+(8)(1))/(sqrt(16+1+64)sqrt(4+4+1))`
`impliescos theta=(18)/(sqrt81sqrt9)=(18)/(9xx3)=2/3`
`impliestheta=cos ^(-1)((2)/(3))`
49.

A black body at a temperature of `227^(@)C` radiates heat energy at the rate of 5 cal/`cm^(2)`-sec. At a temperature of `727^(@)C`, the rate of heat radiated per unit area in cal/`cm^(2)`-sec will beA. 80B. 160C. 250D. 500

Answer» Correct Answer - A
`(E_(2))/(E_(1))=((T_(2))/(T_(1)))^(4)`
`(E_(2))/(E_(1))=((273+727)/(273+227))`
`(E_(2))/(5)=((1000)^(4))/((5000)^(4))=16`
`E_(2)=80cal//cm^(2)`
50.

Which of the following properties does correspond to the order? `HI lt HBr lt HCl lt HF`A. Thermal stabilityB. Reducting powerC. Ionic characterD. Dipole moment

Answer» Correct Answer - B
Reducing power increase in the order as H-X bond length increase from HF to HI.
`HF lt HCl lt HBrlt HI`